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Extraction Of Aluminum From Lunar Regolith Through Molten Salt Electrolysis, Jacob N. Ortega, Todd P. Sander, Jeffrey D. Smith, Fateme Rezaei, David J. Bayless, William Schonberg, Daniel S. Stutts, Frank D. Han Oct 2025

Extraction Of Aluminum From Lunar Regolith Through Molten Salt Electrolysis, Jacob N. Ortega, Todd P. Sander, Jeffrey D. Smith, Fateme Rezaei, David J. Bayless, William Schonberg, Daniel S. Stutts, Frank D. Han

Materials Science and Engineering Faculty Research & Creative Works

This paper presents the methodology, development, and results of an end-to-end regolith-to-metal concept for producing aluminum in-situ on the lunar surface, namely, the Lunar In-Situ Aluminum Production through Molten Salt Electrolysis (LISAP-MSE) method. Using electrolytic reduction, aluminum oxide (i.e., alumina) can be reduced into aluminum and oxygen via electrolysis in a molten salt bath. A steady supply of hydrogen chloride could allow this in-situ resource utilization (ISRU) method to supply several necessary materials consumed in the electrolytic reduction step of the process to produce bulk aluminum metal, oxygen, water, and silica from anorthite abundant in lunar highland regions. In this …


Tensile Performance Sensitivity To Variations Of Standard 17-4 Ph Heat Treatments On Lpbf-Produced Material, Ben Brown, Cory Read, Joseph Newkirk, Frank Liou Oct 2025

Tensile Performance Sensitivity To Variations Of Standard 17-4 Ph Heat Treatments On Lpbf-Produced Material, Ben Brown, Cory Read, Joseph Newkirk, Frank Liou

Materials Science and Engineering Faculty Research & Creative Works

Standard heat treatments for metals of a particular composition are typically designed with the assumption of a conventional starting microstructure, such as that produced by casting or wrought processing. When applied to metals fabricated by Laser Powder Bed Fusion (LPBF) metal additive manufacturing (AM), these heat treatments can produce inconsistent performance due to the unique as-built microstructures. This study investigates how modifications to standard heat treatments for 17-4 PH steel influence the microstructure and mechanical properties of LPBF-fabricated material. Specimens were produced and subjected to varying solutionizing and homogenizing treatments followed by standard aging treatments. Microstructures were characterized using optical …


Stochastic Modeling Of Electromagnetic Wave Propagation Through Extreme Dust Conditions In Underground Mines Using Vector Parabolic Approach, Emmanuel Atta Antwi, Samuel Frimpong, Muhammad Azeem Raza, Sanjay Madria Oct 2025

Stochastic Modeling Of Electromagnetic Wave Propagation Through Extreme Dust Conditions In Underground Mines Using Vector Parabolic Approach, Emmanuel Atta Antwi, Samuel Frimpong, Muhammad Azeem Raza, Sanjay Madria

Mining Engineering Faculty Research & Creative Works

Post-disaster underground (UG) mine environments are characterized by complex and rapidly changing conditions, adding extra attenuation to propagating electromagnetic (EM) waves. One such complex condition is the extreme generation of dust and sudden rise in humidity contributing to extra attenuation effects to propagating waves, especially under varying airborne humidity and dust levels. The existing wave propagation prediction models, especially those that factor in the effect of dust particles, are deterministic in nature, limiting their ability to account for uncertainties, especially during emergency conditions. In this work, the vector parabolic equation (VPE) model is modified to include dust attenuation effects. Using …


Chemistry Of Inclusions By Size In Three Primary Copper Anodes, Charles Campbell, Michael Moats Oct 2025

Chemistry Of Inclusions By Size In Three Primary Copper Anodes, Charles Campbell, Michael Moats

Materials Science and Engineering Faculty Research & Creative Works

Three copper anodes from different commercial electro refineries were characterized to measure inclusion chemistry, size (diameter), and morphology. An automated scanning electron microscope (SEM) paired with energy-dispersive X-ray spectroscopy (EDS) was used to examine hundreds of inclusions near the mold and set sides of each anode. The investigation revealed that in the two anodes with less impurities (99.65% Cu and 99.75% Cu), many of the inclusions were Cu2O with an average diameter of 2 microns. The greater impurity anode (99.05% Cu, 4076 ppm Pb, 1939 ppm As, 635 ppm Bi) contained significant numbers of complex oxide inclusions, averaging 4.6 microns …


