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Tricatalytic Organocatalyst-Enzyme Hybrid Cascade For Improving Complete Oxidation Of Glucose To Carbon Dioxide, Adam Milam, Rokas Gerulskis, Jose Intano, Shelley D. Minteer Jan 2025

Tricatalytic Organocatalyst-Enzyme Hybrid Cascade For Improving Complete Oxidation Of Glucose To Carbon Dioxide, Adam Milam, Rokas Gerulskis, Jose Intano, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

Advancing energy harvesting is crucial for the development of wearable and implantable technologies. Given the high concentration of complex fuels, such as glucose, in biological fluids, biofuel cells present a promising avenue for exploration. However, glucose fuel cells that have been published to date typically catalyze only one or two of the maximum 12 oxidation steps for glucose, resulting in low energy density. Although known multienzyme cascades, which are sequential biochemical reactions where multiple enzymes work in tandem to convert a substrate into a final product, have addressed this inefficiency, they come with several trade-offs, such as reduced power density …


Mindful Or Mindless? How And Why Virtual Communities Fail To Contain Information Pollution Across Different Disasters, Mahmudul Hasan, Varqa Shamsi Bahar, Cecil Eng Huang Chua, Michael David Myers Jan 2025

Mindful Or Mindless? How And Why Virtual Communities Fail To Contain Information Pollution Across Different Disasters, Mahmudul Hasan, Varqa Shamsi Bahar, Cecil Eng Huang Chua, Michael David Myers

Business and Information Technology Faculty Research & Creative Works

People visit virtual communities to find trusted information (i.e. verifiable, accurate and reliable information) during disasters. Virtual communities are open spaces where people interact and share information. However, virtual communities often suffer from information pollution (including too much information and false or contradictory information) which decreases peoples' ability to find trusted information. Oddly, some virtual communities will develop useful practices for combatting information pollution during one disaster but subsequently fail to effectively employ the same practices or adapt them in subsequent disasters. We conducted a longitudinal, exploratory cross-case study to better understand how and why this occurs. Using the lenses …


Virtual Network Embedding: Literature Assessment, Recent Advancements, Opportunities, And Challenges, Anurag Satpathy, Manmath Narayan Sahoo, Chittaranjan Swain, Paolo Bellavista, Mohsen Guizani, Khan Muhammad, Sambit Bakshi Jan 2025

Virtual Network Embedding: Literature Assessment, Recent Advancements, Opportunities, And Challenges, Anurag Satpathy, Manmath Narayan Sahoo, Chittaranjan Swain, Paolo Bellavista, Mohsen Guizani, Khan Muhammad, Sambit Bakshi

Computer Science Faculty Research & Creative Works

Network virtualization (NV) allows service providers (SPs) to instantiate logically isolated entities called virtual networks (VNs) on top of a substrate network (SN). Though VNs bring about multiple benefits, particularly in terms of economic costs and elasticity, they also force various technical challenges to be addressed. The primary one is the issue of optimally allocating resources to VNs, also termed virtual network embedding (VNE). This paper presents an exhaustive survey of VNE by extensively covering the state-of-the-art research field in this very active field and focusing on the emerging research trends in industry and academia over the last decade. In …


Citrus: Cost And Ischemia Time Reduction Using Urban Air Mobility Solutions For Organ Transport, Debjyoti Sengupta, Anurag Satpathy, Arindam Khanda, Sajal K. Das Jan 2025

Citrus: Cost And Ischemia Time Reduction Using Urban Air Mobility Solutions For Organ Transport, Debjyoti Sengupta, Anurag Satpathy, Arindam Khanda, Sajal K. Das

