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Articles 301 - 330 of 32986
Full-Text Articles in Entire DC Network
Hardness Of (Hf,Ti,W,Zr)B2/(Hf,Ti,W,Zr)C-Based Ceramics With Varying Wb Content, Suzana Filipović, William G. Fahrenholtz, Gregory E. Hilmas, Nina Obradović, Stefano Curtarolo
Hardness Of (Hf,Ti,W,Zr)B2/(Hf,Ti,W,Zr)C-Based Ceramics With Varying Wb Content, Suzana Filipović, William G. Fahrenholtz, Gregory E. Hilmas, Nina Obradović, Stefano Curtarolo
Materials Science and Engineering Faculty Research & Creative Works
Compositionally complex (Hf,Ti,Zr,W)B2/(Hf,Ti,Zr,W)C-based ceramics were produced with different boride and carbide phase contents by varying the C/B4C molar ratio used in boro/carbothermal reduction. A monoboride phase based on WB was detected in all compositions. As the C/B4C ratio was varied, the WB content decreased from 23.7 vol% for a C/B4C ratio of 6.0–15.3 vol% for a C/B4C ratio of 10.3. Further increases in the C/B4C ratio increased the WB content. The monoboride phase contained mainly W and Ti in a solid solution with the nominal composition of (W …
Rheological Modification Of Alkali-Activated Slag Mortar: Roles Of Sodium Gluconate Retarder And Dispersants, Tae Yong Shin, Seongho Han, Ryong You, Yubin Jun, Jae Hong Kim
Rheological Modification Of Alkali-Activated Slag Mortar: Roles Of Sodium Gluconate Retarder And Dispersants, Tae Yong Shin, Seongho Han, Ryong You, Yubin Jun, Jae Hong Kim
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Alkali-activated materials have emerged as promising low-carbon alternatives to ordinary Portland cement-based binders; however, their practical application is strictly limited by rapid setting and poor workability. To address these challenges, this study proposes an evaluation methodology combining setting time measurement, cloud point tests for chemical stability, and wide-range rheological analysis. While conventional superplasticizers like polycarboxylate ether (PCE) proved unstable in high-alkaline environments, cloud point tests revealed that polynaphthalene sulfonate (PNS) and butyl acrylate (BA) exhibited superior chemical stability. Notably, BA was identified as a novel and effective dispersant in 3.5 M KOH-activated systems, reducing yield stress of fresh mortar by …
Neuproio: A Dual-Action Solid Drug Nanoparticle Topical Formulation For Simultaneous Intraocular Pressure Reduction And Neuroprotection For Glaucoma, Lei Xu, Mu Li, Lin Qi, Tzu Chen Wang, Dong Liu, Vimalin Jeyalatha Mani, Hsin Yin Chuang, Qingbo Yang, Ruipu Mu, Samira Mahdi, Da Huang, Honglan Shi, Yang Hu, Hu Yang
Neuproio: A Dual-Action Solid Drug Nanoparticle Topical Formulation For Simultaneous Intraocular Pressure Reduction And Neuroprotection For Glaucoma, Lei Xu, Mu Li, Lin Qi, Tzu Chen Wang, Dong Liu, Vimalin Jeyalatha Mani, Hsin Yin Chuang, Qingbo Yang, Ruipu Mu, Samira Mahdi, Da Huang, Honglan Shi, Yang Hu, Hu Yang
Chemical and Biochemical Engineering Faculty Research & Creative Works
Glaucoma is a leading cause of irreversible blindness, primarily due to elevated intraocular pressure (IOP) that damages the retina and optic nerve. Most topical glaucoma treatments focus solely on IOP-lowering without direct neuroprotection, as drug delivery to the posterior eye is challenging. Here, we developed NeuProIO, a dual-action solid drug nanoparticle (NP) eye drop for simultaneous IOP reduction and neuroprotection. Using flash nanoprecipitation in a multi-inlet vortex mixer, we fabricated the first NeuProIO solid drug NPs incorporating the repurposed neuroprotective agent maprotiline (MAP) and the IOP-lowering agent betaxolol (BX), forming MAP/BX NPs for synergistic glaucoma treatment. The NeuProIO improved stability …
Long-Range Fit: A Software Package For The Representation And Study Of Long-Range Molecular Interactions, Adrian L. Batista-Planas, Ernesto Quintas-Sánchez, Richard Dawes
