Digital Commons Network^™

A Four-Step Thermocatalytic Route For Converting Co2 Into High-Purity Oxalic Acid, Hao Feng, Muhammad Kashif Khan, Lei Li, Hongyan Ma, Xinhua Liang

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

This research outlines a four-step methodology for transforming CO₂ into high-purity oxalic acid. CO2 was first sequestered as KHCO₃ through its reaction with aqueous KOH, followed by hydrogenation using a supported AgPd/CNT catalyst in a batch reactor at an initial H₂ pressure of 60 bar and a temperature of 150°C. The formate yield reached 91.8% at optimum conditions. Potassium formate in the solid state was thermally coupled in the presence of KOH at 400°C under N2 flow, yielding potassium oxalate of up to 76% yield. The final step was the selective precipitation of potassium oxalate with ferrous …

Reflections On Linear B (Part 13): Sign 21 May Derive From The Ancient Egyptian 'Wedjat Eye’ (‘Eye Of Horus’ But Also Associated With Ra), Gerald Leonard Cohen

Arts, Languages and Philosophy Faculty Research & Creative Works

This article suggests that Linear B sign 21 (of unknown origin)

may derive ultimately from the Ancient Egyptian ‘wedjat eye’

(Eye of Horus). A point of special interest here is the possibility

that the pronunciation of Linear B sign 21 (designated as ‘qi’)

derives in abbreviated form from the Proto-Indo-European dual

of ‘eye’ and would therefore be the oldest Greek attestation of

that reconstructed PIE form.

The Impact Of Value Homophily, Rational And Emotional Persuasion On Information Passing Of Social Media Advertisements: A Model Comparison Approach, Gloria Hui Wen Liu, Cecil Eng Huang Chua, Neil Chueh An Lee, Jenny Hua Jen Wu

Business and Information Technology Faculty Research & Creative Works

Increasingly, businesses collaborate with influencers and content creators (the source) to advertise on social media, with social media users being exposed to an environment saturated with unsolicited advertisements. With social contacts remaining the most trusted advertisement sources, users' passing of such advertisements helps their dissemination and creates a specific kind of electronic word of mouth called information passing. Information passing involves users forwarding advertisements about products/services to someone else. Prior studies have found at least three factors influence information passing, including value homophily (similarity with the source as perceived by users), rational appeal (information about how a product can meet …

Hardware Without Humanware: Robot Adoption, Talent Structure Degradation, And Firm Innovation, Wenhao Sun, Zhenyu Wu, Chevy-Hanqing Fang

Business and Information Technology Faculty Research & Creative Works

Contrary to the prevailing view that automation complements skilled labor in advanced economies, this study examines the unintended consequences of robot adoption in emerging markets. Drawing on strategic human capital theory, we exploit China's manufacturing sector as a natural experiment to identify the causal impact of industrial intelligence on firm-level innovation. Using a unique dataset of more than 90,000 public and private firms from the National Enterprise Innovation Database (2008–2014), we uncover a counterintuitive result: robot adoption significantly reduces firm innovation, which is notably more pronounced for private-owned firms and those with weaker innovation capabilities. Mediation analyses further show that …

Gubernatorial Re-Election Incentives, Local Investment Bias, And Pension Fund Performance, Hongxian Zhang, Liang Guo, Jun Hao, Yu Liu

Business and Information Technology Faculty Research & Creative Works

We investigate the impact of gubernatorial re-election incentive and political factors on US public pension funds from 1990 to 2022. Our empirical analysis finds no significant overall relationship between gubernatorial re-election incentives and local bias in the full sample. However, the effect of gubernatorial re-election incentives on local bias is influenced by a state's level of corruption. Specifically, in states within the lowest corruption quantile, governors eligible for re-election tend to prioritize local investments to gain consistent support. In contrast, in states within the highest corruption quantile, heightened scrutiny may encourage re-election-eligible governors to adopt conservative investment policies that do …

