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Recommendations From The 2023 International Evidence-Based Guideline For The Assessment And Management Of Polycystic Ovary Syndrome, Helena J. Teede, Chau Thien Tay, Joop Laven, Anuja Dokras, Lisa J. Moran, Terhi T. Piltonen, Michael F. Costello, Jacky Boivin, Leanne M. Redman, Jacqueline A. Boyle, Robert J. Norman, Aya Mousa, Anju E. Joham, Wiebke Arlt, Ricardo Azziz, Adam Balen, Lisa Bedson, Lorna Berry, Leah Brennan, Wendy Brown, Tania Burgert, Maureen Busby, Carolyn Ee, Rhonda M. Garad, Melanie Gibson-Helm, Cheryce Harrison, Roger Hart, Kim Hopkins, Angelica Lindén Hirschberg, Tuong Ho, Kathleen Hoeger, Cailin Jordan, Richard S. Legro, Rong Li Oct 2023

Recommendations From The 2023 International Evidence-Based Guideline For The Assessment And Management Of Polycystic Ovary Syndrome, Helena J. Teede, Chau Thien Tay, Joop Laven, Anuja Dokras, Lisa J. Moran, Terhi T. Piltonen, Michael F. Costello, Jacky Boivin, Leanne M. Redman, Jacqueline A. Boyle, Robert J. Norman, Aya Mousa, Anju E. Joham, Wiebke Arlt, Ricardo Azziz, Adam Balen, Lisa Bedson, Lorna Berry, Leah Brennan, Wendy Brown, Tania Burgert, Maureen Busby, Carolyn Ee, Rhonda M. Garad, Melanie Gibson-Helm, Cheryce Harrison, Roger Hart, Kim Hopkins, Angelica Lindén Hirschberg, Tuong Ho, Kathleen Hoeger, Cailin Jordan, Richard S. Legro, Rong Li

Clinical Research Faculty Publications

STUDY QUESTION: What is the recommended assessment and management of those with polycystic ovary syndrome (PCOS), based on the best available evidence, clinical expertise, and consumer preference? SUMMARY ANSWER: International evidence-based guidelines address prioritized questions and outcomes and include 254 recommendations and practice points, to promote consistent, evidence-based care and improve the experience and health outcomes in PCOS. WHAT IS KNOWN ALREADY: The 2018 International PCOS Guideline was independently evaluated as high quality and integrated multidisciplinary and consumer perspectives from six continents; it is now used in 196 countries and is widely cited. It was based on best available, but …

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Environmentally Persistent Free Radicals: Methods For Combustion Generation, Whole-Body Inhalation And Assessing Cardiopulmonary Consequences, Ankit Aryal, Alexandra Noël, Lavrent Khachatryan, Stephania A. Cormier, Pratiti H. Chowdhury, Arthur Penn, Tammy R. Dugas, Ashlyn C. Harmon Oct 2023

Environmentally Persistent Free Radicals: Methods For Combustion Generation, Whole-Body Inhalation And Assessing Cardiopulmonary Consequences, Ankit Aryal, Alexandra Noël, Lavrent Khachatryan, Stephania A. Cormier, Pratiti H. Chowdhury, Arthur Penn, Tammy R. Dugas, Ashlyn C. Harmon

Division of Basic Science Faculty Publications

Particulate matter (PM) containing environmentally persistent free radicals (EPFRs) results from the incomplete combustion of organic wastes which chemisorb to transition metals. This process generates a particle-pollutant complex that continuously redox cycles to produce reactive oxygen species. EPFRs are well characterized, but their cardiopulmonary effects remain unknown. This publication provides a detailed approach to evaluating these effects and demonstrates the impact that EPFRs have on the lungs and vasculature. Combustion-derived EPFRs were generated (EPFR lo: 2.1e−16 radical/g, EPFR hi: 5.5e−17 radical/g), characterized, and verified as representative of those found in urban areas. Dry particle aerosolization and whole-body inhalation were established …

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Recruitment Methods And Yield Rates For A Multisite Clinical Trial Exploring Risk Reduction For Alzheimer's Disease (Rrad), Amanda N. Szabo-Reed, Tristyn Hall, Eric D. Vidoni, Angela Van Sciver, Monica Sewell, Jeffrey M. Burns, C. Munro Cullum, William P. Gahan, Linda S. Hynan, Diana R. Kerwin, Heidi Rossetti, Ann M. Stowe, Wanpen Vongpatanasin, David C. Zhu, Rong Zhang, Jeffrey N. Keller, Ellen F. Binder Oct 2023