Long-Range Fit: A Software Package For The Representation And Study Of Long-Range Molecular Interactions, Adrian L. Batista-Planas, Ernesto Quintas-Sánchez, Richard Dawes
Chemistry Faculty Research & Creative Works
Describing intermolecular forces is fundamental to modeling and predicting the behavior of molecular systems. In particular, long-range molecular interactions with electrostatic, induction, and dispersion as the main components play a critical role, especially for low-temperature and low-density regimes. Long-range interactions are often described through perturbation theory, representing the electronic charge distribution via a multipolar series of the moments and polarizability tensors corresponding to each molecule. However, while the theory is well established, obtaining the resulting analytical expressions (and their practical implementation) constitutes a highly complex and system-dependent task. To address this challenge, we developed long-range-fit (LRF), an interactive and user-friendly …
Cationic Poly(Glucosamine)-Based Polymers Bind To Glycans With Varying Affinity Facilitating Transport Across The Glycocalyx Of Endothelial Cells, Claire Bridges, Lu Fu, Dan Wang, James D. Sterling, Susanna Liang, Shenda M. Baker, Jonathan Yeow, Megan S. Lord
Cationic Poly(Glucosamine)-Based Polymers Bind To Glycans With Varying Affinity Facilitating Transport Across The Glycocalyx Of Endothelial Cells, Claire Bridges, Lu Fu, Dan Wang, James D. Sterling, Susanna Liang, Shenda M. Baker, Jonathan Yeow, Megan S. Lord
Business and Information Technology Faculty Research & Creative Works
Natural polysaccharides, such as chitosan, offer promising avenues for drug delivery due to their cytocompatibility and ability to interact with cell surfaces. However, the endothelial glycocalyx, a glycan-rich extracellular matrix, presents a barrier that must be navigated for effective intracellular delivery. This study investigates how cationic poly(glucosamine)-based polymers, functionalized with guanidinium or ammonium groups, interact with key glycocalyx components including hyaluronan (HA) and heparan sulfate (HS). We demonstrate that these cationic polymers form tunable biomolecular condensates with glycans, with stronger binding observed for sulfated glycans, HS and heparin, than unsulfated HA. Derivatized chitosan polymers with varied cationic side chains exhibit …
Early Detection Of Infectious Diseases: A Review Of Recent Advances In Pathogen Identification, Molecular Tools, And Metabolomics-Driven Biomarker Discovery, Patrica Ivy Agorsor, Michael O. Eze
Early Detection Of Infectious Diseases: A Review Of Recent Advances In Pathogen Identification, Molecular Tools, And Metabolomics-Driven Biomarker Discovery, Patrica Ivy Agorsor, Michael O. Eze
Chemistry Faculty Research & Creative Works
The recent COVID-19 pandemic has heightened public interest in noninvasive methods for early diagnosis of infectious diseases. In addition, various government agencies have implemented "infectious disease preparedness" to mitigate future outbreaks. This review highlights conventional and advanced methods for infectious disease diagnosis with an emphasis on emerging mass spectrometry methods. Conventional methods for pathogen identification, such as culture-based techniques and molecular methods, have limitations with respect to sensitivity, specificity, and turnaround time. Recent advances in high-resolution mass spectrometry have revolutionized the field of infectious disease biomarker discovery. These techniques enable the comprehensive profiling of metabolites in various biological samples, identification …
Probing Proximal Intramolecular Hydrogen Bonding Interactions On A Norbornane Scaffold, Carly A. Rock, Dakota B. Green, Martin J. Flores, Jeremy M. Carr, Thufail M. Ismail, Gregory S. Tschumper
