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Enhancing The Performance Of Microbial Fuel Cells Via Metabolic Engineering Of Escherichia Coli For Phenazine Production, Olja Simoska, Dale A. Cummings, Erin M. Gaffney, Claire Langue, Tommy G. Primo, Courtney J. Weber, Corbin E. Witt, Shelley D. Minteer Aug 2023

Enhancing The Performance Of Microbial Fuel Cells Via Metabolic Engineering Of Escherichia Coli For Phenazine Production, Olja Simoska, Dale A. Cummings, Erin M. Gaffney, Claire Langue, Tommy G. Primo, Courtney J. Weber, Corbin E. Witt, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

One of the central roles in the design, development, and application advances in mediator-Based microbial electrochemical systems, such as microbial fuel cells (MFCs), is the establishment of efficient and successful communication between conductive electrode surfaces and microorganisms via modes of extracellular electron transfer (EET). Most microbial-Based systems require the use of artificial electroactive mediators in order to facilitate and/or enhance electron transfer. Our previous work established an exogenous phenazine-Based library as a mediator system to enable EET from the model microorganism Escherichia coli as a promising biotechnological host. However, the addition of exogenous mediators to a microbial electrochemical system has …


Crystal Environment Induced Symmetry Reduction (Ceisr): Deep Analysis Of Para-Chloroacetophenone Azine And Generalization, Harmeet Bhoday, Kaidi Yang, Steven P. Kelley, Rainer Glaser Aug 2023

Crystal Environment Induced Symmetry Reduction (Ceisr): Deep Analysis Of Para-Chloroacetophenone Azine And Generalization, Harmeet Bhoday, Kaidi Yang, Steven P. Kelley, Rainer Glaser

Chemistry Faculty Research & Creative Works

The morphologies of sixteen crystal structures of ten symmetrical Xpara-Ph-(Me)C 00000000 00000000 00000000 00000000 11111111 = N-N = C (Me)-Ph-Xpara azines: 1 (Cl), 2 (Br), 3 (I), 4 (OH), 5 (PhO), 6 (CF3), 7 (F), 8 (Me), 9 (NO2), and 10 (PrO) are described. All the azines crystallize forming idioteloamphiphile monolayers (IAMs) and their morphologies fall into the two main classes of "flat" and "shiplap" depending on the lateral offsets between next neighbors in the monolayer. Ab initio studies show that the (E,E)-configured p-disubstituted acetophenone azines are C2-symmetric in the gas phase and that the azine and phenyl twists are …


Final Report - Augmenting Bridge Inspection With Augmented Reality And Haptics Based Aerial Manipulation, Paul Oh, Blake Hament, Dongbin Kim Aug 2023

Final Report - Augmenting Bridge Inspection With Augmented Reality And Haptics Based Aerial Manipulation, Paul Oh, Blake Hament, Dongbin Kim

Project AS-7

Insight and leverage from prior project identified the need for haptics; the inspector’s sense of touch is often used in bridge assessment. Envisioned is the augmentation of bridge personnel by providing a haptics-based aerial manipulator. Such a manipulator would reduce needs to ascend elevated structures like under bridge decks and cabling. There is recent work that uses haptics in aerial manipulation. But these center on autonomous multi-drone flight formation for aerial shows or cooperative object delivery and are relatively straight-forward. The sense of touch is used to provide spatial distance between drones. By contrast, this proposal’s novelty and merit are …


Utilizing Waste Latex Paint Toward Improving The Performance Of Concrete, Mohamed Leithy, Eslam Gomaa, Ahmed A. Gheni, Mohamed Elgawady Aug 2023

Utilizing Waste Latex Paint Toward Improving The Performance Of Concrete, Mohamed Leithy, Eslam Gomaa, Ahmed A. Gheni, Mohamed Elgawady

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

In this paper, incorporating the waste latex paint (WLP) into the conventional concrete as a partial replacement of sand to improve its durability was investigated. The fresh and hardened characterizations, in addition to the durability of concrete, were examined. The slump test was used to evaluate the fresh properties, while the hardened properties were evaluated through the volume of voids and absorption rate, in addition to the compressive, splitting tensile, and flexural strengths tests. The durability performance was evaluated by the surface resistivity, bulk electrical resistivity, as well as freeze and thaw resistance tests. The results showed a reduction in …


Behavior Of Ultrahigh-Performance Concrete Plates Encasing Steel H-Piles, Mohamed Elgawady, Binod Shrestha Aug 2023

Behavior Of Ultrahigh-Performance Concrete Plates Encasing Steel H-Piles, Mohamed Elgawady, Binod Shrestha

