Digital Commons Network^™

Theory Of The Effect Of Temperature On The Electron Diffraction Patterns Of Diatomic Molecules, Russell A. Bonham, Jerry Peacher

Physics Faculty Research & Creative Works

The effect of temperature on the electron diffraction pattern of a diatomic molecule is considered from the standpoint of the simple kinematic scattering theory utilizing a quartic vibrational potential. The potential is obtained by an expansion of ħ²J( J+1)/2μr²+D exp[-2a(r-r_e)]-2D exp[-a(r-r_e)] about its minimum value r₀. The second-order wavefunction for the nth vibrational and 7th rotational state of the system has been obtained, and expressions for the electron diffraction quantities r_g, l_e ², and M (s) have been computed. General results for the quantity M (s) …

The Missouri Miner, April 26, 1963

The Missouri Miner Newspaper

No abstract provided.

Magnetic Structure Investigations At The Nuclear Center, R. Ballestracci, E. F. Bertaut, J. Coing-Boyat, A. Delapalme, William Joseph James, R. Lemaire, R. Pauthenet, G. Roult

Chemistry Faculty Research & Creative Works

The magnetic structure of the compounds UOS, ß-CoSO₄, YCO₅, and HoCO₅ is briefly described.

UOS is antiferromagnetic. The Néel temperature is T_n=55°K. The magnetic cell is doubled in the c direction with a ++ - - sequence of U moments along c. The apparent spin is S∼1. The negative interaction corresponds to U-O-U links.

In ß-CoSO₄ (high-temperature modification, space group Pbnm), Co atoms are in 000, 00½, ½½½, ½½0. Here three different antiferromagnetic spin modes, mutually perpendicular, A_x(+ - - +), G_y(+-+-), and C_z(++ - - …

Missouri S&T Magazine, February 1963, Miner Alumni Association

Missouri S&T Magazine

No abstract provided.

Investigation Of Ablation Materials, John Martyn Schattyn

Masters Theses

"The desired result of this paper is to determine what effect the physical and thermal properties of a material have on the ability of that material to act as an ablation heat shield. On the basis of their physical properties, five materials, nickel, beryllium, fused quartz, teflon, and phenolic-nylon, were chosen as examples.

The tools used for this study are heat transfer equations involving a change in material phase. The resulting criteria may be assumed applicable to any material exhibiting one of the four types of ablation processes"--Abstract, page 2.

The Performance Of A Mechanically-Aided Countercurrent Extraction Column., Jerry James Carr

Masters Theses

"In recent years liquid extraction has become a major industrial method for the separation of liquid solutions. Liquid extraction has proven successful in some separations performed only with great difficulty by other, more common mass-transfer operations. Th e industrial utilization of liquid extraction has resulted in considerable interest in the design and performance correlations of high-capacity, high-efficiency extraction equipment.

Continuous countercurrent columns, filled with various packings, baffles, and plates, have been found to be relatively ineffective in liquid extract on service. The density difference of the contacted phases is generally insufficient to, by itself, cause the intimate contact necessary for …

A Study Of A Method For Determining Properties Of Metals At High Strain Rates., Warren Heidbreder

Masters Theses

"An experimental method has been developed for determining the tensile and other physical properties of metals under high loading rates. Experimental equipment was designed, fabricated and tested. It was desirable to keep the equipment simple and inexpensive so that it could be used by operators Lacking experience in electronics and high-speed photography which are required for some of the more sophisticated methods now in use. The energy for pulling the specimens is supplied by smokeless gun powder. The firing of a cartridge into a closed cylinder with movable piston accomplishes the breaking of the specimen. A record of the time, …

Hydraulic Transportation Of Coal In Open Flumes., Nallapu Narayan Reddy

Masters Theses

"The objective of this study is to design a simplified form of hydraulic transportation system using open-flumes and operated by gravity in pitching coal seams. This type of system is to be used in conjunction with mining by hydraulic methods where the water used for the extraction of coal can also be used for the loading and transport functions"--Introduction p. 1