Counterfactual Indeterminacy Bias In Family Firm Research, Chevy-Hanqing Fang, James J. Chrisman, Alfredo De Massis

Business and Information Technology Faculty Research & Creative Works

Ever since scholars recognized that family firms are heterogeneous, many studies have attempted to compare different types of family firms without ensuring that the source of heterogeneity is unique to family firms. When the source of heterogeneity among family firms resembles the source of heterogeneity among nonfamily firms, the problem of counterfactual indeterminacy bias can lead to misleading or irrelevant findings that fail to distinguish the effects of family influence from factors that affect all firms. We delineate common forms of this bias and offer recommendations to prevent it in research on family firm behavior and performance.

Scalable Transfer Of Dna Origami–Directed Nanoparticle Arrays Onto Functional Surfaces Using Thermal Release Tape, Yuwei Zhang, Chikadibia Genevieve Edward, Ethan Keuhn, Shelley D. Minteer, Risheng Wang

Chemistry Faculty Research & Creative Works

Precise integration of DNA origami nanostructures onto functional substrates is essential for advancing electronics, photonics, and biosensing. However, most surface-assembly methods are highly sensitive to substrate type, limiting their broader applications. Here, we introduce a thermal release tape (TRT)-assisted transfer method that enables efficient, large-area printing of DNA origami-guided gold nanoparticle (AuNP-DNA origami) arrays from mica onto diverse surfaces. The method relies on differential adhesion: AuNP-DNA origami arrays form strong electrostatic and hydrogen-bonding interactions with 3-aminopropyltriethoxysilane (APTES)-functionalized receiver substrates, while the TRT adhesive weakens upon heating to 120°C, allowing release from the tape. Using this approach, well-ordered AuNP-DNA origami arrays …

Closing The Nitrogen Loop In Groundwater With Biohybrid Technologies, Linjie Zhou, Biao Li, Jianhua Guo, Shelley D. Minteer, Yifeng Zhang

Chemistry Faculty Research & Creative Works

Nitrate in groundwater should be treated as a nitrogen source rather than a contaminant. Biohybrid technologies coupling microbial selectivity with renewable electro(photo)chemical energy offer opportunities to convert nitrate to value-added ammonium, although challenges remain in scalability, microbial stability, material–microbe integration, process engineering, regulatory compliance, and economic feasibility.

Evaluation Of Chromium-Crosslinked Amps-Hpam Copolymer Gels: Effects Of Key Parameters On Gelation Time And Strength, Maryam Sharifi Paroushi, Baojun Bai, Thomas P. Schuman, Yin Zhang, Mingzhen Wei

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Controlling CO₂ channeling in heterogeneous reservoirs remains a major challenge for both enhanced oil recovery (EOR) and secure geological storage. AMPS-HPAM copolymers exhibit high-temperature resistance and brine tolerance compared with conventional HPAM gels, making them well suited for the harsh environments associated with CO₂ injection. Chromium-based crosslinkers (CrAc and CrCl₃) were investigated because sulfonic acid groups in AMPS can coordinate with trivalent chromium ions, enabling dual ionic crosslinking and the formation of a robust gel network. While organic crosslinked AMPS-HPAM gels have been widely studied, the behavior of chromium-crosslinked AMPS-containing systems, particularly their gelation kinetics under …

Effect Of Ionic Strength On Gelation Time And Strength Of Amps-Based Polymer Gels, Maryam Sharifi Paroushi, Xuyang Tian, Baojun Bai, Thomas P. Schuman, Yin Zhang, Mingzhen Wei

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Polymer gel treatment has been widely applied for improving sweep efficiency and controlling excessive water and gas production. Their performance depends on gelation time and final gel strength. In most studies, brine salinity is used to describe the effect of formation water on gel behavior. However, changing salinity also changes ionic strength and ion composition at the same time. Because of this coupling, it is difficult to identify the mechanisms controlling gelation, which has led to inconsistent trends in the literature. Increasing salinity has been reported to either slow or accelerate gelation and to weaken or strengthen gels depending on …

Robust Broadband Characterization Of Flexible Absorbers, Sheet Material, And Liquids Using A Coaxial Structure, Joseph Christopher Stecher

Masters Theses

Modern high-frequency measurement systems require reliable calibration and sample positioning to ensure measurement fidelity. This thesis presents three studies addressing practical limitations in broadband material parameter extraction and instrumentation.