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Steel H-piles are exposed during their service life to wet-dry cycles in combination with salts, such as deicing, that may result in corrosion, leading to cross-sectional loss and reduction in axial load-carrying capacity. This paper proposes an innovative repair method for corroded steel H-piles using ultrahigh-performance concrete (UHPC) plates. The UHPC plates are reinforced with carbon fiber-reinforced polymer (CFRP) grids. The UHPC plates bridge the corroded segment so that the axial force bypasses the corroded segment. The UHPC are bolted to the steel H-pile using high-strength bolt connectors (HSBCs). Eleven steel H-piles bolted with UHPC plates were investigated experimentally under …


Libra: Harvesting Idle Resources Safely And Timely In Serverless Clusters, Hanfei Yu, Christian Fontenot, Hao Wang, Jian Li, Xu Yuan, Seung Jong Park Aug 2023

Libra: Harvesting Idle Resources Safely And Timely In Serverless Clusters, Hanfei Yu, Christian Fontenot, Hao Wang, Jian Li, Xu Yuan, Seung Jong Park

Computer Science Faculty Research & Creative Works

Serverless computing has been favored by users and infrastructure providers from various industries, including online services and scientific computing. Users enjoy its auto-scaling and ease-of-management, and providers own more control to optimize their service. However, existing serverless platforms still require users to pre-define resource allocations for their functions, leading to frequent misconfiguration by inexperienced users in practice. Besides, functions' varying input data further escalate the gap between their dynamic resource demands and static allocations, leaving functions either over-provisioned or under-provisioned. This paper presents Libra, a safe and timely resource harvesting framework for multi-node serverless clusters. Libra makes precise harvesting decisions …


Discovery Of Gamma Rays From The Quiescent Sun With Hawc, A. Albert, R. Alfaro, C. Alvarez, J. C. Arteaga-Velázquez, D. Avila Rojas, H. A. Ayala Solares, R. Babu, E. Belmont-Moreno, C. Brisbois, K. S. Caballero-Mora, T. Capistrán, A. Carramiñana, S. Casanova, O. Chaparro-Amaro, U. Cotti, J. Cotzomi, S. Coutiño De León, E. De La Fuente, R. Diaz Hernandez, B. L. Dingus, M. A. Duvernois, M. Durocher, J. C. Diaz-Velez, R. W. Ellsworth, K. Engel, C. Espinoza, K. L. Fan, K. Fang, M. Fernandez Alonso, H. Fleischhack, N. Fraija, J. A. Garcia-Gonzalez, F. Garfias, M. M. Gonzalez, J. A. Goodman, J. P. Harding, S. Hernandez, J. Hinton, D. Huang, F. Hueyotl-Zahuantitla, P. Huntemeyer, A. Iriarte, V. Joshi, S. Kaufmann, J. Lee, J. T. Linnemann, A. L. Longinotti, G. Luis-Raya, K. Malone, O. Martinez, J. Martinez-Castro, J. A. Matthews, P. Miranda-Romagnoli, J. A. Morales-Soto, E. Moreno, M. Mostafa, A. Nayerhoda, L. Nellen, M. U. Nisa, R. Noriega-Papaqui, L. Olivera-Nieto, N. Omodei, Y. Perez Araujo, E. G. Perez-Perez, C. D. Rho, D. Rosa-Gonzalez, E. Ruiz-Velasco, H. Salazar, D. Salazar-Galeggos, A. Sandoval, M. Schneider, J. Serna-Franco, A. J. Smith, Y. Son, R. W. Springer, O. Tibolla, K. Tollefson, I. Torres, R. Torres-Escobedo, R. Turner, F. Urena-Mena, E. Varela, J. Villasenor, Xiaojie Wang, I. J. Watson, E. Willox, S. Yun-Carcamo, H. Zhou, C. De Leon Aug 2023