Probing Proximal Intramolecular Hydrogen Bonding Interactions On A Norbornane Scaffold, Carly A. Rock, Dakota B. Green, Martin J. Flores, Jeremy M. Carr, Thufail M. Ismail, Gregory S. Tschumper
Chemistry Faculty Research & Creative Works
A systematic computational study was conducted on 12 unique 2,6-disubstituted norbornane derivatives to assess the ability of various acceptor groups (A = F, Cl, Br, OH, OCH3, SH, SCH3, NHCH3, N(CH3)2, PH2, PHCH3, and P(CH3)2) to engage in intramolecular hydrogen bonding with a proximal OH donor. 32 unique minima have been characterized with M06-2X and df-MP2 geometry optimizations as well as PNO-LCCSD(T)-F12 single point energy computations. Conformations with the OH donor oriented toward the acceptor to form an OH···A contact (+HB) consistently had lower electronic energies (by approximately 2 to 8 kcal mol–1) than their counterparts with the …
Use Of Gamma-Ray Spectroscopy In Thickness Gauging Of A Complex-Shaped Lead Shield, Joseph T. Graham, Brian Durtschi, Ashish Avachat, Seth Kilby
Use Of Gamma-Ray Spectroscopy In Thickness Gauging Of A Complex-Shaped Lead Shield, Joseph T. Graham, Brian Durtschi, Ashish Avachat, Seth Kilby
Nuclear Engineering and Radiation Science Faculty Research & Creative Works
Methods for measuring the thickness of lead shielding based on 60Co gamma-ray spectroscopy are presented. In applications where a shield's thickness is multiple mean free paths and the shield has a complex shape (i.e. cannot be approximated as a simple solid such as a slab, sphere, semi-infinite medium, etc.), the necessary buildup factors are not available. Thus, determination of shield thickness by means of the Beer–Lambert law requires separating the counts from uncollided photons from the scattered photon contribution. It is demonstrated how the 1332 keV gamma ray of 60Co can be used to precisely quantify lead thicknesses …
Modeling And Characterizing The Electron Backscatter In A Cylindrical Anode-Based Distributed X-Ray Source, Jordan Fox, Seth Kilby, Hyoung Koo Lee, Ayodeji Alajo, Ashish Avachat
Modeling And Characterizing The Electron Backscatter In A Cylindrical Anode-Based Distributed X-Ray Source, Jordan Fox, Seth Kilby, Hyoung Koo Lee, Ayodeji Alajo, Ashish Avachat
Nuclear Engineering and Radiation Science Faculty Research & Creative Works
Upcoming advancements in computed tomography architectures warrants the investigation of new X-ray source designs and the impacts that electron backscatter can have on these designs. One such design being investigated is a distributed, cylindrical anode-based X-ray source. For such a distributed X-ray source, we developed a modeling pipeline for simulating electron optics and transport to characterize the quality of the primary X-ray beam and the electron backscatter behavior. We report our results on the energy distributions of the bremsstrahlung spectra; electron backscatter ratio; and spatial, temporal, and energy distributions of backscattered electrons that return to the anode.
Positive Solutions Of Semipositone Singular Three-Points Boundary Value Problems For Nonlinear Fractional Differential Equations, Xueyan Zhang, Zhaocai Hao, Martin Bohner
Positive Solutions Of Semipositone Singular Three-Points Boundary Value Problems For Nonlinear Fractional Differential Equations, Xueyan Zhang, Zhaocai Hao, Martin Bohner
Mathematics and Statistics Faculty Research & Creative Works
This study introduces the existence of one positive solution for a specific category of semipositive singular three-point boundary value problems associated with Caputo fractional differential equations. The proof relies on the application of the Guo–Krasnosel'skii fixed point theorem. In the end, we provide an illustrative example.