Recruitment Methods And Yield Rates For A Multisite Clinical Trial Exploring Risk Reduction For Alzheimer's Disease (Rrad), Amanda N. Szabo-Reed, Tristyn Hall, Eric D. Vidoni, Angela Van Sciver, Monica Sewell, Jeffrey M. Burns, C. Munro Cullum, William P. Gahan, Linda S. Hynan, Diana R. Kerwin, Heidi Rossetti, Ann M. Stowe, Wanpen Vongpatanasin, David C. Zhu, Rong Zhang, Jeffrey N. Keller, Ellen F. Binder

Clinical Research Faculty Publications

INTRODUCTION: The risk reduction for Alzheimer's disease (rrAD) trial was a multisite clinical trial to assess exercise and intensive vascular pharmacological treatment on cognitive function in community-dwelling older adults at increased risk for Alzheimer's disease. METHODS: Eligibility, consent, and randomization rates across different referral sources were compared. Informal interviews conducted with each site's project team were conducted upon study completion. RESULTS: Initially, 3290 individuals were screened, of whom 28% were eligible to consent, 805 consented to participate (87.2% of those eligible), and 513 (36.3% of those consented) were randomized. Emails sent from study site listservs/databases yielded the highest amount (20.9%) …

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Impact Of A Nutrient Formulation On Longitudinal Myelination, Cognition, And Behavior From Birth To 2 Years: A Randomized Clinical Trial, Nora Schneider, Mickaël Hartweg, Jonathan O’Regan, Jennifer Beauchemin, Leanne Redman, Daniel S. Hsia, Pascal Steiner, Owen Carmichael, Viren D’Sa, Sean Deoni Oct 2023

Impact Of A Nutrient Formulation On Longitudinal Myelination, Cognition, And Behavior From Birth To 2 Years: A Randomized Clinical Trial, Nora Schneider, Mickaël Hartweg, Jonathan O’Regan, Jennifer Beauchemin, Leanne Redman, Daniel S. Hsia, Pascal Steiner, Owen Carmichael, Viren D’Sa, Sean Deoni

Clinical Research Faculty Publications

Observation studies suggest differences in myelination in relation to differences in early life nutrition. This two-center randomized controlled trial investigates the effect of a 12-month nutritional intervention on longitudinal changes in myelination, cognition, and behavior. Eighty-one full-term, neurotypical infants were randomized into an investigational (N = 42) or a control group (N = 39), receiving higher versus lower levels of a blend of nutrients. Non-randomized breastfed infants (N = 108) served as a reference group. Main outcomes were myelination (MRI), neurodevelopment (Bayley-III), social-emotional development (ASQ:SE-2), infant and toddler behavior (IBQ-R and TBAQ), and infant sleep (BISQ) during the first 2 …

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Qtls And Candidate Loci Associated With Drought Tolerance Traits Of Kaybonnet X Zhe733 Recombinant Inbred Lines Rice Population, Yheni Dwiningsih, Julie Thomas, Anuj Kumar, Chirag Gupta, Navdeep Gill, Charles Ruiz, Jawaher Alkahtani, Niranjan Baisakh, Andy Pereira Oct 2023

Qtls And Candidate Loci Associated With Drought Tolerance Traits Of Kaybonnet X Zhe733 Recombinant Inbred Lines Rice Population, Yheni Dwiningsih, Julie Thomas, Anuj Kumar, Chirag Gupta, Navdeep Gill, Charles Ruiz, Jawaher Alkahtani, Niranjan Baisakh, Andy Pereira

Faculty Publications

Rice is the most important staple crop for the sustenance of the world’s population, and drought is a major factor limiting rice production. Quantitative trait locus (QTL) analysis of drought-resistance-related traits was conducted on a recombinant inbred line (RIL) population derived from the self-fed progeny of a cross between the drought-resistant tropical japonica U.S. adapted cultivar Kaybonnet and the drought-sensitive indica cultivar ZHE733. K/Z RIL population of 198 lines was screened in the field at Fayetteville (AR) for three consecutive years under controlled drought stress (DS) and well-watered (WW) treatment during the reproductive stage. The effects of DS were quantified …

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Toward Food Security In 2050: Gene Pyramiding For Climate-Smart Rice, Isnaini Isnaini, Yudhistira Nugraha, Niranjan Baisakh, Nono Carsono Oct 2023

Toward Food Security In 2050: Gene Pyramiding For Climate-Smart Rice, Isnaini Isnaini, Yudhistira Nugraha, Niranjan Baisakh, Nono Carsono

Faculty Publications

The decline in crop productivity due to climate change is a major issue that threatens global food security and is the main challenge for breeders today in developing sustainable varieties with a wider tolerance to abiotic and biotic stresses. Breeding climate-smart rice (CSR) cultivars may be the best adaptation to climate change, with the potential to improve future food security and profitability for farmers in many nations. The main objective of this review is to highlight the direction of development of superior rice breeding from time to time, and various studies of new techniques of breeding methods for pyramiding various …