Discovery Of Gamma Rays From The Quiescent Sun With Hawc, A. Albert, R. Alfaro, C. Alvarez, J. C. Arteaga-Velázquez, D. Avila Rojas, H. A. Ayala Solares, R. Babu, E. Belmont-Moreno, C. Brisbois, K. S. Caballero-Mora, T. Capistrán, A. Carramiñana, S. Casanova, O. Chaparro-Amaro, U. Cotti, J. Cotzomi, S. Coutiño De León, E. De La Fuente, R. Diaz Hernandez, B. L. Dingus, M. A. Duvernois, M. Durocher, J. C. Diaz-Velez, R. W. Ellsworth, K. Engel, C. Espinoza, K. L. Fan, K. Fang, M. Fernandez Alonso, H. Fleischhack, N. Fraija, J. A. Garcia-Gonzalez, F. Garfias, M. M. Gonzalez, J. A. Goodman, J. P. Harding, S. Hernandez, J. Hinton, D. Huang, F. Hueyotl-Zahuantitla, P. Huntemeyer, A. Iriarte, V. Joshi, S. Kaufmann, J. Lee, J. T. Linnemann, A. L. Longinotti, G. Luis-Raya, K. Malone, O. Martinez, J. Martinez-Castro, J. A. Matthews, P. Miranda-Romagnoli, J. A. Morales-Soto, E. Moreno, M. Mostafa, A. Nayerhoda, L. Nellen, M. U. Nisa, R. Noriega-Papaqui, L. Olivera-Nieto, N. Omodei, Y. Perez Araujo, E. G. Perez-Perez, C. D. Rho, D. Rosa-Gonzalez, E. Ruiz-Velasco, H. Salazar, D. Salazar-Galeggos, A. Sandoval, M. Schneider, J. Serna-Franco, A. J. Smith, Y. Son, R. W. Springer, O. Tibolla, K. Tollefson, I. Torres, R. Torres-Escobedo, R. Turner, F. Urena-Mena, E. Varela, J. Villasenor, Xiaojie Wang, I. J. Watson, E. Willox, S. Yun-Carcamo, H. Zhou, C. De Leon

Physics Faculty Research & Creative Works

We report the first detection of a TeV γ-ray flux from the solar disk (6.3σ), based on 6.1 years of data from the High-Altitude Water Cherenkov (HAWC) observatory. The 0.5-2.6 TeV spectrum is well fit by a power law, dN/dE=A(E/1 TeV)-γ, with A=(1.6±0.3)x10-12 TeV-1 cm-2 s-1 and γ=3.62±0.14. The flux shows a strong indication of anticorrelation with solar activity. These results extend the bright, hard GeV emission from the disk observed with Fermi-LAT, seemingly due to hadronic Galactic cosmic rays showering on nuclei in the solar atmosphere. However, current theoretical models are unable to explain the details of how solar …


Variable Rates Of Hybridization Among Contact Zones Between A Pair Of Topminnow Species, Fundulus Notatus And F. Olivaceus, David D. Duvernell, Naznin S. Remex, Jeffrey T. Miller, Jacob F. Schaefer Aug 2023

Variable Rates Of Hybridization Among Contact Zones Between A Pair Of Topminnow Species, Fundulus Notatus And F. Olivaceus, David D. Duvernell, Naznin S. Remex, Jeffrey T. Miller, Jacob F. Schaefer

Biological Sciences Faculty Research & Creative Works

Pairs of species that exhibit broadly overlapping distributions, and multiple geographically isolated contact zones, provide opportunities to investigate the mechanisms of reproductive isolation. Such naturally replicated systems have demonstrated that hybridization rates can vary substantially among populations, raising important questions about the genetic basis of reproductive isolation. The topminnows, Fundulus notatus and F. olivaceus, are reciprocally monophyletic, and co-occur in drainages throughout much of the central and southern United States. Hybridization rates vary substantially among populations in isolated drainage systems. We employed genome-wide sampling to investigate geographic variation in hybridization, and to assess the possible importance of chromosome fusions to …


Effect Of Competitive Adsorption Between Specialty Admixtures And Superplasticizer On Structural Build-Up And Hardened Property Of Mortar Phase Of Ultra-High-Performance Concrete, Le Teng, Jingjie Wei, Kamal Khayat, Joseph J. Assaad Aug 2023

Effect Of Competitive Adsorption Between Specialty Admixtures And Superplasticizer On Structural Build-Up And Hardened Property Of Mortar Phase Of Ultra-High-Performance Concrete, Le Teng, Jingjie Wei, Kamal Khayat, Joseph J. Assaad

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This study aims to enhance structural build-up of ultra-high-performance concrete (UHPC) without influencing the initial flowability, which is critical in repair applications (e.g., use of UHPC in thin bonded overlays for bridge deck rehabilitation). Specialty admixtures, such as a viscosity-modifying admixture (VMA), have been used to enhance the structural build-up at rest. However, the use of specialty admixtures can increase superplasticizer (SP) demand to maintain proper flowability; the synergistic effect of these admixtures on structural build-up is not well understood as the coupled admixture content can reverse the net effect on yield stress, viscosity, and thixotropy. In this study, VMAs …