Melting Behavior Of Direct Reduced Iron Pellets With Different Carbon Content In Molten Steel And Molten Slag, Fabian Andres Calderon Hurtado, Joseph Govro, Arezoo Emdadi, Ronald J. O'Malley Oct 2025

Melting Behavior Of Direct Reduced Iron Pellets With Different Carbon Content In Molten Steel And Molten Slag, Fabian Andres Calderon Hurtado, Joseph Govro, Arezoo Emdadi, Ronald J. O'Malley

Materials Science and Engineering Faculty Research & Creative Works

This study investigates the melting behavior of direct reduced iron (DRI) pellets in molten slag and steel baths, focusing on how the carbon content influences the melting rate through the stirring effects of gas evolution on heat transfer. A computational model using COMSOL Multiphysics 6.1 is developed to simulate the temperature profile at the pellet's core and the gas evolution resulting from the reaction between FeO and carbon within the pellet. The model is validated using experimental data from this study as well as literature on the DRI pellet–molten slag system. Results indicate that, despite the increased enthalpy demand associated …


Selective Nickel Leaching And Preparation Of Battery-Grade Nickel Carbonate From Copper-Rich Industrial Intermediate, Janaka Jayamini Wijenayake, Michael S. Moats, Lloyd Masuzyo Mseteka, Lana Alagha Oct 2025

Selective Nickel Leaching And Preparation Of Battery-Grade Nickel Carbonate From Copper-Rich Industrial Intermediate, Janaka Jayamini Wijenayake, Michael S. Moats, Lloyd Masuzyo Mseteka, Lana Alagha

Materials Science and Engineering Faculty Research & Creative Works

The rising demand for electric vehicles (EVs) has driven a significant increase in nickel consumption, a critical element in EV battery production. An industrially viable hydrometallurgical process was developed for the selective recovery of nickel from a copper-rich industrial intermediate, containing approximately 70 wt.% Cu and 6 wt.% Ni, predominantly as sulfides alongside minor impurities. Approximately 90% of nickel was selectively extracted via single-stage atmospheric pressure leaching using HCl and H2O2 at 95 °C for 12 h, with the majority of copper retained in the leach residue, which can be utilized as a valuable feedstock for copper smelters. The selectivity …


Competition Of Light-And Phonon-Dressing In Microwave-Dressed Bose Polarons, G. M. Koutentakis, S. I. Mistakidis, F. Grusdt, H. R. Sadeghpour, P. Schmelcher Oct 2025

Competition Of Light-And Phonon-Dressing In Microwave-Dressed Bose Polarons, G. M. Koutentakis, S. I. Mistakidis, F. Grusdt, H. R. Sadeghpour, P. Schmelcher

Physics Faculty Research & Creative Works

We theoretically investigate the stationary properties of a spin-1/2 impurity immersed in a one-dimensional confined Bose gas. In particular, we consider coherently coupled spin states with an external field, where only one spin component interacts with the bath, enabling light dressing of the impurity and spin-dependent bath-impurity interactions. Through detailed comparisons with ab-initio many-body simulations, we demonstrate that the composite system is accurately described by a simplified effective Hamiltonian. The latter builds upon previously developed effective potential approaches in the absence of light dressing. It can be used to extract the impurity energy, residue, effective mass, and anharmonicity induced by …


Effective Two- And Three-Body Interactions Between Dressed Impurities In A Tilted Double-Well Potential, F. Theel, A. G. Volosniev, D. Diplaris, F. Brauneis, S. I. Mistakidis, P. Schmelcher Oct 2025

Effective Two- And Three-Body Interactions Between Dressed Impurities In A Tilted Double-Well Potential, F. Theel, A. G. Volosniev, D. Diplaris, F. Brauneis, S. I. Mistakidis, P. Schmelcher

Physics Faculty Research & Creative Works

We explore the impact and scaling of effective interactions between two and three impurity atoms, induced by a bosonic medium, on their density distributions. To facilitate the detection of mediated interactions, we propose a setup where impurities are trapped in a tilted double-well potential, while the medium is confined to a ring. The tilt of the potential breaks the spatial inversion symmetry allowing us to exploit the population of the energetically elevated well as a probe of induced interactions. For two impurities, the interaction with the medium reduces the impurity population at the energetically elevated well, which we interpret as …


