Digital Commons Network^™

Development Of Alternative Air Filtration Materials And Methods Of Analysis, Ivan Philip Beckman

Theses and Dissertations

Clean air is a global health concern. Each year more than seven million people across the globe perish from breathing poor quality air. Development of high efficiency particulate air (HEPA) filters demonstrate an effort to mitigate dangerous aerosol hazards at the point of production. The nuclear power industry installs HEPA filters as a final line of containment of hazardous particles. Advancement air filtration technology is paramount to achieving global clean air. An exploration of analytical, experimental, computational, and machine learning models is presented in this dissertation to advance the science of air filtration technology. This dissertation studies, develops, and analyzes …

The Chemistry And Catalytic Activity Of Dehydrogenative Silylation And Hydroboration Of Complexes Bearing Semirigid Ligands With Group 14 Elements, Niroshani S. Abeynayake

Theses and Dissertations

Incorporation of silicon in the ligand backbone would yield electron-rich metal complexes upon coordination to transition metal complexes. The coordination chemistry of semirigid benzyl phosphines bearing a single or multiple phosphorus atoms and varying number of Si−H moieties has gained interest in recent years. This dissertation focuses on synthesizing silyl and germyl transition metal complexes of groups 9 and 10. Chapter II presents the synthesis of a family of four coordinated 14-electron rhodium complexes. The newly synthesized complexes were characterized in solution by multinuclear NMR spectroscopy and in the solid-state by single-crystal X-ray diffraction. These d⁶ complexes possess sawhorse …

Comparing Importance Of Knowledge And Professional Skill Areas For Engineering Programming Utilizing A Two Group Delphi Survey, John F. Hutton

Theses and Dissertations

All engineering careers require some level of programming proficiency. However, beginning programming classes are challenging for many students. Difficulties have been well-documented and contribute to high drop-out rates which prevent students from pursuing engineering. While many approaches have been tried to improve the performance of students and reduce the dropout rate, continued work is needed. This research seeks to re-examine what items are critical for programming education and how those might inform what is taught in introductory programming classes (CS1). Following trends coming from accreditation and academic boards on the importance of professional skills, we desire to rank knowledge and …

A Constitutive Material Model For Simulating Texture Evolution And Anisotropy Effects In Cold Spray., Creston Michael Giles

Theses and Dissertations

Cold spray has seen rapid advancement since its inception and has shown significant potential as a method of additive manufacturing. However, the large plastic deformation and repeated heating/cooling cycles that the material undergoes during the cold spray process can result in gradients in material structure and large residual stresses. The purpose of this study is to extend the existing EMMI material model to include anisotropic material response through the use of orientation distribution functions to predict residual stresses and anisotropy resulting from cold spray and similar additive manufacturing processes. Through the use of a finite element simulation, yield surfaces for …

Combined Effects Of Cyclosporine And Prednisone On T-Cell Cytokine Production In Healthy Dogs, Brittany Moore-Henderson

Theses and Dissertations

Cyclosporine and prednisone are immunosuppressive drugs that are commonly used in combination for the treatment of immune-mediated diseases, and have been shown to individually cause significant suppression of IL-2. Currently, no studies have been performed to determine how a combination of the two drugs would impact suppression of IL-2, and if an additive or synergistic effect on cytokine production could be demonstrated, as in studies of other species. An additive effect of immunosuppression associated with this drug combination could allow clinicians to decrease dosages of drugs, thereby reducing drug costs and minimizing adverse drug side effects. In a cross-over study …

Augmented Reality Fonts With Enhanced Out-Of-Focus Text Legibility, Mohammed Safayet Arefin

Theses and Dissertations

In augmented reality, information is often distributed between real and virtual contexts, and often appears at different distances from the viewer. This raises the issues of (1) context switching, when attention is switched between real and virtual contexts, (2) focal distance switching, when the eye accommodates to see information in sharp focus at a new distance, and (3) transient focal blur, when information is seen out of focus, during the time interval of focal distance switching. This dissertation research has quantified the impact of context switching, focal distance switching, and transient focal blur on human performance and eye fatigue in …

Analysis Of Process And Environmental Parameters Impacting Membrane Fouling, Methane Production, Soluble Microbial Products, Extracellular Polymeric Substances And Chemical Oxygen Demand Removal In Anaerobic Membrane Bioreactors Wastewater Treatment, James Mark-Ige

