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Influence Of Food Security Status And Diet Quality On Maternal Gestational Weight Gain, Joshua R. Sparks, Candice A. Myers, Suzanne Phelan, Robert L. Newton, Shengping Yang, Leanne M. Redman May 2024

Influence Of Food Security Status And Diet Quality On Maternal Gestational Weight Gain, Joshua R. Sparks, Candice A. Myers, Suzanne Phelan, Robert L. Newton, Shengping Yang, Leanne M. Redman

Clinical Research Faculty Publications

Background: Recommended gestational weight gain (GWG) is crucial for health of women and their offspring. Food security status is hypothesized to influence diet quality and GWG. Therefore, we examined the relationship between diet quality and GWG by food security status. Methods: Participants (n = 679) were enrolled in the Initial Vanguard Study of the National Children's Study. GWG was calculated as third trimester weight minus prepregnancy weight. Food security status and diet quality (Healthy Eating Index [HEI]-2015) were assessed using the Household Food Security Survey and a Diet History Questionnaire, respectively. General linear models evaluated the relationship between GWG and …


Associations Of Epigenetic Age Acceleration With Cvd Risks Across The Lifespan: The Bogalusa Heart Study, Xiao Sun, Wei Chen, Alexander C. Razavi, Mengyao Shi, Yang Pan, Changwei Li, Maria Argos, Brian T. Layden, Martha L. Daviglus, Jiang He, Owen T. Carmichael, Lydia A. Bazzano, Tanika N. Kelly May 2024

Associations Of Epigenetic Age Acceleration With Cvd Risks Across The Lifespan: The Bogalusa Heart Study, Xiao Sun, Wei Chen, Alexander C. Razavi, Mengyao Shi, Yang Pan, Changwei Li, Maria Argos, Brian T. Layden, Martha L. Daviglus, Jiang He, Owen T. Carmichael, Lydia A. Bazzano, Tanika N. Kelly

Clinical Research Faculty Publications

Although epigenetic age acceleration (EAA) might serve as a molecular signature of childhood cardiovascular disease (CVD) risk factors and further promote midlife subclinical CVD, few studies have comprehensively examined these life course associations. This study sought to test whether childhood CVD risk factors predict EAA in adulthood and whether EAA mediates the association between childhood CVD risks and midlife subclinical disease. Among 1,580 Bogalusa Heart Study participants, we estimated extrinsic EAA, intrinsic EAA, PhenoAge acceleration (PhenoAgeAccel), and GrimAge acceleration (GrimAgeAccel) during adulthood. We tested prospective associations of longitudinal childhood body mass index (BMI), blood pressure, lipids, and glucose with EAAs …


Multiband Analyses Of The Bright Grb 230812b And The Associated Sn2023pel, T. Hussenot-Desenonges, T. Wouters, N. Guessoum, I. Abdi, A. Abulwfa, C. Adami, J. F. Agüí Fernández, T. Ahumada, V. Aivazyan, D. Akl, S. Anand, C. M. Andrade, S. Antier, S. A. Ata, P. D'Avanzo, Y. A. Azzam, A. Baransky, S. Basa, M. Blazek, P. Bendjoya, S. Beradze, P. Boumis, M. Bremer, R. Brivio, V. Buat, M. Bulla, O. Burkhonov, E. Burns, S. B. Cenko, M. W. Coughlin, W. Corradi, F. Daigne, T. Dietrich May 2024

Multiband Analyses Of The Bright Grb 230812b And The Associated Sn2023pel, T. Hussenot-Desenonges, T. Wouters, N. Guessoum, I. Abdi, A. Abulwfa, C. Adami, J. F. Agüí Fernández, T. Ahumada, V. Aivazyan, D. Akl, S. Anand, C. M. Andrade, S. Antier, S. A. Ata, P. D'Avanzo, Y. A. Azzam, A. Baransky, S. Basa, M. Blazek, P. Bendjoya, S. Beradze, P. Boumis, M. Bremer, R. Brivio, V. Buat, M. Bulla, O. Burkhonov, E. Burns, S. B. Cenko, M. W. Coughlin, W. Corradi, F. Daigne, T. Dietrich