How To Measure, Analyze, And Interpret Age-Related Changes In Caenorhabditis Elegans: Lessons For Mechanistic And Evolutionary Theories Of Aging, Zuzana Kocsisova, Brian M. Egan, Andrea Scharf, Xavier Anderson, Franziska Pohl, Aaron Anderson, Kerry Kornfeld
How To Measure, Analyze, And Interpret Age-Related Changes In Caenorhabditis Elegans: Lessons For Mechanistic And Evolutionary Theories Of Aging, Zuzana Kocsisova, Brian M. Egan, Andrea Scharf, Xavier Anderson, Franziska Pohl, Aaron Anderson, Kerry Kornfeld
Biological Sciences Faculty Research & Creative Works
Aging is characterized by progressive degenerative changes in tissue organization and function, some of which increase the probability of mortality. Major goals of aging research are to elucidate the series of events that cause degenerative changes, and to identify environmental, pharmacological, and genetic factors that influence these changes; this information might lead to new strategies to extend health span and lifespan. Mechanistic studies of aging depend on accurate and precise descriptions of age-related changes, since these descriptions define the aging phenotype. Here, we review studies that describe age-related changes in C. elegans, including measurements of integrated functions such as behavior …
Nondestructive Burnup Evaluation And Gamma Spectroscopy Analysis Of Spent Fuel Elements In The Itu Triga Mark Ii Research Reactor, A. Kaya, O. Erbay, Z. Boduroglu, I. A. Reyhancan, M. S. Kiziltas, T. Akyurek
Nondestructive Burnup Evaluation And Gamma Spectroscopy Analysis Of Spent Fuel Elements In The Itu Triga Mark Ii Research Reactor, A. Kaya, O. Erbay, Z. Boduroglu, I. A. Reyhancan, M. S. Kiziltas, T. Akyurek
Nuclear Engineering and Radiation Science Faculty Research & Creative Works
This study presents a comprehensive burnup analysis of all fuel elements in the ITU TRIGA Mark II research reactor core using non-destructive assay (NDA) techniques based on gamma spectroscopy. Two distinct fuel inspection systems were employed to measure the gamma activity, with137Cs used as the primary burnup indicator due to its strong correlation with fuel depletion. The results show a clear burnup pattern, with higher values in the inner core rings that gradually decreases toward the outer rings. This asymmetric burnup distribution underscores the need for reactor core reconfiguration, for which an optimized layout is proposed. Additionally, gamma …
Hybrid Data-Driven Cement-Stabilized Soil Design: An Integration Of Machine Learning, Multi-Objective Optimization, And Life Cycle Assessment, Chikezie Chimere Onyekwena, Yunli Li, Ikenna J. Okeke, Ubani Obinna Uzodimma, Monday Uchenna Okoronkwo, Wenping Wu
Hybrid Data-Driven Cement-Stabilized Soil Design: An Integration Of Machine Learning, Multi-Objective Optimization, And Life Cycle Assessment, Chikezie Chimere Onyekwena, Yunli Li, Ikenna J. Okeke, Ubani Obinna Uzodimma, Monday Uchenna Okoronkwo, Wenping Wu
Chemical and Biochemical Engineering Faculty Research & Creative Works
Soil stabilization is crucial in geotechnical engineering, yet conventional methods are often time-consuming, resource-intensive, and environmentally unsustainable. Despite growing interest in Machine Learning (ML) and optimization tools for mix design, few studies integrate these methods with decision-making techniques and environmental assessment to support practical implementation. This study proposes a hybrid data-driven framework for predicting strength, optimizing mix compositions, and evaluating environmental impacts via life cycle assessment of cement-stabilized soft soils. Six ML models were evaluated, and the top-performing eXtreme Gradient Boosting (XGB) model was further improved using the Grey Wolf Optimizer (GWO). The optimized XGB-GWO model, integrated with a polynomial …
Computational Characterization Of A Recently Identified Disinfection Byproduct In Drinking Water: The Chloronitramide Anion And Its Monohydrate Complex, Thufail M. Ismail, Max R. Tucker, Gregory S. Tschumper
Computational Characterization Of A Recently Identified Disinfection Byproduct In Drinking Water: The Chloronitramide Anion And Its Monohydrate Complex, Thufail M. Ismail, Max R. Tucker, Gregory S. Tschumper
Chemistry Faculty Research & Creative Works
