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Development Of Stalling Detection Algorithms And Operator Behavior Models For Evaluating Hydraulic Excavator Performance, Mateo Fernando Montenegro Defaz Jan 2025

Development Of Stalling Detection Algorithms And Operator Behavior Models For Evaluating Hydraulic Excavator Performance, Mateo Fernando Montenegro Defaz

Masters Theses

This study aims to develop a reliable algorithm for stalling detection and investigate how operator behaviors impact the truck-loading process, focusing on swing and bucket rotations. While the study of excavator digging conditions and equipment performance is well understood, describing stalling from telemetry data and the influence of operators’ behavior on overall system efficiency remain underexplored. This study seeks to: (i) develop a reliable algorithm for stall detection by analyzing key operational variables such as velocity and angles; (ii) implement statistical and machine learning techniques, specifically a Support Vector Machine (SVM) classification algorithm, to differentiate between ideal and non-ideal digging …


Overall Tropospheric Noise Over The St. Louis Using Isce And Fringe Processing, Maryann Lee Jan 2025

Overall Tropospheric Noise Over The St. Louis Using Isce And Fringe Processing, Maryann Lee

Masters Theses

Interferometric Synthetic Aperture Radar (InSAR) is a satellite-based technique that is used to measure various aspects such as ground deformation, earthquakes, volcanic activity, and motions of glaciers. Although the technique has proved very useful, measurements errors such as ionospheric and tropospheric noise, and deformation often cause problems with making precise measurements. InSAR is a tool used in geodesy that is used to measure the change of surface deformation over time through a series of repeated SAR acquisitions. These errors in the acquisitions occur from factors of signal decorrelation, atmospheric delays, and phase unwrapping errors that affect the accuracy and precision …


Frequency-Tracker And Power Supply For Piezoelectric Lunar Dust Removal Actuator, Praneeth Uddarraju Jan 2025

Frequency-Tracker And Power Supply For Piezoelectric Lunar Dust Removal Actuator, Praneeth Uddarraju

Masters Theses

"This work presents a reconfigurable phase-locked loop (PLL)-based control system for the resonant excitation of piezoelectric actuators aimed at automated removal of particulate contaminants from photovoltaic (PV) surfaces—particularly in extraterrestrial environments such as the lunar surface. Regolith or lunar dust buildup on solar panels is a serious hazard to the effectiveness of energy harvesting on extended missions. By using high-frequency structural excitation and inertial forces the suggested system removes surface impurities. Tunable Sallen-Key low-pass filters for reliable feedback conditioning are used in conjunction with a digitally implemented PLL on an FPGA (XLR8 platform) to precisely lock the drive frequency to …


Design Of A Spacecraft Power System Experiment, Jay Bakulkumar Kamdar Jan 2025

Design Of A Spacecraft Power System Experiment, Jay Bakulkumar Kamdar

Masters Theses

This research delves into the design, implementation, and analysis of a controlled experimental framework for photovoltaic cell characterization and its application in spacecraft power systems. Such a system was simulated and validated by benchmarking characteristics of a photovoltaic module and implementing them in a system design simulation yielding performance data for comparative analysis. A hardware setup was developed to perform IV characterization tests under steady state thermal conditions. Experiments conducted across various thermal regulation profiles helped quantify the effects of temperature on the photovoltaic performance parameters. Active cooling reduced the steady state cell temperature by 17.9% and improved the cell …


Enabling Drone-Integrated Active Microwave Thermography Via A Slot Antenna Design, Alec P. Fitzmaurice Jan 2025

Enabling Drone-Integrated Active Microwave Thermography Via A Slot Antenna Design, Alec P. Fitzmaurice

Masters Theses

Civil infrastructure inspection quality and inspector safety may be enhanced from the advancement in the capabilities of nondestructive testing and evaluation of remote or otherwise hard-to-reach areas such as nuclear power plants, wind turbines, bridges, or other civil infrastructure using drone-based Active Microwave Thermography (AMT). AMT is a nondestructive testing technique that utilizes high frequency energy (often radiated from an antenna) to induce heating in a specimen. Following this thermal excitation, an infrared camera is used to measure the resulting surface thermal profile. From this, defect indications may be detected. To enable drone-based deployment of AMT, where the antenna size …


