Digital Commons Network^™

Design And Synthesis Of Donor-Acceptor-Donor Xanthene-Based Near Infrared I And Shortwave Infrared (Swir) Dyes For Biological Imaging, Chathuranga Rathnamalala

Theses and Dissertations

Small molecule organic dyes with absorption and emission in the near infrared region (NIR) attracted much attention for various applications such as dye sensitized solar cells, fluorescent guided surgery, stimuli responsive bioimaging and photodynamic therapy. Dyes with high absorption and emission in the NIR region are beneficial for stimuli responsive bioimaging due to the deeper penetration of NIR light, less cell damage, high resolution, and low background autofluorescence from biomolecules. Of the many small molecule dyes, xanthene-based dyes exhibit outstanding photophysical properties and good stimuli response for use in bioimaging applications. However, absorption and emission of the xanthene dyes lie …

Automated Mapping Of Oblique Imagery Collected With Unmanned Vehicles In Coastal And Marine Environments, Jacob B. Freeman

Theses and Dissertations

Recent technological advances in unmanned observational platforms, including remotely operated vehicles (ROVs) and small unmanned aerial systems (sUAS), have made them highly effective tools for research and monitoring within marine and coastal environments. One of the primary types of data collected by these systems is video imagery, which is often captured at an angle oblique to the Earth’s surface, rather than normal to it (e.g., downward looking). This thesis presents a newly developed suite of tools designed to digitally map oblique imagery data collected with ROV and sUAS in coastal and marine environments and quantitatively evaluates the accuracy of the …

Macroecological Patterns Of Frugivorous Fishes’ Diversity (Serrasalmidae) In The Amazon Drainage Basin, Karold Vivianna Coronado Franco

Theses and Dissertations

The Amazon River drainage basin is known as the most biodiverse region in the world. Regarding freshwater fish, this region contains around 15% of the world's fish richness. The fish family Serrasalmidae have a variety of feeding preferences including Pacus (herbivores) and Piranhas (carnivores). Fruit eating fish species are evolutionarily the oldest species in the family and have a mutualistic interaction with flooded forests. Considering the diversity of feeding habits of the Serrasalmidae family, it represents an excellent model to study ecological questions related to factors that influence the spatial distribution of species and factors that contribute to the maintenance …

The Response Of An Avian Community To Intercropping And Forest Management Practices In A Private Working Pine Forest, Rebecca Doyne Bracken

Theses and Dissertations

Within managed pine forest systems, a plethora of bird species exist throughout the lifecycle of a stand akin to what may be experienced through post-disturbance regeneration in a natural forest system. I sought to address how breeding avian communities shift across time in response to stand aging and forest management, evaluate species-specific responses to stand conditions, investigate the responses of at-risk avian species to forest management, and determine avian non-breeding, over-wintering presence in a managed loblolly pine (Pinus taeda) forest. I conducted breeding bird point count and vegetation surveys within five stands of privately owned and managed pine forest in …

A Generalizable Method And Case Application For Development And Use Of The Aviation Systems – Trust Survey (As-Ts)., Jamison Hicks

Theses and Dissertations

Automated systems are integral in the development of modern aircraft, especially for complex military aircraft. Pilot Trust in Automation (TIA) in these systems is vital for optimizing the pilot-vehicle interface and ensuring pilots use the systems appropriately to complete required tasks.

The objective of this research was to develop and validate a TIA scale and survey methodology to identify and mitigate trust deficiencies with automated systems for use in Army Aviation testing. There is currently no standard TIA assessment methodology for U.S. Army aviation pilots that identifies trust deficiencies and potential mitigations.