The first study introduces a modified Nicolson–Ross–Weir (NRW) technique for flexible, compression-sensitive materials from 100 MHz to 18 GHz. Rigid 3D-printed spacers ensure precise sample positioning, and a T-matrix–based de-embedding procedure removes spacer effects. Validation using microstrip measurements and full-wave simulation confirms accurate permittivity extraction across compression levels.

The second study extends NRW to sheet materials enabling accurate material characterization. Independent validation using toroidal inductors with leakage correction and parallel-plate capacitors …

Empirical-Based Model Of Spatio-Temporal Errors, Godwin Naaba Ndaa

Masters Theses

This research develops an empirical model to characterize spatial-temporal InSAR errors and improve the accuracy of deformation time-series analysis. Using standardized Sentinel-1 HyP3 products and MintPy, the study quantifies how correlated noise affects velocity precision and validates the results against continuous GNSS velocities.

Residual velocities are near-Gaussian, with σ ~0.92–2.04 cm/yr and ~1 cm/yr on average. Variograms show power-law spatial structure with a non-zero nugget implicating troposphere and decorrelation while errors drop exponentially with more acquisitions; spatial uncertainty is strongly affected by unwrapping errors, coherence, and tropospheric noise, not simply troposphere.

A comparative assessment of on-demand cloud processing with other …

Optimal Slotting In Hybrid Warehousing For Industry 4.0, Teng Yang

Masters Theses

In the era of Industry 4.0, the warehouse management system (WMS) employed by many firms prescribes hybrid storage, i.e., products with high turnover, called fast movers, are kept in random storage for a short time duration before being shifted to a dedicated storage area, while products with low turnover, called slow movers, remain in random storage. From dedicated storage, the products are dispatched to the customer. The challenge for managers is selecting the slot in dedicated storage to assign to each product while demand data change because of fluctuating market conditions; this problem is referred to as slotting in the …

Calcium Based Carbon Negative Fillers And Additives: Effects On Hydration And Performance Of Low-Carbon Cement Systems, Smita Bhowmick Shithi

Masters Theses

Cement production is a major source of global CO₂ emissions creating an urgent need for carbon-negative fillers and functional additives that lower clinker use while maintaining cement performance. This thesis investigates the effects of organic mineral salts as fillers and additives on cement hydration, fresh properties, compressive strength and pore structure. In the first study, ordinary Portland cement (OPC) was partially replaced with calcium carbonate or calcium oxalate to enable a direct comparison under controlled particle size distribution (PSD). Rheology, flowability, hydration kinetics, phase evolution, mechanical performance and water absorption were evaluated. Calcium carbonate promoted early hydration through nucleation and …

Developing Discharge Estimation Algorithm Using Low-Cost Velocity Sensor And Machine Learning, Barkha Gautam

Masters Theses

Accurate river discharge estimation is essential for flood forecasting, water resources management, and hydraulic decision-making; however, continuous discharge records are unavailable at many river locations. Traditional stage-discharge rating curves are widely used but their reliability may decrease when channel conditions change or flow conditions vary rapidly. This study develops and evaluates Long Short-Term Memory (LSTM) models for discharge prediction using 15-minute time-series data from river monitoring stations in Missouri. Two model configurations, a baseline stage-only model and an enhanced stage-plus-velocity model, are developed and evaluated independently at two river sites to determine whether the inclusion of surface velocity improves discharge …

Examination Of Laser Microwelding As A Technique For The Repair Of Steel Castings, Allan John Woldow