Bound Deuteron-Antideuteron System (Deuteronium): Leading Radiative And Internal-Structure Corrections To Bound-State Energies, Gregory S. Adkins, Ulrich D. Jentschura Oct 2025

Bound Deuteron-Antideuteron System (Deuteronium): Leading Radiative And Internal-Structure Corrections To Bound-State Energies, Gregory S. Adkins, Ulrich D. Jentschura

Physics Faculty Research & Creative Works

We evaluate the energy levels of the deuteronium bound system, which consists of a deuteron and an antideuteron, with a special emphasis on states with nonvanishing orbital angular momenta. The excited atomic bound states of deuteronium constitute probes for the understanding of higher-order quantum electrodynamic corrections for spin-1 particles in a bound system where the typical field strength of the binding Coulomb field (at a distance of the generalized Bohr radius) exceeds Schwinger's critical field strength. For states with nonvanishing angular momenta, effects due to the internal structure of the deuteron and virtual annihilation contributions are highly suppressed. Relevant transitions …


Co2-Induced Changes In Rheology, Structural Evolution, And Particle Characteristics Of Cement Paste, Seongho Han, Tae Yong Shin, Seung Mo Kim, Jae Hong Kim, Kamal H. Khayat Oct 2025

Co2-Induced Changes In Rheology, Structural Evolution, And Particle Characteristics Of Cement Paste, Seongho Han, Tae Yong Shin, Seung Mo Kim, Jae Hong Kim, Kamal H. Khayat

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The injection of carbon dioxide (CO2) into cementitious systems has emerged as a promising approach to enhancing sustainability in concrete production. This study explores the impact of CO2 injection on the rheological behavior, structural build-up, and particle size evolution of cement paste by systematically varying the water-to-cement ratio (w/c) (0.35, 0.4, and 0.5) and CO2 concentration (0.06, 0.28, and 0.84 mol). Rheological analysis revealed a significant increase in initial yield stress with CO2 injection. Using the Modified Bingham model, yield stress increased by 72 % and 150 % for 0.28- and 0.84-mol CO2, …


Functional Analysis Of R144 In The Flavin Oxidation Mechanism Of A Flavin-Dependent N-Monooxygenase, Reeder Robinson, Korliss Britt, Pablo Sobrado Oct 2025

Functional Analysis Of R144 In The Flavin Oxidation Mechanism Of A Flavin-Dependent N-Monooxygenase, Reeder Robinson, Korliss Britt, Pablo Sobrado

Chemistry Faculty Research & Creative Works

Flavin-dependent N-monooxygenases (NMOs) are key enzymes in the biosynthesis of hydroxamate-containing siderophores, which are critical virulence factors in pathogenic microorganisms. SidA, an NMO from Aspergillus fumigatus, catalyzes the NADPH- and O2-dependent hydroxylation of L-ornithine (Orn) via a stable C4a-hydroperoxyflavin (FADOOH) intermediate. This study investigates the role of Arg144 in the catalytic cycle of SidA. Site-directed mutagenesis of Arg144 to alanine (R144A) significantly impaired both oxygen consumption and Orn hydroxylation, resulting in an approximately 60-fold reduction in kcat and a ~300-fold decrease in kcat/KM. The pH dependence, solvent kinetic isotope effects, and rapid-reaction kinetics reveal that R144 influences protonation events crucial …


An Analysis Of Mergers In The Presence Of Uncertainty In Renewable Energy Integration Costs, Wassim Daher, Jihad Elnaboulsi, Mahelet G. Fikru, Luis Gautier Oct 2025

An Analysis Of Mergers In The Presence Of Uncertainty In Renewable Energy Integration Costs, Wassim Daher, Jihad Elnaboulsi, Mahelet G. Fikru, Luis Gautier

Economics Faculty Research & Creative Works

This study examines how uncertainty in renewable integration costs affects the profitability of mergers among energy producers. As the energy sector shifts toward decentralized renewables, centralized producers face industry-wide and firm-specific cost uncertainties due to the variable and intermittent nature of distributed generation. Although previous models have examined mergers in the presence of greener energy, they have largely assumed deterministic costs and ignored the impact of the dual sources of uncertainty on merger profitability. This study incorporates both industry-wide and private shocks into renewable integration costs, using two theoretical models – without and with uncertainty – to identify how these …


