Digital Commons Network^™

Nmr Study Of Co2 Capture By Butylamine And Oligopeptide Kdde In Aqueous Solution: Capture Efficiency And Gibbs Free Energy Of The Capture Reaction As A Function Of Ph**, Kaidi Yang, Joseph Schell, Fabio Gallazzi, Wei Wycoff, Rainer Glaser

Chemistry Faculty Research & Creative Works

We Have Been Interested in the Development of Rubisco-Based Biomimetic Systems for Reversible CO₂ Capture from Air. Our Design of the Chemical CO₂ Capture and Release (CCR) System is Informed by the Understanding of the Binding of the Activator CO₂ (^ACO₂) in Rubisco (Ribulose-1,5-Bisphosphate Carboxylase/oxygenase). the Active Site Consists of the Tetrapeptide Sequence Lys-Asp-Asp-Glu (Or KDDE) and the Lys Sidechain Amine is Responsible for the CO₂ Capture Reaction. We Are Studying the Structural Chemistry and the Thermodynamics of CO₂ Capture based on the Tetrapeptide CH₃CO−KDDE−NH₂ ("KDDE") in Aqueous …

Nanostructured Ternary Nickel-Based Mixed Anionic (Telluro)-Selenide As A Superior Catalyst For Oxygen Evolution Reaction, Ibrahim Munkaila Abdullahi, Siby Thomas, Alessio Gagliardi, Mohsen Asle Zaeem, Manashi Nath

Chemistry Faculty Research & Creative Works

Developing Protocols for Designing High-Efficiency, Durable, Cost-Effective Electrocatalysts for Oxygen Evolution Reaction (OER) Necessitates Deeper Understanding of Structure–property Correlation as a Function of Composition. Herein, It Has Been Demonstrated that Incorporating Tellurium into Binary Nickel Chalcogenide (NiSe) and Creating a Mixed Anionic Phase Perturbs its Electronic Structure and Significantly Enhances the OER Activity. a Series of Nanostructured Nickel Chalcogenides Comprising a Layer-By-Layer Morphology Along with Mixed Anionic Ternary Phase Are Grown in Situ on Nickel Foam with Varying Morphological Textures using Simple Hydrothermal Synthesis Route. Comprehensive X-Ray Diffraction, X-Ray Photoelectron Spectroscopy, and in Situ Raman Spectroscopy Analysis Confirms the Formation …

Natural Product Co-Metabolism And The Microbiota–Gut–Brain Axis In Age-Related Diseases, Mark Obrenovich, Sandeep Kumar Singh, Yi Li, George Perry, Bushra Siddiqui, Waqas Haq, V. Prakash Reddy

Chemistry Faculty Research & Creative Works

Complementary alternative medicine approaches are growing treatments of diseases to standard medicine practice. Many of these concepts are being adopted into standard practice and orthomolecular medicine. Age-related diseases, in particular neurodegenerative disorders, are particularly difficult to treat and a cure is likely a distant expectation for many of them. Shifting attention from pharmaceuticals to phytoceuticals and "bugs as drugs" represents a paradigm shift and novel approaches to intervention and management of age-related diseases and downstream effects of aging. Although they have their own unique pathologies, a growing body of evidence suggests Alzheimer's disease (AD) and vascular dementia (VaD) share common …

Electrodeposition Of Epitaxial Wide Bandgap P-Type Semiconductors And Copper Metal For Energy Conversion And Flexible Electronics, Bin Luo

Doctoral Dissertations

"Epitaxial electrodeposition is a simple, low-cost technology to produce highly ordered materials on single-crystal surfaces. This research focuses on the epitaxial electrodeposition of wide bandgap p-type semiconductors and epitaxial Cu thin films via a self-assembled monolayer for energy conversion and flexible electronics. Paper I introduces the epitaxial electrodeposition of hole conducting CuSCN nanorods onto Au (111) surface, and lift-off to produce flexible and transparent foils. Highly ordered CuSCN could serve as an inorganic transport layer in various opto-electronic devices such as perovskite solar cells, LEDs, and transistors. An ordered and transparent CuSCN foil was also produced by epitaxial lift-off following …

