Digital Commons Network^™

Electrochemically Active Molybdenum Phosphate With Open-Framework Structure, Sutapa Bhattacharya, Milad Aghayi-Anaraki, Nikolay Gerasimchuk, Steven P. Kelley, Amitava Choudhury

Chemistry Faculty Research & Creative Works

Somewhat less investigated, lithium ion containing molybdenum phosphate compounds are synthesized via simple template free hydrothermal method. Single-crystal X-ray diffraction (SCXRD) study reveals that the compounds Li_0.89Mo₂O_1.89F_0.11(PO₄)2(H₂PO₄)·xH₂O (x ≈1) and Li₃Mo₂O₂(PO₄)₃·xH₂O (x ≈1) crystallize in monoclinic C2/m and C2/c space group, respectively. The structures are built of alternate corner-sharing of MoO₆ octahedra and PO₄ tetrahedra forming layers, which are pillared by phosphate groups creating a 3D framework with channels. These …

Atomistic Mechanisms Of Ti3alc2 Etching: Oxidation, Surface Stability, And Selectivity, Valentina Nesterova, Ana Maria Stratulat, Walter Malone, Vadym Mochalin, Majid Beidaghi, Konstantin Klyukin

Chemistry Faculty Research & Creative Works

Mechanisms governing MAX-phase etching set the properties and stability of resulting MXenes, yet the details of this complex process remain poorly understood. Combining thermodynamic analysis of surface chemistries with ab initio molecular dynamics and enhanced free-energy sampling, we directly model elementary steps at the MAX/etching solution interface. We find that purely thermodynamic analysis overestimates etching selectivity, which is governed by the kinetics of elementary reaction steps. Our calculations reveal that initial exposure to water drives localized, thermodynamically favored edge oxidation that seeds MXene-like terminations into the uppermost layers of Ti₃AlC₂ with oxygen occupying the interlayer space between …

Reevaluating The Van’T Hoff And Arrhenius Equations: How Temperature And Pressure Affect Chemical Reaction Thermodynamics, Equilibrium, And Kinetics, Jianmin Wang

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The van’t Hoff equation, which is used to calculate the effect of temperature on equilibrium constants, was derived from the Gibbs – Helmholtz equation that relates the molar Gibbs free energy to the molar enthalpy of a chemical reaction. However, the Gibbs – Helmholtz equation was developed for systems that do not consider contributions of Gibbs free energy from chemical species. Consequently, the van’t Hoff equation and the Arrhenius equation derived from it are technically incomplete.

By employing Hess’s law and the appropriate Gibbs free energy equation for chemical reaction systems, this investigation develops theoretical equations to calculate the effects …

Deep Reinforcement Learning-Based Optimal Takeoff Trajectory Design Of An Evtol Drone, Nathan M. Roberts, Bingling Huang, Xiaosong Du

Mechanical and Aerospace Engineering Faculty Research & Creative Works

The continuing development of electric vertical take-off and landing (eVTOL) aircraft presents promising opportunities to alleviate transportation congestion. However, designing and executing takeoff trajectories that optimally balance energy usage, passenger comfort, and aircraft constraints remains challenging. Conventional design optimization provides a solution for pre-defined flight conditions and environments but is not ideal in real-world applications. In contrast, deep reinforcement learning (DRL) implements optimal policy making real-time decisions with no assumption of mathematical models. Seeing the lack of literature on DRL-based takeoff trajectory design of eVTOL aircraft, we implement and conduct DRL-based optimal takeoff trajectory designs for the Airbus³ Vahana …

Thermo-Rheological And Tribological Properties Of Low- And High-Oleic Vegetable Oils As Sustainable Bio-Based Lubricants, Abiodun Saka, Tobechukwu K. Abor, Anthony C. Okafor, Monday U. Okoronkwo