Performance Of Standard Medical Mllms On Ecg Image Data, Prisha Anil Jan 2025

Performance Of Standard Medical Mllms On Ecg Image Data, Prisha Anil

Masters Theses

This work presents a structured benchmarking study of multimodal large language models (MLLMs) applied to electrocardiogram (ECG) interpretation tasks. We evaluate three representative architectures: MedGemma, HuatuoGPT-Vision, and LLaVA-Med, across progressive experimental stages involving text-only structured prompt normalization, text–image fusion with ECG plots, and full multimodal fusion incorporating time-series signals. A standardized five-section cardiology prompt was designed to enforce consistent output structure and SCP-code alignment, enabling reproducible metric computation across models. Quantitative evaluation using BERTScore, token-level F1, and diagnostic accuracy demonstrates that HuatuoGPT-Vision achieves the highest semantic and diagnostic alignment, while MedGemma exhibits superior formatting stability and reproducibility. In contrast, LLaVA-Med …


Investigation Of Arm Stiffness Modulation During Overground Physical Human-Human Interaction, Henry Tien Jan 2025

Investigation Of Arm Stiffness Modulation During Overground Physical Human-Human Interaction, Henry Tien

Masters Theses

The vision of advancing robots capable of direct physical engagement with humans begins with an understanding of how humans interact with each other. Even rudimentary interactive tasks, such as shaking hands, provides tremendous challenges for modern robotics and current research into the biomechanics of such interactions is limited. Thus, further analysis of physical Human-Human Interaction (pHHI) will bolster efforts to enhance collaborative robot capabilities. To this end, a custom Force Perturbation Handle (FPH) was developed, including the requisite mechanical, electrical, and software systems, to investigate the unique role of arm stiffness modulation in haptic communication between humans. The novel device …


Aerodynamic Design Workflow Optimization For Fsae: Advanced Cfd And Hpc Automation, Kyle Maynor Jan 2025

Aerodynamic Design Workflow Optimization For Fsae: Advanced Cfd And Hpc Automation, Kyle Maynor

Masters Theses

This research identifies and resolves inefficiencies in the Computational Fluid Dynamics (CFD) workflow of the Missouri S&T Racing Formula SAE Team’s aerodynamic development. Key bottlenecks were found in simulation runtime, laborious simulation preparation, an overly manual simulation submission process, and unchecked mesh quality. A fully reimagined workflow was implemented with simulation parameters to adjust vehicle attitudes. From this, an automated design sweep could be executed to generate aero maps of the developing vehicle using the Design Manager Project. A Python-based submission app handles the terminal interfacing and macro editing that significantly slowed the job submission process before. Using a university …


Multimodal Spatio-Temporal Pest Prediction In Precision Agriculture, V N S Kameswari Sri Sindhu Manchikanti Jan 2025

Multimodal Spatio-Temporal Pest Prediction In Precision Agriculture, V N S Kameswari Sri Sindhu Manchikanti

Masters Theses

Accurate and timely prediction of pest outbreaks is a cornerstone of Agriculture 5.0, which emphasizes intelligent, data-driven, and sustainable decision-making in crop production. This research presents a multimodal deep learning framework that integrates heterogeneous data sources, including weather parameters, satellite-derived vegetation indices, and static and dynamic soil attributes, to forecast pest population dynamics under varying management and ecological conditions. The proposed framework employs modality-specific deep encoders to capture distinct temporal and spatial representations from each data stream and merges them through a late-fusion architecture that learns cross-modal dependencies critical to pest emergence. The design further incorporates treatment-aware and multiclass extensions, …


Extraction And Separation Of Metal Cations From Synthetic Acidic Solutions Using Emulsion Liquid Membrane, Nouhaila Filali Jan 2025

Extraction And Separation Of Metal Cations From Synthetic Acidic Solutions Using Emulsion Liquid Membrane, Nouhaila Filali

Masters Theses

The work is organized into two main papers supported by experimental and comparative studies using Emulsion Liquid Membrane (ELM) systems. The first paper explores the individual extraction of heavy metals (Cd, Cr, As, Ni) from synthetic phosphoric acid using Alamine 336 and D2EHPA as carriers. Alamine 336 achieved the highest extraction efficiency (>90%) and stability, offering a promising route to reduce toxic impurities in fertilizer-grade acid. The second paper examines the selective separation of Ni2+ and Co2+ from various acidic solutions using the ELM configuration. Systematic variation of carriers, stripping agent and feed acidity, clarified transport mechanisms and stability, …


Selective Surface Activation And Flotation Of Pyrite For The Recovery Of Tellurium From Sulfide Tailings, Mulenga Mutema Chibesa Jan 2025