Faculty Publications

GRB 230812B is a bright and relatively nearby (z = 0.36) long gamma-ray burst (GRB) that has generated significant interest in the community and has thus been observed over the entire electromagnetic spectrum. We report over 80 observations in X-ray, ultraviolet, optical, infrared, and submillimetre bands from the GRANDMA (Global Rapid Advanced Network for Multimessenger Addicts) network of observatories and from observational partners. Adding complementary data from the literature, we then derive essential physical parameters associated with the ejecta and external properties (i.e. the geometry and environment) of the GRB and compare with other analyses of this event. We spectroscopically …


The Lsu-Argonne Conversion Electron Spectrometer: A New Detector For The X-Array And Saturn Decay Station, S. Lopez-Caceres, S. T. Marley, M. P. Carpenter, G. Savard, F. G. Kondev, P. Copp, W. Reviol, C. Müller-Gatermann, D. Seweryniak, J. A. Clark, D. Santiago-Gonzalez, G. E. Morgan, A. J. Mitchell, G. L. Wilson, M. L. Smith May 2024

The Lsu-Argonne Conversion Electron Spectrometer: A New Detector For The X-Array And Saturn Decay Station, S. Lopez-Caceres, S. T. Marley, M. P. Carpenter, G. Savard, F. G. Kondev, P. Copp, W. Reviol, C. Müller-Gatermann, D. Seweryniak, J. A. Clark, D. Santiago-Gonzalez, G. E. Morgan, A. J. Mitchell, G. L. Wilson, M. L. Smith

Faculty Publications

A new conversion electron detector has been commissioned at the ATLAS/ CARIBU facility at Argonne National Laboratory. The LSU-Argonne Conversion Electron Spectrometer (LACES) is a LN2-cooled Si(Li) detector system designed to be incorporated into a decay station that comprises the dedicated HPGe clover array with a box geometry (X-Array) and the Scintillator and Tape Using Radioactive Nuclei (SATURN) device. This integration enables simultaneous measurements of conversion electrons and gamma-rays in decay experiments, yielding novel information on transition multipolarities, electric monopole transitions, and isomeric states that decay mostly via conversion electrons. A measurement of the energy resolution of LACES yielded 2.3-keV …


The Roles Of Perceived Safety Climate And Innovativeness In The Performance Of Sport And Recreation Organizations, Minjung Kim, Han Soo Kim, Brent D. Oja, Jasamine Hill, Claire Zvosec, Paul Yuseung Doh May 2024

The Roles Of Perceived Safety Climate And Innovativeness In The Performance Of Sport And Recreation Organizations, Minjung Kim, Han Soo Kim, Brent D. Oja, Jasamine Hill, Claire Zvosec, Paul Yuseung Doh

Faculty Publications

The recent COVID-19 pandemic created an unpredictable environment regarding the safety operations of sport and recreation organizations. This study was designed to examine how safety climate and organizational innovativeness could promote preferred organizational behavior outcomes in college campus sport and recreation centers. A total of 227 sport and recreation employees were recruited through the National Intramural and Recreational Sports Association. With the collected data, we employed structural equation modeling to assess the research hypotheses. The results indicated that safety climate and innovativeness positively influenced job engagement, therefore leading to enhanced safety compliance and employee innovativeness, which ultimately resulted in higher …


Complementing Model Species With Model Clades, Makenzie E. Mabry, R. Shawn Abrahams, Ihsan A. Al-Shehbaz, William J. Baker, Simon Barak, Michael S. Barker, Russell L. Barrett, Aleksandra Beric, Samik Bhattacharya, Sarah B. Carey, Gavin C. Conant, John G. Conran, Maheshi Dassanayake, Patrick P. Edger, Jocelyn C. Hall, Yue Hao, Kasper P. Hendriks, Julian M. Hibberd, Graham J. King, Daniel J. Kliebenstein, Marcus A. Koch, Ilia J. Leitch, Frederic Lens, Martin A. Lysak, Alex C. Mcalvay, Michael T.W. Mckibben, Francesco Mercati, Richard C. Moore, Klaus Mummenhoff, Daniel J. Murphy, Lachezar A. Nikolov, Michael Pisias, Eric H. Roalson May 2024