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Responses Of Phytoplankton Communities To Internal Waves In Oligotrophic Oceans, Lingqi Ma, Xiaolin Bai, Edward A. Laws, Wupeng Xiao, Cui Guo, Xin Liu, Kuo Ping Chiang, Kunshan Gao, Bangqin Huang Oct 2023

Responses Of Phytoplankton Communities To Internal Waves In Oligotrophic Oceans, Lingqi Ma, Xiaolin Bai, Edward A. Laws, Wupeng Xiao, Cui Guo, Xin Liu, Kuo Ping Chiang, Kunshan Gao, Bangqin Huang

Faculty Publications

Understanding the potential impacts of internal waves on phytoplankton communities in oligotrophic oceans remains an important research challenge. In this study, we elucidated the impact of internal waves on phytoplankton communities through a comprehensive 154-hr time-series of observations in the South China Sea (SCS). We identified distinctive variations in phytoplankton pigment biomass and composition across the upper, middle, and lower layers of the euphotic zone, which we attributed to the perturbations triggered by internal waves. Phytoplankton other than Prochlorococcus in the lower, nutrient-replete layer likely benefitted from allochthonous nutrients introduced by internal waves, but their growth rates were constrained by …

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Multimessenger Diagnostics Of The Engine Behind Core-Collapse Supernovae, Christopher L. Fryer, Eric Burns, Aimee Hungerford, Samar Safi-Harb, R. T. Wollaeger, Richard S. Miller, Michela Negro, Samalka Anandagoda, Dieter H. Hartmann Oct 2023

Multimessenger Diagnostics Of The Engine Behind Core-Collapse Supernovae, Christopher L. Fryer, Eric Burns, Aimee Hungerford, Samar Safi-Harb, R. T. Wollaeger, Richard S. Miller, Michela Negro, Samalka Anandagoda, Dieter H. Hartmann

Faculty Publications

Core-collapse supernova explosions play a wide role in astrophysics by producing compact remnants (neutron stars or black holes) and the synthesis and injection of many heavy elements into their host galaxy. Because they are produced in some of the most extreme conditions in the universe, they can also probe physics in extreme conditions (matter at nuclear densities and extreme temperatures and magnetic fields). To quantify the impact of supernovae on both fundamental physics and our understanding of the universe, we must leverage a broad set of observables of this engine. In this paper, we study a subset of these probes …

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Deep Multimessenger Search For Compact Binary Mergers In Ligo, Virgo, And Fermi/Gbm Data From 2016-2017, Marion Pillas, Tito Dal Canton, Cosmin Stachie, Brandon Piotrzkowski, Fergus Hayes, Rachel Hamburg, Eric Burns, Joshua Wood, Pierre Alexandre Duverne, Nelson Christensen Oct 2023

Deep Multimessenger Search For Compact Binary Mergers In Ligo, Virgo, And Fermi/Gbm Data From 2016-2017, Marion Pillas, Tito Dal Canton, Cosmin Stachie, Brandon Piotrzkowski, Fergus Hayes, Rachel Hamburg, Eric Burns, Joshua Wood, Pierre Alexandre Duverne, Nelson Christensen

Faculty Publications

GW170817-GRB 170817A provided the first observation of gravitational waves from a neutron star merger with associated transient counterparts across the entire electromagnetic spectrum. This discovery demonstrated the long-hypothesized association between short gamma-ray bursts and neutron star mergers. More joint detections are needed to explore the relation between the parameters inferred from the gravitational wave and the properties of the gamma-ray burst signal. We developed a joint multimessenger analysis of LIGO, Virgo, and Fermi/GBM data designed for detecting weak gravitational-wave transients associated with weak gamma-ray bursts. As such, it does not start from confident (GWTC-1) events only. Instead, we take the …

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Sexually Dimorphic Oxytocin Receptor-Expressing (Oxtr) Neurons In The Anteroventral Periventricular Nucleus (Avpv) In The Postpartum Female Mouse Are Involved In Maternal Behavior, Kaustubh Sharma, Armita A. Govar, Bandana Ghimire, Katsuhiko Nishimori, Elizabeth Hammock, Ryoichi Teruyama Oct 2023

Sexually Dimorphic Oxytocin Receptor-Expressing (Oxtr) Neurons In The Anteroventral Periventricular Nucleus (Avpv) In The Postpartum Female Mouse Are Involved In Maternal Behavior, Kaustubh Sharma, Armita A. Govar, Bandana Ghimire, Katsuhiko Nishimori, Elizabeth Hammock, Ryoichi Teruyama

Faculty Publications

Maternal care is crucial for the survival and development of offspring. Oxytocin modulates maternal behavior by binding to oxytocin receptors (OXTRs) in various parts of the brain. Previously, we showed that OXTRs are expressed in the anteroventral periventricular nucleus (AVPV) of female, but not male mice. Because the AVPV is involved in the regulation of maternal behavior and oxytocin enhances its induction, this finding leads to the hypothesis that the female specific population of OXTR neurons in the AVPV regulates maternal behavior. To address this hypothesis, OXTR-Venus reporter mice were used to assess if expression levels of OXTR in the …