Masters Theses

"Metal castings have long been plagued with minor defects caused by various process and design conditions. Commonly, minor defects are not seen until after machining operations have been completed, and by the time they are identified, they cannot be salvaged in a manner that is structurally sound and does not have other detrimental effects on the product. Detrimental effects may include warping from high heat input in traditional welding, warping from reheat treatment, oxidation of machined surfaces, microstructural anomalies, and reduced mechanical properties. Micro laser welding has the potential to provide a solution to these issues by providing a low …

Aura-Visionpose: Creating Datasets For Vision-Based Pose Estimation, Mohanad Alameer

Masters Theses

"Spacecraft rendezvous is an integral part of many orbital missions, including active space debris removal (ADR) and in-orbit servicing, assembly, and manufacturing (ISAM). Traditionally, rendezvous missions rely mainly on manual ground-based control to perform rendezvous and docking. While this can be effective on an individual basis, it becomes less practical at scale. Autonomous vision-based methods can reduce reliance on human control, and may improve scalability, response time, and reduce the possibility of human error for both ADR and ISAM. This work lays the necessary groundwork for developing a machine learning (ML) model for autonomous rendezvous by creating a labeled image …

Near-Field Scan Method For Radiated Susceptibility Analysis And The Design And Optimization Of A Miniaturized Spiral Antenna For Ultra-Wideband Applications, Mckennan Edward Starkey

Masters Theses

"The work presented in this thesis consists of two separate topics. The first topic is a new method for the characterization of radiated susceptibility of electronic devices, while the second topic is on antenna design. The first topic proposes an approach to experimentally determine locations within an electronic system that are well coupled to external far-field radiators. This method is performed by using a differential magnetic field probe to sweep across the target device while measuring the total radiated power (TRP) produced by the device in a mode stirred tent. Scan locations where the TRP is larger than the background …

Castrip Process Technology: Non-Grain Oriented (Ngo) Si Steels Extension And Carbide-Free Bainitic (Cfb) For Flat Products, Naram Naidu Meesala

Masters Theses

"This research explores the development of advanced steel grades manufactured through Castrip® twin-roll thin strip casting technology, with particular attention to non-grain-oriented electrical Si-Steels (NGOES) and carbide-free bainitic (CFB) steels. The Castrip® process offers a near-net-shape route for producing thin steel strips, which greatly decreases the number of processing stages, lowers energy demand, and reduces carbon dioxide emissions when compared with traditional steel production methods.

In the NGOES part of the study, several industrial Fe–Si steel compositions were cold rolled to final thicknesses ranging from 0.35 mm to 0.15 mm. These materials were then exposed to short-duration continuous annealing at …

Injectable Borate/Borosilicate Bioactive Glass Systems For The Regeneration Of Hard Tissue – A Critical Review Of The Literature, S. Sina Mohammadi, Sunjeev S. Phull, Ryan J. Gilbert, Mark R. Towler

Chemical and Biochemical Engineering Faculty Research & Creative Works

Bone defects caused by trauma, infection, or tumor resection remain difficult to treat because successful repair requires both structural restoration and control of the local pathological microenvironment. Osteolysis, defined as pathological bone resorption, is central to many of these conditions and is commonly driven by excessive osteoclast activity. Clinically translated injectable products such as NovaBone® Putty demonstrate the value of moldable bioactiveglass grafts for defect filling; however, conventional silicate bioactive glasses are permanent and provide limited therapeutic ion release. This limitation has motivated the development of injectable borate bioactive glass (B-BGs) and injectable borosilicate bioactive glass (BS-BG) systems as more …

Evaluation Of A Novel Re-Crosslinkable Preformed Particle Gel For Conformance Control In Ultra-High Temperature Reservoirs, Yanbo Liu, Tao Song, Caleb Kwasi Darko, Thomas P. Schuman, Mingzhen Wei, Baojun Bai