Novel Quantum Materials For Spintronic And Opto-Electronic Applications, Ali Sarikhani

Doctoral Dissertations

"Multi-functional quantum materials play a crucial role in the development of spintronics and opto-electronics, as their properties can greatly influence device performance. For instance, in spintronics, materials such as ferromagnetic half-metals, Giant Magnetoresistants (GMR), and magnetic semiconductors have been extensively studied due to their ability to manipulate the spin of electrons for applications in magnetic storage. In opto-electronics, materials such as Diluted Magnetic Semiconductors (DMS) and non-oxide Transparent Conductors (TC) offer advantages such as tunable bandgap and high absorption coefficients, which enable improved device performance.

For this purpose, we have experimentally investigated the compounds that have shown theoretically interesting physical …

Application Of Modeling Methodologies To Improve An Emergency Departments Workflow, Prachita Humane

Doctoral Dissertations

"The healthcare system in the United States is complex and challenging to understand, and the emergency department (ED) serves as a bridge between outpatient and inpatient care. According to the Centers for Disease Control and Prevention, over 130 million people visited emergency rooms in the United States in 2018. The ED is composed of multiple subunits and components that make it difficult to comprehend fully. In this study, a combination of engineering analysis methods was used to identify and understand the issues in the ED.

The first contribution of this research involved collecting data through job shadowing of human entities …

Sustainable Development: A Data Analysis Investigation For A New Conceptual Model, Case Study Comparison And Validation Techniques, Tiffanie Marie Toles

Doctoral Dissertations

"The three pillars model for sustainability, often represented with three intersecting circles described as economic, environmental, and social factors with sustainability being at the center is a complex and philosophically open model [1]. As society promotes efforts to reduce carbon impacts, there becomes a need to critically review the models employed for understanding. This research presents a validated methodology, an updated conceptual configuration of sustainability for overall use, as well as a sustainable development performance measurement system. Using the 2020 Sustainable Development Goals Index Data, 232 indicators from 193 countries were used to evaluate the efficacy of using more than …

Efficient High Order Ensemble For Fluid Flow, John Carter

Doctoral Dissertations

"This thesis proposes efficient ensemble-based algorithms for solving the full and reduced Magnetohydrodynamics (MHD) equations. The proposed ensemble methods require solving only one linear system with multiple right-hand sides for different realizations, reducing computational cost and simulation time. Four algorithms utilize a Generalized Positive Auxiliary Variable (GPAV) approach and are demonstrated to be second-order accurate and unconditionally stable with respect to the system energy through comprehensive stability analyses and error tests. Two algorithms make use of Artificial Compressibility (AC) to update pressure and a solenoidal constraint for the magnetic field. Numerical simulations are provided to illustrate theoretical results and demonstrate …

Advances In Differentially Methylated Region Detection And Cure Survival Models, Daniel Ahmed Alhassan

Doctoral Dissertations

"This dissertation focuses on two areas of statistics: DNA methylation and survival analysis. The first part of the dissertation pertains to the detection of differentially methylated regions in the human genome. The varying distribution of gaps between succeeding genomic locations, which are represented on the microarray used to quantify methylation, makes it challenging to identify regions that have differential methylation. This emphasizes the need to properly account for the correlation in methylation shared by nearby locations within a specific genomic distance. In this work, a normalized kernel-weighted statistic is proposed to obtain an optimal amount of "information" from neighboring locations …

Data Analytics Of Wettability Alteration With Surfactants In Carbonate Reservoirs, Ya Yao

Doctoral Dissertations

"Wettability alteration with surfactants has been widely applied to improve oil recovery in carbonate reservoirs. An effective surfactant huff-puff application design requires comprehensive guidelines about where, how, and when this method could be applied. Besides, traditional methods to design an effective application and optimize surfactant performance are dependent on extensive experiments and are time-consuming. This study is to assist in the design of surfactant huff-puff via statistical methods and machine learning techniques.