Computer Science Faculty Research & Creative Works

Urban Air Mobility (UAM) involves the use of both piloted and autonomous aerial vehicles, ranging from small unmanned aerial vehicles (UAVs), such as drones, to larger passenger-carrying personal air vehicles (PAVs). This ground-breaking approach holds the potential to transform healthcare logistics by facilitating the fast and efficient transportation of organs between hospitals, addressing critical mobility challenges in healthcare delivery. However, scheduling organ transport is fraught with challenges, including (1) the limited availability of UAM vehicles at specific hospital branches, (2) the critical Cold Ischemia Time (CIT) for various organs, and (3) the high flying costs associated with moving organs from …


Content Subversion Against 1 Information-Based Systems, Junjie Xiong, Ian Markwood, Dakun Shen, Yao Liu, Zhuo Lu Jan 2025

Content Subversion Against 1 Information-Based Systems, Junjie Xiong, Ian Markwood, Dakun Shen, Yao Liu, Zhuo Lu

Computer Science Faculty Research & Creative Works

We present a novel class of content subversion attacks against information-based services, causing documents to appear to humans dissimilar to the underlying content extracted by information-based services. We demonstrate the significant impact of these attacks on real-world systems through five distinct variants. Our first attack allows academic paper writers and reviewers to collude via subverting the automatic reviewer assignment systems in current use by academic conferences including INFOCOM, which we reproduced. Our second attack renders ineffective plagiarism detection software, particularly Turnitin, targeting specific small plagiarism similarity scores to appear natural and evade detection. In our third attack, we place masked …


Applications Of Uav In Landslide Research: A Review, Boneng Chen, Jeremy Maurer, Weibing Gong Jan 2025

Applications Of Uav In Landslide Research: A Review, Boneng Chen, Jeremy Maurer, Weibing Gong

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Uncrewed aerial vehicles (UAVs), commonly known as drones, have gained significant popularity in landslide research due to their operational flexibility, near real-time planning capabilities, cost-effectiveness, high-resolution data outputs, and enhanced safety. This review aims to provide an analysis of UAV-based landslide investigation methodologies and their applications. It begins with an examination of UAV platforms and UAV-equipped sensors employed in landslide research, evaluating their advantages and limitations to guide appropriate platform and sensor selection. The review then explores UAV applications across three primary landslide investigation domains: landslide mapping, landslide monitoring, and landslide hazard assessment, highlighting some representative achievements in each domain. …


Visual Understanding Of Rock Wettability Distribution To Contact Angle Regions And Oil Displacement Patterns In The Silty Sand Reservoir Via 2d Pore-Scale Modeling, H. Al-Ajaj, W. Al-Bazzaz, Ralph E. Flori, S. Alsayegh, H. Almubarak, D. S. Ibrahim, H. Al-Saedi Jan 2025

Visual Understanding Of Rock Wettability Distribution To Contact Angle Regions And Oil Displacement Patterns In The Silty Sand Reservoir Via 2d Pore-Scale Modeling, H. Al-Ajaj, W. Al-Bazzaz, Ralph E. Flori, S. Alsayegh, H. Almubarak, D. S. Ibrahim, H. Al-Saedi

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

This study, conducted using a silty sand reservoir rock extracted from a Kuwait-producing oilfield, provides crucial insights into fluid distribution patterns and mineralogy, as well as wettability contact angle preferences. The method used for visual identification not only captures rock physics but also suggests effective oil recovery displacement strategies. Visual identification is presented using 2D image technology and a Scanning Electron Microscope (SEM). Analytical data are presented from electron bombardments and backscattering reflections collected in the BSE detector. These analyses were used to characterize the various surface boundary morphology parameters of the silty sand mineral surfaces, including area, perimeter, mineral …


Investigation Of Dynamic Adsorption And Desorption Of Polymer Nanogel In Porous Media Through Microfluidics, Junchen Liu, Fuqiao Bai, Abdulaziz A. Almakimi, Mingzhen Wei, Xiaoming He, Ibnelwaleed A. Hussein, Baojun Bai Jan 2025

Investigation Of Dynamic Adsorption And Desorption Of Polymer Nanogel In Porous Media Through Microfluidics, Junchen Liu, Fuqiao Bai, Abdulaziz A. Almakimi, Mingzhen Wei, Xiaoming He, Ibnelwaleed A. Hussein, Baojun Bai

