Digital Commons Network^™

Nmr Investigations Of Aggregation Of Nonionic Surfactants In A Hydrocarbon Medium, Hugo Christenson, Stig Friberg, David W. Larsen

Chemistry Faculty Research & Creative Works

Proton NMR, carabon-13 NMR, light-scattering, and density measurements were used to investigate association structures and molecular interactions during water solubilization in polyoxymethylene dodecyl ether/benzene systems at high surfactant concentrations. The results indicated an absence of association aggregates at low water concentrations. At water contents between 10 and 20%, association structures started to form, probably micelles of the inverse type, in which the water-polyoxymethylene chain interaction is the predominant feature. There is evidence that the average chain conformation changes with water content, and that bound water molecules are distributed evenly along the polyethoxyethylene chain. At higher water concentration, the results indicated …

Solutions Of Differential Inequalities And Existence Theorems For Multi-Point Boundry Value Problems, Paul W. Eloe

Doctoral Dissertations

"Consider the boundary value problem y = 0, y(a) = 0, y(b) = O. The Green's function G(x,s) for this problem is negative for all (x,s) in (a,b) x (a,b). More generally, define the operator L by (formula presented).

If L is disconjugate on [a,b], then the Green's function for the problem

Ly = 0,

y⁽ⁱ⁾ (x.) = O, j=1, ..., k and i=0, ..., n^j-1

where rn_j = n and a= x₁ < x₂ < ... < x_k = b, satisfies the inequality (formula presented)

This implies G(x,s) satisfies the condition, called Condition S, that its sign is independent …

A Molecular Dynamics Study Of The Stability Of Small Prenucleation Water Clusters, Tze-Shan Chen

Doctoral Dissertations

"The dynamical stability and internal energy distribution of prenucleation water embryos have been studied by the molecular dynamic's method. Water clusters containing either five or twenty molecules were chosen to represent prenucleation embryos of small or intermediate size. A central force potential model of water which allows energy to be absorbed into intramolecular modes so that bond lengths and bond angles could adjust to changes in molecular environments was employed to describe the interaction between all pairs of atoms. The motion of the molecules was followed for extended time periods (of the order of several picoseconds) at each of a …

The Effect Of Availability Improvement Of A Nuclear Power Plant On The Cost Of Generating Electricity, Seyyed Mohammad Reza Nejat

Doctoral Dissertations

"The objective of this investigation is to study the economic benefits in operating a nuclear power plant as a result of improving the availability of the secondary (steam) loop of the plant. A new method has been developed to obtain availability, frequency of failure, probability and frequency of operation, cycle time, and uptime for different capacity states of a parallel-series system having components with failure and repair rates distributed exponentially. The method has been applied to different subsystems, systems, and the secondary loop as a whole. The effect of having spare parts for several components, as measured by savings in …

Amorphous-Damage Depth Distributions And The Amorphization Of Silicon By Ion Bombardment, Joseph Sadowski

Doctoral Dissertations

"Depth distributions of the radiation damage in moderately to heavily ion bombarded silicon was obtained in the following manner: The electron spin resonance signal from an ion bombarded silicon target was measured. This ESR signal was proportional to the amount of amorphous silicon present in the target. A thin oxide of specified thickness was then grown on the surface of the target by anodic oxidation and subsequently stripped off in a HF etch. The depth of the stripped impression below the unoxidized surface was measured using a multibeam interferometer. The amorphous ESR signal was again measured, and the strip / …

Angular Differential Cross Sections For Excitation Of Atomic Hydrogen To Its N=2 Level By Impact Of 15-100 Kev He⁺ Ions, John Eldon Aldag

Doctoral Dissertations

Differential cross sections Ear excitation of atomic hydrogen to its n = 2 level by 15-100 keV He⁺ ions have been determined for cm. angles from Oto 8 m rad. The cross sections were obtained from an analysis of the angular distribution of the scattered ions which had lost an energy corresponding to the excitation of the target to its n= 2 level. The shape of the differential cross section changes rapidly with increasing incident energy. At 15 keV, the cross section falls off by a factor of 5 in 6 m rad. At 100 keV, the cross section …

An Alternate High Pressure Injection System For Pressurized-Water Reactors, Gary Edward Mueller

Doctoral Dissertations

"To evaluate the In-Core Injection System (ICIS) performance during a loss-of-coolant accident (LOCA) due to a major rupture in the primary system of a pressurized water reactor (PWR), tests were conducted using the thermal-hydraulic computer code RELAP4/MOD5.