Theses and Dissertations

Aerobic (AeMBRs) and Anaerobic Membrane Bioreactors (AnMBRs) are an essential part of the advanced wastewater treatment options, which offer advantages in terms of higher effluent discharge and smaller footprints over the traditional wastewater treatment. This study evaluates the performance of (AnMBRs) by analyzing the cumulative effect of eleven physico-chemical parameters from the data obtained from the studies conducted from year 2000 onwards. Effect of various parameters such as Solid Retention Time (SRT), Hydraulic Retention Time (HRT), Mixed Liquor Suspended Solids (MLSS), influent Chemical Oxygen Demand (COD), Organic Loading Rate (OLR), influent COD, and temperature on the COD removal, methane production …

A Fully Coupled Implementation Approach To Study Hydrogen Embrittlement In Metals Using Finite Element Analysis, Sofia Yassir

Theses and Dissertations

Diverse hypotheses are behind the strength degradation in metals due to hydrogen diffusion, leading to a severe, sudden failure. These diverse hypotheses of hydrogen embrittlement include various mechanisms that are responsible for the embrittlement of metals due to hydrogen exposure in their microstructures. This research study focuses on one hydrogen embrittlement mechanism: Hydrogen-Enhanced-Localized-Plasticity (HELP). The HELP is the only single mechanism characterized by promoting localization of plastic flow ahead of the crack by increasing dislocation motion in that region. The current state of the art is a development of a numerical model representing a fully diffusion-mechanical coupled model. This fully …

Surrogate Model-Based Design Optimization Of A Mobile Deployable Structure For Overpressure Load And Vehicular Impact Mitigation, Daniela F. Tellkamp

Theses and Dissertations

Artificial Neural Network (ANN) ensemble and Response Surface Method (RSM) surrogate models were generated from Finite Element (FE) simulations to predict the overpressure load and vehicle impact response of a novel rapidly deployable protective structure. A Non-dominated Sorting Genetic Algorithm-II (NSGA-II) was used in conjunction with the surrogate models to determine structure topology input variable configurations which were suited to produce the optimal balance of minimum mass, minimum rotation angle, minimum displacement, and maximum total length of the deployable structure. The structure was designed to retract into a container, be lightweight to facilitate transportation, and be able to adapt to …

Unraveling The Anti-Inflammatory Mechanisms And Efficacy Of Cannabidiol On The Progression Of A Murine Model Of Multiple Sclerosis From The Innate To The Adaptive Immune System To Clinical Symptoms, Christa Marie Frodella

Theses and Dissertations

Cannabidiol (CBD), a non-psychotropic phytocannabinoid with structural similarity to Δ 9 -tetrahydrocannabinol (THC), is currently being investigated as a therapeutic for its immunosuppressive effects. One disease for which CBD is extensively researched is multiple sclerosis (MS), a demyelinating, autoimmune disorder, and its murine model counterpart, experimental autoimmune encephalomyelitis (EAE). The focus of this dissertation aimed to analyze the transcriptomic brain pathways in EAE and its comparison to MS in addition to CBD’s immunosuppressive mechanisms in the innate and adaptive immune systems. Evidence presented here showed that transcriptomic signaling pathways in the EAE brain of mice with clinical symptoms were similar …

Evaluation Of Soybean [Glycine Max (L.) Merr.] Cultivar Response To Prophylactic Fungicide Application, Steven B. Stoker

Theses and Dissertations

Soybean growers in the southern United States commonly deal with disease issues that can limit yield potential. As a result, growers have adopted prophylactic fungicide application targeted at specific growth stages as a standard management practice. However, yield responses to prophylactic applications have become sporadic over time. One major change that has occurred is adoption of cultivars with improved disease tolerances. Therefore, the objective of this research was to evaluate yield response of cultivars representing multiple genetic backgrounds to fungicides applied prophylactically at the R4 soybean growth stage. Experiments were conducted in 2020 and 2021 to determine the yield impact …

Design And Synthesis Of Novel Donor-Acceptor-Donor Xanthene-Based Dyes From Heteronuclear Ring Systems For Chemical, Electrochemical, And Biological Sensory Materials, Ishanka Nirmani Rajapaksha