Complementing Model Species With Model Clades, Makenzie E. Mabry, R. Shawn Abrahams, Ihsan A. Al-Shehbaz, William J. Baker, Simon Barak, Michael S. Barker, Russell L. Barrett, Aleksandra Beric, Samik Bhattacharya, Sarah B. Carey, Gavin C. Conant, John G. Conran, Maheshi Dassanayake, Patrick P. Edger, Jocelyn C. Hall, Yue Hao, Kasper P. Hendriks, Julian M. Hibberd, Graham J. King, Daniel J. Kliebenstein, Marcus A. Koch, Ilia J. Leitch, Frederic Lens, Martin A. Lysak, Alex C. Mcalvay, Michael T.W. Mckibben, Francesco Mercati, Richard C. Moore, Klaus Mummenhoff, Daniel J. Murphy, Lachezar A. Nikolov, Michael Pisias, Eric H. Roalson

Faculty Publications

Model species continue to underpin groundbreaking plant science research. At the same time, the phylogenetic resolution of the land plant tree of life continues to improve. The intersection of these 2 research paths creates a unique opportunity to further extend the usefulness of model species across larger taxonomic groups. Here we promote the utility of the Arabidopsis thaliana model species, especially the ability to connect its genetic and functional resources, to species across the entire Brassicales order. We focus on the utility of using genomics and phylogenomics to bridge the evolution and diversification of several traits across the Brassicales to …


Cellulose Nanofiber As Mask/Personal Protective Equipment Surface Agent For Enhanced Anti-Bacterial Performance, Sophia Jackson, Jonathan Chen May 2024

Cellulose Nanofiber As Mask/Personal Protective Equipment Surface Agent For Enhanced Anti-Bacterial Performance, Sophia Jackson, Jonathan Chen

Faculty Publications

The utilization of face-covering masks as an extended form of personal protective equipment has led to exponential waste measures during the COVID-19 pandemic, with estimations of up to 7200 tons of medical-type waste daily. A primary cause of this waste is surgical layered disposable masks that are constructed by melt-blown nonwovens usually made of non-biodegradable thermoplastic polymers like polypropylene. To increase widespread sustainable options to the public, commercialized or do-it-yourself-based fabric masks serve as a solution, but their resistance to harmful molecules is less than that of the medical-grade masks due to the fabric structure that leaves space for penetration. …


Cpeb3 Maintains Developmental Competence Of The Oocyte, Lucie Lamacova, Denisa Jansova, Zongliang Jiang, Michal Dvoran, Daria Aleshkina, Rajan Iyyappan, Anna Jindrova, Heng Yu Fan, Yuxuan Jiao, Andrej Susor May 2024

Cpeb3 Maintains Developmental Competence Of The Oocyte, Lucie Lamacova, Denisa Jansova, Zongliang Jiang, Michal Dvoran, Daria Aleshkina, Rajan Iyyappan, Anna Jindrova, Heng Yu Fan, Yuxuan Jiao, Andrej Susor

Faculty Publications

Mammalian oocyte development depends on the temporally controlled translation of maternal transcripts, particularly in the coordination of meiotic and early embryonic development when transcription has ceased. The translation of mRNA is regulated by various RNA-binding proteins. We show that the absence of cytoplasmic polyadenylation element-binding protein 3 (CPEB3) negatively affects female reproductive fitness. CPEB3-depleted oocytes undergo meiosis normally but experience early embryonic arrest due to a disrupted transcriptome, leading to aberrant protein expression and the subsequent failure of embryonic transcription initiation. We found that CPEB3 stabilizes a subset of mRNAs with a significantly longer 3’UTR that is enriched in its …


Aerial, Surface, And Subsurface Multimodal Mapping In Coastal Peru: Insights From Cerro San Isidro, Moro Region, Nepeña Valley, Kayla Golay Lausanne, David Chicoine, Jeisen Navarro Vega, George F. Lau May 2024