Mathematics and Statistics Faculty Research & Creative Works

Understanding the transport and retention of elastic nanogel and microgel particles in porous media has been a significant research subject for decades, essential to the application of enhanced oil recovery (EOR). However, a lack of dynamic adsorption and desorption studies, in which the kinetics in porous media are seldom investigated, hinders the design and application of polymer nanogel in underground porous media. In this work, we visualized and quantified the transport and dynamic adsorption of polymer nanogel in 3D glass micromodels that were manufactured by packing glass beads in capillaries. Calibrating the linearity of fluorescence intensity to concentration, we calculated …


A Novel Technique For Improved Measurement Of Graphite And Inclusions In Ductile Iron Contaminated By Boron, Chase Schroeder, Colleen Lehrer, Simon Lekakh, Laura Bartlett Jan 2025

A Novel Technique For Improved Measurement Of Graphite And Inclusions In Ductile Iron Contaminated By Boron, Chase Schroeder, Colleen Lehrer, Simon Lekakh, Laura Bartlett

Materials Science and Engineering Faculty Research & Creative Works

The highly heterogeneous microstructure of ductile iron in casting includes graphite particles, non-metallic inclusions, microporosity, and other features, such as carbides distributed in the ferrite–pearlite matrix. Determination and comprehensive quantification of microstructural features are practically important however challenging. An advanced methodology based on an automated SEM/EDX analysis was developed and compared to the standard optical imaging method. In addition to backscattered electron contrast, sensitive to atomic number, a novel methodology added EDX data to identify and classify the multiple structural features at micron resolution thresholding. To quantify the shape of individual phases, the eight chord raster algorithms was used and …


Radio Frequency Wave Propagation Modeling Within Obstructed Underground Mining Environments For Effective Miner Localization During Mine Emergencies, Emmanuel Atta Antwi Jan 2025

Radio Frequency Wave Propagation Modeling Within Obstructed Underground Mining Environments For Effective Miner Localization During Mine Emergencies, Emmanuel Atta Antwi

Doctoral Dissertations

The reliability of underground wireless communication systems remains a significant challenge, particularly during emergencies when the mine environment becomes severely obstructed by debris, dust, and humidity. These environmental and geometric conditions result in significant attenuation of electromagnetic (EM) waves and multipath effects that undermine miner localization and rescue operations. Existing Vector Parabolic Equation (VPE) models are efficient for straight or mildly curved tunnels but fail to account for the random and obstructive conditions typically encountered during underground emergencies. This research develops a novel radio propagation model for EM wave behavior in underground mine drifts under geometrically obstructed conditions. The model …


The Role Of Mineral Raw Material Imports In Driving The Energy Transition, Mahelet G. Fikru, Nurcan Kilinc-Ata Jan 2025

The Role Of Mineral Raw Material Imports In Driving The Energy Transition, Mahelet G. Fikru, Nurcan Kilinc-Ata

Economics Faculty Research & Creative Works

This study contributes to the mineral-energy nexus by examining the role of importing mineral raw materials (ores and concentrates) on subsequent progress in the energy transition among 33 countries from 1992 to 2015. We focus on net imports of ores and concentrates for five energy transition minerals (copper, cobalt aluminum, nickel, and manganese) and present an economic production framework to link the mineral raw materials with renewable electricity generation shares. The distinction between mineral raw materials and processed/refined inputs is important because processing capabilities vary among nations, influencing their import-export dynamics and energy transition strategies. Our empirical analysis based on …


Re-Crosslinkable Particle For Conformance Control And Temporary Plugging, Yifu Long, Bowen Yu, Baojun Bai, Thomas P. Schuman Jan 2025

Re-Crosslinkable Particle For Conformance Control And Temporary Plugging, Yifu Long, Bowen Yu, Baojun Bai, Thomas P. Schuman

Patents

The present invention generally relates to the composition of particle gels for conformance control, well drilling and well treatments. More particularly, this invention relates to swellable polymer particle gels that can re-crosslink, i.e., reassociate and self-heal, at subterranean conditions. These particle gels can be deployed to improve the conformance of water flooding of especially matrix bypass events (MBEs), that are also known as void space conduits. Moreover, these particle gels can be deployed for controlling the water production and increasing of petroleum recovery. The inventive particles can also be deployed as diverter for well stimulation.