Microstructure Densification In Cement Pastes Enabled By Novel Graphene Types, Sahil Surehali, Taihao Han, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath Sep 2025

Microstructure Densification In Cement Pastes Enabled By Novel Graphene Types, Sahil Surehali, Taihao Han, Ranjith Divigalpitiya, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

The primary barriers hindering graphene's widespread adoption as a performance-enhancing additive in cement-based systems have traditionally been its prohibitive cost and the sustainability concerns associated with conventional manufacturing processes. However, these impediments have recently been mitigated by advancements in detonation synthesis techniques, enabling scalable, cost-effective, and environmentally favorable production of novel graphene types—specifically fractal graphene (FG) and reactive graphene (RG). This paper explores the influence of ultra-low dosages of FG and RG (≤ 0.04 % by mass of cement, which results in ∼20 % increase in compressive strengths) on the pore-structure features of cement pastes. Compared to the control paste, …


Carbonated High-Al Steel Slag As Supplementary Cementitious Material: Synergy Of Carbonation At Elevated Temperature And Addition Of Gypsum, Nannan Zhang, Gao Deng, Wenyu Liao, Chuanlin Hu, Lingyu Chi, Hongyan Ma Sep 2025

Carbonated High-Al Steel Slag As Supplementary Cementitious Material: Synergy Of Carbonation At Elevated Temperature And Addition Of Gypsum, Nannan Zhang, Gao Deng, Wenyu Liao, Chuanlin Hu, Lingyu Chi, Hongyan Ma

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

High-Al steel slags, such as ladle metallurgy furnace (LMF) slag, substantially retard the early hydration of cement when incorporated into cement pastes, primarily due to the high mayenite content. In this study, carbonation of slag at elevated temperatures of 60°C and 80°C, combined with gypsum addition, was proposed to synergistically mitigate the retardation effect and enhance the early-age strength of cement pastes. The physical and chemical properties of slags carbonated at various temperatures were analyzed to elucidate their impact on cement performance as a supplementary cementitious material. The results indicate that higher temperatures enhance carbonation reactivity, accelerating the carbonation of …


Pendant Micro-Droplet Evaporation Fabricates Fiber-Optic Mof Gas Sensor In Seconds, Abhishek Prakash Hungund, Bohong Zhang, Narasimman Subramaniyam, Thomas Spudich, Ryan O'Malley, Farhan Mumtaz, Rex E. Gerald, Jie Huang Sep 2025

Pendant Micro-Droplet Evaporation Fabricates Fiber-Optic Mof Gas Sensor In Seconds, Abhishek Prakash Hungund, Bohong Zhang, Narasimman Subramaniyam, Thomas Spudich, Ryan O'Malley, Farhan Mumtaz, Rex E. Gerald, Jie Huang

Electrical and Computer Engineering Faculty Research & Creative Works

The development of photonic-based gas sensors using metal–organic frameworks (MOFs) and other microporous solids is often a multistep, complex process, typically involving MOF synthesis, purification, and attachment of microcrystals to an optical fiber end face. This study introduces a one-step method that integrates MOF synthesis and sensor head fabrication directly onto the fiber end face, forming an extrinsic Fabry–Perot interferometer (EFPI) with a thin film of MOF microcrystals. The resulting film, only 3–10-μm-thick, enhances sensor response by enabling rapid gas detection within seconds. Utilizing a pendant micro-droplet evaporation technique, this method forms a microporous MOF layer in situ, allowing unreacted …


Magnesium Sulfate Attack Of Alite Paste And Mitigation By Surface Carbonation: Monitoring And Comparison Using Novel Portable Fiber-Optic Raman Probe, Bohong Zhang, Gao Deng, Hongyan Ma, Jie Huang Sep 2025

Magnesium Sulfate Attack Of Alite Paste And Mitigation By Surface Carbonation: Monitoring And Comparison Using Novel Portable Fiber-Optic Raman Probe, Bohong Zhang, Gao Deng, Hongyan Ma, Jie Huang