Genesis Of The 1.45 Ga Kratz Spring Iron Oxide-Apatite Deposit Complex In Southeast Missouri, Usa: Constraints From Oxide Mineral Chemistry, Brandon Sullivan, Marek Locmelis, Bolorchimeg N. Tunnell, Cheryl M. Seeger, Marilena Moroni, Sarah Dare, Ryan Mathur, Thomas Schott Aug 2023

Genesis Of The 1.45 Ga Kratz Spring Iron Oxide-Apatite Deposit Complex In Southeast Missouri, Usa: Constraints From Oxide Mineral Chemistry, Brandon Sullivan, Marek Locmelis, Bolorchimeg N. Tunnell, Cheryl M. Seeger, Marilena Moroni, Sarah Dare, Ryan Mathur, Thomas Schott

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Seven major and numerous lesser Fe oxide occurrences within the 1.47 Ga St. Francois Mountains terrane in Missouri (USA) have previously been described as iron oxide-apatite (IOA) and iron oxide-copper-gold (IOCG) deposits. Researchers speculate that these contain significant amounts of critical minerals, most notably rare earth elements and cobalt. One of the less-studied deposits in the region is the 1.455 Ga Kratz Spring deposit. The deposit consists of two steeply dipping magnetite bodies beneath 450 m of sedimentary cover. The genesis of the Kratz Spring deposit and its relationship to nearby IOA-IOCG deposits remains poorly constrained. To better understand the …


An Integrated Finite Element Method And Machine Learning Algorithm For Brain Morphology Prediction, Poorya Chavoshnejad, Liangjun Chen, Xiaowei Yu, Jixin Hou, Nicholas Filla, Dajiang Zhu, Tianming Liu, Gang Li, Mir Jalil Razavi, Xianqiao Wang Aug 2023

An Integrated Finite Element Method And Machine Learning Algorithm For Brain Morphology Prediction, Poorya Chavoshnejad, Liangjun Chen, Xiaowei Yu, Jixin Hou, Nicholas Filla, Dajiang Zhu, Tianming Liu, Gang Li, Mir Jalil Razavi, Xianqiao Wang

Computer Science Faculty Research & Creative Works

The human brain development experiences a complex evolving cortical folding from a smooth surface to a convoluted ensemble of folds. Computational modeling of brain development has played an essential role in better understanding the process of cortical folding but still leaves many questions to be answered. A major challenge faced by computational models is how to create massive brain developmental simulations with affordable computational sources to complement neuroimaging data and provide reliable predictions for brain folding. In this study, we leveraged the power of machine learning in data augmentation and prediction to develop a machine-learning-based finite element surrogate model to …


A Direct Data Approach To Joint 2-D Doa And Frequency Estimation With L-Shaped Array, Yanming Zhang, Lijun Jiang Aug 2023

A Direct Data Approach To Joint 2-D Doa And Frequency Estimation With L-Shaped Array, Yanming Zhang, Lijun Jiang

Electrical and Computer Engineering Faculty Research & Creative Works

This article presents a joint two-dimensional dynamic mode decomposition (JTDDMD) approach to estimate the azimuth angle, elevation angle, and frequency for multiple narrowband sources using the L-shaped array. According to the placement position of different coordinate axes of the receiving antenna in the array, i.e., x- or z-axis, the received signal is divided into two datasets. Two-dimensional dynamic mode decomposition (TDDMD), the sub algorithm of JTDDMD, is used twice to deal with these two datasets separately. Through the analysis of the x-axis subarray received signal using TDDMD, the electrical angle in the x-direction and frequency are obtained with automatic pairing. …


Effect Of Shock Tunnel Geometry On Shockwave And Vortex Ring Formation, Propagation, And Head On Collision, Rachel L. Bauer, Emily M. Johnson, Alexander D. Douglas, Catherine E. Johnson Aug 2023

Effect Of Shock Tunnel Geometry On Shockwave And Vortex Ring Formation, Propagation, And Head On Collision, Rachel L. Bauer, Emily M. Johnson, Alexander D. Douglas, Catherine E. Johnson

Mining Engineering Faculty Research & Creative Works

Vortex ring research primarily focuses on the formation from circular openings. Consequently, the role of tunnel geometry is less understood, despite there being numerous research studies using noncircular shock tunnels. This experimental study investigated shockwaves and vortex rings from different geometry shock tunnels from formation at the tunnel opening to head on collision with another similarly formed vortex ring using schlieren imaging and statistical analysis. The velocity of the incident shockwave was found to be consistent across all four shock tunnel geometries, which include circle, hexagon, square, and triangle of the same cross-sectional area. The velocity was 1.2 ± 0.007 …