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Vegetable oil-based lubricants have attracted increased research attention in recent decades as sustainable alternatives to conventional petroleum-based lubricants in metal machining. However, more studies are required to fully elucidate the thermo-rheological and tribological properties. This study presents an investigation of the thermo-rheological and tribological properties of different vegetable oils, including low- and high-oleic soybean oil, high-oleic sunflower, safflower, and canola oils. The lubricity, and evolution of viscosity and thermodynamic properties as a function of temperature were investigated to obtain important parameters including the viscosity index, flow behavior index, flow activation energy, specific heat capacity, thermal conductivity, coefficient of friction, contact …

Ai-Powered Image-Based Assessment Of Pressure Injuries Using You Only Look Once (Yolo) Version 8 Models, Mehedi Hasan Tusar, Fateme Fayyazbakhsh, Niloofar Zendehdel, Eduard Mochalin, Igor Melnychuk, Lisa Gould, Ming C. Leu

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Objective: The primary objective of this study is to enhance the detection and staging of pressure injuries using machine learning capabilities for precise image analysis. This study explores the application of the You Only Look Once version 8 (YOLOv8) deep learning model for pressure injury staging. Approach: We prepared a high-quality, publicly available dataset to evaluate different variants of YOLOv8 (YOLOv8n, YOLOv8s, YOLOv8m, YOLOv8l, and YOLOv8x) and five optimizers (Adam, AdamW, NAdam, RAdam, and stochastic gradient descent) to determine the most effective configuration. We followed a simulation-based research approach, which is an extension of the Consolidated Standards of Reporting Trials …

Hands-Free Uav Control: Real-Time Eye Movement Detection Using Eog And Lstm Networks, Niloofar Zendehdel, Khosro Ghorbani Zadeh, Haodong Chen, Yun Seong Song, Ming C. Leu

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Industry 4.0 has created a growing need for effective human-robot collaboration (HRC). As robots and humans work more closely together, efficient communication becomes essential for coordinating their actions seamlessly. While speech may seem like the obvious choice for communication, noisy factory environments can render it impractical. Additionally, workers often have their hands occupied with assembly tasks, making hand-controlled interfaces less practical for controlling robots. To address these challenges, this paper presents a novel, hands-free method for robot control using electrooculography (EOG) signals–specifically, eye movements and blinks–with unmanned aerial vehicles (UAVs) used as the demonstration platform. We developed a real-time system …

Emi Mitigation, Material Characterization, Transformer Equivalent Circuit Modeling, Reza Vahdani

Masters Theses

Modern high-frequency electronic systems demand precise characterization and modeling techniques to ensure signal integrity and electromagnetic compatibility. This thesis presents three core studies focused on real-world challenges in high-speed and power electronics: EMI mitigation using 3D printed absorbers, wideband liquid dielectric characterization, and accurate transformer modeling.

The first study demonstrates a targeted approach to mitigating electromagnetic interference (EMI) in a commercial router. By using holography imaging to identify radiation hotspots, custom absorber structures were designed with commercially available materials, fabricated via 3D printing, and applied directly to emission sources. Radiated emission tests in a reverberation chamber showed up to 9 …

Hyper B-Ary Representations Of A Number, Mingway Wang

Masters Theses

In this work, we summarize combinatorial, analytical, and computational properties of Stern's diatomic sequence, and do the same for a generalization of a combinatorial property of this sequence to higher bases. We then construct special ``bit conversion'' functions $g_{b}$ that allows us to find a semi-explicit formula for the generalized sequences. Lastly, we analyze some of the properties of these $g_{b}$ functions.