Electrical and Computer Engineering Faculty Research & Creative Works

Sulfate attack on cement matrix is still a "confused world" especially when magnesium sulfate (MgSO4) is the sulfate source. Accurate assessment of sulfate attack is essential for evaluating the structural integrity and durability of concrete in relevant environments. This study presents a portable fiber-optic Raman probe approach with 125 μm spatial resolution, designed for depth-resolved sulfate ingress monitoring in tricalcium silicate (C₃S, Alite) pastes. The probe is also used to evaluate the effectiveness of surface carbonation in mitigating sulfate attack. The results demonstrate a strong correlation between sulfate penetration depth and Raman spectral intensity ratios of sulfate-related vibrational …


Effect Of Clays On The Spontaneous Imbibition Behavior Of Surfactant Solutions In Shale Oil Reservoirs, Ning Xu, Yanling Wang, Baojun Bai, Chuanbao Zhang, Shizhang Cui, Yu Zhang, Di Li, Wenjing Shi, Wenhui Ding Sep 2025

Effect Of Clays On The Spontaneous Imbibition Behavior Of Surfactant Solutions In Shale Oil Reservoirs, Ning Xu, Yanling Wang, Baojun Bai, Chuanbao Zhang, Shizhang Cui, Yu Zhang, Di Li, Wenjing Shi, Wenhui Ding

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Surfactant-enhanced spontaneous imbibition is a proven method of enhancing oil recovery from shale reservoirs. However, a significant knowledge gap concerning the impact of clay minerals on surfactant-enhanced imbibition in shale reservoirs remains. Therefore, this study first analyzed the mineral composition and pore structure of the shale reservoirs. Subsequently, three surfactants were selected for spontaneous imbibition experiments. The influence of various clay minerals on the surfactant imbibition was assessed by considering various properties of the imbibition system. The results showed that the shale pores primarily consisted of macropores (44.03%) and mesopores (43.94%). Surfactants enhance the imbibition recovery by altering the wettability …


An Improved Method To Calculate Stripping Inflection Point (Sip) And Its Application In Evaluating Moisture Susceptibility Of Asphalt Mixtures, Ping Jiang, Bo Lin, Yizhuang David Wang, Jenny Liu, Seyed Alireza Ghanoon Sep 2025

An Improved Method To Calculate Stripping Inflection Point (Sip) And Its Application In Evaluating Moisture Susceptibility Of Asphalt Mixtures, Ping Jiang, Bo Lin, Yizhuang David Wang, Jenny Liu, Seyed Alireza Ghanoon

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Accurately assessing asphalt mixtures' moisture susceptibility is critical because moisture damage can significantly reduce pavement durability, leading to premature failure and structural integrity of the pavement. The stripping inflection point (SIP), a moisture susceptibility index derived from the Hamburg Wheel Track (HWT) test, has practical merits in evaluating moisture susceptibility. However, current methods for determining the SIP showed low accuracy and high variability due to poor regression quality. Hence, this study aims to propose an improved method for calculating the SIP by modifying existing approaches to better capture the characteristics of rutting curves. Typical asphalt mixtures were used to conduct …


Nonlinear Stage Of Modulational Instability In Repulsive Two-Component Bose-Einstein Condensates, S. Mossman, S. I. Mistakidis, G. C. Katsimiga, A. Romero-Ros, G. Biondini, P. Schmelcher, P. Engels, P. G. Kevrekidis Sep 2025

Nonlinear Stage Of Modulational Instability In Repulsive Two-Component Bose-Einstein Condensates, S. Mossman, S. I. Mistakidis, G. C. Katsimiga, A. Romero-Ros, G. Biondini, P. Schmelcher, P. Engels, P. G. Kevrekidis

Physics Faculty Research & Creative Works

Modulational instability (MI) is a fundamental phenomenon in the study of nonlinear dynamics, spanning diverse areas such as shallow water waves, optics, and ultracold atomic gases. In particular, the nonlinear stage of MI has recently been a topic of intense exploration and has been shown to manifest, in many cases, in the generation of dispersive shock waves (DSWs). In this Letter, we experimentally probe the MI dynamics in an immiscible two-component ultracold atomic gas with exclusively repulsive interactions, catalyzed by a hard-wall-like boundary produced by a repulsive optical barrier. We analytically describe the expansion rate of the DSWs in this …


Coupled-Channel Calculations Of Fully Differential Cross Sections For Ionization In 75-Kev P + He Collisions, K. H. Spicer, N. W. Antonio, M. S. Schöffler, Michael Schulz, A. S. Kadyrov Sep 2025

