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Petrography, Chemical Composition, And Stratigraphic Setting Of The Coals Of North-Central Missouri, William Keith Wedge

Doctoral Dissertations

"Under a grant from the National Air Pollution Control Administration, the Missouri Geological Survey undertook a core drilling program to learn more about the coals in north-central Missouri. The stratigraphic setting and chemical and petrographic characteristics of 43 complete samples of coal recovered from 13 diamond drill holes in the exploration program in north-central Missouri are major contributions of this study. These samples represent twelve different coal beds of the Atokan and Desmoinesian Series of the Pennsylvanian System of Missouri and range in thickness from 9.6 to 44.4 inches. They have an average thickness of 20.4 inches and a combined …

Dynamic Instability And Ultimate Capacity Of Inelastic Systems Parametrically Excited By Earthquakes, Wu-Hsiung Tseng

Doctoral Dissertations

"A procedure of analysis is presented for determining the dynamic instability and response of framed structures subjected to pulsating axial loads, time-dependent lateral forces, or foundation movements. Included in the analytical work are the instability criterion of a structural system, the finite element technique of structural matrix formulation, and the computer solution methods.

The dynamic instability is defined by a region in relation to transverse natural frequency, longitudinal forcing frequency and the magnitude of axial dynamic force. The axial pulsating load is expressed in terms of static buckling load for ensuring that the applied load is not greater than the …

Nucleate Boiling From Polymer Coated Surfaces., David Franklin Warner

Doctoral Dissertations

"This study consisted of an examination of both the effects of nucleate boiling on polymer coated surfaces and the effects of the polymer coated surfaces on the nucleate boiling curve. The nucleate boiling curve (the curve resulting from plotting heat transferred per unit area versus the temperature difference between the boiling surface and the liquid pool) of the polymer coated surfaces were compared with the nucleate boiling curve of gold-plated surfaces with no polymer coat and it was found that the thicker the polymer coat, the more the curve deviated from that of the metal uncoated surfaces.

All surfaces were …

A Study Of Gas-Surface Interactions Through Sticking Coefficient, Condensation Coefficient And Sublimation Rate Measurements, Charles E. Bryson Iii

Doctoral Dissertations

"The behavior of the sticking coefficient of CO₂ on an H₂O substrate as a function of time is interpreted in terms of a microscopic nucleation theory. For a substrate temperature near 75 K and an incident flux near 10¹³ molecule cm⁻² sec⁻¹, a critical cluster size of four molecules and and activation energy of nucleation of 22 ± 2.4 Kcal mole⁻¹ is obtained. The analysis treats the nucleation processes as continuous rather than as a discontinuous process at some critical temperature.

In addition the same molecular beam apparatus used for the above experiment was used to measure the condensation …

Numerical Simulation Of Individual Wells In A Field Simulation Model, Ali Mohammed Akbar

Doctoral Dissertations

"Conventional numerical simulation of hydrocarbon reservoirs is inadequate for the prediction of bottom-hole pressures at production wells. This problem can be overcome by using a special mathematical model which combines individual well simulation with reservoir simulation. Severe computational instability is commonly encountered in the radial models due to the relatively small grid-blocks and high fluid velocities in the vicinity of the well bore. This instability is found to be more pronounced during depletion of the reservoir when the pressure near the well bore is below bubble-point pressure. A new technique is introduced here for saturation calculations in the critical region …

Applications Of Frequency Domain Stability Criteria In The Design Of Nonlinear Feedback Systems, Allen Joseph Rushing

Doctoral Dissertations

"The Popov criterion for absolute stability of nonlinear feedback systems is applied to several example problems. Model transformations such as pole shifting and zero shifting extend the class of systems to which the criterion applies. Extensions of the criterion having simple graphical interpretations yield stronger results for systems with constant monotonic slope-bounded nonlinearities. Additional extensions lacking simple graphical interpretations in the complex plane are also demonstrated by example.