The results for the overall plant system show that the maximum core average fuel cladding temperature reached during an intermediate size cold-leg break in a Combustion Engineering PWR with ICIS is equal to the initial operating temperature of 335°c (636°F). The maximum core average fuel cladding temperature reached during a large size cold-leg break with ICIS is 478°c (893°F). This temperature is approximately …

A Development Of Regression Models For Predicting Two-Phase Relative Permeability In Consolidated Rock, Mehdi Honarpour

Doctoral Dissertations

"The primary objective of this study was the development of prediction equations for the water-oil imbibition relative permeability and gas-oil drainage relative permeability from experimental data.

Laboratory relative permeability data along with the corresponding rock and fluid properties were collected, and stepwise linear regression analysis was applied. Relative permeability models were developed in terms of rock and fluid properties.

The prediction models were tested against laboratory values and previously published correlations. It was found that the models developed in this study yield results that are generally in better agreement with experimental values than the previously published correlations"--Abstract p. ii

More On Calculators In Beginning Physics Courses, Harry A. Brown

Physics Faculty Research & Creative Works

No abstract provided.

Total Penning Ionization Cross Sections Of Cd And Zn For He(2 ³S1) Atoms, D. W. Fahey, William F. Parks, Laird D. Schearer

Physics Faculty Research & Creative Works

The total Penning ionization cross sections for Cd and Zn for He(2 3S1) atoms have been measured. The method used was that of Penning ion collection from a vapor cell through which a He(2 3S1) beam was passed. The beam energy was 66 meV with a velocity spread of 45%. The measured cross sections were 106(±22) and 35(±7) Å2 for the Cd and Zn targets, respectively. © 1980 American Institute of Physics.

Water And Ice Nucleation Sites From Ion Implantation Of Silicon, William H. Stlnebaugh, Don M. Sparlin, James L. Kassner

Physics Faculty Research & Creative Works

Ion implantation has a substantial effect on the heterogeneous nucleation of water and ice. An enhancement of water nucleation and a suppression of ice nucleation occurred for samples of silicon implanted with ions of various species and dosage. These effects were noticeable only for samples implanted with ion doses approaching or exceeding the critical dose necessary to produce amorphous silicon. The behavior of the water droplet and ice crystal growth can be related to the amount of ion produced damage to the substrate surface. The nature of the damage can be controlled by variation of the incident ion species, dose, …

Injection-Locked Dye Laser Pumped By A Xenon-Lon Laser, E. R. Carney, D. W. Fahey, Laird D. Schearer

Physics Faculty Research & Creative Works

Injection locking of a dye laser is reported for a 4-minor ring-cavity dye User pumped by a xenon-ion laser. Both a He-Ne laser and tunable CW dye laser were used as the injection sources. Copyright © 1980 by The Institute of Electrical and Electronics Engineers, Inc.

Large-Angle Electron-Photon Coincidence Experiment In Atomic Hydrogen, E. Weigold, L. Frost, K. (Kaare) J. Nygaard

Physics Faculty Research & Creative Works

1s-2p excitation in hydrogen has been studied by observing the angular correlation of Lyman photons detected in coincidence with inelastically scattered electrons at 54.4 eV incident energy. The electron scattering angles ranged from 10°to 133°; the results at scattering angles larger than 20°cannot be explained by currently available theories. © 1980 The American Physical Society.

Interframe Television Coding Using Gain And Displacement Compensation, J. A. Stuller, A. N. Netravali, J. D. Robbins

Electrical and Computer Engineering Faculty Research & Creative Works

This Paper Presents Algorithms for Predicting Luminance Changes in Successive Television Frames. the Changes Can Result When Objects in a TV Scene Move or When Illumination Varies. by a Gradient Search Technique, Which Seeks to Minimize a Functional of the Interframe Prediction Error, We Estimate Two Parameters Associated with These Luminance Changes—displacement and Gain. using the Estimates of These Parameters, We Also Develop, for Interframe Coding, Adaptive Predictors and a Segmentor to Determine Which Pels Need to Be Transmitted. We Describe Several Coder Variations and Compare Them by Computer Simulations using Three Substantially Different Scene Sequences. for These Sequences, Gain …

Rubber Covered Rolls-The Nonlinear Elastic Problem, R. C. Batra

Mechanical and Aerospace Engineering Faculty Research & Creative Works

The problem of the indentation of a rubberlike layer bonded to a rigid cylinder and indented by another rigid cylinder is analyzed. The rubberlike layer is assumed to be made of a homogeneous Mooncy-Rivlin material. The materially and geometrically nonlinear problem is solved by using the finite-element code developed by the author. Results computed and presented graphically include the pressure profile at the contact surface, stress distribution at the bond surface and the deformed shape of the indented surface. © 1980 by ASME.