Coupled-Channel Calculations Of Fully Differential Cross Sections For Ionization In 75-Kev P + He Collisions, K. H. Spicer, N. W. Antonio, M. S. Schöffler, Michael Schulz, A. S. Kadyrov

Physics Faculty Research & Creative Works

The fully differential cross section is the most detailed quantity that can be measured or calculated to study ionization in few-body systems. For 75 keV proton collisions with helium, various experimental data are available. However, previous theoretical calculations found significant discrepancies across the entire range of data. In this work the wave-packet convergent close-coupling method is extended to calculating these cross sections for electrons ejected with energies from 1 to 75.4 eV. The approach utilizes a two-center expansion and correlated two-electron helium wave functions to describe the four-body proton-helium system. While there is good agreement with the experiment for electrons …


Bioelectrochemical Systems: Prioritizing Energy Density, Long-Term Stability, And Validation, Luana C.I. Faria, Steffane Q. Nascimento, Filipe C.D.A. Lima, Graziela C. Sedenho, Thiago Bertaglia, Rodrigo M. Iost, João C.P. De Souza, Senentxu Lanceros-Méndez, Shelley D. Minteer, Serge Cosnier, Ariel L. Furst, Frank N. Crespilho Sep 2025

Bioelectrochemical Systems: Prioritizing Energy Density, Long-Term Stability, And Validation, Luana C.I. Faria, Steffane Q. Nascimento, Filipe C.D.A. Lima, Graziela C. Sedenho, Thiago Bertaglia, Rodrigo M. Iost, João C.P. De Souza, Senentxu Lanceros-Méndez, Shelley D. Minteer, Serge Cosnier, Ariel L. Furst, Frank N. Crespilho

Chemistry Faculty Research & Creative Works

Pioneering work in bioelectrochemistry, particularly the employing of yeast cells to generate electrical current, had substantially favored the comprehension of bio electrochemical reactions. This foundational research has boosted the development of bio electrochemical systems (BES), which are significant for sustainable energy solutions. BES technologies, such as biobatteries, bio supercapacitors, and enzymatic and microbial biofuel cells, harness organic and biological systems to provide environmentally friendly alternatives for energy storage and conversion. Despite their potential, these technologies face challenges in achieving competitive energy densities and long-term stability compared to traditional accumulators and converters. Here, we introduce a new Ragone plot for BES, …


Paleoseismic Evidence Of Directivity For The 1976 Mw 7.5 Motagua Earthquake, Guatemala, Jonathan Obrist-Farner, Jeremy Maurer, Derek Gibson, Trenton Mcenaney, Andreas Eckert, William F. Kenney, Jeffrey Beeson, Nigel Wattrus, Quin Stangeland, Fatima Reyes Sep 2025

Paleoseismic Evidence Of Directivity For The 1976 Mw 7.5 Motagua Earthquake, Guatemala, Jonathan Obrist-Farner, Jeremy Maurer, Derek Gibson, Trenton Mcenaney, Andreas Eckert, William F. Kenney, Jeffrey Beeson, Nigel Wattrus, Quin Stangeland, Fatima Reyes

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

On 4 February 1976, a Mw 7.5 earthquake along the Motagua fault, Guatemala, ruptured ∼230 km of the North American and Caribbean plate boundary. Today, the plate boundary remains poorly monitored, and the 1976 earthquake is still not fully understood. Here, we present seismic reflection profiles and radiometrically dated sediment core data from six lakes around the Motagua fault, together with reports of destruction and a quasi-dynamic rupture model, which show that the 1976 earthquake experienced strong directivity that impacted the distribution of shaking. The earthquake left behind a detailed record of event deposits (EDs) in five of the six …


Multiply Differential Study Of Detachment With Simultaneous Target Excitation In Anion-Atom Collisions, M. Schulz, F. Herrmann, W. Zhang, D. V. Chicharro, A. Dorn, M. Grieser, F. Grussie, H. Kreckel, O. Novotny, F. Trost, A. Wolf, T. Pfeifer, C. D. Schröter Sep 2025

Multiply Differential Study Of Detachment With Simultaneous Target Excitation In Anion-Atom Collisions, M. Schulz, F. Herrmann, W. Zhang, D. V. Chicharro, A. Dorn, M. Grieser, F. Grussie, H. Kreckel, O. Novotny, F. Trost, A. Wolf, T. Pfeifer, C. D. Schröter

Physics Faculty Research & Creative Works

We have measured momenta of electrons and recoil ions in triple coincidence with neutralized projectiles for slow collisions between various anions and target atoms. From the data we extracted triple differential momentum and angular distributions of electrons ejected in detachment, in detachment with simultaneous target ionization (DI), and in detachment with simultaneous target excitation (DE). The DI rates relative to the DE rates depend sensitively on the projectile speed and on the properties of the target.


