Digital Commons Network^™

Friction Stir Welding Of High Temperature Alloys, Jiye Wang

Doctoral Dissertations

"Friction stir welding (FSW) of Ti-6Al-4V alloy, nickel-based and iron-based oxide dispersion strengthened (ODS) alloys (MA754 and MA956) has been studied. The main aspects covered include tool evaluation, microstructural evolution, mechanical properties, and correlation between processing, microstructure and mechanical properties. Tool performance study was carried out for Ti-6Al-4V alloy with refractory tools made of W-1.1%La₂O₃ and two different grades of WC-Co based materials. The results showed that tool degradation can be attributed to mechanical and chemical interaction with processed material. The nature of tool-workpiece interaction was tool material dependent and influenced the resultant microstructure and weld quality in the stirred …

Influence Of Temperature And Microstructural Modification On Formability Of Magnesium Alloys, Arun Mohan

Doctoral Dissertations

"The ß-precipitate free AZ31, ß-precipitate rich AZ91 and a few Mg-Y-Zn alloys were studied to understand the dependence of Mg formability on microstructural condition and temperature. Friction stir processing (FSP) was used to refine the grain size and to obtain desirable distribution of precipitates in the matrix. Since Mg alloys exhibit challenges in achieving room temperature formability, superplastic deformation was utilized. This work focused on high strain rate superplasticity (HSRS, ≥10⁻² s⁻¹) which is more attractive for industrial applications as compared to the slower rates of conventional superplasticity.

Thermally stable fine grains and pinning particles at HSRS temperatures were essential …

Small Sample Inference For Exponential Survival Times With Heavy Right-Censoring, Noroharivelo Volaniaina Randrianampy

Doctoral Dissertations

"We develop a saddlepoint-based method and several generalized Bartholomew methods for generating confidence intervals about the rate parameter of an exponential distribution in the presence of heavy random right-censoring. Butler's conditional moment generating function formula is used to derive the relevant moment generating function for the rate parameter score function which provides access to a saddlepoint-based bootstrap method. Moment generating functions also play a key role in the generalized Bartholomew methods we develop. Since heavy censoring is assumed, the possible non-existence of the rate parameter maximum likelihood estimate (MLE) is nonignorable. The overwhelming majority of existing methods condition upon the …

Investigation Of Different Approaches To Combine Cable Information And Near-Field Scan Data For Radiated-Field Estimation, Keong W. Kam

Doctoral Dissertations

"Near-field scanning is often used to solve EMC problems. Aside from the purpose of visualization of near-fields, measured near-field data can be used to estimate far-field. One of many challenges associated with using near-field to far-field transform (NFFFT) technique for EMC application is the handling of attached cables. The objective of this investigation is to evaluate different methods to add cable information to the near-field data for far-field estimation. The investigation is carried out using numerical experiments in EMCoS EMC studio, which is a commercial MoM (Method of Moment) tool for EM simulation. Measurement results from a test structure are …

Imaging The Subsurface In Karst Terrain Using Electrical Resistivity Tomography, Evgeniy V. Torgashov

Doctoral Dissertations

"Five electrical resistivity tomography (resistivity) case studies are presented. The first case study, entitled "Springfield Underground", includes ERT data acquired with the purpose of imaging the ceiling of an limestone aggregate mine following simultaneous localized roof failure. The interpretation of the ERT data indicates roof rock failure occurred at the intersection of two previously unmapped near-vertical solution-widened fractures.

At the "Chesterfield Dam" site, resistivity data were acquired to identify the zone of seepage through an earthfill dam. The seepage pathway beneath the dam is interpreted as through a solution-widened fracture, the top of which constituted a segment of the original …

Theoretical Studies Of Few-Body Problems, Uttam Chowdhury

Doctoral Dissertations

"Heavy ion collisions with atomic and molecular targets produce many outcomes. The Schrödinger equation is not analytically soluble for more than two mutually interacting particles. As a result, theory must resort to using approximations, the validity of which is determined by comparison with experiment. This work is focused on finding better approximations to describe ionization and capture processes in proton collisions.