In this study, a dataset including 402 effective surfactant imbibition tests is established by collecting information from nearly 50 publications. The dataset provides a foundation for further data …

Essays On Conditional Heteroscedastic Time Series Models With Asymmetry, Long Memory, And Structural Changes, K C M R Anjana Bandara Yatawara

Doctoral Dissertations

"The volatility of asset returns is usually time-varying, necessitating the introduction of models with a conditional heteroskedastic variance structure. In this dissertation, several existing formulations, motivated by the Generalized Autoregressive Conditional Heteroskedastic (GARCH) type models, are further generalized to accommodate more dynamic features of asset returns such as asymmetry, long memory, and structural breaks. First, we introduce a hybrid structure that combines short-memory asymmetric Glosten, Jagannathan, and Runkle (GJR) formulation and the long-memory fractionally integrated GARCH (FIGARCH) process for modeling financial volatility. This formulation not only can model volatility clusters and capture asymmetry but also considers the characteristic of long …

Design, Modeling And Analysis Of An Ac-Ac Dual Active Bridge Converter, Kartikeya Jayadurga Prasad Veeramraju

Doctoral Dissertations

"The Solid-State Transformer (SST) is gaining attention as an alternative to conventional iron-core transformers in the power electronic community. The power industry's increasing demands for smaller size, higher efficiency, and greater energy density have made the SST an attractive option. Among various power electronic converter topologies, the Dual Active Bridge (DAB) has become popular for its bidirectional power flow capability and galvanic isolation, primarily in the DC application space. Advancements in semiconductor technologies have introduced new bidirectional switches, opening avenues for novel SST topologies. This research investigates the application of the DAB as a single-stage SST and focuses on advancements …

Introduction Of A Variable Inductance Transformer For The Design Of Resonant Power Converters, Angshuman Sharma

Doctoral Dissertations

"Magnetic integration is a hot topic in power electronics that concerns the use of a transformer's leakage and magnetizing inductances purposefully in isolated power electronic converters, thereby giving the opportunity to save the cost and footprint of any additional inductor. This is of prime interest, especially in CLLLC resonant converters which require up to three inductors. For a complete integration of these inductances, the concept of a variable inductance transformer (VIT) is introduced in this thesis. A VIT is an adaptive magnetic structure that facilitates an easy adjustment of both magnetizing and leakage inductances to meet their desired values. However, …

Promoting Enhanced Decision-Making And Proactive Management For Modularization In The Construction Industry Using Risk-Based Approach, Analytical Hierarchy Process, And Graph Theory, Mohamad Abdul Nabi

Doctoral Dissertations

"Modularization is an approach that can potentially mitigate many of the current construction industry’s challenges. Despite the documented advantages of modularization, the industry is still not able to capitalize on its full potential and benefits. The latter is due to the outdated decision-making models that may not reflect the multiple factors involved in modular construction, the unique source of risks associated with modular construction methods, need for continuous improvement, and complex contractual requirements and disputes. As such, the goal is to promote the use of modularization in the construction industry by enhancing decision-making and proactive risk management. The associated objectives …

Fluorination Of Rubisco-Mimetic Co2 Capture Systems. Theoretical And Experimental Studies Of Ammonium Ion Acidity Depression And Carbamylation, Brian Michael Jameson

Doctoral Dissertations

"RuBisCO-inspired CO₂ capture and release (CCR) systems featuring amines have been developed for the purpose of reversable CO₂ capture from air. The enzyme active site consists of the tetrapeptide sequence Lys-Asp-Asp-Glu. The Lys sidechain amine undergoes carbamylation and an Mg²⁺ cation stabilizes the resulting carbamate. The N^a-acyl-lysinyl-aspratyl-aspartyl-glutamide (Lys-Asp-Asp-Glu, KDDE) peptide featured maximum capture at pH ≈ 10; a pH region too high for Mg²⁺ ions to remain in solution. This work aims to achieve pKa depression by introducing fluorine in the proximity of the lysine’s sidechain amine. A comparative analysis was made of butylamine, …