Selective Surface Activation And Flotation Of Pyrite For The Recovery Of Tellurium From Sulfide Tailings, Mulenga Mutema Chibesa

Masters Theses

Copper sulfide tailings from past and present mining operations are important secondary sources of critical elements such as tellurium (Te), a key component in cadmium–telluride photovoltaic solar cells. Characterization of tailing streams from copper porphyry (CP) ore flotation revealed that Te-bearing minerals are predominantly hosted in pyrite, which is usually depressed and discarded. Enhancing pyrite recovery is therefore a critical first step toward concentrating Te minerals for downstream extraction. However, pyrite flotation is often hindered by hydrophilic surface complexes formed during prior processing. This research investigated selective flotation of Te-bearing pyrite from CP tailings using micro flotation and bench-scale flotation, …


Application Of Edge-Enhanced Phase Analysis To Active Microwave Thermographic Measurements, Douglas Blaine Fleetwood Jan 2025

Application Of Edge-Enhanced Phase Analysis To Active Microwave Thermographic Measurements, Douglas Blaine Fleetwood

Masters Theses

Nondestructive testing and evaluation (NDT&E) encompasses a range of inspection techniques that assess materials, components, and structures while maintaining their integrity and performance. Among these techniques, thermography is particularly attractive due to its non-contact imaging approach with easy-to-interpret results. Active Microwave Thermography (AMT) has emerged as a promising NDT&E inspection technique that utilizes electromagnetic energy to heat materials through dielectric and magnetic absorption, with subsequent infrared imaging used to detect subsurface defects. While AMT offers significant advantages including material-specific heating optimization and lower power requirements compared to conventional thermographic methods, the technique faces a persistent challenge related to the thermal …


Design Of Real-Time And Energy-Efficient Driver Assist Systems Using Electroencephalogram And Neuromorphic Computing, Nathan Alan Lutes Jan 2025

Design Of Real-Time And Energy-Efficient Driver Assist Systems Using Electroencephalogram And Neuromorphic Computing, Nathan Alan Lutes

Doctoral Dissertations

Despite the technological breakthroughs in advanced driver assist systems, distracted driving persists as a major challenge to roadway safety. This investigation advances the body of knowledge towards a solution by developing an individualized driver-state detection method using electroencephalogram (EEG) and neuromorphic computing to provide a less invasive and more energy efficient ADAS solution. It furthermore explores the changes in brain functional connectivity under distracted conditions to better understand brain state information that could be used for neuro-feedback intervention systems. The first contribution introduces the concept of using Convolutional Spiking Neural Networks (CSNNs) for recognition of patterns with movement-intention predictive power …


Synthesis And Analysis Of Materials For Quantum Devices, Mathew Pollard Jan 2025

Synthesis And Analysis Of Materials For Quantum Devices, Mathew Pollard

Doctoral Dissertations

Quantum materials play a pivotal role in the advancement of next-generation technology. Superconducting quantum computing, dissipationless spintronics, or valleytronics offer promising ways forward beyond traditional chip miniaturization. Josephson Junctions (JJs) have already revolutionized quantum information and high precision detectors. Quantum systems, however, are either hard to control, produce, and/or maintain. This calls for a better understanding of microscopic properties and tuning of these quantum states.

In this work, we experimentally investigated growth methods to control the electric and magnetic properties of Topological Insulator (TI) Sb2Te3 through Cr-doping. Our results demonstrate the onset of a Magnetic Topological Insulator (MTI) and have …


Higher-Order Statistics And Normalized Decay Analysis For Detector Deadtime Characterization, Abdallah Wazzan Jan 2025

Higher-Order Statistics And Normalized Decay Analysis For Detector Deadtime Characterization, Abdallah Wazzan

Doctoral Dissertations

Detector deadtime limits radiation measurement accuracy at high count rates, yet current methods rely on idealized paralyzable or non-paralyzable models. Real detectors exhibit hybrid behavior requiring advanced characterization approaches. This study explores deadtime characterization using two Monte Carlo simulation approaches: higher-order statistical analysis of inter-arrival times and simplified deadtime correction with hybrid models.