The chloronitramide anion (ClNNO2−) was recently identified as disinfection byproduct in drinking water, and various quantum chemistry methods (CCSD(T), MP2, B3LYP, ωB97XD, and M06-2X) are employed in this study to characterize this negatively charged species and its monohydrate complex. Both vertical and adiabatic quantities indicate the excess electron is bound by 3–4 eV. Four ClNNO2− monohydrate minima were identified, each exhibiting double ionic hydrogen bonding. The computed ClNNO2−⋯H2O interaction approaches 15 kcal/mol, and it induces pronounced vibrational frequency shifts in both fragments. Natural bond orbital analysis shows a redistribution of …
Leveraging Molecular Mechanisms Of Desorption To Enhance Pfas Bioavailability In Contaminated Soils, Husam Kafeenah, Margaret D. Taiwo, Patrica Ivy Agorsor, Michael O. Eze
Leveraging Molecular Mechanisms Of Desorption To Enhance Pfas Bioavailability In Contaminated Soils, Husam Kafeenah, Margaret D. Taiwo, Patrica Ivy Agorsor, Michael O. Eze
Chemistry Faculty Research & Creative Works
Per- and polyfluoroalkyl substances (PFAS) are known for their strong binding properties to soil matrices owing to their amphiphilic properties. While most studies focus on the search for novel PFAS bio degraders, our knowledge of sustainable biomolecules that could drive PFAS desorption and make them more bioavailable is limited. This study investigated the effectiveness of rhamnolipids and organic acids in desorbing PFAS compounds from contaminated soil. Rhamnolipids (25 mg/L) significantly enhanced the release of PFAS compounds from soil, achieving up to 90 % desorption. Acetic acid provided 60–90 % desorption efficiency for most of the PFAS studied, except for PFDA …
Advances And Challenges In Nano-Modified Cementitious Composites: Mechanisms, Dispersion Strategies, And Impact On Mechanical Properties, Fatemeh Mohammadi Ghahsareh, Pengwei Guo, Nusrath Jaha, Yi Bao, Kamal H. Khayat, Weina Meng
Advances And Challenges In Nano-Modified Cementitious Composites: Mechanisms, Dispersion Strategies, And Impact On Mechanical Properties, Fatemeh Mohammadi Ghahsareh, Pengwei Guo, Nusrath Jaha, Yi Bao, Kamal H. Khayat, Weina Meng
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Nanomaterials are increasingly utilized to enhance the mechanical properties, durability, and functionality of concrete materials but face challenges such as agglomeration and uneven dispersion in cementitious systems, which can offset the intended improvements. This paper reviews the advances and challenges associated with nano-modified cementitious composites, elucidating fundamental mechanisms and highlighting strategies for overcoming the challenges through experimental and computing techniques. The reviewed contents include (1) the classification of nanomaterials commonly used in cementitious systems and the mechanisms through which they enhance the mechanical properties of cementitious composites; (2) challenges of nanomaterials such as agglomeration in water, re-agglomeration in cementitious systems, …
Zirconium And Hafnium Interdiffusion Study In Zrb2–Hfb2 System, Yue Zhou, Ana C. Feltrin, William G. Fahrenholtz, Gregory E. Hilmas
Zirconium And Hafnium Interdiffusion Study In Zrb2–Hfb2 System, Yue Zhou, Ana C. Feltrin, William G. Fahrenholtz, Gregory E. Hilmas
Materials Science and Engineering Faculty Research & Creative Works
Interdiffusion of Zr and Hf in the diboride system was investigated. High-purity zirconium diboride (ZrB2) and hafnium diboride (HfB2) were prepared by a combination of boro-/carbothermal reduction synthesis and densification by spark plasma sintering. The bulk ceramics had relative densities of 99.3% for ZrB2 and 99.7% for HfB2, and both ceramics were phase-pure by x-ray diffraction analysis. Diffusion couples of ZrB2 and HfB2 were annealed at temperatures ranging from 2000°C to 2200°C for times from 4 to 12 h. Zr and Hf elemental concentration profiles were measured using energy dispersive spectroscopy …
Hold Paramount The Health, Safety, And Welfare Of The Public And The Planet, Daniel B. Oerther
Hold Paramount The Health, Safety, And Welfare Of The Public And The Planet, Daniel B. Oerther
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
No abstract provided.