A comprehensive literature review was conducted to identify …

The Influence Of Overwatering, Underwatering, And Waterlogging On The Growth Of Kale (Brassica Oleracea Var. Acephala), Skyler R. Brazel

Theses and Dissertations

The Intergovernmental Panel on Climate Change has predicted that there will be increases in precipitation and heat-induced drought events globally. Information on kale response to waterlogging is minimal. The purpose of this project was to identify the response of kale to three treatments of water stress: underwatering, overwatering, and waterlogging. Plant pigments analyzed displayed a varied response to underwatering and overwatering, with concentrations changing with maturity but with reductions and no changes, respectively, at full harvest maturity. Glucosinolate concentrations were also influenced by maturity and increased under waterlogging and underwatering but no differences with overwatering. Overall, water stress to any …

Surface Modification Of Wood Using Nano-Sized Titania Particles Coated By Liquid-Precursor Flame Spray Pyrolysis, Ganesh Sedhain

Theses and Dissertations

Wood is a renewable resource and versatile material used in tasks ranging from tools and furniture to advanced engineering structures. Although wood is light, mechanically robust, environmentally friendly, and abundant, some inherent properties of wood, such as degradation due to moisture and UV radiation from sunlight, are less desirable for extended service life and dimensional stability. In this dissertation, a novel surface modification of wood is explored by depositing nano-sized titania particles on wood veneers and cross-laminated timber (CLT) blocks by liquid-precursor flame spray pyrolysis to confer reversible wettability switching and enhanced durability to UV irradiation. The reaction between a …

Pairing And Rotation-Induced Nuclear Exotica In Covariant Density Functional Theory, Saja Teeti

Theses and Dissertations

Covariant density functional theory (CDFT) is one of the modern theoretical tools for describing the nuclear structure physics of finite nuclei. Its performance is defined by underlying covariant energy density functionals (CEDFs). In this dissertation and within the framework of the CDFT, different physical properties of the ground and the excited states of rotating and non-rotating nuclei have been investigated.

A systematic global investigation of pairing properties based on all available experimental data on pairing indicators has been performed for the first time in the framework of covariant density functional theory. It is based on separable pairing interaction of Ref.\ …

The Effect Of Four Decades Of Deregulation On Competition And Productivity Of The U.S. Freight Transportation Industry, Seungjae Shin

Theses and Dissertations

This study reviews the competition and productivity of the U.S. freight transportation industry for the past 41 years. This study investigated the trends of HHI market concentration index values and labor productivity values of rail and truck sectors and tried to find any relationships between the two values in the separate periods before and after the abolishment of the ICC. This study also investigated how the existence of a regulatory body impacted productivity of the freight transportation industry by using a Cobb Douglas production function on annual financial statement data in the U.S. stock exchange market. This study found that: …

Spatial Conservation Planning In The Southeastern United States: Alignments And Opportunities, Bradly Stewart Thornton

Theses and Dissertations

Conservation managers and planners need the ‘best available science’ to support robust and defensible decisions, ensuring that public resources are appropriately allocated. Spatial planning products and decision-support tools developed for this purpose should enable partner organizations to achieve focus, coordination, and increased effectiveness in their investments and actions. Whereas conservation partnerships have historically created distinct planning tools, there is increasing interest for improved coordination, communication, and unifying biological datasets to improve the cohesiveness of regional management activities. We sought to inform spatial conservation planning efforts in the southeastern United States through the development of species distribution models for focal avian …

Advancements In Geospatial Monitoring Of Structures, Jordan Keith Baldwin

Theses and Dissertations

The need for advancements in geospatial monitoring of structures has evolved naturally as structures have become larger, more complex, and technology has continued to rapidly develop. Greater building heights generally lead to greater challenges for surveyors, limiting the practical use of traditional measurement methods. For this reason, a new complimentary method was developed and implemented to support elevation monitoring activities during construction of the Salesforce Tower in San Francisco, California. While some studies have explored the use of strain gauges to monitor strain development within individual members, the primary contribution of this work is that it presents a practical and …

Compromised Health: Examining Growth And Health In A Late Antique Roman Infant And Child Cemetery, Sierra Malis