Design And Simulation Of A Utility Oilfield Flare In Iraq/Kurdistan Region Using Cfd And Api-521 Methodology, Ahmed A. Maaroof, Joseph D. Smith, Mohammed H.S. Zangana Aug 2023

Design And Simulation Of A Utility Oilfield Flare In Iraq/Kurdistan Region Using Cfd And Api-521 Methodology, Ahmed A. Maaroof, Joseph D. Smith, Mohammed H.S. Zangana

Chemical and Biochemical Engineering Faculty Research & Creative Works

This paper aims at reviewing and analyzing the operation and design of a utility flare in an oilfield in the Iraq/Kurdistan region. The flare supports a gas separation unit that separates 100 MMSCFD of natural gas from other liquid compounds in petroleum refining. The actual flare dimensions are 50 m high and 0.6 m diameter and works in summer where the crosswind speed is 9 m/s and a flow of 1.2 MMSCFD of treated natural gas is flaring through it. At the beginning, the flare design was performed using the API-521 recommended approach based on full operating capacity of the …


Development And Characterization Of Coal-Based Thermoplastic Composite Material For Sustainable Construction, Haibin Zhang, Wenyu Liao, Genda Chen, Hongyan Ma Aug 2023

Development And Characterization Of Coal-Based Thermoplastic Composite Material For Sustainable Construction, Haibin Zhang, Wenyu Liao, Genda Chen, Hongyan Ma

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The exploitation of coal and the disposal of waste plastic present significant environmental and economic challenges that require sustainable and profitable solutions. In response, we propose a renewable construction composite material of coal-based thermoplastic composite (CTC) that can be made from low-grade coal and plastic waste. We developed and tested the hot-press fabrication method for this CTC, using coal with a maximum particle size of 4.75 mm and recycled high-density polyethylene (HDPE). The effects of the coal fraction (50–80 wt.%) on compressive properties, thermal properties, microstructure, and ecological and economic efficiencies of the CTC were investigated. Test results revealed that …


Outgassing Behavior And Heat Treatment Optimization Of Jsc-1a Lunar Regolith Simulant, Ryan P. Wilkerson, Mihail P. Petkov, Gerald E. Voecks, Catherine S. Lynch, Holly S. Shulman, Santhoshkumar Sundaramoorthy, Amitava Choudhury, Douglas L. Rickman, Michael R. Effinger Aug 2023

Outgassing Behavior And Heat Treatment Optimization Of Jsc-1a Lunar Regolith Simulant, Ryan P. Wilkerson, Mihail P. Petkov, Gerald E. Voecks, Catherine S. Lynch, Holly S. Shulman, Santhoshkumar Sundaramoorthy, Amitava Choudhury, Douglas L. Rickman, Michael R. Effinger

Chemistry Faculty Research & Creative Works

As NASA Strives towards a Long Duration Presence on the Moon, It Has Become Increasingly Important to Learn How to Better Utilize Resources from the Lunar Surface for Everything from Habitats, Vehicle Infrastructure, and Chemical Extraction. to that End, a Variety of Lunar Simulants Have Been Sourced from Terrestrially Available Volcanic Minerals and Glass as Apollo Regolith is Unavailable for Experimentation Needing Large Masses. However, While Mineralogy and Chemical Composition Can Approach that of Lunar Material in These Simulants, There Are Still Distinct Non-Lunar Phases Such as Hydrates, Carbonates, Sulfates, and Clays that Can Cause Simulants to Behave Distinctly Non-Lunar …


Machine Learning-Based Seismic Damage Assessment Of Residential Buildings Considering Multiple Earthquake And Structure Uncertainties, Xinzhe Yuan, Liujun Li, Haibin Zhang, Yanping Zhu, Genda Chen, Cihan H. Dagli Aug 2023

Machine Learning-Based Seismic Damage Assessment Of Residential Buildings Considering Multiple Earthquake And Structure Uncertainties, Xinzhe Yuan, Liujun Li, Haibin Zhang, Yanping Zhu, Genda Chen, Cihan H. Dagli

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Wood-frame structures are used in almost 90% of residential buildings in the United States. It is thus imperative to rapidly and accurately assess the damage of wood-frame structures in the wake of an earthquake event. This study aims to develop a machine-learning-based seismic classifier for a portfolio of 6,113 wood-frame structures near the New Madrid Seismic Zone (NMSZ) in which synthesized ground motions are adopted to characterize potential earthquakes. This seismic classifier, based on a multilayer perceptron (MLP), is compared with existing fragility curves developed for the same wood-frame buildings near the NMSZ. This comparative study indicates that the MLP …