Using Preformed Particle Gels To Control Transport In Geothermal Reservoirs: Mathematical Modeling, Philip Winterfeld, Baojun Bai, Yu Shu Wu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

We are developing swellable Preformed Particle Gels (PPG), which can control preferential fluid and heat flow through fracture networks to increase the performance of EGS reservoirs. Part of this development is a mathematical model and numerical simulator to simulate PPG treatments by considering coupled thermal-hydraulic-mechanical effects, and gel swelling kinetics and plugging efficiency, from which an optimized gel treatment design and operation can be achieved. The starting point for our mathematical model is the TOUGH2-CSM formulation and code. The TOUGH2-CSM fluid and heat flow formulation is based on the TOUGH2 one for multiphase, multicomponent, and multi-porosity systems, with the latter …

Predictive Modeling For Optimal Gel Treatment Design In Brownfields Using Ensemble Machine Learning And Data Upsampling Via Generative Ai, Munqith Aldhaheri, Baojun Bai, Mingzhen Wei

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Efficiently designed gel treatments play a vital role in extending the lifespan of brownfields through rejuvenating oil production. Recently, a three-mode mathematical methodology named the VCR approach has been proposed for designing effective treatments. To optimize this approach, it is crucial to determine the appropriate design mode systematically rather than relying solely on the intuitive judgments of field operators. This study introduces an advanced methodology for predicting the optimal design type of gel treatments using 12 reservoir and production variables. The methodology integrates ensemble machine-learning (EML) models with historical data from 65 field projects across 11 countries (1985-2020). The Random …

Identifying Potential Risk Areas Close To The Oil And Gas Pipelines Due To Subsidence In Qazvin Plain, Mahmoud Rajabi, Sanaz Vajedian, Ryan Smith, Neil Grigg, Hossein Nahavandchi, Mehdi Goli

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Surface displacement caused by natural and anthropogenic activities poses a significant risk to subsurface pipelines, particularly in areas experiencing subsidence. Stress and strain induced by deformation can lead to pipeline buckling and potential vulnerability. This study applies a multidisciplinary approach integrating interferometric synthetic aperture radar (InSAR) deformation analysis, well data, and geological context to assess the risk to oil and gas pipelines in Iran's Qazvin plain. The focus is on evaluating the impact of an unconfined aquifer, which has a lower risk of subsidence compared to a confined aquifer, on pipeline infrastructure. We analyzed multitemporal Sentinel-1 data collected between 2014 …

Individual Design Task Final Report Security Design, Ciarrah Bell

Honors Academy

"The Environmental Services Campus project is a comprehensive development designed to support the City of Springfield’s Environmental Services operations, with a focus on functionality, sustainability, and safety. The campus includes administrative office space, staff parking, a maintenance vehicle garage, and educational facilities aimed at community outreach. A component of the project is establishing site-wide security that not only protects personnel and assets but also integrates seamlessly with the architectural and environmental goals of the facility.

The primary focus of the Security IDT is the development and implementation of a comprehensive security strategy for the entire site. This includes designing and …

Evaluation Of The Impact Of Secondhand E-Cigarette Aerosols On Ros-Mediated Alterations Of Epigenetic Events: Implications For Copd Pathogenesis And Assessment Of The Efficacy Of Cold Atmospheric Plasma In Degrading Organophosphate Pesticides On Kevlar Materials, Ta-Chun Lin

Masters Theses

"We explored 1) the toxicological impacts of e-cigarette aerosols and 2) the decontamination efficacy of Cold Atmospheric Plasma (CAP) technology over organophosphates. In examining the effects of firsthand and secondhand e-cigarette aerosol exposure on A549 and BEAS-2B lung cells, we observed significant cytotoxicity, increased ROS levels, and epigenetic modifications, including heightened DNA methylation and downregulation of histone deacetylases (HDACs). These molecular alterations may contribute to chronic respiratory conditions, such as COPD, underscoring the health risks of e-cigarette exposure.