Recurrent Event Data Analysis With Mismeasured Covariates, Ravinath Alahakoon Mudiyanselage

Doctoral Dissertations

"Consider a study with n units wherein every unit is monitored for the occurrence of an event that can recur with random end of monitoring. At each recurrence, p concomitant variables associated to the event recurrence are recorded with q (q ≤ p) collected with errors. Of interest in this dissertation is the estimation of the regression parameters of event time regression models accounting for the covariates. To circumvent the problem of bias and consistency associated with model's parameter estimation in the presence of measurement errors, we propose inference for corrected estimating functions with well-behaved roots under additive measurement errors …

Applied Geochemistry, Geochronology And Biostratigraphy: Case Studies From The 38th Parallel Structures In Missouri And Orange Basin, Offshore Western South Africa, Marissa Kay Spencer

Doctoral Dissertations

"The unique alignment of the Decaturville, Crooked Creek, and Weaubleau geological structures in central Missouri, three of nine known such structures along the 38th parallel in Illinois, Missouri, and Kansas, has puzzled geoscientists for decades. Research using palynology (palynomorphs and particulate organic matter) and radiometric dating of impact spherules were used to constrain age and a relationship between these enigmatic structures and infer their paleoenvironmental conditions. Novel melting damages, unique to impact, were documented in the palynomorphs in all the three structures. Early Ordovician acritarchs with melted processes correlate with ⁴⁰Ar-³⁹Ar stepwise heating age of impact spherules …

Bidirectional Asymmetric Clllc Resonant Dc-Dc Converter For Onboard Electric Vehicle Chargers, Angshuman Sharma, Alvaro Cardoza, Kartikeya J.P. Veeramraju, Oroghene Oboreh-Snapps, Jonathan W. Kimball

Electrical and Computer Engineering Faculty Research & Creative Works

Bidirectional CLLLC resonant dc-dc converters with an asymmetric tank can narrow the switching frequency bandwidth required to meet the asymmetric voltage gains in the two directions of power flow. Consequently, higher power density and efficiency may be feasible. in this paper, a CLLLC resonant converter with asymmetric primary and secondary capacitances is investigated for charging and discharging the next-generation 900 V traction battery of an electric vehicle. First, a new voltage gain equation is formulated using the First Harmonic Approximation. Then, the proposed gain equation is used to design the asymmetric resonant tank. the effects of asymmetric capacitances on the …

Retracted: A Robust Integrated Approach For Optimal Management Of Power Networks Encompassing Wind Power Plants, Aliasghar Baziar, Mohammad Reza Akbarizadeh, Amin Hajizadeh, Mousa Marzband, Rui Bo

Electrical and Computer Engineering Faculty Research & Creative Works

This paper basically concentrates on providing some significant steps for congestion management of the power systems based on an interval-Based robust chance constrained transmission switching (IBRCC-TS) approach for decreasing the congestion of the system while increasing the robustness of the system against uncertainties of the wind turbines. However, the utilization of TS approach in the power system is a severe challenge, since there is no limitation over the switching rate during a certain timespan in the network as well as the power switches' failure uncertainty. Besides, the frequent switching by the TS method decreases the switch maintenance and puts the …

Small Signal Stability Analysis Of Virtual Impedance Control In Islanded Microgrid, Oroghene Oboreh-Snapps, Kartikeya J.P. Veeramraju, Arnold Fernandes, Alvaro Cardoza, Angshuman Sharma, Jonathan Saelens, Jonathan W. Kimball