Proton-impact ionization of molecular hydrogen is treated as a 3-body problem. Usually the target is treated as an atomic target and the results are multiplied by an ad hoc factor to account for the molecular structure. Measured cross sections …

Influence Of Microstructural Length Scale On Deformation Behavior Of Magnesium Alloys, Wei Yuan

Doctoral Dissertations

"Friction stir processing (FSP) is emerging as an effective tool for microstructural modification. Mg-Al-Zn alloys with different aluminum contents were subjected to FSP to achieve fine grained and ultrafine grained (UFG) structure. The objective of this work was to study the influence of microstructural length scale on the governing deformation and strengthening mechanisms of FSP magnesium alloys.

FSP introduced strong basal fiber texture and processing parameter dependent grain/precipitate size and distribution. Grain refinement promoted non-basal dislocation activation at room temperature. The strength of the alloy increased as a consequence of grain refinement following classic Hall-Petch relationship to different extents due …

Quantitative Analysis Of Co-Enzyme A In A Plant Tissues And Cancer Biomarkers In Urine Samples By Using Capillary Electrophoresis And Liquid Chromatography-Mass Spectrometry, Yongqing Jiang

Doctoral Dissertations

"Despite continuous effort and progress in cancer detection and therapy, cancer remains one of our greatest health concerns because of its low survival rate and rapid incidence increase. One reason for this is the late detection and therefore pre-cancer diagnosis is crucial. In pre-cancer studies, cancer biomarkers become significant because of the useful information it contains such as possible cancer type and stage. Separation and detection technique plays an important role in cancer biomarker identification.

Coenzyme A (CoA) facilitates more than 100 chemical reactions in cells. Because of its low abundance accumulated in cells, it is critical to develop a …

Plate Kinematics Of The Afro-Arabian Rift System With An Emphasis On The Afar Depression, Helen Carrie Bottenberg

Doctoral Dissertations

This work utilizes the Four-Dimensional Plates (4DPlates) software, and Differential Interferometric Synthetic Aperture Radar (DInSAR) to examine plate-scale, regional-scale and local-scale kinematics of the Afro-Arabian Rift System with emphasis on the Afar Depression in Ethiopia. First, the 4DPlates is used to restore the Red Sea, the Gulf of Aden, the Afar Depression and the Main Ethiopian Rift to development of a new model that adopts two poles of rotation for Arabia. Second, the 4DPlates is used to model regional-scale and local-scale kinematics within the Afar Depression. Most plate reconstruction models of the Afro-Arabian Rift System relies on considering the Afar …

Manufacturing And Characterization Of Soy-Based Polyurethane Composites, Rama Bhadra Raju Vuppalapati

Doctoral Dissertations

"The major cost drivers for composites are raw materials and manufacturing process. Automated manufacturing processes like pultrusion and low cost bio-based raw materials can significantly lower the cost of composites. Polyurethane (PU) resin systems are being introduced in the pultrusion industry as they have higher performance characteristics and manufacturing feasibility when compared to conventional resin systems such as polyester and vinyl ester. PU resin systems are generally characterized as aromatic and aliphatic. Aliphatic PU has lower mechanical properties than the aromatic resin system due to its chemical structure. Nano materials can be used to increase the mechanical properties of aliphatic …

Modeling And Synthesis Of Pvdf-Based Dielectrics For Energy Storage Applications, Xuhui Lu

Doctoral Dissertations

"The purpose of this research was to develop dielectric films for high energy density capacitor applications. Also desired was to develop a deeper understanding of dielectric breakdown and electric energy storage related phenomena through simulation, theoretical analysis, and experimental investigation.

An analytical model incorporating Weibull dielectric strength statistics was developed to establish quantitative relationships between material properties and device performance of self-healing capacitors. The model is useful for designing high voltage capacitors and developing dielectric materials where the effects of electric field-dependent permittivity need to be considered.

In the experimental work, solution-cast poly(vinylidene difluoride) (PVDF) homopolymer PVDF films with high …

Monitoring The Reductive And Oxidative Half-Reactions Of A Flavin-Dependent Monooxygenase Using Stopped-Flow Spectrophotometry., Elvira Romero, Reeder Robinson, Pablo Sobrado