We investigated CAP’s effectiveness in degrading organophosphate pesticide (OP) residues on fabric surfaces, revealing that CAP treatment effectively decomposes OPs such as …

Automated Generation Of Malware Metadata Signatures, Joel Schott

Masters Theses

In advanced, targeted malware attacks, the custom software tools used to package and send malicious files and messages can lead to distinctive metadata values that facilitate creation of a malware metadata signature. Manual creation of these signatures requires expert domain knowledge and is time-consuming and error-prone. Our goal is to automate this process. We created several methods of automatically generating malware metadata signatures for ZIP files and emails. We evaluated these methods by comparing signatures generated with these methods to existing expert-created signatures. We found automated methods for ZIP files and emails that are capable of generating metadata signatures that …

Influence Of Alloy Composition On The Process Robustness Of Steels Consolidated Via Laser-Directed Energy Deposition, Jonathan Kelley

Masters Theses

"To ensure consistent quality of additively manufactured parts, it is advantageous to identify alloys which can meet performance criteria while being robust to process variations. Toward this end, this work investigated the effect of alloy composition on the robustness of steels consolidated via laser-directed energy deposition (L-DED). Ultra-high-strength low-alloy steel (UHSLA) and pure iron powders were mixed in-situ to produce 10 compositions containing 10-100% UHSLA by mass. JMatPro material simulations roughly predicted phases and mechanical properties. Two sets of experiments were used to evaluate the sensitivity of as-built hardness (all 10 compositions) and tensile properties (5 select compositions) to process …

Modeling Of Slot-Backed Microstrip Line For Emi Applications, Jongsuk Hyun

Masters Theses

Radiated emissions from printed circuit boards (PCBs) are a significant concern in electromagnetic interference (EMI) and radio frequency interference (RFI). Shielding cans are widely used to mitigate these emissions but evaluating requires accurate characterization of equivalent noise sources. Slot-backed microstrip antennas are employed for this purpose due to their near-zero height, low parasitic radiation, and PCB-compatible structure, offering a practical alternative to conventional loop antennas. This paper presents a physics-based analytical model that integrates both the discontinuity effects and radiated characteristics of slot-backed microstrip structures within a unified circuit framework. An analytical expression for the dipole moment is proposed based …

Gfrp Reinforced Bridge Barriers: Experiment Testing, Manish Kumar Gadhe

Masters Theses

This study focused on evaluating the performance of concrete bridge barriers reinforced with Glass Fiber Reinforced Polymer (GFRP) compared to those reinforced with conventional mild steel. Four full-scale barriers were constructed, three using GFRP bars as the reinforcement and one with mild steel reinforcement. These were cast on two concrete slabs to ensure consistent support conditions. The use of GFRP aims to address durability concerns associated with steel reinforced concrete (RC), particularly corrosion of these bars in harsh environments.

To simulate real-world impact scenarios, a weighted cart was launched at each barrier using a guided sled system. Sensors, including load …

Development Of A Method To Measure Blast Overpressure Exposure Using Orthogonal Sensor Orientations, Nicholas Kuehl

Masters Theses

Measuring and recording blast exposure to military personnel from shoulder-fired weaponry or improvised explosive devices to correlate health outcomes like mild traumatic brain injury has been a goal for many years. As such, many wearable sensors have been developed and tested for accuracy and reliability. Despite this, knowing the sensor orientation in relation to the blast source is important to fully correlate the actual personnel exposure to clinical outcomes. This research investigates whether pressures recorded at three independent orientations in the x, y and z planes can be combined to a representative pressure that is independent of orientation. Important metrics …

An Experimental Study Into The Methods Of Water Coupling And Their Impact On Kinetic Energy And Blast Over Pressure Through The Use Of A Ballistic Pendulum, Jeremiah Alan Cohn

Masters Theses

Water coupled charges utilize the material properties of water to alter their behavior for reductions in overpressure and increases in kinetic energy. Although water coupling has been studied directly, combined usage of the two primary methods of water coupling, tamping and pushing, hinders further research. This study addresses the gap in literature by comparing ballistic pendulum and blast data for charges with water tamping and pushing to determine differences in kinetic energy, peak overpressure, impulse, noise and duration of fireball. The results showed that water tamping provided a 69.1% increase in kinetic energy, an 18.6% reduction in incident overpressure, a …