Using MATLAB (PULSE-WIZ), we analyzed full decay curves spanning ~4.5 half-lives of Cobalt-60 and Vanadium-52, examining coefficient of variation (CV), skewness, and kurtosis of inter-arrival times, plus normalized decay curves with Full Width at Half Maximum (FWHM) analysis. Hybrid models incorporated paralyzable and non-paralyzable components with dead …


Tailoring Selected Aerogels To Targeted Applications, Stephen Yaw Owusu Jan 2025

Tailoring Selected Aerogels To Targeted Applications, Stephen Yaw Owusu

Doctoral Dissertations

Aerogels are ultra-lightweight, porous solid materials characterized by a three-dimensional nanostructured network. Owing to their exceptional physical and chemical properties, aerogels have garnered considerable attention within the materials science community and were recognized by IUPAC in 2022 as one of the top ten emerging technologies in chemistry. Although numerous aerogels have been synthesized, only a few have been effectively tailored for specific applications. Optimizing the properties of known aerogels for targeted uses remains challenging. This dissertation investigates strategies for tailoring aerogels derived from isocyanate-benzoxazine, benzodiazine, and phenolic resins to meet the requirements of various advanced applications. The approaches employed include …


Characterization And Deportment Of Anode Impurities In Copper Electrorefining, Charles Michael Campbell Jan 2025

Characterization And Deportment Of Anode Impurities In Copper Electrorefining, Charles Michael Campbell

Doctoral Dissertations

The objective of this research was to study the deportment of the group 15 elements, arsenic, antimony and bismuth during copper electrorefining. Samples were collected from six industrial copper anodes with different compositions. Specimens were physically characterized and electro refined to understand the differences in the behavior of selected impurities. Inclusions in the cast metal structures were characterized using automated scanning electron microscopy and energy dispersive spectroscopy to measure and correlate their size, shape and composition. Arsenic and lead were found to have a positive correlation between concentration and size of inclusions. Using wavelength dispersive spectroscopy, multiphase inclusions were examined, …


Machine Learning Models For Location Prediction, Message Routing And Path Planning For Rescue Of Underground Miners, Abhay Goyal Jan 2025

Machine Learning Models For Location Prediction, Message Routing And Path Planning For Rescue Of Underground Miners, Abhay Goyal

Doctoral Dissertations

Self-rescue during underground mine disasters is vital for miner safety. Evolving hazards and post-disaster conditions demand solutions that enable navigation under severe communication and computational constraints. Centralized systems often fail in such rugged settings, while decentralized methods—particularly Delay Tolerant Networks (DTNs), proven in battlefields and space missions—offer distinct advantages for underground applications. This research addresses five core challenges: (i) predicting miners’ next locations on low-power devices using points of interest and movement sequences; (ii) delivering timely updates on safe routes, evacuation zones, and hazardous areas; (iii) evaluating energy efficiency and comparing graph-based approaches to existing methods; (iv) enabling edge-ready frameworks, …


Generalizations Of Finiteness Conditions And Extension Monads In Algebras With Infinitely Many Or Infinitary Operations, Danielle Christienne Bowerman Jan 2025

Generalizations Of Finiteness Conditions And Extension Monads In Algebras With Infinitely Many Or Infinitary Operations, Danielle Christienne Bowerman

Doctoral Dissertations

In this work, we extend the results of finiteness conditions and extension monads found in Insall from finitely many finitary operations to infinitely many finitary operations, as well as touching on infinitary operations. We also examine varieties of algebras, including the notion of strong varieties introduced in Insall, and common constructions of extension monads in varieties of algebras. We see that for finite collections of algebras of the same signature, the extension monad operation on a variety of algebras commutes with the direct product operation, and all retractions from an enlargement or extension monad are trivial. We also see that …


Applying Human System Integration Principles To The Investigation, Design And Validation Of Interventions For Self-Escape In Underground Mines, Eugene Adubofour Gyawu Jan 2025

Applying Human System Integration Principles To The Investigation, Design And Validation Of Interventions For Self-Escape In Underground Mines, Eugene Adubofour Gyawu

Doctoral Dissertations

This dissertation investigates the use of human systems integration (HSI) to develop technologies for miners’ self-escape during a mine emergency, addressing barriers that compromise miner safety during emergencies.

Recognizing the inherently hazardous nature of underground mining, this study has three core objectives: (1) assessing miners' perceptions of proposed self-escape interventions, (2) designing interventions based on these insights, and (3) validating their effectiveness using experimental testing. This work evaluates self-escape interventions for both coal and metal/non-metal miners using scenario-based surveys, information design reviews, label designs and experimental testing methods varying across three distinct studies.