Determining Stability Of Nonlinear Control Systems Via Lyapunov's Method., John Joseph Komo

Masters Theses

"The problem undertaken in this thesis is to present Lyapunov's method of stability as i t applies to control systems and to use it in the stability analysis of nonlinear control systems. The variable gradient method of generating Lyapunov functions is presented since this seems the best general procedure for obtaining Lyapunov functions. Also, the integration of matrices method is presented as a comparison. ii

Procedures for the use of the variable gradient method and the integration of matrices method are written and several examples are used to illustrate these procedures.

It is concluded that Lyapunov's method is very definitely …

Analysis Of A Char-Forming Ablator, William J. Reilly

Masters Theses

"The purpose of this thesis is to conduct an analytical analysis of a char-forming ablation material. This is one phase of ablation heat transfer.

Fourier's general equation for one dimensional heat conduction is transformed to moving coordinates and is then solved using the applicable boundary conditions. Solutions of this equation are valid for initial studies in ablation heat transfer"--Abstract, page ii.

The Anodic Dissolution Of Zinc In Aqueous Solutions, Glenn E. Stoner

Masters Theses

"The increasing demand for protective metals as coatings and non-corrosive alloys has stimulated extensive research on the fundamental behavior of metals in corrosive media.

One of the problems still unsolved is the nature of the mechanism of the anodic dissolution of metals like zinc, magnesium, beryllium, cadmium, and aluminum in aqueous salt solutions. Several schools of investigators have proposed different and opposing theories to explain the discrepancies which often arise between coulometric data and the weight loss of metal electrodes in certain salt solutions.

The purpose of this investigation was to obtain experimental data for the anodic dissolution of zinc …

Determination Of The Standard Free Energy Of Formation Of Zr₃S₂, Peter E. Otten

Masters Theses

"The Knudsen effusion method was used to find the equilibrium magnesium pressure for the reaction

3 Zr (s) + 2 MgS (s) = 'Zr₃S₂' (s) + 2 Mg (v)

By using known standard free energy data for the formation of magnesium sulfide and by using the equilibrium magnesium pressure, the standard free energy of formation of Zr₃S₂ was calculated and could be expressed by the equation

Δ F° = -139,800 + 49.13 T cal/mole

in the temperature range 900 to 1100°C.

It was also found that Zr₃S₂ was the zirconium …

Swelling Properties Of Putnam Soil, Oscar M. Palma

Masters Theses

"Volume change of Putnam soil under different moisture contents and the swelling pressure developed by the soil at the same moisture contents were investigated using standard test procedures.

The theory of one dimensional consolidation of Terzaghi was reviewed as well as the literature on swelling and swell pressure.

It was found that swell depends mainly on the initial water content, while swelling pressure depends mainly on the dry density of the soil"--Abstract, page ii.

The Design, Construction, And Calibration Of A Hydrodynamic Journal Bearing Testing Machine., John H. Roberts

Masters Theses

"The purpose of this investigation was to design, construct, and calibrate a journal bearing testing apparatus. The design, construction, and operation of the apparatus are described.

Two bronze bearings with length to diameter ratios of 1.0 and 0.5 were tested using a gravity oil reed system. The speed and the location of inlet oil supply were varied, and the resulting coefficients or friction, oil flow rates, outlet oil temperatures, bearing shell temperatures, and eccentricities of the bearings were determined. These results were evaluated and compared with theoretical solutions.

The results compared favorably with the theoretical solutions and substantiated the use …

A Thermodynamic Study Of The Molybdenum-Sulfur System At 1100⁰C, Seth C. Schaefer

Masters Theses

"A static method was used to determine equilibrium sulfur pressure for molybdenum-sulfur mixtures at 1100°C.