Theses and Dissertations

Conventional xanthene dyes (eg: fluorescein and rhodamine) have their absorptions and emissions in the visible region, which limits their use in cellular imaging. Absorptions and emissions at longer wavelengths allow for low background cellular autofluorescence, deep tissue penetration, and minimum cell damage. Chapter I discusses the background of fluorescent dyes and the importance of near-infrared (NIR) emissive dyes for biological applications. Chapter II is based on the design and synthesis of new xanthene-based NIR I dyes using simple and short synthetic routes. This study used pyrrole and indole as donor molecules and combined them to the xanthene core by the …

United We Stand? Investigating The Impact Of Unified Dues Agreements Between State And National Career & Technical Education (Cte) Professional Organizations On Cte Funding In The Southern States, Justin Ryan Hall

Theses and Dissertations

Career and Technical Education (CTE) teachers have long been active in lobbying the federal and state governments in support of CTE through their professional organizations, but these are not traditionally considered interest groups. This study sought to determine if the formal relationships—dues agreements—between the two largest national professional organizations, and their state affiliates had an impact on state funding for CTE. The impacts of professional organization unity, membership rates, and lobbying expenses on state-level CTE funding were analyzed through the lens of interest group theory, a subfield of political science. Within this population (N = 13), 1) a link …

Parent-Child Relationships And Parental Distress As Moderators Between Chronic Illness And Psychological Problems In Emerging Adults., Abigail Kukay

Theses and Dissertations

The current study aimed to better understand how parental functioning and parent-child relationships might moderate the effects of chronic illness on psychological problems in emerging adulthood. Three hypotheses were made: (1) the presence and severity of chronic illness would associate positively with emerging adult psychological problems, (2) parental distress would moderate the effects between chronic illness presence/severity and emerging adulthood psychological problems, and (3) parent-child relationship quality would moderate the effects between chronic illness presence/severity and emerging adult psychological problems. Data analysis consisted of testing interaction effects, pairwise parameter comparisons, and multiple group analysis. The three-way interaction between endorsing a …

Additively Manufactured Lenses For Modulating Guided Waves In Laminated Composites, Hajar Righi

Theses and Dissertations

Composite materials have increasingly been used as an alternative to metals and other isotropic materials for primary structural components in aerospace industries. Unlike traditional isotropic materials, composite materials are known to have complex internal microstructures. Therefore, it is essential to develop methods for the inspection, evaluation, and monitoring of composite materials. Ultrasonic-guided waves and, more precisely, Lamb waves have proven to be an efficient and accurate technique for the non-destructive testing. Since guided waves are dispersive and multimodal, it is important to develop a practical method to manipulate Lamb waves to achieve better structural health monitoring and non-destructive inspection results. …

Critical (Re)Approach To Higher Education Admission Policy: The Impact Of Open Enrollment Policy Implementation, Shirdonna Yvonne Lawrence

Theses and Dissertations

Federal and state policies affecting higher education, like the Morrill Land Grant Act of 1832, Brown vs. Board of Education, and Higher Education Act of 1965 have posited change regarding the proliferation of diversity and expansion of access (Thelin, 2011).

I analyzed BOT policies for enrollment and conducted a socio-diagnostic CDA on the implementation of admission policy to understand the impact of the policies’ implementation. I focused on 1) exploring how open enrollment (OE) policies were constructed, 2) how institutions adopt and interpret these policies, and 3) how individuals at the institution enact these policies, by conducting a discourse-historical analysis …

Development Of A Crosslinked Osteochondral Xenograft And A Collagen Stabilizing Intra-Articular Injection To Remediate Cartilage Focal Lesions To Prevent Osteoarthritis, Mark Lewis Mosher

Theses and Dissertations

Osteoarthritis is one of the most common causes of disability in adults in America. It is a progressive and degenerative disease where the articular cartilage is broken down and lost from the surfaces of bones causing chronic pain and swelling in the joints, and currently has no cure. The most commonly osteoarthritis starts from a focal lesion on the cartilage surface, which will expand on the surface and downwards through the thickness of the tissue. The current gold standard for correcting cartilage focal lesions is the osteochondral autograft/allograft transplantation (OAT), which replaces the defect with a fresh osteochondral graft. The …

Effects Of Microcystin-Lr On Channel Catfish (Ictalurus Punctatus) Susceptibility To Microbial Pathogens (Aeromonas Hydrophila And Edwardsiella Piscicida), Alison Marchant