Evaluation Of Processing Conditions For The Reduction Of Electrochemical Salt Waste Using Phosphate-Based Dechlorination, Harmony Werth, Jade Beland, Paige Murray, Dave Liang, Laurel Sharpless, Jonathan Evarts, Charmayne Lonergan, Brian J. Riley, Michael Simpson, Krista Carlson Jan 2025

Evaluation Of Processing Conditions For The Reduction Of Electrochemical Salt Waste Using Phosphate-Based Dechlorination, Harmony Werth, Jade Beland, Paige Murray, Dave Liang, Laurel Sharpless, Jonathan Evarts, Charmayne Lonergan, Brian J. Riley, Michael Simpson, Krista Carlson

Materials Science and Engineering Faculty Research & Creative Works

Electrochemical processing of used nuclear fuel in molten chloride salts generates complex radioactive salt waste. Dechlorination of waste salt using phosphate compounds at elevated temperatures (∼600 °C) reduces the volume of material for disposal while evolving gaseous chlorine compounds that could be used to transform metallic uranium into UCl3. In this study, the effects of processing temperature, environment (air or argon), and H3PO4 precursor-to-chlorine ratio on the dechlorination efficacy of a simple alkali salt mixture (SSM) and a salt waste simulant (ERV3) were evaluated. For both salts, the highest chlorine release was concurrent with the water boiling. For the SSM, …


Yolo-Based Miner Detection Using Thermal Images In Underground Mines, Cyrus Addy, Venkata Sriram Siddhardh Nadendla, Kwame Awuah-Offei Jan 2025

Yolo-Based Miner Detection Using Thermal Images In Underground Mines, Cyrus Addy, Venkata Sriram Siddhardh Nadendla, Kwame Awuah-Offei

Computer Science Faculty Research & Creative Works

Well-designed and effective in-mine robots can expedite miner self-rescue during emergencies and reduce fatalities. These in-mine robots for miner self-rescue can carry out diverse tasks such as scouting (including object detection and autonomous navigation), and payload delivery. However, robots that can effectively detect humans in a dark underground mine do not yet exist. This paper investigates challenges in the design of object detection algorithms for in-mine robots using thermal images, especially to detect people in real-time, in low-light conditions. The research team collected 500 thermal images in the Missouri University of Science & Technology Experimental Mine with the help of …


Exploring The Link Between Hy Wet Ball Mill Work Index And Grinding Energy Consumption, Chen Peng, Hou Ying, Lv Hongxu, Sobhy Ahmed Jan 2025

Exploring The Link Between Hy Wet Ball Mill Work Index And Grinding Energy Consumption, Chen Peng, Hou Ying, Lv Hongxu, Sobhy Ahmed

Mining Engineering Faculty Research & Creative Works

In evaluating ore grinding energy consumption using the Bond ball mill work index, discrepancies were identified. As a result, an investigation into the determination method of Hou Ying (HY) wet ball milling work index (WHY) for Gongchangling magnetite ore was conducted to determine the correlation between WHY and grinding energy consumption at varying particle sizes. The research results indicated that WHY had an error less than 3.33%, which is closely aligned with on-site grinding energy consumption. This surpassed the numerical error of 15.9% in the Bond ball grinding power index and demonstrated superior accuracy in representing ore grinding energy consumption, …


Ultrathin Film Coating And Element Doping For Lithium-Ion Battery Electrodes, Xinhua Liang, Yan Gao Jan 2025

Ultrathin Film Coating And Element Doping For Lithium-Ion Battery Electrodes, Xinhua Liang, Yan Gao

Patents

The present invention relates to various lithium ion battery cathodes as well as lithium ion batteries incorporating one or more of these cathodes. The present invention further relates to processes of preparing the lithium ion battery cathode.


