Susceptibility Of Spodoptera Frugiperda And Helicoverpa Zea Populations In The Southern Region Of The United States To Common Chemical Insecticides, Bhavana Patla

LSU Master's Theses

Abstract

The fall armyworm, Spodoptera frugiperda and corn earworm/bollworm, Helicoverpa zea, are two polyphagous pests prevalent in the U.S. In recent years, there were increased infestations of the two pests in the U.S., especially in its southern region. Information on the susceptibility/resistance status of the two pests in the region to chemical insecticides, especially to some new chemistries, is very limited or has not been updated for many years. In this study, susceptibility of 17 S. frugiperda and six H. zea field collected populations from the southern U.S. during 2021-23 to common insecticides was investigated in the laboratory. Dose-responses with …

Diving Deeper Into Supercuspidal Representations, Prerna Agarwal

LSU Doctoral Dissertations

In 2013, Reeder and Yu introduced certain low positive depth supercuspidal representations of $p$-adic groups called \textit{epipelagic} representations. These representations generalize the simple supercuspidal representations of Gross and Reeder, which have the lowest possible depth. Epipelagic representations also arise in recent work on the Langlands correspondence; for example, simple supercuspidals appear in the automorphic data corresponding to the Kloosterman $l$-adic sheaf. In this thesis, we take a first step towards the construction of ``\textit{mesopelagic} representation (of Iwahori type)'' which are the higher depth analogues of simple supercuspidal representations. We see that these constructions can be done in a similar way …

An Analysis Of The Development Of Cognitive Control In Young Children Within An Auditory And Visual Modality., Lauren A. Schiro

LSU Master's Theses

The Dual Mechanisms of Cognitive Control Framework (DMC) posits that cognitive control is directed through two different modes: proactive and reactive control. Proactive control involves the maintenance and manipulation of information in preparation of a response while reactive control would involve little to no preparation until after a response prompt. The AX-Continuous Performance Task (AX-CPT) is a cognitive control task that is often utilized in studies looking at proactive and reactive control as it measures context processing and goal maintenance. The aims of this study were to validate the auditory version of the AX-CPT and to then apply this task …

The Behavioral Specialization Of African Ant-Following Birds On Dorylus Driver Ants, Patricia F. Rodrigues

LSU Doctoral Dissertations

Ant-following birds, that forage on arthropods flushed by swarm raiding army ants, are an iconic phenomenon in tropical forests around the globe. Despite capturing the attention of naturalists for over a century, research on ant-following birds has largely focused on Neotropical species. Decades of research on Neotropical ant-following birds has revealed fascinating aspects of their specialization, including complex cognitive and behavioral adaptations that allow birds to locate and track nomadic army ants. Despite this breadth of research on Neotropical species, virtually nothing is known of the behavioral ecology of African ant-following birds, and it remains unknown whether they exhibit adaptations …

Reality Capture Technologies For Continuous Inline Quality Monitoring In Construction 3d Printing, Michael J. Martin Ii

LSU Master's Theses

Extrusion-based construction 3D printing (C3DP) is an innovative and emerging technology aiming at the modernization of the construction industry. It uses robots and computer control to reduce the need for human labor and to decrease construction time and cost. C3DP creates elements layer by layer without using formworks, and it is critical to detect layer defects and deformations to ensure that each layer is printed with the desired dimensions. These defects can lead to a variety of issues during or after the construction process, including the collapse of freshly printed elements. In order to detect such deformations and to enable …

An Exploration Of The Drivers Of Intraspecific Variation In Arthropod Phenotypes, Jamie Phelps

LSU Doctoral Dissertations

Herein we explore the various forces that drive phenotypic variation in arthropods focusing on spatial and temporal differences as well as sexual dimorphism. We use both marine, Tigriopus californicus, and terrestrial, Melitaeini, organisms to investigate these forces.