Stability throughout a region in parameter space is discussed, and the Kalman conjecture is verified for a new class of systems. The Popov criterion is also used to prove BIBO stability, process …

A Stochastic Theory Of The Stepwise Growth Of Ice Crystal Surfaces, Andreas Kasimir Goroch

Doctoral Dissertations

"Previous theories have had limited success in explaining the presence of a peak in the behavior of the rate of advance of a step on an ice crystal surface with respect to temperature. In the present work we examine the temperature dependence of the advance of steps on the basal face of an ice crystal from several points of view. An alternate derivation is presented for the random motion of adsorbents on a cubic lattice with absorbing points, and this theory is applied for the advance of a step on an ice surface. The velocity of step advance according to …

Some Results On Quasi-Uniform Spaces, Karen Sylvia Carter

Doctoral Dissertations

"An example of a quasi-uniform space which is complete but not strongly complete is constructed. We also give an example to show that a T₁ space does not necessarily have a T₁ strong completion.

The definition of Cauchy filter is discussed. An alternate definition, referred to as C-filter, is considered. A construction of a C-completion is given and it is shown that if a quasi-pseudometric is complete, then the corresponding quasi-uniform structure is C-complete.

Conjugate quasi-uniform spaces are discussed. A theorem relating a transitive base of a quasi-uniform structure to a transitive base of the conjugate structure is …

Linear Stability Of Non-Parallel Flow In The Entrance Region Of Ducts, Francis Chung-Ti Shen

Doctoral Dissertations

"An investigation is made of the linear stability of the developing flow of an incompressible fluid in the entrance region of annular ducts, circular tubes, and parallel-plate channels. Small axisymmetric disturbances for annular duct and tube flows and small two-dimensional disturbances for channel flow are considered in the analysis. In formulating the stability problems, account is taken of the transverse velocity component of the mainflow. This results in the modified Orr-Sommerfeld equations, one for annular duct and tube flows and the other for channel flow. The mainflow velocity fields utilized in the stability analysis are those from the solutions of …

A Comparison Of Three Urban Hydrology Models, Richard F. Astrack

Masters Theses

"Three models, the British Road Research Laboratory Hydrograph Method, the Hydrocomp Simulation Program, and the HEC-1 Flood Hydrograph Package, are applied to the Boneyard Creek basin. Comparing the ability of these models to reproduce the observed peak discharge, time of the peak, and the first runoff volume determines the accuracy of these models"--Abstract, page iii.

Use Of Radioactive Iodine Evolved Into Reactor Cooling Water To Locate Defective Fuel Elements, Carl Mozel Stroud

Masters Theses

"The relative amount of radioactive iodine evolved in reactor cooling water by each fuel element provides an excellent indication of defective cladding on fuel elements. The radioactive iodine evolved into the reactor cooling water from a defective fuel element should be higher than the average radioactive iodine evolved by other fuel elements into the cooling water by an order of magnitude or more.

Radioactive iodine with non-radioactive iodine carrier is adsorbed on DOWEX SBR resin in the iodide form. The iodide is eluted from the resin with sodium hypochlorite and extracted into carbon tetrachloride. The iodine is reduced to iodide …

A Study Of The Measurement Of Noise Power, Larry Smith Heflin

Masters Theses

"In order to compute a power signal-to-noise ratio in the numerical simulation of a communication system, it is necessary to measure the power of the noise present. The required integration can be approximated by many numerical techniques. Five numerical integration methods are available in the user-oriented System/360 Continuous System Modeling Program. Measurements of the power of an additive Gaussian noise waveform are performed, and an analysis of the accuracy of the measurement compared to theoretical values is presented"--Abstract, page ii.

Heat Transfer Of A High Prandtl Number Oil In Laminar Flow, John Robert Lee Iii

Masters Theses

"A numerical model was developed for the purpose of studying the flow and heat transfer of a hypothetical oil in laminar flow within a horizontal pipeline. Free convection, work of compression, and axial conduction were neglected, but the fluid properties - i.e., density, specific heat, viscosity, and thermal conductivity - were allowed to vary and the effect of viscous dissipation was included in the analysis of the system.

The mathematical forms of the momentum, continuity, and energy equations require that numerical solutions be obtained with a digital computer. These numerical approximations of the partial differential equations are presented and the …

Analysis And Design For Semi-Automatic And Automatic Control Of Vehicles By Permanent Magnets, Hari K. Mehta

Masters Theses

"The analysis and design carried out in this study relates to automatic or semi-automatic lateral control of a vehicle. This is one of the three essential subsystems needed for a complete automatic control system. The other two subsystems provide longitudinal control, and intersection or lane-changing control.