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Association Of Prolactin With All-Cause And Cardiovascular Mortality Among Patients With Type 2 Diabetes: A Real-World Study, Yun Shen, Qing Yang, Tingting Hu, Yaxin Wang, Lei Chen, Fei Gao, Wei Zhu, Gang Hu, Jian Zhou, Chunfang Wang, Yuqian Bao Oct 2023

Association Of Prolactin With All-Cause And Cardiovascular Mortality Among Patients With Type 2 Diabetes: A Real-World Study, Yun Shen, Qing Yang, Tingting Hu, Yaxin Wang, Lei Chen, Fei Gao, Wei Zhu, Gang Hu, Jian Zhou, Chunfang Wang, Yuqian Bao

Population and Public Health Science Faculty Publications

Aims The association between prolactin and mortality has been less studied, and findings were inconsistent among different populations. We aimed to investigate the association between serum prolactin (PRL) and mortality among patients with type 2 diabetes. Methods We performed a retrospective cohort study of 10 907 patients with at least 2 prolactin measurements within 2 years since and results their first inpatient diagnosis of type 2 diabetes. Baseline and mean values of serum PRL were used as exposures. A multivariable-adjusted Cox proportional hazards model was used to estimate the association between PRL and mortality. During a mean follow-up of 5.34 …

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Deficiency Of Healthcare Accessibility Of Elderly People Exposed To Future Extreme Coastal Floods: A Case Study Of Shanghai, China, Xinmeng Shan, Paolo Scussolini, Jun Wang, Mengya Li, Jiahong Wen, Lei Wang Oct 2023

Deficiency Of Healthcare Accessibility Of Elderly People Exposed To Future Extreme Coastal Floods: A Case Study Of Shanghai, China, Xinmeng Shan, Paolo Scussolini, Jun Wang, Mengya Li, Jiahong Wen, Lei Wang

Faculty Publications

Socioeconomic development, subsidence, and climate change have led to high flood risks in coastal cities, making the vulnerable, especially elderly people, more prone to floods. However, we mostly do not know how the accessibility of life-saving public resources for the elderly population will change under future scenarios. Using Shanghai as a case, this study introduced a new analytical framework to fill this gap. We integrated for the first time models of coastal flooding, local population growth, and medical resource supply-demand estimation. The results show that under an extreme scenario of coastal flooding in the year 2050, in the absence of …

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U-Net-Lstm: Time Series-Enhanced Lake Boundary Prediction Model, Lirong Yin, Lei Wang, Tingqiao Li, Siyu Lu, Jiawei Tian, Zhengtong Yin, Xiaolu Li, Wenfeng Zheng Oct 2023

U-Net-Lstm: Time Series-Enhanced Lake Boundary Prediction Model, Lirong Yin, Lei Wang, Tingqiao Li, Siyu Lu, Jiawei Tian, Zhengtong Yin, Xiaolu Li, Wenfeng Zheng

Faculty Publications

Change detection of natural lake boundaries is one of the important tasks in remote sensing image interpretation. In an ordinary fully connected network, or CNN, the signal of neurons in each layer can only be propagated to the upper layer, and the processing of samples is independent at each moment. However, for time-series data with transferability, the learned change information needs to be recorded and utilized. To solve the above problems, we propose a lake boundary change prediction model combining U-Net and LSTM. The ensemble of LSTMs helps to improve the overall accuracy and robustness of the model by capturing …

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Machine-Learning-Based Thermal Conductivity Prediction For Additively Manufactured Alloys, Uttam Bhandari, Yehong Chen, Huan Ding, Congyuan Zeng, Selami Emanet, Paul R. Gradl, Shengmin Guo Oct 2023

Machine-Learning-Based Thermal Conductivity Prediction For Additively Manufactured Alloys, Uttam Bhandari, Yehong Chen, Huan Ding, Congyuan Zeng, Selami Emanet, Paul R. Gradl, Shengmin Guo

Faculty Publications

Thermal conductivity (TC) is greatly influenced by the working temperature, microstructures, thermal processing (heat treatment) history and the composition of alloys. Due to computational costs and lengthy experimental procedures, obtaining the thermal conductivity for novel alloys, particularly parts made with additive manufacturing, is difficult and it is almost impossible to optimize the compositional space for an absolute targeted value of thermal conductivity. To address these difficulties, a machine learning method is explored to predict the TC of additive manufactured alloys. To accomplish this, an extensive thermal conductivity dataset for additively manufactured alloys was generated for several AM alloy families (nickel, …