Tip Penetration Test For Rapid In-Line Assessment Of Static Yield Stress During 3d Concrete Printing Process, Ali Fasihi, Nicolas A. Libre
Tip Penetration Test For Rapid In-Line Assessment Of Static Yield Stress During 3d Concrete Printing Process, Ali Fasihi, Nicolas A. Libre
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
The static yield stress of printable cementitious materials is a critical parameter governing the shape stability and buildability of 3D printed concrete structures. Among various testing techniques, the penetration test has emerged as a promising method for in-situ measurement of static yield stress during printing process. However, the applicability of the penetration test for in-line monitoring of static yield stress remains limited due to the necessity for substantial material thickness. To address this challenge, this study proposes a novel tip penetration test, which enables static yield stress determination without the requirement for full cone submergence, thereby facilitating assessment of thin …
Rheological And Micro Properties Of High-Viscosity Binder-Incorporated Polyphosphoric Acid And Rock Asphalt, Feng Ma, Xinye Jiang, Zhen Fu, Chongxin Zhu, Jenny Liu, Ke Shi, Yalu Wen, Yao Zhang
Rheological And Micro Properties Of High-Viscosity Binder-Incorporated Polyphosphoric Acid And Rock Asphalt, Feng Ma, Xinye Jiang, Zhen Fu, Chongxin Zhu, Jenny Liu, Ke Shi, Yalu Wen, Yao Zhang
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
To enhance the performance of high-viscosity modified asphalt (HVMA), polyphosphoric acid (PPA) and North American rock asphalt (NA-RA) were incorporated into styrene-butadiene-styrene (SBS)/crumb rubber (CR) composite modified asphalt, resulting in two distinct types of HVMA. The two HVMA types were evaluated at various dosages using a dynamic shear rheometer (DSR), bending beam rheometer (BBR), fluorescence microscope (FM), and Fourier infrared spectroscopy (FT-IR) tests. These tests provided both macroscopic and microscopic insights into their properties. The findings indicated that both PPA and NA-RA modify the asphalt's internal structure, enhancing its temperature resistance. PPA primarily improved high-Temperature performance, while NA-RA enhanced low-Temperature …
A Rapid Field Moisture Measurement Unit For Compaction Acceptance Of Unbound Materials, Chuanjun Liu, Xiong Zhang, Jenny Liu
A Rapid Field Moisture Measurement Unit For Compaction Acceptance Of Unbound Materials, Chuanjun Liu, Xiong Zhang, Jenny Liu
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
The moisture content (MC) was a critical parameter that needed to be monitored in geomaterial compaction. Nuclear density gauges (NDGs) had been the practice in MC and density measurement for decades but had become less desirable due to cost, regulatory, and safety concerns. Meanwhile, lightweight deflectometers (LWDs), proposed as an alternative to NDGs, did not have a function of MC measurement. This study aimed to identify a rapid field moisture analyzer to work with LWDs for evaluating the compaction acceptance of unbound materials in situ. The study started with evaluating the effectiveness and practicability of two existing moisture analyzers recommended …
Influence Of Wicking Geotextile Installation On Moisture Migration In Silt Under Rainfall Infiltration, Yipeng Guo, Dahao Zou, Min Hu, Xiong Zhang, Fang Xu, Yongjie Zhang, Jiejing Chen
Influence Of Wicking Geotextile Installation On Moisture Migration In Silt Under Rainfall Infiltration, Yipeng Guo, Dahao Zou, Min Hu, Xiong Zhang, Fang Xu, Yongjie Zhang, Jiejing Chen
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Silt is widely used in subgrade construction in the middle and lower reaches of the Yellow River in China due to limited availability of high-quality fill. However, its high moisture sensitivity and low strength often lead to pumping, settlement, and deformation. This study investigates the hydraulic performance of a wicking geotextile in silt under simulated rainfall infiltration using one-dimensional soil column experiments. Three installation configurations were evaluated: (i) a control sample (CS) without geotextile, (ii) an embedded sample (ES) with the geotextile fully installed as a capillary barrier, and (iii) a surface-exposed sample (SES) with the geotextile extended to the …
A Note On Sufficient Dimension Folding For Regression Mean Function With Categorical Predictors, Bilin Zeng, Akim Adekpedjou, Xuerong Meggie Wen
A Note On Sufficient Dimension Folding For Regression Mean Function With Categorical Predictors, Bilin Zeng, Akim Adekpedjou, Xuerong Meggie Wen