Results reveal that miners identified improvements to …


Quantum And Classical Phase Transitions In Disordered Systems, Gaurav Ramesh Khairnar Jan 2025

Quantum And Classical Phase Transitions In Disordered Systems, Gaurav Ramesh Khairnar

Doctoral Dissertations

This work examines the effects of quenched disorder on classical and quantum phase transitions. There are countless examples of phase transitions in nature. Here, we study phase transitions in condensed matter with the help of simple models that focus on the essential unifying features of the problems. We are particularly interested in investigating how the presence of disorder changes the behavior of the system in the vicinity of a phase transition.

Here, we discuss three closely related problems regarding phase transitions. First we consider the behavior of highly diluted magnets with varying dilution levels in order to explain the unusual …


Experimental Study Of Defects In Coaxial Wire-Based Laser Metal Deposition, Remy Mathenia Jan 2025

Experimental Study Of Defects In Coaxial Wire-Based Laser Metal Deposition, Remy Mathenia

Doctoral Dissertations

This work seeks to improve the usability and capability of coaxial wire-based laser metal deposition (LMD) through the experimental study of process parameters on output geometry, directional effects, and defect formation. Wire-based LMD is a directed energy deposition (DED) strategy that uses a focused laser heat source to melt and fuse metal wire as it is deposited. This process is used to build parts layer-by-layer until a desired geometry is accomplished. LMD enables the creation of complex components at a high build rate with low material and energy waste. This work focuses on the deposition of titanium wire in the …


Development Of Dual-Scan Nuclear Magnetic Resonance (Nmr) Pulse Programs For Spin-Lattice Relaxation Measurements, Zachary Mayes Jan 2025

Development Of Dual-Scan Nuclear Magnetic Resonance (Nmr) Pulse Programs For Spin-Lattice Relaxation Measurements, Zachary Mayes

Doctoral Dissertations

This research develops and refines the Split Inversion Pulse and Recovery (SIP R) methodology for spin-lattice relaxation (T₁) measurements in NMR spectroscopy. SIP R introduces a two-scan difference technique using a split inversion pulse sequence, where the 180° pulse is split into two 90° pulses phase-shifted with respect to each other. This approach simplifies data fitting, requiring only two parameters to extract T₁ values, compared to the traditional inversion-recovery method, which needs three. The SIP-R-DS and SIP-R-S adaptations extend this framework by incorporating selective NMR resonance excitations, enhancing its applicability to cross-polarization experiments and enabling unobstructed NOE measurements. These adaptations …


Metal-Organic Thin Film Coated On Optical Fiber, Nahideh Salehifar Jan 2025

Metal-Organic Thin Film Coated On Optical Fiber, Nahideh Salehifar

Doctoral Dissertations

This dissertation explores the development of metal-organic framework (MOF)-based optical fiber sensors for detecting volatile organic compounds (VOCs) at low concentrations (parts-per-billion to parts-per-million). In the first part of the study, theoretical calculations were performed using effective medium approximation (EMA) models, including Lorentz–Lorentz, Maxwell–Garnett, and Bruggeman equations, to predict the refractive index changes of MOFs upon gas adsorption. These models were applied to MOFs such as ZIF-7, ZIF-8, ZIF-90, MIL-101(Cr), and HKUST-1 to evaluate their potential for gas sensing.

In the second part of the dissertation, experimental work was conducted to validate the theoretical predictions. MOF-coated optical fibers were fabricated …


Deep Learning And Adaptive Clustering Approaches For Flood Prediction And Efficient Sensor Placement In Missouri, Fahimeh Sharafkhani Jan 2025

Deep Learning And Adaptive Clustering Approaches For Flood Prediction And Efficient Sensor Placement In Missouri, Fahimeh Sharafkhani

Doctoral Dissertations

Floods represent formidable natural calamities, posing a significant threat to communities and infrastructure due to their unpredictable and often devastating consequences. The occurrence of floods is influenced by a convergence of meteorological, hydrological, and geographical factors, resulting in changes to the patterns of rising water levels. Machine learning models have emerged as favored tools in recent times for modeling water levels and enhancing the precision of flood predictions. This research employs both supervised and unsupervised machine learning models, with the main objective of improving the accuracy of flood predictions and sensor placement. Four distinct deep learning models are used to …


Measurement Method And Applications Of Transfer Function In Rf Desensitization Problem, Xiangrui Su Jan 2025

Measurement Method And Applications Of Transfer Function In Rf Desensitization Problem, Xiangrui Su