Incremental Cluster Validity Index-Based Offline Clustering For Machine Learning, Leonardo Enzo Brito Da Silva, Donald C. Wunsch Ii, Nagasharath Rayapati Jan 2025

Incremental Cluster Validity Index-Based Offline Clustering For Machine Learning, Leonardo Enzo Brito Da Silva, Donald C. Wunsch Ii, Nagasharath Rayapati

Patents

A neural network model replaces the supervised labeling component of a supervised learning system with an incremental cluster validity index-based unsupervised labeling component. An implementation is presented combining fuzzy adaptive resonance theory predictive mapping (ARTMAP) and incremental cluster validity indices (iCVI) for unsupervised machine learning purposes, namely the iCVIARTMAP. An iCVI module replaces the adaptive resonance theory (ART) module B of a fuzzy ARTMAP neural network model and provides assigmnents of input samples to clusters (i.e., labels) at each learning iteration in accordance to any of several possible iCVI methods described. A map field incrementally builds a many-to-one mapping of …


Mobile Robot Configured To Determine Human Arm Stiffness During Overground Interaction, Sambad Regmi, Yun Seong Song Jan 2025

Mobile Robot Configured To Determine Human Arm Stiffness During Overground Interaction, Sambad Regmi, Yun Seong Song

Patents

A mobile robot system and method for determining the stiffness of a human arm while moving with a user during overground interaction as the user holds the robot's handle and exchanges forces with it. A mobile base moves with the user, a robot arm interacts with the user, and a controller determines the stiffness. The robot arm includes servomotors driving a linkage mechanism, an end effector including the handle supported by the linkage mechanism, and a force transducer measuring a force applied by the user to the handle. The controller causes the robot arm to generate a force perturbation at …


Hydrogen Permeation In Iron-Chromium-Aluminum (Fecral) Alloys And The Effects Of Microstructure And Surface Oxide, Nathan T. Gehmlich, Thomas F. Fuerst, Hanns Gietl, Chase N. Taylor, Joshua Rittenhouse, Haiming Wen, M. Nedim Cinbiz Jan 2025

Hydrogen Permeation In Iron-Chromium-Aluminum (Fecral) Alloys And The Effects Of Microstructure And Surface Oxide, Nathan T. Gehmlich, Thomas F. Fuerst, Hanns Gietl, Chase N. Taylor, Joshua Rittenhouse, Haiming Wen, M. Nedim Cinbiz

Materials Science and Engineering Faculty Research & Creative Works

Iron–chromium–aluminum (FeCrAl) class alloys are candidates for use as cladding for accident-tolerant fuels and moderators. In this context, hydrogen isotope permeation in FeCrAl alloys is an important material property. In the present work, the apparent permeability, effective diffusivity, and apparent solubility of hydrogen in the FeCrAl alloys C26M and Kanthal D (KD) were measured with gas-driven hydrogen permeation. Permeation measurements were conducted at temperatures of 400 to 700 °C and at gas-driven pressures from 1 to 100 kPa. In particular, the effect of grain size on hydrogen transport was studied with KD samples with three different microstructures: nanocrystalline (NC), ultra-fine …


Dual-Bed Radioiodine Capture From Complex Gas Streams With Zeolites: Regeneration And Reuse Of Primary Sorbent Beds For Sustainable Waste Management, Krista Carlson, Brian J. Riley, Joshua Turner, David C. Cantu, Dev Chidambaram, Charmayne Lonergan, Jeffrey D. Rimer Jan 2025

Dual-Bed Radioiodine Capture From Complex Gas Streams With Zeolites: Regeneration And Reuse Of Primary Sorbent Beds For Sustainable Waste Management, Krista Carlson, Brian J. Riley, Joshua Turner, David C. Cantu, Dev Chidambaram, Charmayne Lonergan, Jeffrey D. Rimer

Materials Science and Engineering Faculty Research & Creative Works

No abstract provided.