Continuous Pump-Probe Experiment To Observe Zeeman Wave-Packet Dynamics, K. L. Romans, K. Foster, S. Majumdar, B. P. Acharya, O. Russ, A. H.N.C. De Silva, Daniel Fischer Sep 2025

Continuous Pump-Probe Experiment To Observe Zeeman Wave-Packet Dynamics, K. L. Romans, K. Foster, S. Majumdar, B. P. Acharya, O. Russ, A. H.N.C. De Silva, Daniel Fischer

Physics Faculty Research & Creative Works

In this work, we study the coherent dynamics of an atomic Zeeman wave packet using a continuous pump-probe scheme. A polarized Zeeman wave packet is created in laser-cooled lithium atoms via few-photon excitation by a femtosecond laser pulse, producing a state with a magnetic moment tilted relative to an external magnetic field. The subsequent Larmor precession of the atomic magnetic moment is probed via continuous ionization by an optical dipole trap (ODT) laser. The resulting ionization fragments—photoelectrons and photo ions—are detected in coincidence using a cold target recoil ion momentum spectrometer (COLTRIMS). While the ODT facilitates further cooling of the …


High-Capacity, Reversible, And Energy-Efficient Water Vapor Sorption By Hierarchical Micro-To-Macroporous Carbon Aerogels From Polybenzoxazine And Polybenzodiazine, Vaibhav A. Edlabadkar, Rushi U. Soni, Stephen Y. Owusu, A. B.M.Shaheen Ud Doulah, Nicholas Leventis, Chariklia Sotiriou-Leventis Sep 2025

High-Capacity, Reversible, And Energy-Efficient Water Vapor Sorption By Hierarchical Micro-To-Macroporous Carbon Aerogels From Polybenzoxazine And Polybenzodiazine, Vaibhav A. Edlabadkar, Rushi U. Soni, Stephen Y. Owusu, A. B.M.Shaheen Ud Doulah, Nicholas Leventis, Chariklia Sotiriou-Leventis

Chemistry Faculty Research & Creative Works

Quantitative, reversible water vapor sorption is in rising demand for applications ranging from home appliances to atmospheric water harvesting. However, most sorbents suffer from low water-uptake capacities, nonreusability, and especially high regeneration temperatures. This study addresses this challenge by introducing polybenzoxazine- (PBO) and polybenzodiazine-derived (PBDAZ) carbon aerogels as reversible high-capacity desiccants. PBO and PBDAZ aerogels were prepared from structurally related monomers via HCl-catalyzed ring opening polymerization. Both types of aerogels were first aromatized at 200–240 °C under air or O2 and then were carbonized at 800 °C under Ar. These as-prepared carbon aerogels were further etched at 1000 °C under …


Generalized Transversality Conditions For Fuzzy Quantum-Symmetric Variational Problems Via Granular Approach, Martin Bohner, Ewa Girejko, Agnieszka B. Malinowska, Linh Nguyen, Baruch Schneider, Tri Truong Sep 2025

Generalized Transversality Conditions For Fuzzy Quantum-Symmetric Variational Problems Via Granular Approach, Martin Bohner, Ewa Girejko, Agnieszka B. Malinowska, Linh Nguyen, Baruch Schneider, Tri Truong

Mathematics and Statistics Faculty Research & Creative Works

This paper investigates fuzzy q-symmetric variational problems with natural boundary conditions. Based on the relative distance measure fuzzy arithmetic and horizontal membership functions (HMFs), we propose novel concepts of differentiability and integrability for fuzzy functions on quantum geometric subsets of real numbers. Then, fundamental foundations of q-symmetric calculus of variations based on HMFs are provided. With the help of HMFs and granular q-symmetric differentiability, we derive necessary optimality conditions for fuzzy q-symmetric variational problems that depend on free endpoints. Moreover, sufficient conditions for minimizers of q-symmetric variational problems are obtained. Some numerical examples illustrating the proposed approach are presented.