The results obtained were:
(1) The molybdenum disulfide phase was stable in a sulfur pressure range of 1.023 x 10^-5 to 6.026 x 10^-1 atmospheres. A range of non-stoichiometry from MoS_2.00 to MoS_2.22 was determined under these conditions.
(2) The upper limit of sulfur content of molybdenum sesquisulfide (Mo₂S₃) is nearly stoichiometric.
(3) The extent of solid solution of sulfur in molybdenum is approximately 1.5 atomic % (0.5 wt %).
(4) Molybdenum sesqu-isulfide (Mo₂S_{3 …}

Small Signal Gain Analysis For A Seven Cavity Klystron Amplifier., William E. Hord

Masters Theses

"The problem was to find a suitable method of using the digital computer to calculate the small signal gain characteristics of a seven cavity klystron amplifier. Background material relevant to the problem was reviewed. The differential equations for small signal conditions in a gridless gap klystron were developed. These equations were then solved and put in a matrix form suitable for digital computer analysis. Suggestions for additional development were proposed"--Abstract p. ii

Convective Heat Transfer In Small Enclosed Air Spaces., Joseph Charles Kroutil

Masters Theses

No abstract provided.

Infrared Modulation Using The Field-Effect Properties Of Germanium., Lloyd E. Brunkhorst

Masters Theses

"The absorption of infrared radiation, by free carriers in germanium, has been used to amplitude modulate infrared radiation. In the experiment, a space charge layer consisting of free carriers is established at the inner surface of a germanium sample by using the field-effect technique. Infrared radiation of a wavelength to which the germanium is transparent is then Internally reflected from this surface. The infrared radiation passes twice through the space charge layer for each internal reflection. With each pass through the space charge layer, the amplitude of the transmitted infrared is decreased. Amplitude modulation of the transmitted infrared is accomplished …

Thermocouple Shape Influence On Response In A Dynamic Compressible Fluid Atmosphere, Philip J. Steger

Masters Theses

"This investigation was performed to determine whether the geometrical shape of a thermocouple used to measure the temperature of a dynamic fluid atmosphere had any affect on its recovery factor and time response.

A converging nozzle was used to establish a dynamic fluid stream in which shaped silver solder junctions of copper-constantan thermocouples were tested. The velocity of the working fluid, air, was about 1000 ft/sec at the test point.

The investigation was successful, within experimental limits, in determining that the recovery factor of a bare thermocouple junction is not influenced by geometrical shape The results agreed substantially with available …

A Graphical Solution Method For The Tchebychev Elliptic Function Filter, Gene S. Luckfield

Masters Theses

"This thesis is concerned with the design of the Tchebychev elliptic function filter. The Darlington synthesis procedure is discussed and salient points from Darlington's paper needed for the design of this filter are presented.

It is shown that the design of the Tchebychev elliptic function filter requires a knowledge of the elliptic functions, particularly the elliptic sine. Since the use of these functions is not common, a brief review of their properties is presented.

Using the elliptic functions, a development of the equations describing the behavior of the Tchebychev elliptic function filter is given for the case of a normalized …

A Numerical Approach To A Sturm-Liouville Type Problem With Variable Coefficients And Its Application To Heat Transfer And Temperature Prediction In The Lower Atmosphere., Troyce Don Jones

Masters Theses

No abstract provided.

A New Method Of Making Stainless Steel Powder By Electrochemical Disintegration, Mohammed Maher Saad

Masters Theses

"This paper describes a new method of making austenitic stainless steel (18/8) powder by electrochemical disintegration. The method used an external direct current applied to a heat-treated stainless steel anode, and a platinum cathode in an electrolyte of an aqueous solution of 20% HNO₃ and 1% H₂SO₄ by weight respectively.