Distinct Modes Of Aged Soil Carbon Export In A Large Tropical Lake Basin Identified Using Bulk And Compound-Specific Radiocarbon Analyses Of Fluvial And Lacustrine Sediment, Wesley G. Parker, Jason M.E. Ahad, Jonathan Obrist-Farner, Benjamin Keenan, Peter M.J. Douglas Aug 2023

Distinct Modes Of Aged Soil Carbon Export In A Large Tropical Lake Basin Identified Using Bulk And Compound-Specific Radiocarbon Analyses Of Fluvial And Lacustrine Sediment, Wesley G. Parker, Jason M.E. Ahad, Jonathan Obrist-Farner, Benjamin Keenan, Peter M.J. Douglas

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The 14C content of sedimentary organic matter (OM) and specific organic molecules provide valuable information on the source and age of OM stored in sediments, but these data are limited for tropical fluvial and lake sediments. We analyzed 14C in bulk OM, palmitic acid (C16), and long-chain n-alkanoic acids (C24, C26, and C28), within fluvial and lake sediments in the catchment of Lake Izabal, a large tectonic lake basin in Guatemala. We combined these measurements with bulk and compound-specific δ13C measurements, as well as sediment organic carbon to nitrogen (OC:N) ratios, to understand the source and age of sedimentary OM …


Electrosteric Control Of The Aggregation And Yielding Behavior Of Concentrated Portlandite Suspensions, Sharu Bhagavathi Kandy, Narayanan Neithalath, Mathieu Bauchy, Aditya Kumar, Edward Garboczi, Torben Gaedt, Samanvaya Srivastava, Gaurav Sant Aug 2023

Electrosteric Control Of The Aggregation And Yielding Behavior Of Concentrated Portlandite Suspensions, Sharu Bhagavathi Kandy, Narayanan Neithalath, Mathieu Bauchy, Aditya Kumar, Edward Garboczi, Torben Gaedt, Samanvaya Srivastava, Gaurav Sant

Materials Science and Engineering Faculty Research & Creative Works

Portlandite (calcium hydroxide: CH: Ca (OH)2) suspensions aggregate spontaneously and form percolated fractal aggregate networks when dispersed in water. Consequently, the viscosity and yield stress of portlandite suspensions diverge at low particle loadings, adversely affecting their processability. Even though polycarboxylate ether (PCE)-based comb polyelectrolytes are routinely used to alter the particle dispersion state, water demand, and rheology of similar suspensions (e.g., ordinary portland cement suspensions) that feature a high pH and high ionic strength, their use to control portlandite suspension rheology has not been elucidated. This study combines adsorption isotherms and rheological measurements to elucidate the role of PCE composition …


Localization And Identification Of Emi Sources In Shielding Enclosures Based On A Two-Step Source Reconstruction Method, Zi An Wang, Jun Fa Mao, Li (Lijun) Jun Jiang, Ping Li Aug 2023

Localization And Identification Of Emi Sources In Shielding Enclosures Based On A Two-Step Source Reconstruction Method, Zi An Wang, Jun Fa Mao, Li (Lijun) Jun Jiang, Ping Li

Electrical and Computer Engineering Faculty Research & Creative Works

Localization and identification of unknown electromagnetic interference (EMI) sources in shielding enclosures is a great challenge due to the complex electromagnetic environment. In this work, a two-step source reconstruction method is proposed to address this issue. The actual EMI sources are initially modeled by equally distributed equivalent electric dipoles in the shielding enclosure. Effects of surrounding environments are rigorously incorporated using the numerical Green's function which bridges between the equivalent dipoles and planar scanned tangential magnetic near-field. Next, the initial equivalent sources are downsized via evaluating the contribution of each equivalent dipole. The parameters of remaining equivalent dipoles are updated …


Quantum Electrodynamic Corrections To Cyclotron States In A Penning Trap, Ulrich D. Jentschura, Christopher Moore Aug 2023

Quantum Electrodynamic Corrections To Cyclotron States In A Penning Trap, Ulrich D. Jentschura, Christopher Moore

Physics Faculty Research & Creative Works

We analyze the leading and higher-order quantum electrodynamic corrections to the energy levels for a single electron bound in a Penning trap, including the Bethe logarithm correction due to virtual excitations of the reference quantum cyclotron state. The effective coupling parameter αc in the Penning trap is identified as the square root of the ratio of the cyclotron frequency, converted to an energy via multiplication by the Planck constant, to the electron rest mass energy. We find a large, state-independent, logarithmic one-loop self-energy correction of order α αc4mc2ln(αc-2), where m is the …