Theses and Dissertations

Microcystin-LR is a hepatotoxin produced by cyanobacteria. Aeromonas hydrophila and Edwardsiella piscicida infections are leading causes of losses in market-sized channel catfish (Ictalurus punctatus). These older fish should have natural immunity in place and a predisposing factor is likely a prerequisite for these disease outbreaks. While microcystin-LR rarely causes mortality in warm-water aquaculture, we believe it may be a predisposing factor that leads to bacterial disease outbreaks during the summer months due to its ability to damage the liver. Our study investigated microcystin-LR’s effects on channel catfish susceptibility to these pathogens. We found that a sublethal dose of microcystin-LR induced …

Inequity Of Access Across America: A Spatial, Temporal, And Modal Disparity Analysis, Sanju Maharjan

Theses and Dissertations

The overarching goal of this dissertation is to examine the spatial, temporal, and modal disparity of access across America. This is achieved by posing three research objectives. The first objective determines the spatial and temporal disparity of transit and automobile access gap, its impact on transit use, and its socioeconomic and built environment correlates. The second objective examines the spatial and temporal disparity of slightly and extremely risky bike infrastructure and measures the social inequity of access to bike infrastructure. The third objective indicates spatial transit access mismatch between high- and low-wage employment across metropolitans. Three findings are discerned. First, …

Recruiting More U.S. Women Into Engineering Based On Stories From Morocco: A Qualitative Study, Soundouss Sassi

Theses and Dissertations

The objective of this project is to examine the differences between Moroccan and American students with regards to the cultural influences that led them to pursue an engineering degree. Annually since 2015, a partnership between a university in Morocco and MSU allows senior engineering Moroccan students to study at MSU to obtain their graduate degree in aerospace or mechanical engineering. The roughly equal gender representation in most Moroccan cohorts prompted our research question: “How do students from Morocco and the United States describe the cultural reasons that factored into their choice to pursue an engineering degree?” This exploratory qualitative study …

Effect Of Spray Droplet Size On Pronamide Control Of Annual Bluegrass (Poa Annua L.) And The Role Of Absorption And Translocation In The Mechanism Of Pronamide Resistance, Martin Ignes

Theses and Dissertations

Annual bluegrass (Poa annua L.) is a problematic weed in turfgrass that has evolved resistance to twelve different herbicide sites of action. The mitotic-inhibiting herbicide pronamide has both pre- and post-emergence activity on susceptible annual bluegrass populations. Still, post-emergence activity may be compromised in some resistant populations due to the lack of root uptake or an unknown foliar resistance mechanism. Spray droplet size may affect foliar and soil deposition of pronamide, thus potentially explaining variation in population control or differential foliar and root uptake. Pronamide, flazasulfuron, and pronamide + flazasulfuron deposition were quantified on annual bluegrass as affected by spray-droplet …

Vegetation And Nutritional Changes Over 20 Years Of White-Tailed Deer Exclusion, Gabrielle Nicole Ripa

Theses and Dissertations

Knowledge of the impacts of white-tailed deer (Odocoileus virginianus; hereafter deer) as dominant herbivores throughout the Southeastern United States of America is lacking. To address this, three paired experimental units of exclosures and controls were constructed in 2000 on three Wildlife Management Areas across Mississippi within the ecoregions of the Upper Coastal Plain, Lower Coastal Plain, and the Mississippi Alluvial Valley. Vegetation was sampled in the summers of 2000, 2005, and 2021 including vegetation structure, canopy coverage, basal area, and species composition. Additionally, in 2005 and 2021, biomass was sampled to determine potential impacts on nutritional carrying capacity. Among the …

Congestion Based Truck Drone Intermodal Delivery Optimization, Ankith Thodupunoori

Theses and Dissertations

Commerce companies have experienced a rise in the number of parcels that need to be delivered each day. The goal of this study is to provide a decision-making procedure to assist carriers in taking a more significant role in selecting cost and risk-efficient truck-drone intermodal delivery routing plan. The congestion-based model is developed to select the method of parcel delivery utilizing a truck and a drone for optimizing cost and time. A study also has been conducted to compare drone-only and truck-only delivery routing plan. The proposed A* Heuristic algorithm and the OSRM application generate the travel path for drone …

Molecular And Phenotypic Characterization Of Escherichia Coli Isolated From Broiler Chicken Flocks In Mississippi, Priyanka Devkota