Tigriopus californicus and Heat Hardening: The study explores how Tigriopus californicus, a copepod, adapts to thermal variation along the North American Pacific Coast. Researchers investigated intraspecific variation in heat hardening, measuring differences in upper lethal limits (ULLs) and potential fecundity costs across five populations. We found a cost of heat hardening: the size of the first brood produced after heat shock …

Computational Design Of An Electro-Organocatalyst For Conversion Of Co2 Into Long Chain Aldehydes, Foroogh Khezeli, Craig Plaisance

Faculty Publications

Density functional theory calculations employing a hybrid implicit/explicit solvation method were used to demonstrate that an electro-organocatalyst designed in our previous work for reducing CO2 to formaldehyde could also be capable of coupling formaldehyde to form long chain aldehydes. The catalytic activity is enabled by an electron-rich vicinal enediamine (>N-C═C-N<) backbone that activates formaldehyde by reversing the polarity on the carbon atom, enabling it to act as a nucleophile in the subsequent aldol addition step. The catalyst then enables reductive dehydroxylation of the aldol addition product by facilitating outer-sphere electron transfer. The optimal pH as well as the limiting potential and formaldehyde concentration are identified and related to the kinetic balance between several rate limiting steps. Finally, the optimal conditions for coupling with the CO2 reduction cycle are discussed, demonstrating that the electro-organocatalyst is capable of efficiently converting CO2 into aldehyde products with a turnover frequency (per carbon atom) on the order of 0.1-1 s-1

Harmony In Collaboration: Curating Sustainability In Post-Pandemic Arts, Natalie M. Stepaniak

LSU Doctoral Dissertations

In an interconnected world, collaboration in the arts is rising, challenging the traditional notion of the solitary artist. Interdisciplinary collaboration is crucial for advancing performing and visual arts, especially amidst declining audience attendance. Despite the COVID-19 pandemic exacerbating challenges for the arts sector, recent data suggests a gradual recovery, with collaborative efforts fostering resilience.

This dissertation investigates the transformative potential of interdisciplinary collaboration from the perspective of musicians and their organizations. Through three case studies—collaborations between the Rapides Symphony Orchestra and Play On Theater Company, The Next Festival for Emerging Artists, and violist-composer Leilehua Lanzilotti and her collaborative relationship with …

Revisiting The Preparation And Catalytic Performance Of A Phosphine-Modified Co(Ii) Hydroformylation Precatalyst, David R. Holzknecht, Alexandra K. Van Alstine, Brandon P. Russell, David J. Vinyard, Fabrizio Donnarumma, Matthew B. Chambers

Faculty Publications

In light of recent conflicting reports regarding the hydroformylation catalytic activity derived from cationic Co(II) precatalysts of the form [Co(acac)(bis(phosphine))]BF4, the synthetic procedures and characterization of [Co(acac)(dppBz)]BF4, 1, are evaluated. Leveraging calibrated ESI-TOF MS methodologies, substantial quantities of Co(acac)2(dppBz), 2, were observed within samples of 1. The source of the impurity, 2, is determined to derive from incomplete protonolysis of the Co(acac)2 precursor and ligand scrambling occurring during the synthesis of 1. Revised synthetic procedures using lower temperature conditions and longer reaction times afford analytically pure samples of 1 based on ESI-TOF MS and NMR spectroscopic analysis. Complex 1 is …

Unveiling Competitive Adsorption In Tio2 Photocatalysis Through Machine-Learning-Accelerated Molecular Dynamics, Dft, And Experimental Methods, Omar Allam, Mostafa Maghsoodi, Seung Soon Jang, Samuel D. Snow

Faculty Publications

The efficient harnessing of solar power for water treatment via photocatalytic processes has long been constrained by the challenge of understanding and optimizing the interactions at the photocatalyst surface, particularly in the presence of nontarget cosolutes. The adsorption of these cosolutes, such as natural organic matter, onto photocatalysts can inhibit the degradation of pollutants, drastically decreasing the photocatalytic efficiency. In the present work, computational methods are employed to predict the inhibitory action of a suite of small organic molecules during TiO2 photocatalytic degradation of para-chlorobenzoic acid (pCBA). Specifically, tryptophan, coniferyl alcohol, succinic acid, gallic acid, and trimesic acid were selected …

Limit Theorems For Increments Of Branching Particle Systems With Linear Rates And Poisson Initial Condition, Alexander Kreinin, Vladimir V. Vinogradov

Journal of Stochastic Analysis

No abstract provided.