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The Standard For Assessing Water Resistance Properties Of Lubricating Grease Using Contact Angle Measurements, Koottaparambil Lijesh, Roger A. Miller, Raj Shah, Khosro Shirvani, Michael M. Khonsari Oct 2023

The Standard For Assessing Water Resistance Properties Of Lubricating Grease Using Contact Angle Measurements, Koottaparambil Lijesh, Roger A. Miller, Raj Shah, Khosro Shirvani, Michael M. Khonsari

Faculty Publications

Many grease-lubricated machines operate in wet environments, and are vulnerable to contamination because of water exposure. Reports suggest that even the presence of 1% water in grease reduces the life of a bearing by 90%. Nevertheless, only a few qualitative tests and standards are available to characterize the water resistance properties of greases. In this paper, we propose a standard for evaluating the water resistance properties of greases by studying their hydrophobic and hydrophilic nature via a custom-designed apparatus for measuring the grease contact angle. In this approach, a water droplet is dispensed onto the surface of the grease and …

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In Situ Prediction Of Metal Fatigue Life Using Frequency Change, Ali Mahmoudi, Mohammad A. Amooie, Lijesh Koottaparambil, Michael M. Khonsari Oct 2023

In Situ Prediction Of Metal Fatigue Life Using Frequency Change, Ali Mahmoudi, Mohammad A. Amooie, Lijesh Koottaparambil, Michael M. Khonsari

Faculty Publications

A reliable technique for rapid prediction of the remaining useful life (RUL) of components experiencing fatigue degradation is introduced. The approach is based on measuring the temperature signature of a component upon rapidly changing its operating frequency for a short period of time. The temperature variations caused by alterations in plastic work rate are correlated to the loading history. The efficacy of the approach is investigated by conducting a series of axial fatigue tests on stainless steel 316 specimens. The material characterization involves subjecting the material to a constant amplitude fatigue load at 4 Hz and 12 Hz frequencies. The …

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Comparative Analyses Of Covariance Matrix Adaptation And Iterative Ensemble Smoother On High-Dimensional Inverse Problems In High-Resolution Groundwater Modeling, Shuo Yang, Frank T.C. Tsai, Peter Bacopoulos, Christopher E. Kees Oct 2023

Comparative Analyses Of Covariance Matrix Adaptation And Iterative Ensemble Smoother On High-Dimensional Inverse Problems In High-Resolution Groundwater Modeling, Shuo Yang, Frank T.C. Tsai, Peter Bacopoulos, Christopher E. Kees

Faculty Publications

Parameter estimation is an inverse problem which is crucial to reliable groundwater model predictions and management. Numerous techniques have been developed to address this challenging problem. This study aims to compare the performance of a stochastic optimization method, covariance matrix adaptation-evolution strategy (CMA-ES), and a data assimilation method, Levenberg-Marquardt based iterative ensemble smoother (ES-LM), on solving inverse problems in groundwater modeling. This study also presents a parallelization strategy to accelerate their implementation. The comparative analysis involves synthetic inverse problems and a real-world case study of calibrating a high-resolution groundwater model. Results from the synthetic problems suggest that both the CMA-ES …

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Coupled Wellbore-Reservoir Modelling To Evaluate Co2 Injection Rate Distribution Over Thick Multilayer Storage Zones, Mohamed Abdelaal, Mehdi Zeidouni Oct 2023

Coupled Wellbore-Reservoir Modelling To Evaluate Co2 Injection Rate Distribution Over Thick Multilayer Storage Zones, Mohamed Abdelaal, Mehdi Zeidouni

Faculty Publications

Technical and economic feasibility of Geologic CO2 Storage (GCS) projects requires maximizing the amount of stored CO2 per unit pore space of the storage zone per well. Considering injection through a fully penetrating vertical well in a multi-layer thick aquifer, CO2 would be unevenly distributed over the aquifer thickness, underutilizing the available pore space. In this work, we use coupled wellbore-reservoir modelling to investigate the interplay between the parameters that control CO2 pore-space filling. Flow capacity profile and gravity/buoyancy override are the primary factors controlling CO2 flux into a layered system. In addition, a higher fraction of CO2 would flow …

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Weakly Forced Thunderstorms In The Southeast Us Are Stronger Near Urban Areas, P. Miller, N. Debbage Sep 2023

Weakly Forced Thunderstorms In The Southeast Us Are Stronger Near Urban Areas, P. Miller, N. Debbage

Faculty Publications

While cities are well documented to enhance precipitation through the urban rainfall effect (URE), the distinguishing characteristics of urban-influenced storms that help establish the URE are poorly understood. The purpose of this study is to examine the morphological traits (i.e., size, duration, intensity, etc.) and near-storm environmental conditions of weakly forced thunderstorms (WFTs) occurring near urban areas in the Southeast US relative to storms forming in surrounding rural areas. Urban WFTs are found to have higher reflectivities, are more likely to contain hail, and produce more lightning than nearby non-urban storms, but their sizes and shapes are statistically indistinguishable. When …