Aerial, Surface, And Subsurface Multimodal Mapping In Coastal Peru: Insights From Cerro San Isidro, Moro Region, Nepeña Valley, Kayla Golay Lausanne, David Chicoine, Jeisen Navarro Vega, George F. Lau

Faculty Publications

This article describes a series of steps to integrate multiple modes of archaeological mapping in arid and agricultural settings. We use the coastal region of Peru as a case study and share our recent field experience at Cerro San Isidro, a multicomponent hill site located in the agriculture-intensive and mid-elevation (about 500 m asl) Moro region of the Nepeña Valley. In June and July 2022, we spent eight weeks deploying a combination of drone aerial imagery, pedestrian GPS reconnaissance, and GPR survey to map the surface and subsurface features at the site and in the adjacent agricultural fields. Our efforts …


Enhanced Microstructural Stability And Hardness Of Multi-Component Nanocrystalline Nickel Alloys Processed Via Mechanical Alloying, Mari Therese S. Burton, B. Chad Hornbuckle, Vincent H. Hammond, Kristopher A. Darling, Helen M. Chan, Christopher J. Marvel, Martin P. Harmer May 2024

Enhanced Microstructural Stability And Hardness Of Multi-Component Nanocrystalline Nickel Alloys Processed Via Mechanical Alloying, Mari Therese S. Burton, B. Chad Hornbuckle, Vincent H. Hammond, Kristopher A. Darling, Helen M. Chan, Christopher J. Marvel, Martin P. Harmer

Faculty Publications

Nanocrystalline alloys are noteworthy for their high strength, and nanocrystalline Ni is being investigated for high-temperature applications. However, nanocrystalline alloys are unstable against coarsening, thereby prone to degradation of strength. In this work, two nanocrystalline alloys, Ni–(0, 11 at pct W)–3 at pct Ta–2 at pct Y, were designed to exhibit microstructural stability and high strength by forming nanoscale precipitates, maintaining stable nanoscale grains to exploit Hall–Petch hardening, and decreasing the stacking fault energy of the Ni-based matrix. Produced via high-energy cryogenic mechanical alloying, both alloys exhibited thermal stability and enhanced mechanical properties due to beneficial impurity yttrium oxide/nitride particles …


Laser-Induced Breakdown Spectroscopy Analysis Of Tourmaline: Protocols, Procedures, And Predicaments, Nancy J. Mcmillan, Barbara L. Dutrow Apr 2024

Laser-Induced Breakdown Spectroscopy Analysis Of Tourmaline: Protocols, Procedures, And Predicaments, Nancy J. Mcmillan, Barbara L. Dutrow

Faculty Publications

Laser-induced breakdown spectroscopy (LIBS) is an appropriate choice of analytical tool for analysis of complex minerals because it is rapid, requires little sample preparation, and acquires major and trace element compositional information on all naturally occurring elements at concentrations above their intrinsic levels of detection for the specific analyte material. Tourmaline, a complex borosilicate mineral supergroup, was chosen as a test mineral due to the complexity of its major and minor element composition. Four analytical issues were investigated during project development: (1) the spacing between analytical laser shots to avoid analysis of the recast from previous laser ablations, (2) the …


Molybdenum Alkylidyne Complexes With Phenoxide Ligands For Alkyne Metathesis, Marvin L. Stewart Jr Apr 2024

Molybdenum Alkylidyne Complexes With Phenoxide Ligands For Alkyne Metathesis, Marvin L. Stewart Jr

LSU Doctoral Dissertations

Abstract

Alkyne metathesis is a powerful synthetic tool, which provides easy access to complex organic molecules in a single-step. It is a dynamic covalent reaction that scrambles alkynes, carbon-carbon triple bonds (C≡C). Molybdenum- or tungsten-alkylidyne (Mo≡C, W≡C) complexes are typically used as catalyst to cleave and reform alkyne bonds. Our goal has been to gain a deeper understanding of the intrinsic differences between functional ligands by the development of novel phenoxide ligands.