Biological Computing From Microscopic To Macroscopic Evolution, Xiaofeng Ding

Masters Theses

A unified theory from microscopic to macroscopic DNA-based biological systems is explained in terms of the rule components used when the system size is increased. Even though the eight female rules in each ruleset are provided with an equal probability of the computation-state outcomes, the initial ensemble of the computation states will exponentially settle into one dominant rule that supports the nutrition needed for growth. The remaining seven rules form into two minority groups to provide the biological characteristics of the system's growth from a micro to macroscopic evolution. The object of this study is to prove that such a …

Mechanistic Scale-Up Of Gas-Solid Fluidized Beds Via Local Hydrodynamic Similarity, Faraj M. Zaid, Thaar M. Aljuwaya, Muthanna H. Al-Dahhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

This study presents a detailed experimental evaluation of a newly developed mechanistic scale-up methodology for gas-solid fluidized beds. Traditional scale-up approaches typically rely on matching global dimensionless groups, which often fail to ensure local hydrodynamic similarity. In contrast, the new mechanistic method aims to achieve scale-up by matching the radial profiles of gas holdup between geometrically similar beds at corresponding dimensionless axial positions (z/D_c). This approach is based on the premise that when gas holdup profiles align, other key hydrodynamic parameters—such as solids holdup and particle velocity—also become similar. To validate this methodology, experiments were conducted in two …

Tricatalytic Organocatalyst-Enzyme Hybrid Cascade For Improving Complete Oxidation Of Glucose To Carbon Dioxide, Adam Milam, Rokas Gerulskis, Jose Intano, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

Advancing energy harvesting is crucial for the development of wearable and implantable technologies. Given the high concentration of complex fuels, such as glucose, in biological fluids, biofuel cells present a promising avenue for exploration. However, glucose fuel cells that have been published to date typically catalyze only one or two of the maximum 12 oxidation steps for glucose, resulting in low energy density. Although known multienzyme cascades, which are sequential biochemical reactions where multiple enzymes work in tandem to convert a substrate into a final product, have addressed this inefficiency, they come with several trade-offs, such as reduced power density …

Virtual Network Embedding: Literature Assessment, Recent Advancements, Opportunities, And Challenges, Anurag Satpathy, Manmath Narayan Sahoo, Chittaranjan Swain, Paolo Bellavista, Mohsen Guizani, Khan Muhammad, Sambit Bakshi

Computer Science Faculty Research & Creative Works

Network virtualization (NV) allows service providers (SPs) to instantiate logically isolated entities called virtual networks (VNs) on top of a substrate network (SN). Though VNs bring about multiple benefits, particularly in terms of economic costs and elasticity, they also force various technical challenges to be addressed. The primary one is the issue of optimally allocating resources to VNs, also termed virtual network embedding (VNE). This paper presents an exhaustive survey of VNE by extensively covering the state-of-the-art research field in this very active field and focusing on the emerging research trends in industry and academia over the last decade. In …

Citrus: Cost And Ischemia Time Reduction Using Urban Air Mobility Solutions For Organ Transport, Debjyoti Sengupta, Anurag Satpathy, Arindam Khanda, Sajal K. Das

Computer Science Faculty Research & Creative Works

Urban Air Mobility (UAM) involves the use of both piloted and autonomous aerial vehicles, ranging from small unmanned aerial vehicles (UAVs), such as drones, to larger passenger-carrying personal air vehicles (PAVs). This ground-breaking approach holds the potential to transform healthcare logistics by facilitating the fast and efficient transportation of organs between hospitals, addressing critical mobility challenges in healthcare delivery. However, scheduling organ transport is fraught with challenges, including (1) the limited availability of UAM vehicles at specific hospital branches, (2) the critical Cold Ischemia Time (CIT) for various organs, and (3) the high flying costs associated with moving organs from …

Content Subversion Against 1 Information-Based Systems, Junjie Xiong, Ian Markwood, Dakun Shen, Yao Liu, Zhuo Lu