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Greater Male Variability In Daily Energy Expenditure Develops Through Puberty, Lewis G. Halsey, Vincent Careau, Philip N. Ainslie, Heliodoro Alemán-Mateo, Lene F. Andersen, Liam J. Anderson, Leonore Arab, Issad Baddou, Linda Bandini, Kweku Bedu-Addo, Ellen E. Blaak, Stephane Blanc, Alberto G. Bonomi, Carlijn V.C. Bouten, Pascal Bovet, Soren Brage, Maciej S. Buchowski, Nancy Butte, Stephan G. Camps, Regian Casper, Graeme L. Close, Lisa H. Colbert, Jamie A. Cooper, Richard Cooper, Prasangi Dabare, Sai Krupa Das, Peter S.W. Davies, Sanjoy Deb, Christine Delisle Nyström, William Dietz, Lara R. Dugas, Simon Eaton, Ulf Ekelund Sep 2023

Greater Male Variability In Daily Energy Expenditure Develops Through Puberty, Lewis G. Halsey, Vincent Careau, Philip N. Ainslie, Heliodoro Alemán-Mateo, Lene F. Andersen, Liam J. Anderson, Leonore Arab, Issad Baddou, Linda Bandini, Kweku Bedu-Addo, Ellen E. Blaak, Stephane Blanc, Alberto G. Bonomi, Carlijn V.C. Bouten, Pascal Bovet, Soren Brage, Maciej S. Buchowski, Nancy Butte, Stephan G. Camps, Regian Casper, Graeme L. Close, Lisa H. Colbert, Jamie A. Cooper, Richard Cooper, Prasangi Dabare, Sai Krupa Das, Peter S.W. Davies, Sanjoy Deb, Christine Delisle Nyström, William Dietz, Lara R. Dugas, Simon Eaton, Ulf Ekelund

Faculty Publications

There is considerably greater variation in metabolic rates between men than between women, in terms of basal, activity and total (daily) energy expenditure (EE). One possible explanation is that EE is associated with male sexual characteristics (which are known to vary more than other traits) such as musculature and athletic capacity. Such traits might be predicted to be most prominent during periods of adolescence and young adulthood, when sexual behaviour develops and peaks. We tested this hypothesis on a large dataset by comparing the amount of male variation and female variation in total EE, activity EE and basal EE, at …

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End Block Dynamics In Unentangled Polymers By Dielectric Spectroscopy, Mengchun Wu, Karin J. Bichler, Bruno Jakobi, Alyssa Grzesiowski, Gerald J. Schneider Sep 2023

End Block Dynamics In Unentangled Polymers By Dielectric Spectroscopy, Mengchun Wu, Karin J. Bichler, Bruno Jakobi, Alyssa Grzesiowski, Gerald J. Schneider

Faculty Publications

Dielectric spectroscopy measures the dynamics of polymer melts over a broad frequency range. Developing a theory for the spectral shape can extend the analysis of dielectric spectra beyond determining relaxation times from the peak maxima and adds physical meaning to shape parameters determined with empirical fit functions. Toward this goal, we use the experimental results on unentangled poly(isoprene), and unentangled poly(butylene oxide), polymer melts, to test whether the concept of end blocks could be one reason for the Rouse model deviating from experimental data. These end blocks have been suggested by simulations and neutron spin echo spectroscopy and are a …

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Synthesis, Crystal And Electronic Structure Of The Zintl Phase Ba16sb11. A Case Study Uncovering Greater Structural Complexity Via Monoclinic Distortion Of The Tetragonal Ca16sb11 Structure Type., Sviatoslav Baranets, Alexander Ovchinnikov, S. M.Gayomi K. Samarakoon, Svilen Bobev Sep 2023

Synthesis, Crystal And Electronic Structure Of The Zintl Phase Ba16sb11. A Case Study Uncovering Greater Structural Complexity Via Monoclinic Distortion Of The Tetragonal Ca16sb11 Structure Type., Sviatoslav Baranets, Alexander Ovchinnikov, S. M.Gayomi K. Samarakoon, Svilen Bobev

Faculty Publications

The binary Zintl phase Ba16Sb11 has been synthesized and structurally characterized. Detailed studies via single-crystal X-ray diffraction methods indicate that although Ba16Sb11 appears to crystallize in the tetragonal Ca16Sb11 structure type (space group P (Figure presented.) 21m with a=13.5647(9) Å, c=12.4124(12) Å, Z=2, R1=3.14 %; wR2=4.77 %), there exists an extensive structural disorder. Some Ba16Sb11 crystals were found to be monoclinic and the structure was solved and refined in space group P21 (a=18.3929(12) Å, b=13.5233(8) Å, c=18.3978(12) Å, β=94.6600(10)°; Z=4, R1=5.84 %; wR2=9.58 %). The latter corresponds to a 2-fold superstructure of the tetragonal one, which provides a disorder-free structural …