In chapter 2 we explore the detailed synthesis of novel phenoxide podand ligands in an effort to identify their mo-alkylidyne complexes. We were able to synthesize a variety …


Totoro: A Scalable Federated Learning Engine For The Edge, Cheng Wei Ching, Xin Chen, Taehwan Kim, Bo Ji, Qingyang Wang, Dilma Da Silva, Liting Hu Apr 2024

Totoro: A Scalable Federated Learning Engine For The Edge, Cheng Wei Ching, Xin Chen, Taehwan Kim, Bo Ji, Qingyang Wang, Dilma Da Silva, Liting Hu

Faculty Publications

Federated Learning (FL) is an emerging distributed machine learning (ML) technique that enables in-situ model training and inference on decentralized edge devices. We propose Totoro, a novel scalable FL engine, that enables massive FL applications to run simultaneously on edge networks. The key insight is to explore a distributed hash table (DHT)-based peer-to-peer (P2P) model to re-architect the centralized FL system design into a fully decentralized one. In contrast to previous studies where many FL applications shared one centralized parameter server, Totoro assigns a dedicated parameter server to each individual application. Any edge node can act as any application's coordinator, …


Benthic Community Response To The Impacts Of Proposed Sediment Diversions In Louisiana Estuaries, Jillian C. Tupitza Apr 2024

Benthic Community Response To The Impacts Of Proposed Sediment Diversions In Louisiana Estuaries, Jillian C. Tupitza

LSU Doctoral Dissertations

Sediment diversions designed to mitigate land loss in coastal Louisiana will likely cause ecosystem-wide shifts. The first diversion, planned for Barataria Bay, will divert fresh water and sediment from the Mississippi River into the surrounding wetlands to help them keep pace with high rates of relative sea-level rise (RSLR). Estuarine benthic communities were used in this study as tools to characterize ecological patterns in the context of anticipated salinity changes. I reviewed relevant literature, conducted a two-year survey of Barataria Bay benthos, executed a reciprocal transplant experiment to describe changes that might occur in both community composition and trophic dynamics, …


The Lowest Discriminant Ideal Of Cayley-Hamilton Hopf Algebras, Zhongkai Mi Apr 2024

The Lowest Discriminant Ideal Of Cayley-Hamilton Hopf Algebras, Zhongkai Mi

LSU Doctoral Dissertations

Discriminant ideals are defined for an algebra R with central subalgebra C and trace tr : R → C. They are indexed by positive integers and more general than discriminants. Usually R is required to be a finite module over C. Unlike the abundace of work on discriminants, there is hardly any literature on discriminant ideals. The levels of discriminant ideals relate to the sums of squares of dimensions of irreducible modules over maximal ideals of C containing these discriminant ideals. We study the lowest level when R is a Cayley-Hamilton Hopf algebra, i.e. C is also a Hopf subalgebra, …


Analysis Of Close Contact Melting, Mohana Durga Gurunadhan Apr 2024

Analysis Of Close Contact Melting, Mohana Durga Gurunadhan

LSU Master's Theses

This report presents a numerical transient analysis of Close Contact Melting (CCM), intended to help in accurate prediction of melt rate and interface configuration, which is to be utilized for a prospective frozen propellant based propulsion system. Three different substrate shapes namely- Flat, Cylindrical and Wedge, are chosen for the study. The domain discretization is based on generation of boundary fitted mesh and the time varying physical domain is transformed to a fixed computational domain, wherein the associated governing equations are solved. Apart from the conventional linear system solvers, an algebraic multigrid based solver is implemented. A non-iterative implicit/explicit melt …


Human-Environment Interactions In Coastal Belize: Insights Into Sea-Level Rise And Ancient Maya Activities At The Paynes Creek Salt Works, Cheryl Mae Foster Apr 2024

Human-Environment Interactions In Coastal Belize: Insights Into Sea-Level Rise And Ancient Maya Activities At The Paynes Creek Salt Works, Cheryl Mae Foster

LSU Doctoral Dissertations

Dissertation excavations were carried out in 2019 and 2022 at the underwater sites of Ta’ab Nuk Na and Ek Way Nal in Paynes Creek National Park, Belize. Sea-level rise submerged the sites in antiquity and preserved the artifact record in red mangrove (Rhizophora mangle) peat. Red mangrove peat can be used as a proxy for sea-level rise. The goals of the two excavations included: 1) excavating a 14m-long transect within and extending beyond building J at Ta’ab Nuk Na to determine the function of the building, 2) investigating the production of salt making pottery at Ta’ab Nuk Na; …