Chemistry Faculty Research & Creative Works

Aspergillus fumigatus siderophore A (SidA) is an FAD-containing monooxygenase that catalyzes the hydroxylation of ornithine in the biosynthesis of hydroxamate siderophores that are essential for virulence (e.g. ferricrocin or N", N'''-triacetylfusarinine C). The reaction catalyzed by SidA can be divided into reductive and oxidative half-reactions. In the reductive half-reaction, the oxidized FAD bound to Af SidA, is reduced by NADPH. In the oxidative half-reaction, the reduced cofactor reacts with molecular oxygen to form a C4a-hydroperoxyflavin intermediate, which transfers an oxygen atom to ornithine. Here, we describe a procedure to measure the rates and detect the different spectral forms of SidA …

Dual Active Bridge Converters In Solid State Transformers, Hengsi Qin

Doctoral Dissertations

"This dissertation presents a comprehensive study of Dual Active Bridge (DAB) converters for Solid State Transformers (SSTs). The first contribution is to propose an ac-ac DAB converter as a single stage SST. The proposed converter topology consists of two active H-bridges and one high-frequency transformer. Output voltage can be regulated when input voltage changes by phase shift modulation. Power is transferred from the leading bridge to the lagging bridge. It analyzes the steady-state operation and the range of zero-voltage switching. It develops a switch commutation scheme for the ac-ac DAB converters. Simulation and experiment results of a scaled down prototype …

Glycerin Reformation In High Temperature And Pressure Water, Jason W. Picou

Doctoral Dissertations

"The noncatalytic reformation of glycerin in supercritical water was studied in a Haynes 282 tubular reactor. In order to determine which parameters were the most influential, a 2³ experimental matrix was conducted, with temperatures of 500 and 700⁰C, water/glycerin molar ratios of 3:1 and 13:1, and residence times of 30 and 90 seconds, all at a pressure of 24 MPa. It was found that temperature had the largest effect on the two gasification parameters deemed most important, gasification percentage and hydrogen yield. Based on this, the effect of temperature was further investigated by looking at 5⁰C intervals from 500 to …

Organoclay Dispersion In Linear Low-Density Polyethylene And Maleated Linear Low-Density Polyethylene Via Supercritical Carbon Dioxide Processing, Matthew J. Factor

Doctoral Dissertations

"Research into polymer-clay nanocomposites (PCN's) has been ongoing for decades as a result of the property enhancements offered by clay. To fully exploit these property enhancements, organically modified clays (organoclays) are utilized to promote clay delamination by reducing the disparity between the hydrophilicity of the clay and the hydrophobicity of the highly used polyolefin polymer. Since the organic modification of organoclays can degrade at temperatures typical to many polymers during melt-mix processing, this work utilizes the low-temperature processing fluid supercritical carbon dioxide (scCO₂) to disperse an organoclay into the highly used polymer LLDPE and ascertains the associated processing conditions for …

Purification Of Metals Through Filtration And Electromagnetic Separation, Lucas Nana Wiredu Damoah

Doctoral Dissertations

"The applicability of a high frequency electromagnetic field to the removal of nonmetallic inclusions from silicon and aluminum, and the mechanism of depth mode filtration during aluminum purification were investigated. Electromagnetic separation experiments at frequencies of 63 - 120 kHz and aluminum filtration experiments using both conventional Al₂O₃ filters and AlF₃ coated Al₂O₃ filters were carried out by flowing molten aluminum through, and partly solidified in the filter bed followed by analysis of the metal and filter material. Materials were characterized with an optical microscope and macroscope, scanning electron microscope (SEM/EDX), x-ray diffraction (XRD), electron probe microanalysis (EPMA) and glow …

Thermal Properties Of Spinel Based Solid Solutions, Kelley R. Wilkerson

Doctoral Dissertations

"Solid solution formation in spinel based systems proved to be a viable approach to decreasing thermal conductivity. Samples with systematically varied additions of MgGa₂O₄ to MgAl₂O₄ were prepared and thermal diffusivity was measured using the laser ash technique. Additionally, heat capacity was measured using differential scanning calorimetry and modeled for the MgAl₂O₄-MgGa₂O₄ system. At 200⁰C thermal conductivity decreased 24% with a 5 mol% addition of MgGa₂O₄ to the system. The solid solution continued to decrease the thermal conductivity by 13% up to 1000⁰C with 5 mol% addition. The decrease in thermal conductivity ultimately resulted in a decrease in heat flux …