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Cationic Cobalt(Ii) Bisphosphine Hydroformylation Catalysis: In Situ Spectroscopic And Reaction Studies, Drew M. Hood, Ryan A. Johnson, David J. Vinyard, Frank R. Fronczek, George G. Stanley Sep 2023

Cationic Cobalt(Ii) Bisphosphine Hydroformylation Catalysis: In Situ Spectroscopic And Reaction Studies, Drew M. Hood, Ryan A. Johnson, David J. Vinyard, Frank R. Fronczek, George G. Stanley

Faculty Publications

[HCo(CO)x(bisphosphine)](BF4), x = 1-3, is a highly active hydroformylation catalyst system, especially for internal branched alkenes. In situ infrared spectroscopy (IR), electron paramagnetic resonance (EPR), and nuclear magnetic resonance studies support the proposed catalyst formulation. IR studies reveal the formation of a dicationic Co(I) paramagnetic CO-bridged dimer, [Co2(μ-CO)2(CO)(bisphosphine)2]2+, at lower temperatures formed from the reaction of two catalyst complexes via the elimination of H2. DFT studies indicate a dimer structure with square-pyramidal and tetrahedral cobalt centers. This monomer-dimer equilibrium is analogous to that seen for HCo(CO)4, reacting to eliminate H2 and form Co2(CO)8. EPR studies on the catalyst …

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Lipid Correction For Carbon Stable Isotope Analysis Of Yellowfin Tuna, Michael A. Dance, Mitchell S. Lovell Sep 2023

Lipid Correction For Carbon Stable Isotope Analysis Of Yellowfin Tuna, Michael A. Dance, Mitchell S. Lovell

Faculty Publications

Carbon stable isotopes (δ13C) are widely used in ecological studies to understand diet, food web dynamics, and movements of marine fishes. Still, δ13C is influenced by lipid content and often requires chemical extraction or mathematical correction. Here, we developed a species-specific mathematical lipid correction for white muscle tissue of yellowfin tuna (Thunnus albacares), a highly migratory finfish of considerable economic and ecological value. Lipid extraction was conducted on yellowfin tuna white muscle tissue (C:N range: 2.96–6.49), and both linear and non-linear lipid correction models for δ13C were fitted and assessed. Lipid extraction increased δ …

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Serum Sulfur-Containing Amino Acids And Risk Of Maternal Gestational Diabetes And Adverse Growth Patterns In Offspring, Ninghua Li, Jing Li, Hui Wang, Yijuan Qiao, Weiqin Li, Ming Gao, Enqing Liu, Zhijie Yu, Gang Hu, Zhongze Fang, Junhong Leng, Xilin Yang Sep 2023

Serum Sulfur-Containing Amino Acids And Risk Of Maternal Gestational Diabetes And Adverse Growth Patterns In Offspring, Ninghua Li, Jing Li, Hui Wang, Yijuan Qiao, Weiqin Li, Ming Gao, Enqing Liu, Zhijie Yu, Gang Hu, Zhongze Fang, Junhong Leng, Xilin Yang

Population and Public Health Science Faculty Publications

Background: To estimate associations of sulfur-containing amino acids (SAAs) in the early trimester of pregnancy and gestational diabetes mellitus (GDM) and estimate associations of maternal SAAs with adverse growth patterns in offspring. Methods: We established a 1:1 matched case-control study (n = 486) from our cohort of pregnant women, and 401 children were followed up at ages 1 to 8 years. We conducted binary conditional logistic regression to estimate the risk associations of serum SAAs with GDM. Multinomial logistic regression was implemented to explore associations of maternal SAAs with adverse growth patterns in the offspring. Results: High serum methionine and …

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New Frontiers In The Measurement Of Energy Metabolism, Alexandra Niclou, Philippe St-Martin, Leanne M. Redman, Audrey Bergouignan Sep 2023

New Frontiers In The Measurement Of Energy Metabolism, Alexandra Niclou, Philippe St-Martin, Leanne M. Redman, Audrey Bergouignan

Clinical Research Faculty Publications

This perspective highlights three key areas of current and future energy metabolism research: intergenerational health, climate change, and interplanetary exploration. We describe the recent advances in determining estimated energy requirements for a large subset of the general population using the gold standard method for free-living total daily energy expenditure estimates, the doubly labeled water method. The global rise in overweight and obesity demands particular attention to energy requirements in pregnancy and early life, as accumulating evidence contributes to our understanding of intergenerational health transmission and the potential for epigenetic programming in utero. We also acknowledge some gaps in necessary guidelines …