Community-Level Post-Hazard Functionality Methodology For Buildings Exposed To Floods, Omar Nofal, Nathanael Rosenheim, Sabarethinam Kameshwar, Jayant Patil, Xiangnan Zhou, John W. Van De Lindt, Leonardo Duenas-Osorio, Eun Jeong Cha, Amin Endrami, Elaina Sutley, Harvey Cutler, Tao Lu, Chen Wang, Hwayoung Jeon Apr 2024

Community-Level Post-Hazard Functionality Methodology For Buildings Exposed To Floods, Omar Nofal, Nathanael Rosenheim, Sabarethinam Kameshwar, Jayant Patil, Xiangnan Zhou, John W. Van De Lindt, Leonardo Duenas-Osorio, Eun Jeong Cha, Amin Endrami, Elaina Sutley, Harvey Cutler, Tao Lu, Chen Wang, Hwayoung Jeon

Faculty Publications

This paper presents a building-level post-hazard functionality model for communities exposed to flood hazards including the interdependencies between the population, buildings, and infrastructure. An existing portfolio of building archetypes is used to model the post-hazard physical flood functionality of different building typologies within the community with the goal of supporting resilience-informed decision-making. Specific fragility-based flood functionality curves were developed for this portfolio to quantify the exceedance probability of a prescribed set of functionality states. While the physical functionality of buildings is significant to the total functionality of a building and community resilience assessment, the functionality of utilities such as power …


Generating Rate Features For Mobile Applications, Shristi Shrestha, Anas Mahmoud Apr 2024

Generating Rate Features For Mobile Applications, Shristi Shrestha, Anas Mahmoud

Faculty Publications

Mobile application (app) stores employ standardized mechanisms for rating hosted apps, typically in the form of free text reviews and numerical rating scales. App users use these mechanisms to express their opinions about their apps and discover apps that fit their specific needs. However, existing app rating systems do not take into account the operational characteristics of application domains. Thus, generated user reviews are often short, subjective, and one-dimensional. To overcome these limitations, in this paper, we propose a multi-dimensional rating system for mobile apps. Our assumption is that an adaptive goal-based app rating system can prompt users to generate …


Improved Modeling And Application Of Data Assimilation In Gas Influx Management During Managed Pressure Drilling, Chen Wei Apr 2024

Improved Modeling And Application Of Data Assimilation In Gas Influx Management During Managed Pressure Drilling, Chen Wei

LSU Doctoral Dissertations

The management of gas influxes in a drilling well has been considered one of the most critical topics for maintaining petroleum drilling safety and efficiency. Reliable modeling of gas influx behaviors in a wellbore or a marine riser greatly benefits the improved understanding of a gas kick event and the development of optimized influx management strategies. However, the current studies on transient multiphase flow modeling show varying limitations on both the model rigorousness and the overall numerical efficiency. Meanwhile, the existence of great system uncertainties, such as the unclear influx sizes and distributions in the well/riser, has brought significant challenges …


A Feasibility Study Of Drilling Fluid Slippage For Wellbore Displacement, John Johnson Apr 2024

A Feasibility Study Of Drilling Fluid Slippage For Wellbore Displacement, John Johnson

LSU Master's Theses

In the ideal plug-flow mode viscoplastic drilling fluids display uniform frontal velocity due to wall slippage (at very low flowrate limited by the fluid’s yield strength). The flow rate could be increased by raising the yield strength that would make the fluid best candidate for frontal displacement. Based on this concept the study qualifies wall slippage effect for wellbore displacement. Using a conceptual model of fluid motion between two parallel plates defines maximum velocity as a function of shearing rate and yield stress. Conversion to coaxial geometry gives practical formulas for fluid testing with rotational viscometer. A new analysis of …


Probing The Electrode-Electrolyte Interface Of Sodium/Glyme-Based Battery Electrolytes, Dodangodage Ishara Senadheera, Orlando Carrillo-Bohorquez, Ernest O. Nachaki, Ryan Jorn, Daniel G. Kuroda, Revati Kumar Apr 2024