Modelling Interruptions Of Human-In-The Loop Tasks, Muhammet Servet Gulum

Doctoral Dissertations

"Interruptions are a part of our everyday experience and are increasingly becoming a part of our work. Systems are typically not designed with consideration of the effects of interrupting a user during a task sequence. Research is being done in the field of interruptions and its effects. There have been various claims about the effects of interruptions on human task performance. It has been shown that interruptions may not only increase the time to perform a task but also decrease the performance. It has also been analyzed that the effect of interruptions depends on many parameters including task complexity, point …

Adaptive Multi-Vehicle Area Coverage Optimization System And Method, Ryan J. Meuth, John Lyle Vian, Emad W. Saad, Donald C. Wunsch

Electrical and Computer Engineering Faculty Research & Creative Works

A system and method for dividing a predefined search region into a map of a plurality of subregions to be searched by a plurality of mobile platforms, taking into account the capabilities of the mobile platforms and varying environmental conditions within the subregions, while minimizing the time needed to search each of the subregions. The system and method updates the map of the subregions as needed, in real time, to account for changing environmental conditions and changes in the capabilities of the mobile platforms being used. The subregions may also be determined using a desired level of probability for detecting …

Investigation Of Polyurea-Crosslinked Silica Aerogels As A Neuronal Scaffold: A Pilot Study, Firouzeh Sabri, Judith A. Cole, M. Cody Scarbrough, Nicholas Leventis

Chemistry Faculty Research & Creative Works

Background: Polymer crosslinked aerogels are an attractive class of materials for future implant applications particularly as a biomaterial for the support of nerve growth. The low density and nano-porous structure of this material combined with large surface area, high mechanical strength, and tunable surface properties, make aerogels materials with a high potential in aiding repair of injuries of the peripheral nervous system. However, the interaction of neurons with aerogels remains to be investigated. Methodology: In this work the attachment and growth of neurons on clear polyurea crosslinked silica aerogels (PCSA) coated with: poly-L-lysine, basement membrane extract (BME), and laminin1 was …

Histological Evaluation Of The Biocompatibility Of Polyurea Crosslinked Silica Aerogel Implants In A Rat Model: A Pilot Study, Firouzeh Sabri, J. D. Boughter Jr., D. Gerth, O. Skalli, T. C. N. Phung, G. R. M. Tamula, Nicholas Leventis

Chemistry Faculty Research & Creative Works

Background: Aerogels are a versatile group of nanostructured/nanoporous materials with physical and chemical properties that can be adjusted to suit the application of interest. In terms of biomedical applications, aerogels are particularly suitable for implants such as membranes, tissue growth scaffolds, and nerve regeneration and guidance inserts. The mesoporous nature of aerogels can also be used for diffusion based release of drugs that are loaded during the drying stage of the material. From the variety of aerogels polyurea crosslinked silica aerogels have the most potential for future biomedical applications and are explored here. Methodology: This study assessed the short and …

Decreasing Time To Market For A Medical Device: New Methods For The Product Development Process, Kelly Marie Davis

Doctoral Dissertations

"Through an example, led at a leading medical device company, this dissertation will demonstrate that by applying certain lean principals and tools to the development of a medical device, shortened development times can be obtained. The two papers presented in the dissertation will fill a gap in current literature. Literature presents lean techniques and applications used in many different industries. But, due to the uniqueness of the medical device industry, these general techniques are not ideal. New methods will be used and validated at a medical device company, Covidien. Instead of trying to implement many general lean principals to their …

Development Of Third Generation Advanced High Strength Steels, Meghan C. Mcgrath

Doctoral Dissertations

"Lightweight duplex steels with combinations of either bainite, acicular ferrite, and austenite or martensite and austenite were investigated as third generation advanced high strength steels targeted for automotive applications. Large additions of manganese (>13 wt%) and carbon (

Duplex steels with different volume fractions of primary δ -ferrite were used to study the crystallography of austenite formed during the peritectic reaction. Solute profiles across the peritectic interface showed aluminum segregated near the interface which promoted bainitic ferrite formation. Thermal treatments were used to manipulate the concentration and type of oxides and the ferrite plate density was found to correlate …

Behavior Of Advanced Innovative Materials For Improved Long-Term Bridge Performance, Wei Zheng

Doctoral Dissertations

"The dissertation is to present the investigation results and comprehensive understanding of the long-term performance and behavior of innovative construction materials. The materials are applied in bridge engineering in order to either enhance the conventional materials or replace them. The dissertation consists of two major parts: structural steel coatings for corrosion mitigation and thermal behavior of concrete bridge.