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The World's 100 Worst Invasive Alien Insect Species Differ In Their Characteristics From Related Non-Invasive Species, Zihua Zhao, Cang Hui, Shuo Peng, Shanqing Yi, Zhihong Li, Gadi V.P. Reddy, Mark Van Kleunen Sep 2023

The World's 100 Worst Invasive Alien Insect Species Differ In Their Characteristics From Related Non-Invasive Species, Zihua Zhao, Cang Hui, Shuo Peng, Shanqing Yi, Zhihong Li, Gadi V.P. Reddy, Mark Van Kleunen

Faculty Publications

While there has been great interest in species characteristics that promote invasiveness, still little is known about the characteristics that distinguish invasive from non-invasive insects. Using a database on the naturalised distributions of alien insects and expert opinions about their impacts, we identified the world's 100 worst invasive insect species. By comparing species characteristics reported in the literature using a meta-analysis, between the 100 worst invasive species and related non-invasive species, we found that invasive insects overall have more pathways of introduction, occur in more habitats, have higher fecundities, higher voltinism, more genes, shorted lifespans and faster development from egg …

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A Smartphone-Enabled Imaging Device For Chromotropic Acid-Based Measurement Of Nitrate In Soil Samples, Veerabhadrappa Lavanya, Anshuman Nayak, Partha Deb Roy, Shubhadip Dasgupta, Subhadip Dey, Bin Li, David C. Weindorf, Somsubhra Chakraborty Sep 2023

A Smartphone-Enabled Imaging Device For Chromotropic Acid-Based Measurement Of Nitrate In Soil Samples, Veerabhadrappa Lavanya, Anshuman Nayak, Partha Deb Roy, Shubhadip Dasgupta, Subhadip Dey, Bin Li, David C. Weindorf, Somsubhra Chakraborty

Faculty Publications

In this study, a novel chromotropic acid-based color development method was proposed for quick estimation of soil nitrate (NO3−). The method utilized a 3D printed device integrated with the rear-end camera of a smartphone and a stand-alone application called SMART NP. By analyzing the mean Value (V) component of the sample’s image, the SMART NP provides instant predictions of soil NO3− levels. The limit of detection was calculated as 0.1 mg L−1 with a sensitivity of 0.26 mg L−1. The device showed a % bias of 0.9% and a precision of 1.95%, indicating its reliability. Additionally, the device-predicted soil NO3− …

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Assessing Water Relations And Carbon Dynamics Of Pinus Taeda Branches Undergoing Shade-Induced Mortality, Adelodun R. Majekobaje, Thomas J. Dean Sep 2023

Assessing Water Relations And Carbon Dynamics Of Pinus Taeda Branches Undergoing Shade-Induced Mortality, Adelodun R. Majekobaje, Thomas J. Dean

Faculty Publications

Light acts as a complex signal, influencing various plant physiological, phenological and morphogenetic traits. Although previous studies have explored the effects of varying light levels on branch growth and survival, the underlying mechanisms of branch mortality under shade conditions remain poorly understood, hindering our understanding of canopy dynamics. In this study, contrasting shade conditions were imposed on Pinus taeda branches, and the changes in their water relations and carbon dynamics were evaluated. Monthly measurements of the photosynthetic light–response curve (LRC), sap flow and water potential of the branches were conducted. Furthermore, the conditions that led to the deaths of lower …

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Exercise-Induced Changes To The Fiber Type-Specific Redox State In Human Skeletal Muscle Are Associated With Aerobic Capacity, James Shadiow, Edwin R. Miranda, Ryan K. Perkins, Corey E. Mazo, Zhen Lin, Kendell N. Lewis, Jacob T. Mey, Thomas P.J. Solomon, Jacob M. Haus Sep 2023

Exercise-Induced Changes To The Fiber Type-Specific Redox State In Human Skeletal Muscle Are Associated With Aerobic Capacity, James Shadiow, Edwin R. Miranda, Ryan K. Perkins, Corey E. Mazo, Zhen Lin, Kendell N. Lewis, Jacob T. Mey, Thomas P.J. Solomon, Jacob M. Haus

Division of Basic Science Faculty Publications

The benefits of exercise involve skeletal muscle redox state alterations of nicotinamide adenine dinucleotide (NAD) and flavin adenine dinucleotide (FAD). We determined the fiber-specific effects of acute exercise on the skeletal muscle redox state in healthy adults. Muscle biopsies were obtained from 19 participants (11 M, 8 F; 26 ± 4 yr) at baseline (fasted) and 30 min and 3 h after treadmill exercise at 80% maximal oxygen consumption (V O2max). Muscle samples were probed for autofluorescence of NADH (excitation at 340-360 nm) and oxidized flavoproteins (Fp; excitation at 440-470 nm) and subsequently, fiber typed to quantify the redox signatures …

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