Doubly Differential Ionization In Proton-Helium Collisions At Intermediate Energies: Energy Distribution Of Emitted Electrons As A Function Of Scattered-Projectile Angle, K. H. Spicer, C. T. Plowman, Michael Schulz, A. S. Kadyrov Aug 2023

Doubly Differential Ionization In Proton-Helium Collisions At Intermediate Energies: Energy Distribution Of Emitted Electrons As A Function Of Scattered-Projectile Angle, K. H. Spicer, C. T. Plowman, Michael Schulz, A. S. Kadyrov

Physics Faculty Research & Creative Works

Differential studies of the proton-helium scattering problem using the two-center wave-packet convergent close-coupling approach is extended to the calculation of the ionization cross section differential in the electron emission energy and the projectile scattering angle. The results obtained using the correlated two-electron and effective one-electron methods are in reasonably good agreement with experiment. While the shape of the doubly differential cross section generally agrees with the results of the experiment, at some emission energies its magnitude does not. This appears consistent with similar disagreement seen in the singly differential cross section at the same emission energies.


Silicon Carbide-Based Dna Sensing Technologies, Abdulla Al Mamun, Mason Mcgarrity, Jong Hoon Kim, Feng Zhao Aug 2023

Silicon Carbide-Based Dna Sensing Technologies, Abdulla Al Mamun, Mason Mcgarrity, Jong Hoon Kim, Feng Zhao

Electrical and Computer Engineering Faculty Research & Creative Works

DNA sensing is critical in various applications such as the early diagnosis of diseases and the investigation of forensic evidence, food processing, agriculture, environmental protection, etc. As a wide-bandgap semiconductor with excellent chemical, physical, electrical, and biocompatible properties, silicon carbide (SiC) is a promising material for DNA sensors. In recent years, a variety of SiC-based DNA-sensing technologies have been reported, such as nanoparticles and quantum dots, nanowires, nanopillars, and nanowire-based field-effect-transistors, etc. This article aims to provide a review of SiC-based DNA sensing technologies, their functions, and testing results.


Best Practices To Promote Field Science Safety, Kristen Yarincik, Anne Kelly, Terry Mcglynn, Robin M. Verble Jul 2023

Best Practices To Promote Field Science Safety, Kristen Yarincik, Anne Kelly, Terry Mcglynn, Robin M. Verble

Biological Sciences Faculty Research & Creative Works

Interventions are necessary to address the ongoing epidemic of sexual harassment and assault in field settings. An evidence-based approach to identifying specific interventions will be most effective at promoting the safety of scientists. We present the results of a workshop conducted by experts in field biology and the study of sexual harassment and assault that identified a comprehensive set of best practices for individuals and organizations. These recommendations are grounded in peer-reviewed scholarship and are separated into four topics: culture change, accountability, policy development, and reporting. The resulting report of the workshop recommends 44 practices, categorized by the resources required …


A Spike-Shaped Anchorage For Steel Reinforced Polymer (Srp)-Strengthened Concrete Structures, Xingxing Zou, Keenan L. Mcburney, Lesley H. Sneed Jul 2023

A Spike-Shaped Anchorage For Steel Reinforced Polymer (Srp)-Strengthened Concrete Structures, Xingxing Zou, Keenan L. Mcburney, Lesley H. Sneed

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Steel reinforced polymer (SRP) composite has recently emerged as an effective and economical solution for strengthening of reinforced concrete (RC) structures. Premature debonding failure of unanchored SRP at low load levels generally governs the performance of RC structures strengthened with externally bonded SRP. Therefore, a novel yet simple spike-shaped anchorage system was proposed in this study to prevent the debonding failure of SRP and to improve the interfacial shear capacity. Experimental investigation through single-lap shear tests of SRP-concrete joints showed that the anchorage system changed the failure mode from composite debonding to fiber rupture. In addition, the anchorage system substantially …


Understanding Formation And Roles Of Niᴵᴵ Aryl Amido And Niiii Aryl Amido Intermediates In Ni-Catalyzed Electrochemical Aryl Amination Reactions, Jian Luo, Michael T. Davenport, Chad Callister, Shelley D. Minteer, Daniel H. Ess, T. Leo Liu Jul 2023

Understanding Formation And Roles Of Niᴵᴵ Aryl Amido And Niiii Aryl Amido Intermediates In Ni-Catalyzed Electrochemical Aryl Amination Reactions, Jian Luo, Michael T. Davenport, Chad Callister, Shelley D. Minteer, Daniel H. Ess, T. Leo Liu