Mti Improvement Factors For Weighted Dfts, Rodger E. Ziemer

Electrical and Computer Engineering Faculty Research & Creative Works

The use of the discrete Fourier transform (DFT) to enhance the detection of moving targets in ground clutter is examined. The improvement factor, defined as the signal-to-clutter ratio at the DFT processor output compared with that of the input, is given as a function of normalized clutter spectral width for various weighting functions on the DFT input. The effect of quantization of the weights on the improvement factor is also examined. Copyright © 1980 by The Institute of Electrical and Electronics Engineers, Inc.

Surface Electromagnetic Wave Field Strength Measurements On Railroad Tracks, Brian C.H. Lai, Brian C.H. Lai, Charles A. Goben

Electrical and Computer Engineering Faculty Research & Creative Works

This paper reports an experimental investigation of surface electromagnetic wave (SEW) energy distribution on railroad tracks. Radial field distribution of SEW on 112-lb/yd rails were examined utilizing a dipole diode detector. Laboratory and on-site measurements were made. The field strength distribution data at frequencies 3.000, 6.000, and 9.733 GHz show that the main part of the SEW TE mode energy (almost 90 percent) is on the head of the rail. Use of dielectric augmentation on the side of rails resulted in lower attenuation of the propagating SEW. Thick dielectric strip augmentation data shows enhancement of SEW propagation in agreement with …

A Survey And Analysis Of Electrical Engineering Curricula In Communications And Signal Processing, Rodger E. Ziemer, William H. Tranter

Electrical and Computer Engineering Faculty Research & Creative Works

No abstract provided.

An Improved Technique For Calibrating And Testing Power System Generator Automatic Synchronizing And Speed Matching Relays, David C. Nagy, Earl F. Richards

Electrical and Computer Engineering Faculty Research & Creative Works

The design of a unique special purpose instrument for calibrating and testing power system automatic synchronizing and speed matching relays is described. The unit is constructed using inexpensive integrated circuit components and provides a direct digital readout of slip frequency from 0.05 Hz to 0.50 Hz resolution and advance angle from 0 to 99.9 degrees with 0.1-degree resolution. This device eliminates the need for expensive test equipment previously required, expedites the test procedure and solves the problem of referencing against a variable bus frequency source. Copyright © 1980 by The Institute Of Electrical and Electronics Engineers, Inc.

Letters. International Engineering Ethics Projects, Carol Ann Smith, Edwin C. Jones

Arts, Languages and Philosophy Faculty Research & Creative Works

Dear Sir: Ethical dilemmas facing engineers practicing in a culture other than their own is the topic of a current research project. The study will identify and collect information concerning ethical conflicts that can arise in all areas of engineering work—design, implementation, management, and interaction with local personnel and institutions. © 1980, American Chemical Society. All rights reserved.

Evidence For An Iminium Cation Intermediate And Its Non‐Oxidative Decarboxylation In A Cerium (Iv)‐Mediated Oxidative Decarboxylation. Preliminary Communication, Samir B. Hanna, Marilyn E. Moehlenkamp

Chemistry Faculty Research & Creative Works

Evidence is provided for the occurrence of a non‐oxidative decarboxylation in an iminium cation intermediate which is produced in an oxidative decarboxylation induced by cerium (IV). Copyright © 1980 Verlag GmbH & Co. KGaA, Weinheim

Mobility Of Solvent Molecules In A Nonaqueous Lyotropic Liquid Crystal, David W. Larsen, Stig Friberg, Hugo Christenson

Chemistry Faculty Research & Creative Works

No abstract provided.