Asymptotic Formula For Scattering Problems Related To Thin Metasurfaces, Zachary Jermain

LSU Doctoral Dissertations

The goal of this work is to develop an asymptotic formula for the behavior of a scattered electromagnetic field in the presence of a thin metamaterial known as a metasurface. By using a carefully chosen Green’s function and the single and double layer potentials we analyze the perturbed scattering problem in the presence of the metamaterial and a background scattering problem. By using Lippman-Schwinger type representation formulas for the two fields we develop the asymptotic formula for the perturbed field. From here we prove the asymptotic formula holds up to a specific error term based on the size of the …

A Confirmatory Factor Analysis Of The Psi-4-Sf In Parents Of Children With Autism Spectrum Disorder, Paige Weir

LSU Doctoral Dissertations

The factor structure of the Parenting Stress Index - Short Form (PSI-4-SF) was evaluated among parents of children with autism spectrum disorder (ASD). Two hypotheses were tested: (1) the original PSI-4-SF model would yield an unsatisfactory fit, and (2) a three-factor alternative model would improve fit compared to the original and other models. A sample of 205 parent-child dyads was analyzed using confirmatory factor analysis (CFA) with the lavaan package in R Studio. Preliminary analyses included descriptive statistics, normality checks, and assessments of skewness and kurtosis. Results supported the first hypothesis, showing poor fit indices for the original PSI-4-SF model. …

Examining Social Anxiety, Generalized Anxiety, And Major Depression’S Symptom Comorbidity In Children And Adolescents: A Longintudinal Test Of The Multiple Pathway Model, Paige Picou

LSU Doctoral Dissertations

Anxiety and depressive disorders are highly prevalent in and impairing for children and adolescents and are highly comorbid. Many theories have been proposed to explain this co- occurrence, with recent models postulating multiple pathways in which specific anxiety disorders and depression may co-occur both concurrently and over time. Unfortunately, little research has evaluated these pathways longitudinally across development in a community sample. The current study tested the multiple pathway model in a sample of 9 to 12-year-old youth (Mage = 9.48, SD= 0.51) at baseline and at two-year follow-up using a subsample of the Adolescent Brain Cognitive Development …

Mental Practice: Practical Application In Violin And Viola Private Lessons, Natasha Sieczkowska

LSU Doctoral Dissertations

This dissertation aimed to better understand how violin and viola private instructors teach Mental Practice in their studios, investigating different approaches on how to apply and teach auditory, motor, and visual imagery, score study, and auditory modeling, as well as its benefits. This research was divided into two different stages. In the first stage, the researcher conducted interviews (n = 19) and collected questionnaire responses (n = 14) from 33 upper-string instructors teaching at the pre-college and collegiate levels in the US. This research stage was based on the grounded theory approach since there was not much research …

Advances In Stereoselective Glycosylation: Electron-Withdrawing Groups, Benzyne-Mediated Stereoinversion, And Visible-Light Photochemistry For 1,2-Cis O-Glycosylation, Erik Giovanni Alvarez Valenzuela

LSU Doctoral Dissertations

The symbiotic relationship between humans and their microbiota is essential for health, with imbalances in the complex microbiota ecosystem linked to a variety of disorders ranging from neurodegenerative to gastrointestinal diseases. Bacteria within the human microbiota, comprising over 1000 known species, are densely and diversely coated with oligosaccharides crucial for functions like cell recognition, communication, signaling, adhesion, proliferation, and pathogenic inhibition. However, studying the structure-activity relationships of these sugars which are also secreted by bacteria is challenging due to difficulties in obtaining homogenous samples from natural sources.

Chemical synthesis offers a solution by enabling the production of well-defined oligosaccharides in …

The Hydrological Impacts Of Woody Plant Encroachment On Coastal Tallgrass Prairie Of Texas, Zhiwei Guo

LSU Master's Theses

Globally, woody plant encroachment into grassland and savanna ecosystems impacts the hydrological functions of grasslands and associated wetlands. In the coastal tallgrass prairie of Texas, encroachment of woody plants has altered vegetation structure, but the hydrological impacts are poorly understood. In this study, I evaluated and quantified how woody plant encroachment affects hydrological processes on the pimple mounds and inter-mound freshwater marsh, including precipitation partitioning, infiltration in the vadose zone, groundwater recharge, and water volume in the inter-mound marsh. I randomly selected three pimple mounds with woody plants and three pimple mounds with tallgrass w to quantify hydrologic processes. The …

Role Of Acute Alcohol Exposure In Klebsiella Pneumoniae-Induced Pneumonia, Prantho Malakar Dipta