Electrical and Computer Engineering Faculty Research & Creative Works

This paper examines the impact of virtual impedance control in an inverter-dominated microgrid (MG) system. the goal is to provide a clear understanding of Virtual Impedance (VI) control toward MG stability. This analysis is performed by developing the system's Small-Signal Model (SSM) and studying the poles' trajectory change when the system's key control parameters are varied. the results indicate that VI will benefit system stability when considering MG with low X/R while negatively affecting MG with high X/R. Also, there is a trade-off between the coupling impedance of the inverter and the VI parameters, which needs to be considered when …

The Application Of Statistical Modeling To Identify Genetic Associations With Mild Traumatic Brain Injury Outcomes, Caroline Schott

Masters Theses

"Traumatic brain injury (TBI) is a growing health concern, with millions of TBI diagnoses in the United States each year. The vast majority of TBI diagnoses are mild traumatic brain injuries (mTBI), which can be challenging to manage due to variation in symptoms and outcomes. Most individuals with mTBI successfully recover quickly, but a small subset has a delayed recovery. Although the factors that contribute to this variation in recovery are not clearly understood, it is possible that genetic differences may play a role. Very few studies have investigated the association between single nucleotide polymorphisms (SNPs) with mTBI outcomes and …

Flight Software Development For A University-Class Microsatellite Mission, Yumeka Nagano

Masters Theses

"The purpose of this research is to present the software development process used by the Command and Data Handling (C&DH) subsystem as a part of a microsatellite mission underway at the Missouri University of Science and Technology. The mission's objective is to evaluate the performance of an innovative cold gas propulsion system for use in formation flying applications and the incorporation of a stereoscopic imaging sensor used to measure the satellite pair's relative position and velocity vectors in real time. C&DH uses a Raspberry Pi 3 Model B as the flight computer running a Linux environment, and the flight code …

Computer Vision In Adverse Conditions: Small Objects, Low-Resoltuion Images, And Edge Deployment, Raja Sunkara

Masters Theses

"Computer vision based on deep learning is an essential field that plays a significant role in object detection, image classification, semantic segmentation, instance segmentation, and other applications. However, these models face significant challenges in adverse conditions, such as small objects, low-resolution images, and edge deployment. These challenges limit the accuracy and efficiency of computer vision algorithms, making it difficult to obtain reliable results.

The primary objective of this thesis is to assess the performance of deep learning- based computer vision models in challenging conditions and provide viable solutions to overcome the obstacles. The study will specifically address three key challenges, …

Meta-Analysis Of Mesenchymal Stem Cell Gene Expression Data From Obese And Non-Obese Patients, Dakota William Shields

Masters Theses

"The prevalence of gene expression microarray datasets in public repositories gives opportunity to analyze biologically interesting datasets without running the laboratory aspect in house. Such experimentation is expensive in terms of finances, time, and expertise, which often results in low numbers of replicates. Meta-analysis techniques attempt to overcome issues due to few biological or technical replicates by combining separate experiments together to increase statistical power. Proper statistical considerations help to offset issues like simultaneous testing of thousands of genes, unintended hybridization, and other noises.

Microarrays contain light intensities from tens of thousands of hybridized probes giving a measure of gene …

Investigation Of Defect Production And Displacement Energies In Wurtzite Aluminum Nitride, Sean Anderson

Masters Theses

"Aluminum Nitride is an active element of sensors that monitor the performance and well-being of the nuclear reactors due to its piezoelectric properties. Yet, the variations of its properties under irradiation are largely unexplored. We report the results of the molecular dynamics simulations of the structural changes in AlN under irradiation via the knock-on atom technique. By creating and evolving the irradiation cascades due to energetic particle interaction with the atom of the crystalline lattice we determine the rate of the defect production as a function of the deposited energy. Further, we determine a displacement energy, a key characteristic that …

Static I-V Curve And Aging Test For Pim Characterization In Metallic Contacts, Kalkidan Anjajo