Theses and Dissertations

This research examines the relationship between growth, growth disruption, and skeletal indicators stress amongst juveniles (n=60) interred at the Late Antique infant and child cemetery at Poggio Gramignano (PG) (ca. 5th century CE), associated with a rural agricultural community. Growth disruption – evidenced by decreased long bone length compared to dental age – and stress experience – evidenced by skeletal stress indicators – were compared to those within juveniles from two urban Roman-era cemeteries (n=66), Villa Rustica (VR) (0-400 CE) and Tragurium City Necropolis (TCN) (400-700 CE). Results indicate that the PG juveniles had significantly smaller femoral lengths-for-age than VR …

​​Evaluating The Utility Of Trial-Based Functional Analyses Of Inappropriate Mealtime Behavior: A Comparison Of Identified Functions Across Functional Analysis Methods, Meredith Huff Staggers

Theses and Dissertations

A critical first step in addressing problem behavior is to identify the function of the problem, or reason for engaging in the problem behavior, using systematic assessment procedures known as a functional analysis (FA). The literature consistently demonstrates the effectiveness of FAs, and variations of FAs (e.g., trial-based functional analysis [TBFA]) for assessing a variety of topographies of problem behaviors across populations, age groups, and settings; however, the use of TBFAs for assessing the function of inappropriate mealtime behavior (IMB) has been documented in the literature only once. The purpose of the current study was to contribute to the research …

The Mississippi Timber Severance Tax: Its Economic Impacts To Forestry And The State Economy, Sakar Nepal

Theses and Dissertations

Millions of dollars are collected through Mississippi’s timber severance tax every year which then funds the Forest Resource Development Program (FRDP). This study analyzed their contributions to Mississippi’s economy and found that the total possible contribution was estimated to be $6.0 million in industrial output and 222 full-time and part-time jobs in 2019. However, only about 70 percent of the FRDP funds were expended in that year, and the actual contribution was short by $1.80 million in output and 80 full-time and part-time jobs. This study also examined the impact of the severance tax and FRDP on forest investment, using …

An Analysis Of Text-Based Machine Learning Models For Vulnerability Detection, Kollin Ryne Napier

Theses and Dissertations

With an increase in complexity of software, developers rely more on reuse and dependencies in their source code via code snippets. As a result, it is becoming harder to identify and mitigate vulnerabilities. Although traditional analysis tools are still utilized, machine learning models are being adopted to expand efforts and combat such threats. Given the possibilities towards usage of such models, research in this area has introduced various approaches which vary in usability and prediction. In generalizing models to a more natural language approach, researchers have opted to train models on source code to identify existing and potential vulnerabilities. Exploratory …

Predicting How Science Self-Efficacy And Identity Contributes To Postsecondary Stem Degree Selection, Bo Jason Hayes

Theses and Dissertations

One of the earliest indications that a student may be interested in STEM paths is the students’ own self-efficacy for science as well as how they may see themselves in a STEM career as part of their science self-identity (Schlegel et al., 2019). Currently, there is a need to contribute to research that can assist agencies such as the National Science Foundation (NSF), Department of Education and the National Academy of Sciences in advising the nation, including high schools and postsecondary institutions on ways to increase the enrollment of students in STEM-related careers. This study examined the extent to which …

Eddy Current Defect Response Analysis Using Sum Of Gaussian Methods, James William Earnest

Theses and Dissertations

This dissertation is a study of methods to automatedly detect and produce approximations of eddy current differential coil defect signatures in terms of a summed collection of Gaussian functions (SoG). Datasets consisting of varying material, defect size, inspection frequency, and coil diameter were investigated. Dimensionally reduced representations of the defect responses were obtained utilizing common existing reduction methods and novel enhancements to them utilizing SoG Representations. Efficacy of the SoG enhanced representations were studied utilizing common Machine Learning (ML) interpretable classifier designs with the SoG representations indicating significant improvement of common analysis metrics.