Theses and Dissertations

Avian pathogenic Escherichia coli (APEC) is the causative agent of colibacillosis. APEC causes significant economic losses to the poultry industry. In this study, 66 E. coli isolates were collected from broiler flocks across Mississippi and categorized as clinical and non-clinical isolates. Genotypic and phenotypic characterization of virulence factors and antimicrobial resistance profiles of these E. coli were examined. The data disclosed a higher prevalence of virulence genes in clinical isolates than in non-clinical isolates. High differences on the genotypic and phenotypic antimicrobial resistance among clinical and non-clinical isolates were observed. Whole genome sequences of avian E. coli elaborated a diverse …

Mapping Forest Structure In Mississippi Using Lidar Remote Sensing, Nitant Rai

Theses and Dissertations

This study aimed at evaluating the agreement of spaceborne Light Detection and Ranging (lidar) ICESat-2 canopy height with Airborne Laser Scanning (ALS) derived canopy height to inform about the performance of ICESat-2 canopy height metrics and understand its uncertainties and utilities. The agreement was assessed for different forest types, physiographic regions, a range of percent canopy cover, and diverse disturbance histories. Results of this study suggest that best agreements are found using strong beam data collected at night for canopy height retrieval using ICESat-2. The ICESat-2 showed great potential for estimating canopy heights, particularly in evergreen forests with high canopy …

Platinum-Iridium Alloys In Jewelry, Nathen C. Christa, Seth Walker, Dylan Hallman

ME 4133/6133 Mechanical Metallurgy

One of the most widely used metals on the periodic table is Platinum (Pt). The name is derived from the Spanish Platina, meaning “silver.” This malleable, ductile material is widely used in applications due to its unique chemical properties. A couple of these unique properties include a high melting point and good resistance to corrosion or chemical attack. Platinum materials have alloys that are indispensable in the chemical laboratory for electrodes. This allows for material applications in crucibles and dishes to withstand elevated temperatures. Platinum is used primarily in catalytic converters in vehicles converting emissions from the vehicle’s engine into …

High-Carbon Steel In Additive Manufacturing, Chidi N. Agusiegbe, Devin Morton, Emmanuel Moore

ME 4133/6133 Mechanical Metallurgy

High-carbon steel can be processed through numerous methods. The method that will be focused on primarily is processing high-carbon steel through means of additive manufacturing. Additive manufacturing is the industrial production name for 3D printing, a computer-controlled process that creates three-dimensional objects by depositing materials, usually in layers. AM methods like wire laser additive manufacturing (WLAM) and electron beam melting (EBM) are all common methods for fabricating high carbon steel. The perks associated with these methods are that they improve some drawbacks of the natural properties of high-carbon steel. This paper discusses the uses of these additive manufacturing methods along …

High Carbon Steel In Additive Manufacturing, Emmanuel Moore Ii, Devin Morton, Chid Agusiegbe

ME 4133/6133 Mechanical Metallurgy

The first known use of carbon steel dates back to 500 A.D. when a blacksmith mistakenly used iron ore as a primary material for smithing. This material, as the name suggests, is made up of both carbon and iron. This material, as one of the most abundant at the time, was used most frequently in European and Asian countries. “Carbon steel first appeared around the year 500 AD in Damascus steel swords as well as Japanese swords. They were prized for their sharp edges and sturdiness compared to other weapons of the era. The composition of these swords was very …

Integration Of Hadfield Steel Into Modern Body Armor, Jason T. Fridlund

ME 4133/6133 Mechanical Metallurgy

The increased lethality of recently fielded projectiles mandates a proportional escalation in armor performance. Recent advancements in ceramic technologies have allowed designers to incorporate harder but more brittle materials into hard armor designs to defeat yet more capable penetrating projectiles. Ceramics suffer from the feature of shattering, however, even when impacted by threats below their design parameters. While this shattering mechanism is used effectively to dissipate energy from high-energy rifle projectiles, it is wasted on low-energy projectiles, and can result in easily damaged lifesaving gear, both of which are undesirable in combat. In contrast, steel body armor has been used …

High Carbon Steel In Additive Manufacturing, Chidi Agusiegbe, Devin Morton, Emmanuel Moore

ME 4133/6133 Mechanical Metallurgy

Infographic demonstrating the composition, and use of high carbon steels as well as the process of the material in additive manufacturing.