Novel Statistical And Topological Data Analyses Of 2d Electronic Images, Robert L. Paige, Vic Patrangenaru Sep 2025

Novel Statistical And Topological Data Analyses Of 2d Electronic Images, Robert L. Paige, Vic Patrangenaru

Mathematics and Statistics Faculty Research & Creative Works

In this paper, novel statistical and topological data analyses of 2D images are developed. One considers methodologies based on the Region Covariance Descriptor (RCD) and Topological Data Analysis (TDA) rooted in the simplicial as well as cubical persistent homologies. These methods provide statistical methods for data from populations of complex data objects that are elements of non-Euclidean spaces. The 2D image data considered consist of pictures of two leaves—A and B—from the same tree, twenty of each leaf, from different perspectives. The novel statistical procedures developed are used for correctly determining that leaf A images and leaf B images are …


Greedy Algorithm For Neural Networks For Indefinite Elliptic Problems, Qingguo Hong, Jiwei Jia, Young Ju Lee, Ziqian Li Sep 2025

Greedy Algorithm For Neural Networks For Indefinite Elliptic Problems, Qingguo Hong, Jiwei Jia, Young Ju Lee, Ziqian Li

Mathematics and Statistics Faculty Research & Creative Works

The paper presents a priori error analysis of the shallow neural network approximation to the solution to the indefinite elliptic equation and a cutting-edge implementation of the Orthogonal Greedy Algorithm (OGA) tailored to overcome the challenges of indefinite elliptic problems, which is a domain where conventional approaches often struggle due to the lack of coerciveness. A rigorous priori error analysis that shows the neural network's ability to approximate the solution of indefinite problems is confirmed numerically by OGA. We also present the error analysis of the relevant numerical quadrature. In particular, massive numerical implementations are conducted to justify the theory, …


A Complicated History Of Mitogenome Introgression Among Luxilus Species (Teleostei, Family Leuciscidae) In The Ozark Highlands, David D. Duvernell, Carson Arnold, Shila Koju, Abby J. Wicks, Thomas E. Dowling Sep 2025

A Complicated History Of Mitogenome Introgression Among Luxilus Species (Teleostei, Family Leuciscidae) In The Ozark Highlands, David D. Duvernell, Carson Arnold, Shila Koju, Abby J. Wicks, Thomas E. Dowling

Biological Sciences Faculty Research & Creative Works

Hybridization is common among minnows and shiners in the family Leuciscidae, and mitonuclear discordance can reveal evidence of historical hybridization and introgression events that have shaped extant species and populations. We have identified a notable case of serial mitogenome replacement in populations of two shiner species, Luxilus zonatus and L. chrysocephalus, which are syntopic in drainages throughout the northern and eastern Ozark Interior Highlands of North America. These mitogenome replacement events involved L. zonatus acquiring the mitogenome of L. chrysocephalus, and populations of L. chrysocephalus acquiring the mitogenome of an allopatric congeneric species, L. cornutus. The latter species has a …


Ibi-Dt: A Novel Approach Combining Individualized Bayesian Inference And Decision Tree For Identifying Cancer Drivers And Their Interactions, Md Asad Rahman, Gregory F. Cooper, Jinying Zhao, Xinghua Lu, Jinling Liu Sep 2025

Ibi-Dt: A Novel Approach Combining Individualized Bayesian Inference And Decision Tree For Identifying Cancer Drivers And Their Interactions, Md Asad Rahman, Gregory F. Cooper, Jinying Zhao, Xinghua Lu, Jinling Liu

Engineering Management and Systems Engineering Faculty Research & Creative Works

Cancer is mainly caused by a relatively small portion of somatic genome alterations (SGAs), called cancer drivers. Despite success in identifying a good number of cancer drivers, many more remain to be discovered to explain various cancers. Moreover, limited tools are available to identify potential interactions among cancer drivers for a better understanding of oncogenesis. To tackle these challenges, we have developed a novel approach called individualized Bayesian inference using a decision tree (IBI-DT). IBI-DT recognizes the genetic heterogeneity among cancer patients, where different individuals or patient subgroups of distinct genomic makeup may have different drivers. IBI-DT works by constructing …