Probing The Electrode-Electrolyte Interface Of Sodium/Glyme-Based Battery Electrolytes, Dodangodage Ishara Senadheera, Orlando Carrillo-Bohorquez, Ernest O. Nachaki, Ryan Jorn, Daniel G. Kuroda, Revati Kumar

Faculty Publications

Sodium-ion batteries (NIBs) are promising systems for large-scale energy storage solutions; yet, further enhancements are required for their commercial viability. Improving the electrochemical performance of NIBs goes beyond the chemical description of the electrolyte and electrode materials as it requires a comprehensive understanding of the underlying mechanisms that govern the interface between electrodes and electrolytes. In particular, the decomposition reactions occurring at these interfaces lead to the formation of surface films. Previous work has revealed that the solvation structure of cations in the electrolyte has a significant influence on the formation and properties of these surface films. Here, an experimentally …


Lithium Ion Speciation In Cyclic Solvents: Impact Of Anion Charge Delocalization And Solvent Polarizability, Ernest O. Nachaki, Daniel G. Kuroda Apr 2024

Lithium Ion Speciation In Cyclic Solvents: Impact Of Anion Charge Delocalization And Solvent Polarizability, Ernest O. Nachaki, Daniel G. Kuroda

Faculty Publications

The increasing demand for lithium batteries has triggered the search for safer and more efficient electrolytes. Insights into the atomistic description of electrolytes are critical for relating microscopic and macroscopic (physicochemical) properties. Previous studies have shown that the type of lithium salt and solvent used in the electrolyte influences its performance by dictating the speciation of the ionic components in the system. Here, we investigate the molecular origins of ion association in lithium-based electrolytes as a function of anion charge delocalization and solvent chemical identity. To this end, a family of cyano-based lithium salts in organic solvents, having a cyclic …


Enhancement Of Applied Rice Breeding Programs: Exploring Factors Impacting Genomic Selection Accuracy And Discovery Of A Novel Gene For Grain Shape, Maria G. Montiel Apr 2024

Enhancement Of Applied Rice Breeding Programs: Exploring Factors Impacting Genomic Selection Accuracy And Discovery Of A Novel Gene For Grain Shape, Maria G. Montiel

LSU Doctoral Dissertations

Plant breeding is a crucial tool in addressing global challenges such as climate change, population growth, and the need for more resilient crops. Rice serves as a staple food for a significant portion of the global population and has served as a model crop for genetic and genomic studies. Genomic selection (GS) has become valuable tool in plant breeding, allowing breeders to predict breeding lines’ performance based on their genotypes. The training (TS) set is a central component of genomic selection and the optimization of the training set is crucial for efficient implementation of genomic selection. The first two objectives …


Research On 3d Printing Resin Exposure Properties And Its Application On Centrifugal Microfluidic Platform Based On Fluorescence Detection, Zheng Qiao Apr 2024

Research On 3d Printing Resin Exposure Properties And Its Application On Centrifugal Microfluidic Platform Based On Fluorescence Detection, Zheng Qiao

LSU Doctoral Dissertations

This dissertation encapsulates significant advancements in the field of SLA 3D printing and centrifugal microfluidics. Central to the research is the development of a novel mathematical model for predicting trapped resin thickness in SLA 3D printing, a groundbreaking contribution that addresses a critical aspect of printing intricate structures. This model, the first to establish a mathematical relationship for resin thickness, is rooted in a comprehensive study of the resin curing process. The research leverages the concept of 'critical dosage' for resin curing, leading to a more refined and theoretically grounded approach for calculating curing thickness. Experimentation further validates the model, …


Surfactant-Specific Ai-Driven Molecular Design: Integrating Generative Models, Predictive Modeling, And Reinforcement Learning For Tailored Surfactant Synthesis, Miriam Nnadili, Andrew N. Okafor, Teslim Olayiwola, David Akinpelu, Revati Kumar, Jose A. Romagnoli Apr 2024