Mathematics and Statistics Faculty Research & Creative Works
Multi-dimensional arrays are referred to as tensors. Tensor-valued predictors are commonly encountered in modern biomedical applications, such as electroencephalogram (EEG), magnetic resonance imaging (MRI), functional MRI (fMRI), diffusion-weighted MRI, and longitudinal health data. In survival analysis, it is both important and challenging to integrate clinically relevant information, such as gender, age, and disease state along with medical imaging tensor data or longitudinal health data to predict disease outcomes. Most existing higher-order sufficient dimension reduction regressions for matrix- or array-valued data focus solely on tensor data, often neglecting established clinical covariates that are readily available and known to have predictive value. …
Examining The Effect Of Newcomers’ Adaptability On Proximal And Distal Outcomes Of Organizational Socialization, Vahe Permzadian, Mishra Vipanchi
Examining The Effect Of Newcomers’ Adaptability On Proximal And Distal Outcomes Of Organizational Socialization, Vahe Permzadian, Mishra Vipanchi
Psychological Science Faculty Research & Creative Works
We investigate the role of individual adaptability (I-ADAPT) in newcomer socialization by exploring its effects on the proximal and distal outcomes of the work-role transition process. Based on I-ADAPT theory, our study assesses how I-ADAPT affects the three key indicators of newcomer adjustment (i.e., role clarity, task mastery, and social acceptance) and, in turn, their effect on the distal socialization outcomes of job satisfaction, turnover intention, and work withdrawal. Using a 2-wave prospective design, we collected data from 280 newcomers recruited through Prolific. Results indicated that I-ADAPT dimensions differentially predict newcomer adjustment, with learning adaptability affecting role clarity, uncertainty adaptability …
Thermodynamic Analysis Of Metal Segregation In Two Metal Boride-Carbide Ceramics Containing V With Cr, Hf, Ti, Or Zr, Ana C. Feltrin, Simon Divilov, Gregory E. Hilmas, Stefano Curtarolo, William G. Fahrenholtz
Thermodynamic Analysis Of Metal Segregation In Two Metal Boride-Carbide Ceramics Containing V With Cr, Hf, Ti, Or Zr, Ana C. Feltrin, Simon Divilov, Gregory E. Hilmas, Stefano Curtarolo, William G. Fahrenholtz
Materials Science and Engineering Faculty Research & Creative Works
Dual-phase carbide-boride ceramics in different vanadium-Me (Me = Cr, Hf, Ti, and Zr) binary systems were synthesized by boro/carbothermal reduction under stoichiometric and carbon-deficient conditions and densified by spark plasma sintering. Thermodynamic analysis was used to evaluate the influence of composition on the phase stability and metal segregation between phases, along with the resulting effects on microstructure and hardness. Pairing vanadium with Group IV elements (Hf, Ti, and Zr) consistently formed one boride and one carbide phase, while the Cr-V system formed a monoboride phase and a carbon-deficient carbide. Metal segregation trends depended on composition. Vanadium preferentially segregated to the …
Exploring Public Opinions On Mining Governance And Preferences For Interventions To Enhance Battery Mineral Access, Mahelet G. Fikru, Sreeja Koppera, Nhien Nguyen
Exploring Public Opinions On Mining Governance And Preferences For Interventions To Enhance Battery Mineral Access, Mahelet G. Fikru, Sreeja Koppera, Nhien Nguyen
Economics Faculty Research & Creative Works
Based on an online survey of 1200 individuals, we examine support for new mining projects in the United States, opinions on mining governance, and preferences for various strategies to access battery minerals. We find support for domestic mining more so at the national (54 % support) than local level (32 % support), with a strong emphasis on environmental protection and multi-level governance. Respondents generally support government intervention to secure access to battery minerals, with over half agreeing with subsidizing electric vehicle (EV) producers and consumers to prioritize the use of domestic minerals in EV batteries. However, there is measurable opposition …
Integrated Computational And Experimental Investigation Of Groups V And Vi Metals In (M,Hf,Ti,Zr)B2-(M,Hf,Ti,Zr)C Ceramics, Ana C. Feltrin, Simon Divilov, Gregory E. Hilmas, Stefano Curtarolo, William G. Fahrenholtz
Integrated Computational And Experimental Investigation Of Groups V And Vi Metals In (M,Hf,Ti,Zr)B2-(M,Hf,Ti,Zr)C Ceramics, Ana C. Feltrin, Simon Divilov, Gregory E. Hilmas, Stefano Curtarolo, William G. Fahrenholtz