Degradation Of Radioactive Waste Encapsulation Of Bao−Feox−P2o5 Glass Evaluated From Electrical Conductivity, Kazuki Mitsui, Nobuyasu Nishioka, Hiromichi Takebe, Richard K. Brow, Akira Saitoh Jan 2025

Degradation Of Radioactive Waste Encapsulation Of Bao−Feox−P2o5 Glass Evaluated From Electrical Conductivity, Kazuki Mitsui, Nobuyasu Nishioka, Hiromichi Takebe, Richard K. Brow, Akira Saitoh

Materials Science and Engineering Faculty Research & Creative Works

We report on the electrical conductivity of barium iron phosphate glass, a candidate for radioactive waste encapsulating glass. The glass composition has been optimized for slow dissolution in hot water because the precipitation of a stable hydration layer of FeO(OH) on the glass surface enhances the water durability of the glass. The mechanism of electrical conductivity of the glass is assumed to be an electron hopping between the electronic energy levels of Fe (II) and Fe (III) ions, obeying the electron carrier generation of Fe (II) → Fe (III) + e−. The electrical conductivity of the base glass was ∼3.2 …


Understanding Heterogeneous Nucleation In Iron Alloys From First Principles: A Review And Discussion, Semen Naumovich Lekakh Jan 2025

Understanding Heterogeneous Nucleation In Iron Alloys From First Principles: A Review And Discussion, Semen Naumovich Lekakh

Materials Science and Engineering Faculty Research & Creative Works

Heterogeneous nucleation during solidification plays a key role in structure formation of different types of iron-based alloys, including steels and cast irons. A review summarizes the novel theoretical methods which were used to understand the nature of heterogeneous nucleation in iron-based alloys. An ab initio simulation of atomic adsorption was used to predict the activity of heterogeneous nuclei, and the thermodynamic methods were applied to design conditions for desired precipitate formation in the iron melts. A high-resolution TEM study of individual nucleus and statistics of nuclei family, obtained from an automated SEM/EDX analysis, illustrates a possibility to design processes of …


Ground Testing Of A Magnetic-Electrostatic Separation System For Lunar Regolith Beneficiation, Peter Bachle, Charles Wood, Jeffrey Smith, Fateme Rezaei, David Bayless, William Schonberg, Daoru Han Jan 2025

Ground Testing Of A Magnetic-Electrostatic Separation System For Lunar Regolith Beneficiation, Peter Bachle, Charles Wood, Jeffrey Smith, Fateme Rezaei, David Bayless, William Schonberg, Daoru Han

Materials Science and Engineering Faculty Research & Creative Works

The separation of lunar regolith by mineral composition and size category is useful forin-situ resource utilization (ISRU). The research presented herein discusses the designing and development of equipment that has the potential to separate lunar regolith into aluminum, iron-titanium, and magnesium-iron ores. Along with the metal ore separation, this equipment shows the potential to separate regolith by size categories. The combined effect of these separation methods generates output that is valuable to subsequent use in metal and oxygen extraction, additive manufacturing, and regolith sintering processes. The designed equipment uses a dual-strength magnet system with N42 and N52 neodymium magnets for …


The Effect Of Carbon Equivalent And Nodularity On Multi-Axial Casting Wall Movement During Spheroidal Graphite Iron Solidification And Cooling, Noah J. Brack, Mingzhi Xu, Jingjing Qing, Simon Lekakh Jan 2025

The Effect Of Carbon Equivalent And Nodularity On Multi-Axial Casting Wall Movement During Spheroidal Graphite Iron Solidification And Cooling, Noah J. Brack, Mingzhi Xu, Jingjing Qing, Simon Lekakh