In First Part, evaluation of advanced structural steel coatings was carried out through laboratory weathering tests (salt-fog resistance test and QUV weathering test), adhesion test, and electrochemical techniques. Fifteen coating systems were evaluated in this part, which covered both coating and recoating …

A Comparison Of Near-Infrared And Visible Imaging For Surveillance Applications, Kathryn Nicole Rodhouse

Masters Theses

"A computer vision approach is investigated which has low computational complexity and which compares near-infrared and visible image systems. The target application is a surveillance system for pedestrian and vehicular traffic. Near-infrared light has potential benefits including non-visible illumination requirements. Image-processing and intelligent classification algorithms for monitoring pedestrians are implemented in outdoor and indoor environments with frequent traffic. The image set collected consists of persons walking in the presence of foreground as well as background objects at different times during the day. Image sets with nonperson objects, e.g. bicycles and vehicles, are also considered. The complex, cluttered environments are highly …

Effects Of Coal Comminution In Relation To Waterjet And Selected Feed Properties, Yaqing Li

Masters Theses

"The necessity to develop a viable alternative to oil means that the development of coal-water fuels (CWF) has become increasingly important. However, the existing methods of comminution to prepare ultrafine particles for CWF are very inefficient. Consequently, a number of novel methods of comminution have been investigated in order to increase the efficiency of the process.

In this research, a new method of comminution using a high-pressure waterjet has been tested to produce ultrafine particle sizes necessary for efficient CWF process. To establish the fundamental performance of the waterjet mill, the influence of the operational pressure, standoff distance, feed size, …

Development Of A Technique For Testing Of Tensile Properties With Miniature Size Specimens For Metal Additive Manufacturing, Sujitkumar Dongare

Masters Theses

"The study of mechanical properties of metals provides a basis to decide on the capability of a particular metal for a task and also to make predictions about its life. The concepts of stress, strain and strength of materials are employed in practically every engineering discipline. Mechanical properties such as stiffness, yield strength, tensile strength, ductility, toughness, impact resistance, creep resistance, fatigue resistance and others, influence the design, fabrication and service life of equipment. Therefore, more than one property is considered for the material selection process for an application. For complete understanding of any material and its feasibility for a …

Pulmonary Fluid Dynamics And Aerosol Drug Delivery In The Upper Tracheobronchial Airways Under Mechanical Ventilation Conditions, Timothy Andrew Van Rhein

Masters Theses

"The effects of mechanical ventilation conditions on fluid flow and particle deposition were studied in a computer model of the human airways. The frequency with which aerosolized drugs are delivered to mechanically ventilated patients demonstrates the importance of understanding the effects that ventilation parameters have on particle deposition in the human airways. Past studies that modeled particle deposition in silico frequently used an idealized geometry with steady inlet conditions. With recent advancements in computational power and medical imaging capabilities, studies have begun to use more realistic geometries or unsteady inlet conditions that model normal breathing. This study focuses specifically on …

Locating Current Paths Via Time Synchronized Measurements In A Multiphase Dcdc Buck Converter And A High Frequency Analytical Model For The Common-Mode Impedance Of A Ferrite Choke, Peng Shao

Masters Theses

"In the first section, it introduces a novel method to localize current from multiple sources. The identification of return current paths is often a key element in understanding the root cause of a product's radiated emissions. In a complex system, multiple sources can contribute to the current at the same location and frequency. The source of the current can be identified by correlating the current to different sources. However, the multiphase buck converter phases do not switch at the same time. Thus, synchronizing to a specific phase makes it possible to determine how the current from a specific phase spreads …

Determination Of Linear Attenuation Coefficients Of Chemically Bonded Phosphate Ceramics, Jason Joseph Pleitt

Masters Theses

"Chemically Bonded Phosphate Ceramics (CBPCs) is a composite based material formed in a manner similar to cements. CBPCs have shown to be a good structural material with excellent thermal resistance properties. They have also been shown to have potential as a radiation shield. By incorporating various powders into the ceramic the improvement in its radiation shielding properties are examined. The method for obtaining the linear attenuation coefficients for CBPCs as well as MCNP simulated results for gamma and neutrons are presented"--Abstract, page iv.