The System Mgo‐Mgcl2‐H2o At 23°C, Ladawan Urwongse, Charles A. Sorrell

Materials Science and Engineering Faculty Research & Creative Works

Solubilities of MgO in aqueous HC1 solutions at 23°±3°C were measured and combined with analyses of neat magnesium oxychloride cements, cured in sealed containers, to construct an equilibrium phase diagram for the system MgO‐MgCl2‐H₂O. Specific gravities and acidities of solutions saturated with MgO and relative humidities of vapor phases over sealed samples were measured and combined with XRD data to define the compositions in equilibrium with two crystalline phases. Studies of relative reaction rates indicated that the 5–1–8 phase crystallizes more rapidly than the 3·1·8 phase and that cements near the 3·1·8 composition react rapidly with atmospheric CO …

Phase Relations In Magnesium Oxysulfate Cements, Ladawan Urwongse, Charles A. Sorrell

Materials Science and Engineering Faculty Research & Creative Works

Solubilities of MgO in H₂SO₄ solutions were measured and X‐ray analyses of over 100 neat cement samples were used to construct an isothermal phase diagram for the system MgO‐H₂SO₄‐H₂O at 23°±3°C. The phases MgO, Mg(OH)₂, 3Mg(OH)₂ MgSO₄·8H₂O (3·1·8), MgSO₄·7H₂O, MgSO₄·6H₂O, and MgSO₄·H₂O were stable at 23°C. The phases Mg(OH)₂· MgSO₄·5H₂O (1·1·5) and MgSO₄·4H₂O were observed but are considered to be metastable, resulting …

Nickel Carbide: Its Formation And Characterization By Transmission Electron Diffraction, Auger Electron Spectroscopy And Electron Spectroscopy For Chemical Analysis, J. Kleefeld, L. L. Levenson

Physics Faculty Research & Creative Works

Nickel carbide (NiC3) films are formed by the carburization of nickel films in CO at 350°C. The presence of Ni3C is demonstrated by transmission electron diffraction. The carbon Auger electron signal of Ni3C is identical with the carbon Auger spectra attributed to Ni3C by previous authors. The position of the C 1s electron spectroscopy for chemical analysis peak is within 1 eV of the C 1s peak produced by graphite. The grain size of polycrystalline Ni3C is significantly larger than the grain size of the nickel film from which it is grown. © 1979.

The Missouri Miner, December 06, 1979

The Missouri Miner Newspaper

No abstract provided.

Missouri S&T Magazine, December 1979, Miner Alumni Association

Missouri S&T Magazine

No abstract provided.

The Hanle Effect In Penning-Excited Ions, D. W. Fahey, William F. Parks, Laird D. Schearer

Physics Faculty Research & Creative Works

A thermal beam of helium (23S1) metastable atoms was used to excite coherently the 2P3/2 levels of Ca, Sr and Ba in a Penning ionizing collision. The coherent excitation of the ions appears as a linear polarization of the optical emission from the excited ions. The degree of linear polarization is 5.5, 3.5 and 0.5% for Ca, Sr and Ba, respectively, with the polarization parallel to the beam direction. Hanle effect signals from the 2P3/2 level of Sr were observed and the radioactive decay rate measured.

Electron Drift Velocities In N2, Co2, And (N 2+Co2) Laser Mixtures, Rafael A. Sierra, Howard L. Brooks, Kaare J. Nygaard

Physics Faculty Research & Creative Works

A time-of-flight technique has been used to obtain electron drift velocities in N₂, CO₂, and N₂-CO₂ mixtures covering the E/N range 3-93 Td. In the case of the pure gases, excellent agreement with previous work is obtained over the entire E/N range. The mixtures, which are of laser importance, have not been studied previously.

Conductive Strontium Titanate Layers Produced By Boron-Ion Implantation, Connie M. Cooper, P. S. Nayar, Edward Boyd Hale, Robert Gerson

Physics Faculty Research & Creative Works

The ion implantation of boron has been found to be an effective method for increasing the conductivity of strontium titanate. A highly conductive layer was formed by implantations at doses of 3.6x1016 to 1.0x1017 ions/cm2, using an accelerating voltage of 100 kV, corresponding to a boron range of about 300 nm. The conductivity of the implanted layer was found to be further enhanced by about four orders of magnitude after annealing at 225 °C. The surface resistivity attained was typically 1000 Ω/square at room temperature. The resistance increased with rising temperature between 77 and 500 K. All samples were found …