Surfactant-Specific Ai-Driven Molecular Design: Integrating Generative Models, Predictive Modeling, And Reinforcement Learning For Tailored Surfactant Synthesis, Miriam Nnadili, Andrew N. Okafor, Teslim Olayiwola, David Akinpelu, Revati Kumar, Jose A. Romagnoli

Faculty Publications

Molecular design is a critical aspect of various scientific and industrial fields, where the properties of molecules hold significant importance. In this study, a 3-fold methodology design is presented that leverages the power of generative artificial intelligence (AI), predictive modeling, and reinforcement learning to create tailored molecules with desired properties. This model synergistically combines deep learning techniques with Self-Referencing Embedded Strings (SELFIES) molecular representation to build a generative model that generates valid molecules and a graphical neural network model that accurately forecasts molecular properties. The Variational Autoencoder (VAE) coupled with reinforcement learning helps refine molecule generation based on targeted attributes. …


Magnetic Control Of Nonmagnetic Living Organisms, Ahmed Al Harraq, Min Feng, Hashir M. Gauri, Ram Devireddy, Ankur Gupta, Qing Sun, Bhuvnesh Bharti Apr 2024

Magnetic Control Of Nonmagnetic Living Organisms, Ahmed Al Harraq, Min Feng, Hashir M. Gauri, Ram Devireddy, Ankur Gupta, Qing Sun, Bhuvnesh Bharti

Faculty Publications

Living organisms inspire the design of microrobots, but their functionality is unmatched. Next-generation microrobots aim to leverage the sensing and communication abilities of organisms through magnetic hybridization, attaching magnetic particles to them for external control. However, the protocols used for magnetic hybridization are morphology specific and are not generalizable. We propose an alternative approach that leverages the principles of negative magnetostatics and magnetophoresis to control nonmagnetic organisms with external magnetic fields. To do this, we disperse model organisms in dispersions of Fe3O4 nanoparticles and expose them to either uniform or gradient magnetic fields. In uniform magnetic fields, living organisms align …


Seeking A Uniform Approach To Trumpet Sound Concept, Coleman T. Scott Apr 2024

Seeking A Uniform Approach To Trumpet Sound Concept, Coleman T. Scott

LSU Doctoral Dissertations

One of the most challenging aspects of trumpet playing that pedagogues must teach is how to produce a professional tone. Trumpet students are often good musicians, play correct notes and rhythms, and even have proficient technique. However, many are unable to consistently produce a tone comparable to that of a professional. There are a number of methods that can be utilized to improve a student’s tone quality. In my own teaching and in the teaching of many professionals, tone concept has been used as a catalyst for the improvement of tone quality. A students’ exposure to a professional-quality trumpet tone …


Building The Church Of San Vitale In Ravenna, Italy, Sally S. Morgan Apr 2024

Building The Church Of San Vitale In Ravenna, Italy, Sally S. Morgan

LSU Master's Theses

This thesis uses the evidence concerning the design and building of the Church of San Vitale in Ravenna to reconstruct, as far as it is possible, the sequence of decisions, activities, and methods that led to the construction of the church, made of bricks and mortar, and whose interiors are covered by glorious colored mosaics and marbles. The historiography on the Church of San Vitale begins with the historian Agnellus, who wrote the Liber pontificalis ecclesiae Ravennatis in the 830s to 840s. According to Agnellus and other sources, the Church of San Vitale was founded by Bishop Ecclesius around 525, …


“Everything Is Not What It Seems”: Discovering Public Relations In Business Sectors In Vietnam, Ba-Anh-Tu Truong Apr 2024

“Everything Is Not What It Seems”: Discovering Public Relations In Business Sectors In Vietnam, Ba-Anh-Tu Truong

LSU Master's Theses

Vietnam is a shining star in emerging markets, with an annual economic growth rate of 6-7%. Its abundant labor supply, stable political climate, and geographic proximity to major global supply chains make it an ideal candidate for manufacturer planning in advanced economies such as the United States, Europe, Australia, Japan, China, and Korea. Investing in public relations and communication management, especially understanding the Vietnamese market, effectively prepares multinational corporations for future business expansion. This mission is difficult for academia and industrial professionals since Vietnam is a “silent country” in public relations research. To fill the gap, this thesis employs the …