Chemistry Faculty Research & Creative Works

Preferential fluid flow remains a major challenge in subsurface energy production and gas storage operations, resulting in excessive water production in mature oil fields, reduced heat extraction in geothermal reservoirs, and low sweep and storage efficiency in CO₂-EOR projects. Polymer gels are widely used to mitigate high-permeability channels; however, conventional systems exhibit limited plugging efficiency and short lifetimes in ultra-high-temperature reservoirs due to poor thermal stability. This study presents a novel ultra-high-temperature-resistant preformed particle gel (UHT-PPG) developed for conformance control in reservoirs with temperatures of 150–275 °C and severe super-K or channeling problems. The material was evaluated in …

Progression Toward Terminal Oxidation Of Starch Via Hybrid Organic–Enzymatic Bioanode For Renewable Carbohydrate Conversion, Adam Milam, Jose Intano, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

The performance of starch-based biofuel cells is fundamentally limited by inefficient utilization of the fuel's inherent energy density. Sequential oxidation of carbohydrate fuels, such as glucose, the monomeric unit of starch, using minimal catalyst systems has therefore emerged as a promising strategy to improve biofuel cell efficiency. Here, we extend a previously reported three-catalyst, organic–enzymatic glucose oxidation cascade to polymeric carbohydrate fuels by integrating enzymatic starch depolymerization with downstream electrochemical oxidation. To our knowledge, this represents the first demonstration of a defined hybrid organic–enzymatic cascade designed to drive progression of starch-derived glucose equivalents toward terminal oxidation using a minimal catalyst …

Environmental Engineers Develop Solutions To Problems Of Planetary Health: The Legacy Of Professor P. Aarne Vesilind, Daniel B. Oerther

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

The principal ethical obligation of the engineering profession, to "hold paramount the health, safety, and welfare of the public," has been challenged for decades. Professor P. Aarne Vesilind identified two primary deficiencies: an anthropocentric bias that values nature only instrumentally and the use of non-mandatory, aspirational language for environmental protection, which resulted in the exclusion of enforceable environmental canons. This paper argues that two recent developments provide a comprehensive response to Vesilind's recommendations for engineering ethics. First, the United States Bureau of Labor Statistics has redefined environmental engineering as "developing solutions to problems of planetary health." Second, Oerther proposed a …

Fairrfl: Fair And Robust Federated Learning In The Presence Of Selfish Clients, Andrea Augello, Ashish Gupta, Giuseppe Lo Re, Sajal K. Das

Computer Science Faculty Research & Creative Works

Federated Learning (FL) is a paradigm that enables collaborative machine learning without disclosing the local data of the participants. However, in real-world FL deployment scenarios, some unscrupolous clients may alter the training process to skew the global model towards their local optimum, unfairly prioritizing their data distribution. Their influence can degrade overall model performance for normal clients and reduce fairness in the system. We call this novel category of misbehaving clients 'selfish'. This work proposes a Fair and Robust strategy for aggregation in the Federated Learning (FL) server to mitigate the effect of Selfish clients (FairRFL). FairRFL incorporates a novel …

Evaluation And Design Of A Footing Hybrid Connection For Innovative Hollow-Core Fiber-Reinforced Polymer–Concrete–Steel Composite Columns, Mohanad M. Abdulazeez, Mohamed A. Elgawady

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

To support the advancement of accelerated bridge construction in high-seismic regions, this study investigates a novel prefabricated column-to-footing connection designed for improved resiliency, constructability, and cost efficiency. The socket connection utilizes hollow-core fiber-reinforced polymer–concrete–steel (HC-FCS) columns with embedded corrugated steel pipes (CSPs). The composite HC-FCS column consists of a concrete shell sandwiched between an outer fiber-reinforced polymer tube and an inner steel tube. The inner steel tube is embedded into the footing connection of the HC-FCS column. The same authors tested the innovative socket connection on a large HC-FCS column under seismic loads, showing high ductility, strong moment and drift …