Materials Science and Engineering Faculty Research & Creative Works
Dual-phase compositionally complex ultra-high temperature ceramics were formulated by incorporating different Groups V and VI metals such as V, Nb, Ta, Cr, Mo, or W into a base composition containing the Group IV elements, Hf, Ti, and Zr. Metal distribution was predicted using first-principles-based thermodynamics simulations and compared with experimental results. Moreover, phase stability, microstructure, and mechanical properties were evaluated for all of the ceramics. Compositions containing Cr, V, Nb, or Ta formed dual-phase ceramics containing only one boride and one carbide phase, while compositions containing Mo or W developed an additional third phase. The experimental metal distribution trends generally …
Performance And Mechanistic Insights Into Cement Systems Modified With Wastewater-Recovered Struvite, Ugochukwu Ewuzie, Rupack R. Halder, Abdulkareem O. Yusuf, Abiodun A. Saka, Godwin I. Ogbuehi, Titus C. Egbosiuba, Damilola A. Daramola, Monday Uchenna Okoronkwo
Performance And Mechanistic Insights Into Cement Systems Modified With Wastewater-Recovered Struvite, Ugochukwu Ewuzie, Rupack R. Halder, Abdulkareem O. Yusuf, Abiodun A. Saka, Godwin I. Ogbuehi, Titus C. Egbosiuba, Damilola A. Daramola, Monday Uchenna Okoronkwo
Chemical and Biochemical Engineering Faculty Research & Creative Works
Struvite, the stable hydration product and primary strength phase in magnesium ammonium phosphate cement (MAPC), derived from wastewater treatment, has recently been utilized as a sustainable additive to Portland cement (PC). However, its impacts on cement hydration kinetics, pore refinement, rheology, and the mechanisms underlying these processes have not been comprehensively studied. This study developed Portland cement-struvite (PCS) systems by replacing PC with 3–20 % struvite (ST wt.%: PCS3–PCS20) and evaluated these processes using isothermal calorimetry, 3D micro-computed tomography (μXCT), time-dependent rheometry, X-ray diffraction (XRD), and Fourier-transform infrared spectroscopy (FTIR), and the Krstulović-Dabić (K-D) model. The FTIR/XRD confirmed the coexistence …
Nanocatalytic Enhancement Of Local Heat Transfer In Continuous-Flow Thermal Reactors, Nasser Zouli, Nujud Maslamani, Ayman Yousef, Muthanna H. Al-Dahhan
Nanocatalytic Enhancement Of Local Heat Transfer In Continuous-Flow Thermal Reactors, Nasser Zouli, Nujud Maslamani, Ayman Yousef, Muthanna H. Al-Dahhan
Chemical and Biochemical Engineering Faculty Research & Creative Works
An experimental investigation was conducted to evaluate the thermal conductivity (TC) and local heat-transfer coefficients (LHTCs) of nanofluids containing alumina (Al2O3), hematite (Fe2O3), and copper oxide (CuO) nanoparticles dispersed in deionized water. A newly developed non-invasive LHTC probe was integrated into the inner wall of the test section to enable direct quantification of interfacial heat-transfer performance. The measurements were conducted under laminar and turbulent flow conditons across Reynolds numbers ranging from 1000 to 10,000. The selected nanoparticles were chosen based on their high intrinsic thermal conductivity, cost effectiveness, and, in the case …
Co-Calcination Of Limestone And Clay Enhances The Performance Of Limestone Calcined Clay Cement (Lc3), Oluwadamilare Charles Adesina, Sahil Surehali, Avinaya Tripathi, Kayla Lauren Lee, Bryan K. Aylas-Paredes, Aditya Kumar, Narayanan Neithalath
Co-Calcination Of Limestone And Clay Enhances The Performance Of Limestone Calcined Clay Cement (Lc3), Oluwadamilare Charles Adesina, Sahil Surehali, Avinaya Tripathi, Kayla Lauren Lee, Bryan K. Aylas-Paredes, Aditya Kumar, Narayanan Neithalath
Materials Science and Engineering Faculty Research & Creative Works
Limestone-calcined clay cements (LC3) reduce the environmental impact of cement production and accelerate the industry transition toward carbon neutrality. While conventional LC3 with 50% clinker replacement (LC3-50) demonstrate long-term performance comparable to ordinary Portland cement (OPC) in concrete, early-age performance is generally compromised. This study explores for the first time, joint thermal treatment—that is, co-calcination—of limestone (LS) and bulk kaolinitic clay in mass ratios of 1:1 to 1:4 under a calcination regime specifically designed to ensure activation of the clay mineral. The co-calcination converts a small fraction of LS to metastable CaO, thus providing an …