LSU Master's Theses

Klebsiella pneumoniae (KP), a Gram-negative bacterium, induces severe pneumonia associated with devastating pathological consequences in the lung, such as substantial parenchymal damage. K. pneumoniae is responsible for causing life-threatening lung infections in patients with alcoholics and diabetics. The need to look for new therapeutic approaches is due to the emergence of Klebsiella pneumoniae strains that are resistant to many drugs. The effects of acute alcohol consumption on the host’s innate immune response to KP during infection remain unclear. Age-matched C57BL/6 female mice were administered 6g/kg of 32% alcohol or same amount of PBS via oral gavage 30 minutes prior to …

Quiet No More: An Analysis Of Women's Protest Music, Jillian Vogel

LSU Doctoral Dissertations

This dissertation explores the multifaceted role of music in women’s protests, emphasizing how it serves as a unifying and rallying tool in the fight against inequality. By delving into the interdisciplinary realms of music theory, sound studies, and women’s and gender studies, this work highlights how women’s protest composers utilize musical texts and content to turn their music into a tool to inspire change. This dissertation investigates the musical structures and harmonic innovations in suffrage movement music, examining how suffragettes with varying musical knowledge engaged with music to further their cause. The suffragette music analyses combine text analysis, harmonic analysis, …

Topics In Photonic Quantum Technology: Polarization Entanglement Dynamics In Optical Fibers And Low-Light Imaging., Pratik J. Barge

LSU Doctoral Dissertations

Recent advances in quantum photonics promise transformative impacts on computing, communication, sensing, and imaging. This thesis explores two areas in photonic quantum technology: polarization entanglement dynamics in optical fibers and low-light imaging. Optical fibers are the most suitable medium for photonic qubits and long-distance entanglement distribution is a critical requirement to realize quantum technologies. We study the decay of polarization-entanglement of the Bell state photons propagating through imperfect optical fibers with spatially fluctuating refractive index. Furthermore, to extend the distribution distance, we propose the use of dynamical decoupling in the optical fiber using half waveplates and show that significant improvement …

Riesz Particle Markov Chain Monte Carlo Methods, Xiongming Dai

LSU Doctoral Dissertations

Markov chain Monte Carlo (MCMC) methods are simulations that explore complex statistical distributions, while bypassing the cumbersome requirement of a specific analytical expression for the target. This stochastic exploration of an uncertain parameter space comes at the expense of a large number of ``burn-in'' samples, and the computational complexity leads to the curse of dimensionality. Although at the exploration level, some methods have been proposed to accelerate the convergence of the algorithm, such as tempering, Hamiltonian Monte Carlo, Rao-redwellization, and scalable methods for better performance, they cannot avoid the stochastic nature of this exploration. We develop algorithms for the energy …

Effects Of Perceived Supervisor And Peer Support On Training Transfer For Frontline Registered Nurses, Carly Penn

LSU Doctoral Dissertations

The purpose of this study was to examine the effect of perceived supervisor support as well as perceived peer support on training transfer behavior outcomes for frontline nursing staff in post-COVID 19 technology-mediated training environments.

This study was guided by the following primary research question: what effect does training delivery, perceived supervisor support, and perceived peer support have on training transfer behavior? The secondary question to further examination of these variables is: How do these factors interact to enhance or inhibit transfer in the context of nurse training?

This study sampled U.S. based registered nurses trained in COVID-19 related protocols. …

Investigation Of Solvation Structures And Dynamics Of Li-Ion Battery Electrolytes And Amides In Water: An Infrared Spectroscopy, Electrochemical And Computational Study, Ernest O. Nachaki

LSU Doctoral Dissertations

The investigation of solvation structures and dynamics in lithium-ion battery electrolytes and amides in water has significant implications for both fundamental science and practical applications. Understanding the solvation dynamics of lithium electrolytes can lead to the development of safer and more efficient LIBs. The study of hydrogen bond dynamics of N-alkyl substituted amides has important implications for the development of thermos-responsive polymers used in biomedical applications. By understanding how N-alkyl substitutions affect the hydration structure and dynamics of amides, this research can inform the design of polymers with tailored properties for drug delivery, tissue engineering, and other medical applications. This …

Entanglement From Rotating Black Holes In Thermal Baths, Ivan Agullo, Anthony J. Brady, Adrià Delhom, Dimitrios Kranas

Faculty Publications

We extend previous efforts to quantify the entanglement generated in Hawking's evaporation process by including rotation and thermal environments (e.g. the cosmic microwave background). Both extensions are needed to describe real black holes in our Universe. Leveraging techniques from Gaussian quantum information, we find that the black hole's ergoregion is an active source of quantum entanglement and that thermal environments drastically degrade entanglement generation. Our predictions are suitable to be tested in the lab using analog platforms and also provide tools to assess the fate of quantum information for black holes in more generic settings.