The system studied employs a series of permanent magnets which have been embedded vertically in the road and spaced at an interval to be used for position reference, leading to discontinuous error signal. This system has been analyzed by classical Z-transform analysis and control models have been developed for two kinds of controls. First, …

Approximate Normal Mode Method To Determine The Response Of Certain Nondiagonalizabel Vibratory Systems, Jayaram Seshadri

Masters Theses

"An approximate normal mode method is developed which permits certain normally nondiagonalizable, nonconservative systems to be solved by superposition of uncoupled coordinates.

An approximate solution for a nonproportionally damped, multi-degree of freedom system is obtained by using a perturbation technique. The system is then reduced to a proportionally damped system by means of a modification to the damping factor so that the effect of the off-diagonal terms of the modal damping matrix is included. This modification produces a damping matrix that can be diagonalized by the normal mode technique. An approximate criterion is used for the determination of the modified …

Structure And Chemical Composition Of The Otoliths Of Cyprinus Carpio, Larry Paul Coen

Masters Theses

"The need for the study of microfossils such as foraminifera, conodonts, and otoliths as stratigraphic tools has been well established. However, disarticulated parts such as otoliths and conodonts cannot be effectively used unless they can be recognized. Otoliths, although somewhat unrecognized in the geological record, are far more abundant than articulated skeletons (Frizzell, 1965, p. 86). Therefore, much investigation is being conducted to reveal the origin, function, morphology, and usefulness of the otoliths of fishes.

In this investigation, the asteriscus, well developed only in Ostariophysins (of which the carp is a member), is studied for morphology. New tentative terms are …

Desorption Of Phosphorus From Si (111) Surfaces, Cesar Michel Magnin

Masters Theses

"Auger electron spectroscopy and mass analysis are used as complementary methods in evaluating desorption kinetics. For phosphorus on silicon, the order of desorption and activation energies of desorption are determined from continuously monitored phosphorus Auger electron signals during heating. These measurements indicate that diatomic phosphorus dissociates when adsorbed onto clean silicon. Mass spectrometer flash desorption spectra show that at least four distinct surface bonds are associated with the desorption of phosphorus. The dominant desorbed species is diatomic phosphorus at high coverage (> 0. 1 monolayer) and atomic phosphorus at low coverage (< 0.07 monolayer)"--Abstract, page ii.

Engineering And Scientific Manpower- A Scarce Resource For The 1970'S, Merl Baker

Mechanical and Aerospace Engineering Faculty Research & Creative Works

No abstract provided.

Pmr Spectra Of The 4-Alkylnitrobenzenes, Donald W. Beistel, Hsin-Liang Chen

Chemistry Faculty Research & Creative Works

Evidence of first-order alkyl-ring proton coupling is reported for the 4-alkylnitrobenzenes. Typical coupling constants of 0.7 Hz and 0.3 Hz were found for α-alkyl coupling with the ortho and meta ring protons, respectively, when the alkyl function was methyl, ethyl, and isopropyl. No β-alkyl coupling with ring protons was observed for the ethyl, isopropyl, or t -butyl groups, suggesting that the magnitude of the coupling constant is vanishingly small.

A Computer-Oriented Course In Chemical Spectroscopy, D. (Donald) W. Beistel

Chemistry Faculty Research & Creative Works

No abstract provided.

Column Research Council: Proceedings 1973, Column Research Council

CCFSS Library (1939 - present)

One of the purposes of the Council is to maintain a forum where problems related to the design and behavior of columns and other compression elements in metal structures can be presented for evaluation and discussion. The Annual Technical Session provides opportunity to carry out this function. The 1973 Annual Technical Session was held on May 2 and 3 at the Los Angeles Hilton Hotel in Los Angeles, California. Sixty persons attended the Session and thirty-three papers were delivered. A panel discussion on "Frame Stability Under Seismic Loading" was held in the evening of May 2, 1973. Panelists were E. …

Experiments On The Structure Of Turbulence In Fully Developed Pipe Flow, T. R. Heidrick, S. Banerjee, R. S. Azad

Symposia on Turbulence in Liquids

This paper describes a series of two-point measurements in fully developed pipe flow. Measurements of the phase shifts between the Fourier components of the axial velocity fluctuations at two points were made with three different orientations of the two points. In all cases the two points were close enough together that the turbulent structure remained essentially "frozen" while passing between the sensors. The phase velocities, C₁(f), and inclinations, α(f) (defined previously by Heidrick et al. (8)), of each frequency component, f, were determined from these measurements.