Materials Science and Engineering Faculty Research & Creative Works

Spheroidal graphite iron, also known as ductile iron, is an iron–carbon casting alloy used in industry for its good castability, balanced mechanical properties, and low cost. Ductile iron consists of round graphite nodules in an iron matrix. During solidification and cooling, ductile iron castings experience dynamic volume changes due to the precipitation of graphite nodules and formation of austenite. These dynamic volume changes can distort external casting surfaces, causing swell and shrinkage porosity. A novel apparatus was custom-built to capture the casting wall movement in real time along three axes. This study found that casting expansion increased with carbon equivalent …


Controlling Nitrogen Pickup During Induction Melting Of Ultrahigh-Strength Cr-Ni-Mo-V Steels, Kingsley T. Amatanweze, Viraj A. Athavale, Mario F. Buchely, Laura N. Bartlett, Ronald J. O'Malley, Daniel M. Field Jan 2025

Controlling Nitrogen Pickup During Induction Melting Of Ultrahigh-Strength Cr-Ni-Mo-V Steels, Kingsley T. Amatanweze, Viraj A. Athavale, Mario F. Buchely, Laura N. Bartlett, Ronald J. O'Malley, Daniel M. Field

Materials Science and Engineering Faculty Research & Creative Works

Nitrogen pickup during air induction melting can result in porosity and a loss of fracture toughness in ultrahigh-strength quenched and tempered steel castings. Nitrogen atoms are easily adsorbed into liquid steel upon exposure to the air, and argon shrouding alone has limited effectiveness. Previous studies have shown that proper charge sequencing and maintaining a high amount of dissolved oxygen in the melt prior to tapping and deoxidation can limit nitrogen pickup in the melt. In the current study, the effect of melt practice and charging procedure on nitrogen pickup was studied as a function of hold time in a series …


Zrc Particle Size Effect On The Mechanical Properties Of Spark Plasma Sintered 60–40 Vol% Zrc–Mo Cermets, Nathaniel Blatt, Jeremy Watts, Brian Taylor, Jhonathan Rosales, Gregory Hilmas Jan 2025

Zrc Particle Size Effect On The Mechanical Properties Of Spark Plasma Sintered 60–40 Vol% Zrc–Mo Cermets, Nathaniel Blatt, Jeremy Watts, Brian Taylor, Jhonathan Rosales, Gregory Hilmas

Materials Science and Engineering Faculty Research & Creative Works

Cermet's of 60 vol% ZrC and 40 vol% Mo with different starting ZrC particle sizes were spark plasma sintered to full density at 1950 °C. Elastic moduli, Vickers hardness and fracture toughness were measured at room temperature and flexural strength was measured up to 1600 °C. Young's modulus was 365 ± 5 GPa, shear modulus was 149 ± 2 GPa, Poisson's ratio was 0.22 ± 0.01, and no significant difference was observed for the moduli with respect to the starting ZrC particle size. Room temperature flexural strength was affected by the ZrC particle size, measured as ∼524 and ∼598 MPa …


Parametric Analysis Of Water Jet Descaling Efficiency Of Reheated Continuously Cast Thin Slab, Tochukwu P. Ojiako, Mario F. Buchely, Simon Lekakh, Ronald J. O'Malley, Richard Osei, Taha Tayebali Jan 2025

Parametric Analysis Of Water Jet Descaling Efficiency Of Reheated Continuously Cast Thin Slab, Tochukwu P. Ojiako, Mario F. Buchely, Simon Lekakh, Ronald J. O'Malley, Richard Osei, Taha Tayebali