Masters Theses

"Spring clips and fabric-over-foams (FOFs) are widely used in mobile devices for electrical connection purposes. However, the imperfect metallic connections tend to induce passive intermodulation (PIM), resulting in a receiver sensitivity degradation, known as RF desensitization. Due to the complexity of the PIM characterization, there is not yet a way to evaluate PIM performance using a simple setup for environments like factories. In this study, a current-voltage (I-V) behavior-based PIM evaluation method is proposed and validated with various metallic contacts and contact forces. The test results demonstrated the feasibility of the PIM performance evaluation based on the measured static I-V …

Implementing The Fast Full-Wave Electromagnetic Forward Solver Using The Deep Convolutional Encoder-Decoder Architecture, He Ming Yao, Lijun Jiang, Michael Ng

Electrical and Computer Engineering Faculty Research & Creative Works

In this communication, a novel deep learning (DL)-based solver is proposed for the electromagnetic forward (EMF) process. It is based on the complex-valued deep convolutional neural networks (DConvNets) comprising an encoder network and a corresponding decoder network with pixel-wise regression layer. The encoder network takes the incident EM wave and the contrast (permittivity) distribution of the object as the input. It channels the processed data into the corresponding decoder network to predict the total EM field due to the scatter of the input incident EM wave. The training of the proposed DConvNets is done using the simple synthetic dataset. Due …

Application Of A Variable Path Length Repetitive Process Control For Direct Energy Deposition Of Thin-Walled Structures, Elias B. Snider, Douglas A. Bristow

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Direct Energy Deposition (DED) Additive Manufacturing is Well Suited to Fabricating Large Thin-Walled Metal Structures Such as Rocket Nozzles but Suffers from Layer-To-Layer Defect Propagation. Propagating Defects May Exhibit as Slumping or a Ripple in Bead Geometry. Recent Works Have Used Repetitive Process Control (RPC) Methods for Additive Manufacturing to Stabilize the Layer-Wise Defect Propagation, But These Methods Require Repetition of the Same Path. However, Typical Thin-Wall DED Applications, Sometimes Referred to as Vase Structures, Have Changing Paths with Each Layer Such as Expanding or Contracting Diameters and Changing Profiles. This Paper Presents an Extension to Optimal RPC that Uses …

Predicting Dissolution Kinetics Of Tricalcium Silicate Using Deep Learning And Analytical Models, Taihao Han, Sai Akshay Ponduru, Arianit Reka, Jie Huang, Gaurav Sant, Aditya Kumar

Electrical and Computer Engineering Faculty Research & Creative Works

The dissolution kinetics of Portland cement is a critical factor in controlling the hydration reaction and improving the performance of concrete. Tricalcium silicate (C₃S), the primary phase in Portland cement, is known to have complex dissolution mechanisms that involve multiple reactions and changes to particle surfaces. As a result, current analytical models are unable to accurately predict the dissolution kinetics of C₃S in various solvents when it is undersaturated with respect to the solvent. This paper employs the deep forest (DF) model to predict the dissolution rate of C₃S in the undersaturated solvent. The …

Synthesis, Densification, And Cation Inversion In High Entropy (Co,Cu,Mg,Ni,Zn)Al2o4 Spinel, Cole A. Corlett, Nina Obradovic, Jeremy Lee Watts, Eric W. Bohannan, William Fahrenholtz

Materials Science and Engineering Faculty Research & Creative Works

The synthesis, densification behavior, and crystallographic site occupancy were investigated for four different spinel-based ceramics, including a high-entropy spinel (Co_0.2Cu_0.2Mg_0.2Ni_0.2 Zn_0.2)Al₂O₄. Each composition was reacted to form a single phase, but analysis of X-ray diffraction patterns revealed differences in cation site occupancy with the high-entropy spinel being nearly fully normal. Densification behavior was investigated and showed that fully dense ceramics could be produced by hot pressing at temperatures as low as 1375°C for all compositions. Vickers' hardness values were at least 10 GPa for all compositions. The …