Developing Systems Engineering And Machine Learning Frameworks For The Improvement Of Aviation Maintenance, Fatine Elakramine

Theses and Dissertations

This dissertation develops systems engineering and machine learning models for aviation maintenance support. With the constant increase in demand for air travel, aviation organizations compete to maintain airworthy aircraft to ensure the safety of passengers. Given the importance of aircraft safety, the aviation sector constantly needs technologies to enhance the maintenance experience, ensure system safety, and limit aircraft downtime. Based on the current literature, the aviation maintenance sector still relies on outdated technologies to maintain aircraft maintenance documentation, including paper-based technical orders. Aviation maintenance documentation contains a mixture of structured and unstructured technical text, mainly inputted by operators, making them …

Physics-Based Modeling Of Post-Wildfire Landslides In Unsaturated Hillslopes, Masood Abdollahi

Theses and Dissertations

Changes in climatic regimes and land use have led to increases in wildfire activities around the world. Wildfires are now happening more frequently, at higher altitudes, and higher severities. Adverse impacts of wildfires can last years after the fire has been contained through post-fire geohazards, such as shallow landslides. Post-wildfire shallow landslides are often mobilized by rainfall and due to fire-induced changes in soil and land cover properties and near-surface processes. This study aims to develop a physics-based framework to evaluate the stability of burned hillslopes against rainfall-triggered shallow landslides. A coupled hydromechanical infiltration model is developed by employing a …

Host-Acquired Virus Genes Support An Ancient Antiviral Role Of The Pirna Pathway In Dipterans, Rebecca Christian

Theses and Dissertations

Endogenous viral elements (EVEs) have been recently investigated as a source of transgenerational immune memory. These “viral fossils” are abundant in Aedes mosquitoes and partner with the host’s primary antiviral defense system, the RNA interference (RNAi) pathways. This partnership appears unique to mosquitoes, which encode an expansion of the Piwi endoribonucleases. To interrogate EVE-Piwi partnerships and their role in antiviral defense, I performed a comparative small RNA analysis of two naturally occurring EVE-virus pairs – one in the mosquito Aedes albopictus, and one in the midge Chaoborus americanus. Both express an EVE related to the nucleoprotein of their …

Oxidation Resistance Of An Atomically Flat Cu(111) Surface: A First-Principles Study, Bipin Lamichhane

Theses and Dissertations

The first-principles calculation based on density functional theory (DFT) was used to study the oxidation resistance of atomically flat and atomic-step edges of Cu(111), diffusion of Cu atoms in different surfaces of alumina and interface properties of alumina and Cu(111), and magnetic properties of Mn-substituted strontium hexaferrite. The dissociation of oxygen molecules is the primary reason for the corrosion of metals, which deteriorates their application. Cu(111) flat surface, mono-atomic, and multi-atomic step edges were used to study oxygen diffusion. Penetration of oxygen on a Cu(111) flat surface requires high energy, indicating oxidation resistance. Our DFT result of oxygen diffusion into …

Relaxing Dc Capacitor Voltage Of Power Electronic Converters To Enhance Their Stability Margins, Ali Zakerian

Theses and Dissertations

Recently, due to the increasing adoption of distributed energy resource (DER) technologies including battery energy storage (BES) and electric vehicle (EV) systems, bidirectional power converters are becoming more popular. These converters are broadly utilized as interface devices and provide a bidirectional power flow in applications where the primary power supply can both supply and receive energy. A dc capacitor, called the dc-link, is an important component of such bidirectional converters. For a wide range of applications, the converter is required to control the dc-link voltage. Commonly, a proportional-integrating (PI) controller is used by the dc capacitor voltage controller to generate …

Populism And Civil Society: The Challenge To Constitutional Democracy. Andrew Arato And Jean L. Cohen, Oxford, Oxford University Press, 2022, Xi+305pp., Stefan Rummens

Emancipations: A Journal of Critical Social Analysis

No abstract provided.