Computer Science Faculty Research & Creative Works

We present a novel class of content subversion attacks against information-based services, causing documents to appear to humans dissimilar to the underlying content extracted by information-based services. We demonstrate the significant impact of these attacks on real-world systems through five distinct variants. Our first attack allows academic paper writers and reviewers to collude via subverting the automatic reviewer assignment systems in current use by academic conferences including INFOCOM, which we reproduced. Our second attack renders ineffective plagiarism detection software, particularly Turnitin, targeting specific small plagiarism similarity scores to appear natural and evade detection. In our third attack, we place masked …

Applications Of Uav In Landslide Research: A Review, Boneng Chen, Jeremy Maurer, Weibing Gong

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Uncrewed aerial vehicles (UAVs), commonly known as drones, have gained significant popularity in landslide research due to their operational flexibility, near real-time planning capabilities, cost-effectiveness, high-resolution data outputs, and enhanced safety. This review aims to provide an analysis of UAV-based landslide investigation methodologies and their applications. It begins with an examination of UAV platforms and UAV-equipped sensors employed in landslide research, evaluating their advantages and limitations to guide appropriate platform and sensor selection. The review then explores UAV applications across three primary landslide investigation domains: landslide mapping, landslide monitoring, and landslide hazard assessment, highlighting some representative achievements in each domain. …

Visual Understanding Of Rock Wettability Distribution To Contact Angle Regions And Oil Displacement Patterns In The Silty Sand Reservoir Via 2d Pore-Scale Modeling, H. Al-Ajaj, W. Al-Bazzaz, Ralph E. Flori, S. Alsayegh, H. Almubarak, D. S. Ibrahim, H. Al-Saedi

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

This study, conducted using a silty sand reservoir rock extracted from a Kuwait-producing oilfield, provides crucial insights into fluid distribution patterns and mineralogy, as well as wettability contact angle preferences. The method used for visual identification not only captures rock physics but also suggests effective oil recovery displacement strategies. Visual identification is presented using 2D image technology and a Scanning Electron Microscope (SEM). Analytical data are presented from electron bombardments and backscattering reflections collected in the BSE detector. These analyses were used to characterize the various surface boundary morphology parameters of the silty sand mineral surfaces, including area, perimeter, mineral …

Integration Of Physics-Informed Neural Networks And Transfer Learning For Rainfall Induced Landslide Forecasting, Shian Cao, Weibing Gong

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Rainfall-induced landslides are a significant geological hazard, causing severe economic losses and casualties. Accurate forecasting of these events is particularly challenging due to the complex interactions of spatial and temporal factors governing slope stability. The Iverson model, which uses the Richards equation to describe water infiltration in unsaturated soils, is a widely adopted framework for analyzing rainfall-induced landslides. However, its reliance on traditional numerical methods limits its scalability and efficiency, particularly for complex boundary conditions and transient behaviors near slope failure. To address these limitations, we propose a physics-informed neural network (PINN) enhanced with transfer learning (TL-PINN) to solve the …

Investigation Of Dynamic Adsorption And Desorption Of Polymer Nanogel In Porous Media Through Microfluidics, Junchen Liu, Fuqiao Bai, Abdulaziz A. Almakimi, Mingzhen Wei, Xiaoming He, Ibnelwaleed A. Hussein, Baojun Bai

Mathematics and Statistics Faculty Research & Creative Works

Understanding the transport and retention of elastic nanogel and microgel particles in porous media has been a significant research subject for decades, essential to the application of enhanced oil recovery (EOR). However, a lack of dynamic adsorption and desorption studies, in which the kinetics in porous media are seldom investigated, hinders the design and application of polymer nanogel in underground porous media. In this work, we visualized and quantified the transport and dynamic adsorption of polymer nanogel in 3D glass micromodels that were manufactured by packing glass beads in capillaries. Calibrating the linearity of fluorescence intensity to concentration, we calculated …