In general, the Fourier components are inclined to the wall - the …

Charge Transfer Between Oˉ Ions And O₂ Molecules In The Ground State And Singlet Delta Excited State, Ronald Floyd Mathis

Doctoral Dissertations

"A crossed-beam apparatus has been built and used to study charge transfer between O⁻ ions and O₂ molecules in the ground state and in the metastable, singlet delta, excited state. The energy of the incident ions ranged from 10 to 10,000 eV.

The cross section for charge transfer between O⁻ and ground state O₂ was found to peak at about 5 keV, as predicted on the basis of the Rapp and Francis theory. At the lower energies there is good agreement with the previous measurements of Snow et al., and Rutherford and Turner, who also used crossed beam techniques. The …

The Synthesis And Spectroscopic Properties Of Vanadium(Iii) Squarate Trihydrate, S. M. Condren, Hector O. Mcdonald

Chemistry Faculty Research & Creative Works

Vanadium(III) squarate trihydrate has been prepared; and the infrared, X-ray diffraction, and electronic spectra of the complex indicate that the central metal atom is in a slightly distorted octahedral field. A thermogravimetric study has shown that the complex loses three water molecules upon heating. A hydroxy-bridged, dimeric structure has been proposed from these data. © 1973, American Chemical Society. All rights reserved.

Letters To The Editor, J. T. Mason, Orrin K. Crosser, Robert D. Gunn, C. Judson King

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

A Study Of Medium And High Internal Phase Ratio Water/Polymer Emulsions, Kenneth J. Lissant, Kenneth G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Medium and high internal phase ratio water/polymer emulsions were studied utilizing scanning electron microscope techniques. Results are reported for the geometry and distribution of droplets for water/polymer ratios from 1 1 to 9 1. Electron micrographs confirm those models which predicts polyhedral droplet formation at high internal phase ratios. © 1973.

A Technique For Improving Material Balance Accuracy In Reservoir Simulation Models, A. R. Merchant, Marion D. Arnold, A. Herbert Harvey

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

One criterion for determining the precision of pressures calculated by a simulation model is the accuracy of the material balance. A high degree of precision in the calculated pressures is a necessary but not sufficient condition for elimination of significant errors in the prediction of fluid migration in the reservoir. A new procedure, called error matrix technique, has been developed for reduction of material balance errors. This reduction is accomplished by adjusting potential gradients at every grid point in the simulation model so that the material balance is accurately maintained. Performance of a hypothetical oil reservoir was simulated both by …

Transmission Measurements Through Liquids In A White Cell, David Earl Hurley

Masters Theses

"The suitability of using the White cell for determining the extinction coefficient of liquids was examined by measuring the attenuation of electromagnetic radiation, in the visible part of the spectrum, through distilled water. The analysis of the transmittance measurements through liquids in a White cell does not provide a sufficient number of independent equations to solve directly for the extinction coefficient. Reasonable estimates however can be made by employing a correction which accounts for changes in the mirror reflectance due to a liquid-mirror interface.

The reduction in the transmittance of distilled water due to an oil film was studied for …

A Study Of The Ability Of Surface Active Materials To Increase The Evaporation Rates Of Small, Freely Falling Water Drops, David Alan Sierawski

Masters Theses

"The evaporation rate at 30°C of water droplets partially covered by surface active materials (SAM) were determined. While two of the SAM were studied at a single dew point depression (ΔT_DP), seven others were examined over a range of ΔT_DP values. It was found, by comparison with pure water drops under identical conditions, that SAM increases the evaporation rate as compared to the rate of an uncontaminated drop. The lack of effect of the hydrophobic chain length and the possible effect of the hydrophilic group on this phenomenon are discussed. The explanation proposed is that at 30°C …

A Study Of The Pulse-Height Response Of Silicon Surface-Barrier Detectors To High-Energy Heavy Ions, Gregory Dan Smith

Doctoral Dissertations

"The pulse-height defect (PHD) of high-energy heavy ions in silicon surface-barrier detectors can be divided into three components: (1) energy loss in the gold-surface layer, (2) a nuclear-stopping defect, and (3) a defect due to recombination of electron-hole pairs in the plasma created by the heavy ion. The plasma recombination portion of the PHD was the subject of this study using the variation of the PHD with (1) the angle of incidence of incoming heavy ions, and (2) changes in the detector bias. The Tandem Van de Graaff accelerator at Argonne National Laboratory was used to produce scattered beam ions …