Exploring Aggregate Morphological Characteristics Under Laboratory Polishing For Enhanced Pavement Skid Resistance, Ahmed S. El-Ashwah, Magdy Abdelrahman

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

As the use of recycled asphalt pavement (RAP) in pavement construction grows for sustainable development, it becomes essential to investigate potential frictional deterioration over time. This study evaluated the friction properties of recovered RAP material aggregates compared with raw aggregates across various polishing cycles. The micro-Deval test was employed to simulate aggregate loss of texture, while morphological and friction properties were measured using an aggregate imaging measurement system (AIMS-II), along with a British pendulum tester (BPT) and dynamic friction tester (DFT). Additionally, Fourier transform infrared spectroscopy (FTIR) was employed to assess its potential in determining the origin and composition of …

Cervical Ligament Systems In Sauropod Dinosaurs: What Support Is There?, Audrey Rose Williams

Masters Theses

"Sauropod dinosaurs, such as Diplodocus, have been the subject of numerous hypotheses about what ligamentous structures could have lifted and supported their long necks. Because the supportive tissues rarely fossilize, palaeontologists rely on osteological correlates on the bone to infer their nature. Options for supportive cervical ligaments in sauropods are mammal-style nuchal ligaments, avian-style interlaminar elastic ligaments, reptilian-style supraspinal ligaments, or some combination thereof. This study tested for the presence of a mammal-style nuchal ligament via histological and micro-computed tomography of posterior cervical hemispinous processes of Apatosaurus and Diplodocus, in addition to examining gross morphological features of the cervical vertebrae …

High Temperature Diffraction From Aerodynamically Levitated Materials, Chris J. Benmore, Stephen K. Wilke, David Lipke, Richard Weber

Materials Science and Engineering Faculty Research & Creative Works

Aerodynamic levitation combined with laser beam heating has become an established technique for studying the structure of materials at ultra-high temperatures and under non-equilibrium conditions. This article briefly highlights some recent technical and scientific advancements in understanding the relationships between a material's behavior and its structure, investigated using diffraction methods. It focuses on three evolving frontiers: sophisticated sample environments for accessing metastable states and reactive chemistries, high-flux photon and neutron probes to reveal atomic structure, and advanced computational modeling frameworks. Free from contamination, containerless processing (levitation) can minimize heterogeneous nucleation at the interface, enabling access to deeply supercooled melts or …

Anisotropic Second-Harmonic Ince-Gaussian Beam Generation Using Nbobr2 Holograms, Jayanta Deka, Xiaodong Yang, Jie Gao

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Ince-Gaussian (IG) modes are a complete and orthogonal set of solutions to the paraxial wave equation in elliptic coordinates representing a continuous transition between Hermite-Gaussian modes and Laguerre-Gaussian modes. Chip-scale platforms to generate IG beams have great significance for various applications, including optical trapping and micromanipulation of particles, optical communication, and quantum optics. On the other hand, materials with high optical anisotropy are crucial for building polarization-sensitive optical devices. In this context, niobium oxide dihalides are a new class of ferroelectric materials exhibiting strong, tailorable, and highly anisotropic second-harmonic generation responses. Here, we report the generation of highly anisotropic second-harmonic …

Supersonic Wind Tunnel Free Stream Turbulence Characterization Using 2-Point Focused Laser Differential Interferometry, Joseph Villarreal, Joshua Gary, Davide Vigano

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Non-intrusive laser-based diagnostics, such as Two-Point Focused Laser Differential Interfer-ometry (2-FLDI), play a crucial role in modern aerodynamic research by enabling simultaneous measurements of density and velocity in compressible flows. A 2-FLDI system has been developed and implemented for the Missouri S&T Supersonic Wind Tunnel to characterize free stream turbulence fluctuations and free stream convective velocity. Design choices that enabled the 2-FLDI to overcome low turbulence to measure free stream velocity are detailed. The free stream velocity measurements are validated against previous particle image velocimetry data, showing good agreement. Analysis of normalized velocities and density-based turbulence intensities found that the …