Doctoral Dissertations

Radio frequency (RF) desensitization issues comprise two components: noise radiation sources and the transfer function from noise sources to the victim antenna. RFI is a critical challenge in modern electronic systems, particularly in densely packed environments. This work presents a comprehensive study of RFI, addressing key aspects through three novel contributions. First, a transfer function measurement method is developed for compact metallic enclosures. This method provides a precise characterization of the electromagnetic (EM) environment within confined spaces, enabling accurate identification of interference pathways. Second, an EM emission management analysis framework is proposed, leveraging transfer functions to quantify and mitigate interference …


Topics On Ai Fairness Preferences In Kidney Transplantation, Mukund Telukunta Jan 2025

Topics On Ai Fairness Preferences In Kidney Transplantation, Mukund Telukunta

Doctoral Dissertations

Modern kidney transplantation incorporates artificial intelligence (AI) decision-support systems which exhibit social discrimination due to biases inherited from training data. Although researchers have proposed various group-based fairness notions to assess biases in AI, it remains uncertain which criterion is most suitable for evaluating biases in such complex healthcare systems. This dissertation explores human perception of fairness to identify the most appropriate fairness criterion for assessing AI tools in kidney transplantation, focusing on the preferences of non-expert (e.g. public, patients) stakeholders. The study examines two distinct AI systems employed in kidney transplantation: a classification model and a regression model. Human subject …


Epitaxial Growth Of Metal-Organic Framwork Thin Films By Electro-Conversion And Electrodeposition, Xiaoting Zhang Jan 2025

Epitaxial Growth Of Metal-Organic Framwork Thin Films By Electro-Conversion And Electrodeposition, Xiaoting Zhang

Doctoral Dissertations

Electrochemical epitaxy is a facile and inexpensive soft-solution process to fabricate highly ordered thin films. This research focuses on the epitaxial growth of metal-organic framework (MOF) thin films by electrochemical methods which include electro-conversion and electrodeposition.

First, an electrochemical conversion pathway was invented to achieve epitaxial MOF thin films. Epitaxial single-domain Cu-BTC(111) thin films were manufactured by electrochemical oxidation of Cu2O(111) films electrodeposited on single-crystal Au(111). The single-crystal-like Cu-BTC(111) thin films with out-of-plane and in-plane order provide well-aligned 3.5 Å triangular windows along the [111] direction. Cu-BTC(111) foils were fabricated from the Cu-BTC/Cu2O system by electrochemical …


Investigation Of Shockwave Behavior To Inform Helmet Design Using Schlieren Imagery And Free-Field Blasts, Cody Jh Thomas Jan 2025

Investigation Of Shockwave Behavior To Inform Helmet Design Using Schlieren Imagery And Free-Field Blasts, Cody Jh Thomas

Doctoral Dissertations

"Ballistic resistance of military helmet designs is a prioritized feature to protect warfighters from traumatic brain injury. However, injuries from shock-based threats have not been optimized for warfighter protection and have resulted in the prevalence of blast-induced traumatic brain injury (bTBI). Research gaps were identified in understanding the under wash effect using free field blasts and schlieren imagery. Thus, the following were investigated: (1) overpressure changes on a warfighter’s head due to directionality from a blast, (2) shock wave dampening effects of viscoelastic materials in helmets, and (3) geometric effects of a helmet brim design in the reduction of bTBI. …


Polybenzodiazine Aerogels: All-Nitrogen Analogues Of Polybenzoxazines - Synthesis, Characterization, And Their Application In Carbon Dioxide Capture, Vaibhav Edlabadkar Jan 2025

Polybenzodiazine Aerogels: All-Nitrogen Analogues Of Polybenzoxazines - Synthesis, Characterization, And Their Application In Carbon Dioxide Capture, Vaibhav Edlabadkar

Doctoral Dissertations

"The rapidly risen concentration of carbon dioxide in the atmosphere over recent years contributed to global warming and ocean acidification. Carbon capture is viewed as an essential tool from keeping atmospheric CO2 levels from rising further. This thesis focuses on the development of new materials for high capacity and selective adsorption of CO2. One such material was based on a newly synthesized tetrahydroquinazoline (THQ), which was designed as an all-nitrogen analogue of main-stream benzoxazine monomers. THQ solutions in DMF gelled at 100 °C via HCl-catalyzed ring opening polymerization to polybenzodiazine (PBDAZ) wet gels, which were dried in …