Chemistry Faculty Research & Creative Works

Ni-catalyzed electrochemical aryl amination (e-amination) is an attractive, emerging approach to building C-N bonds. Here, we report in-depth experimental and computational studies that examined the mechanism of Ni-catalyzed e-amination reactions. Key NiII-amine dibromide and NiII aryl amido intermediates were chemically synthesized and characterized. the combination of experiments and DFT calculations suggest (1) there is coordination of an amine to the NiII catalyst before the cathodic reduction and oxidative addition steps, (2) a stable NiII aryl amido intermediate is produced from the cathodic half-reaction, a critical step in controlling the selectivity between cross-coupling and undesired homo-coupling reaction pathways, (3) the diazabicycloundecene …


In-Situ Lock-In Thermographic Measurement Of Powder Layer Thermal Diffusivity And Thickness In Laser Powder Bed Fusion, Tao Liu, Edward C. Kinzel, Ming-Chuan Leu Jul 2023

In-Situ Lock-In Thermographic Measurement Of Powder Layer Thermal Diffusivity And Thickness In Laser Powder Bed Fusion, Tao Liu, Edward C. Kinzel, Ming-Chuan Leu

Mechanical and Aerospace Engineering Faculty Research & Creative Works

The thermal transport properties of the powder layer play a crucial role in the process of laser powder bed fusion (LPBF). This paper introduces an in-situ measurement method utilizing active lock-in infrared thermography (LIT) to determine the thermal diffusivity and thickness of the powder layer. The proposed method exhibits great potential for accurate powder property and thickness measurements and real-time process monitoring. In this lock-in thermographic technique, the LPBF laser beam is directed through an optical diffuser and modulated into a square thermal wave. This thermal wave serves as an active heat source to heat the surface of the powder …


Experiential Learning And Exposure To Professional Experience In Civil Engineering Education, Sanjay Tewari Jul 2023

Experiential Learning And Exposure To Professional Experience In Civil Engineering Education, Sanjay Tewari

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Experiential learning is increasingly recognized as a crucial component of modern education, especially in fields like civil engineering, where practical skills and real-world exposure are paramount. This paper explores the various avenues through which civil engineering education can offer professional exposure and experiential learning opportunities. By analyzing the impact of senior seminars, internships, co-ops, undergraduate research, study abroad programs, service learning, student design teams, leadership positions, and involvement in technical and professional student organizations, this paper aims to underscore the importance of these approaches in shaping well-rounded and industry-ready civil engineers.


A Natural Organic Artificial Synaptic Device Made From A Honey And Carbon Nanotube Admixture For Neuromorphic Computing, Md Mehedi Hasan Tanim, Zoe Templin, Kaleb Hood, Jun Jiao, Feng Zhao Jul 2023

A Natural Organic Artificial Synaptic Device Made From A Honey And Carbon Nanotube Admixture For Neuromorphic Computing, Md Mehedi Hasan Tanim, Zoe Templin, Kaleb Hood, Jun Jiao, Feng Zhao

Electrical and Computer Engineering Faculty Research & Creative Works

Artificial synaptic devices are the essential hardware component in emerging neuromorphic computing systems by mimicking biological synapse and brain functions. When made from natural organic materials such as protein and carbohydrate, they have potential to improve sustainability and reduce electronic waste by enabling environmentally friendly disposal. In this paper, a new natural organic memristor based artificial synaptic device is reported with the memristive film processed by a honey and carbon nanotube (CNT) admixture, that is, honey-CNT memristor. Optical microscopy, scanning electron microscopy, and micro-Raman spectroscopy are employed to analyze the morphology and chemical structure of the honey-CNT film. The device …


Neuro-Symbolic Representations For Information Retrieval, Laura Dietz, Hannah Bast, Shubham Chatterjee, Jeff Dalton, Jian Yun Nie, Rodrigo Nogueira Jul 2023

Neuro-Symbolic Representations For Information Retrieval, Laura Dietz, Hannah Bast, Shubham Chatterjee, Jeff Dalton, Jian Yun Nie, Rodrigo Nogueira

Computer Science Faculty Research & Creative Works

This tutorial will provide an overview of recent advances on neuro-symbolic approaches for information retrieval. A decade ago, knowledge graphs and semantic annotations technology led to active research on how to best leverage symbolic knowledge. At the same time, neural methods have demonstrated to be versatile and highly effective. From a neural network perspective, the same representation approach can service document ranking or knowledge graph reasoning. End-to-end training allows to optimize complex methods for downstream tasks. We are at the point where both the symbolic and the neural research advances are coalescing into neuro-symbolic approaches. The underlying research questions are …