The Moderating Effect Of Leadership Style On The Relationship Between Perceptions Of Organizational Justice And The Performance Appraisal Satisfaction Of Sport Employees, Jeffrey S. White

LSU Doctoral Dissertations

This dissertation is an examination of how leadership style influences the relationship between sport employee perceptions of organizational justice and their satisfaction with performance appraisals. Sport employees are integral to the sport ecosystem, contributing to the physical, mental, and professional development of athletes, the operational success.

Focusing on these crucial constructs, the purpose of this study is to examine the moderating effect of leadership style on the relationship between organizational justice and performance appraisal satisfaction among sport employees. This quantitative empirical research utilizes PLS-SEM and multiple regression analysis with an aim to confirm the relationship between organizational justice and PAS …

Elementary Science Teachers' Experiences: A Case Study On The Use Of Science+Cyber Curriculum, Laurie Salvail

LSU Doctoral Dissertations

The field of science education in the United States has undergone a major reform since 2015. A little more than twelve years ago, work began on constructing a framework for elementary, middle, and high school science education. This framework emphasized the shift from science being merely a memorization of facts to experiences that include science and engineering practices applied through crosscutting concepts and focused on core ideas in the field of science. With new standards teachers also have to overcome a) not having adequate time available to devote to science instruction b) lack of updated instructional materials aligned to the …

Digital Agriculture Applications In Maize Nutrient Management And Soybean Crop Stands Assessment, Bhawana Acharya

LSU Master's Theses

High soil moisture from frequent excessive precipitation can reduce maize (Zea mays L.) yield and increase nitrogen (N) loss. Early-stage soybeans (Glycine max) are also susceptible to damage under these conditions. Traditional methods for assessing N status in maize and plant stands in soybean are labor-intensive and time-consuming. In this study, UAV remote sensing was used to assess maize N status under different N rates and excessive soil moisture. For soybeans, we compared a blob detection method with the YOLOv8 model to estimate plant density using ground images from a handheld camera. Additionally, YOLOv8 performance was evaluated …

Application Of Automated Radio Telemetry To Explore Space Use Of Golden-Cheeked Warblers (Setophaga Chrysoparia), Michael Gamble

LSU Master's Theses

Understanding the spatiotemporal ecology of birds is essential to inform conservation and management decisions that could help maintain bird populations and reverse current population trends. Advancements in automated radio telemetry systems (ARTS) may improve our ability to monitor animal movements continuously and simultaneously but require further testing and development to maximize their benefits for wildlife research. My goals were (1) to investigate the use of automated telemetry to track fine-scale songbird movements in a forested environment, and (2) to use automated telemetry to quantify home range size, spatial overlap between home ranges, and extraterritorial forays for male and female golden-cheeked …

Evaluation Of Dotd’S Aggregate Sources Friction Using Laboratory And Accelerated Testing, Sudhir Bharati

LSU Master's Theses

Roadway safety is of utmost importance to the state transportation agencies. One of the major factors of roadway safety that agencies have control over is pavement friction which is affected by aggregate and mixture type. The Louisiana Department of Transportation and Development (DOTD) currently uses Polished Stone Values (PSV) obtained from the British Pendulum Device to rate its aggregates. These ratings determine the applicability of aggregates for various projects. However, the ratings are inconsistent, posing significant safety and financial risks. The first part of the thesis compares the currently adopted British Wheel Polisher-based Standard Practice for the Accelerated Polishing of …

Impacts Of Morphological Changes On Water Residence Times In River Deltas, Md. Muzahidul Islam

LSU Master's Theses

Coastal river deltas possess substantial socioeconomic and ecological importance and are expected to encounter increasing risks because of global climate change. The long-term sustainability of many deltaic systems is at risk due to a mix of natural and human-induced factors. Deltas are characterized by their continuous reconfiguration of channels and floodplains due to allogenic and autogenic processes. Sediment supply and composition, sea level rise, vegetation, river discharge, and human development may affect the morphological evolution of river deltas. The timescales and patterns of hydrological transport within a river delta are important indicators of ecological function. One such metric, the water …