Materials Science and Engineering Faculty Research & Creative Works

Efficient oxide scale removal is critical for maintaining surface quality and process efficiency in steel manufacturing. This study optimizes water jet descaling by evaluating the performance of flat and rotary jet nozzles under varying process parameters. Using a combined approach of experimental analysis and computational fluid dynamics, it investigates the influence of pressure (138–275 bar), lead angle (0°, 15°, 25°), working distance (50–100 mm), and spray angle (15°–25°) on descaling efficiency. Findings indicate that flat jet nozzles achieve superior performance at short working distances due to concentrated impact forces, while rotary jet nozzles sustain efficiency over extended distances through dynamic …


Effect Of Gating Design On Filling And Inclusion Control In An Al-Killed Cr-Mo-Ni Steel, Kingsley T. Amatanweze, Koushik Balasubramanian, Soumava Chakraborty, Viraj A. Athavale, Mario F. Buchely, Laura N. Bartlett, Ronald J. O'Malley, Daniel M. Field, Krista R. Limmer, Katherine M. Sebeck Jan 2025

Effect Of Gating Design On Filling And Inclusion Control In An Al-Killed Cr-Mo-Ni Steel, Kingsley T. Amatanweze, Koushik Balasubramanian, Soumava Chakraborty, Viraj A. Athavale, Mario F. Buchely, Laura N. Bartlett, Ronald J. O'Malley, Daniel M. Field, Krista R. Limmer, Katherine M. Sebeck

Materials Science and Engineering Faculty Research & Creative Works

The effect of gating system design on the inclusion population and size distribution in an aluminum-killed low-alloy advanced high strength steel casting was studied. A mold with four different gating systems: pressurized and non-pressurized with side risers, naturally pressurized with a side riser, and naturally pressurized with a top riser, was designed using computational fluid dynamics and solidification software. The design allowed inclusion populations in castings produced with each gating system to be compared during the same pouring event. Samples taken from different positions just below the top surface of each casting were analyzed using an SEM/EDS system with automated …


High-Temperature Performance Of Alloyed Cast Irons And Cr/Ni Austenitic Steels—An Overview And Discussion, Simon N. Lekakh, Mei Li, Larry Godlewski Jan 2025

High-Temperature Performance Of Alloyed Cast Irons And Cr/Ni Austenitic Steels—An Overview And Discussion, Simon N. Lekakh, Mei Li, Larry Godlewski

Materials Science and Engineering Faculty Research & Creative Works

Fe-based cast alloys, including cast irons and steels, have been used in service at a wide range of mechanical and thermal load in oxidizing environment. Special alloying practices can be used to improve high temperature performance of Fe-based cast alloys in an oxidizing atmosphere. At elevated temperatures, alloying elements can produce a protective interface layer which prevents oxidant penetration into the metal matrix. However, a combination of thermo-mechanical loads along with surface oxidation can decrease the materials integrity by destroying the stable protected interface limiting the range of working parameters and lifetime performance of the material. This overview aims to …


Ultrafast Belite (Β-C2s) Production Using Biofuel-Based Combustion Synthesis, Shubham Agrawal, Sayee Srikarah Volaity, Oluwadamilare Charles Adesina, Bryan K. Aylas-Paredes, Taihao Han, Srinivas Kilambi, Aditya Kumar, Narayanan Neithalath Jan 2025

Ultrafast Belite (Β-C2s) Production Using Biofuel-Based Combustion Synthesis, Shubham Agrawal, Sayee Srikarah Volaity, Oluwadamilare Charles Adesina, Bryan K. Aylas-Paredes, Taihao Han, Srinivas Kilambi, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

This study presents a novel low-temperature, combustion synthesis (CS) approach for the rapid production of belite-rich cements. CS leverages the exothermic heat released from the combustion of biofuels such as lignin and/or biomass, intermixed with pelletized limestone and quartz. At an imposed furnace temperature of ∼700°C (as opposed to 1200°C–1300°C required in a conventional kiln), the source materials are rapidly transformed to belite, resulting in energy, emissions, and economic benefits. This work explores the influence of various process parameters, viz., fuel types and contents, airflow rate, porosity, holding temperature, and holding time on the efficiency of CS-based belite synthesis. Through …