Mutual Aid: The Other Law Of The Jungle. Gauthier Chapelle And Pablo Servigne. Cambridge, Polity Press. 2022. 310 Pp, Tom P. Flower Dr

Emancipations: A Journal of Critical Social Analysis

In 1902, the anarchist Peter Kropotkin published Mutual Aid in which he promoted a radical perspective on evolution in which cooperation, as well as selfishness, drive the form, diversification and organization of life on earth. Despite initial recognition, Kropotkin’s contributions have been largely forgotten, even as modern evolutionary theory has recognized the central role of cooperation. In Mutual Aid: the other law of the jungle, Pablo Servigne and Gauthier Chappelle restore Kropotkin’s insights to their rightful place as foundational for our understanding of evolution. They further seek to overturn the pernicious misconception of the 20^th century, that nature is …

The End Of Sovereignty. Antonio Negri, Translated By Ed Emery. Cambridge, Polity Press, 2022. 220 Pp, Jodi Dean

Emancipations: A Journal of Critical Social Analysis

No abstract provided.

A New Dawn For Politics. Alain Badiou. Cambridge, Polity Press, 2022. 145 Pp, James Chamberlain

Emancipations: A Journal of Critical Social Analysis

No abstract provided.

Anxiety In The Capitalism Of Late Modernity, Toyo Kawabata

Emancipations: A Journal of Critical Social Analysis

The logic of capitalism affects both individuals and society. Alienation augments existential anxiety in the current precarity capitalism, which keeps urging competition among individuals to survive in capitalism and grow more. Excessive individualism, materialism, and consumerism in capitalism may weaken social ties and lower self-recognition, augmenting the existential anxiety of individuals. Losers in capitalism aggravate their anxiety whereas even winners may keep being anxious in the never-ending competition in capitalism. As long as people are kept engaged in capitalism, the pressure of the competition leads to a vicious cycle that keeps inducing anxiety, which signifies the precarity of capitalism. Existential …

Asking For It: Gendered Dimensions Of Surveillance Capitalism, Jessica Rizzo

Emancipations: A Journal of Critical Social Analysis

Advertising and privacy were once seen as mutually antagonistic. In the 1950s and 1960s, Americans went to court to fight for their right to be free from the invasion of privacy presented by unwanted advertising, but a strange realignment took place in the 1970s. Radical feminists were among those who were extremely concerned about the collection and computerization of personal data—they worried about private enterprise getting a hold of that data and using it to target women—but liberal feminists went in a different direction, making friends with advertising because they saw it as strategically valuable.

Liberal feminists argued that in …

Social Pathologies As Educational Injustices, Esther Neuhann

Emancipations: A Journal of Critical Social Analysis

For Axel Honneth, not all social problems can be understood as injustices. Therefore, he introduces the additional diagnostic concept of social pathology. In his book Freedom’s Right (FR), it is defined as an accumulation of persons’ inability to adequately participate in social institutions due to misunderstanding them. In contrast, injustices consist in the denial of access to social institutions for certain groups. According to the aim of presenting an ‘extended’ theory of justice in FR, Honneth intends to reconstruct all institutions necessary for realizing individual freedom in a liberal-democratic society. Like in the historical model of his project (Hegel’s Elements …

Dismodernizing The Working Class And Social Reproduction, After The Pandemic Lumpenproletariat: Towards An Autonomist Disability Perspective, Arianna Introna Dr

Emancipations: A Journal of Critical Social Analysis

Capitalism establishes a fundamental connection between the constitution of society and the sphere of production. Whether in the form of direct participation or indirectly through the performance of social reproduction, the working class is expected to be working. The universals of capitalist society as a work-based society revolve around the material and symbolic centrality of the working class, its struggle and its social reproduction. This association is reinforced by the othering effect that the definitional politics of the universal working class has on subjects defined by their non-relation to the sphere of production, but also by the categories we …