Special attention has been paid to the size distribution of sieve and sub-sieve sizes, and the following ranges were found: approximately one-half lies between the limits of 200 and 325 mesh, and one third is finer than 325 mesh, with the remainder about +200 mesh, average …

A Rc Active Delay Time Network., Robert Sun-Wu Han

Masters Theses

"This thesis presents a method for performing an approximate synthesis of a variable delay time network by using RC elements and active analog computer circuits. The delay networks discussed here can provide delay times which range from zero to 96 milliseconds for inputs with frequencies which range between zero 2nd 5 cycles per second.

Basically, the procedure involves approximating the delay time transfer function, e^-jwTd , by the ratio of two polynomials each of which is represented by a finite series of terms. The ratio is then shown to be easily synthesized by RC elements and analog computer circuits. …

Liquid Mercury Embrittlement Of Thin-Walled 2024 Aluminum Tubes, Edward J. Beckemeyer

Masters Theses

"The dislocation theory, Zener-Stroh crack model, and the Petch relationship, which correlates fracture stress and grain size, were used to analyze the embrittlement of 2024 aluminum alloy tubes by liquid mercury.

Surface energy ratios, [formula], were determined for biaxial stress ratios of 1/2, 1, ∞. The values of the surface energy ratios considered were 4.24, 1.79, 1.46, respectively. As part of this study, an approximate Nabarro-Peierls frictional stress was calculated for each stress ratio"--Abstract, page 2.

Interaction Curve For A Beam Column., Mahendra Khushalchand Sanghavi

Masters Theses

"The theoretical interaction curve for a circular section is established. Experimentally the interaction curve f or a beam-column with a varying circular cross section, is established. The effect of stress history is discussed, and the comparisons of different interaction curves are made"--Abstract p.i

An Investigation Of The Acceleration Of Neutrons, Charles Edward Byvik

Masters Theses

"The acceleration of neutrons via their magnetic dipole moment in an axially symmetric magnetic field is considered. Conditions for bunching are derived and expressions for the off-axis forces are developed. It was found that neutrons off axis are forced back onto the axis and that neutrons slightly depolarized remain in their initial state. A calculation of the acceleration is made using the field of a current loop and the conclusion is that under present laboratory capabilities a neutron accelerator is not feasible"--Abstract, page ii.

A Study Of Methods For Determining Confidence Intervals For The Mean Of A Normal Distribution With Unknown Varience By Comparison Of Average Lengths, Karl Richard Kneile

Masters Theses

“The purpose of this thesis is to briefly review various properties which may be desirable for a system of confidence intervals; and to empirically determine whether the system of confidence intervals obtained from the Student’s t distribution will produce shorter average lengths than those obtained by other methods which may be used. It was concluded from the results of an empirical investigation that there was no significant difference between the average lengths of confidence intervals obtained from a family of distributions of which the Student’s t is a member"--Abstract, page ii.

Derivation Of A Method To Determine Reactions And Deflection Of A Continous Beam On An Elastic Foundation, Louis Richard Fuka

Masters Theses

“The purpose of this thesis is to develop a method for determining the reactions and deflection curve of continuous beams partially supported by an elastic foundation. The method involves representation of an arbitrary loading and the intermediate redundant reactions as Fourier Series. Redundant intermediate reactions are determined by the solution of an equal number of linear equations. The remaining reactions are determined by the application of statics.

This same method can be used for simply supported beams on an elastic foundation and for continuous beams without an elastic foundation”--Abstract, page ii.

A Study Of The Angular Velocity In A Liquid Induced By A Vortex In An Emptying Container, James Paul Hartman

Masters Theses

"Previously a limited amount of investigation has been done to describe the rotational motion of fluid in a draining tank. To date tank design has been based on trial and error, since the physical mechanisms of actual draining have not been recognized. This investigation has been made to develop a technique for the measurement of the motion of the fluid during the draining process and to present the results of the observed surface velocity of the liquid as a function of depth of fluid and its distance from the center of the vortex core. Many previous investigators of vortex behavior …

Non-Ferrous Metal Mining And Smelting In Australia, H. R. Hanley

Missouri School of Mines and Metallurgy Bulletins

No abstract provided.