Open Access. Powered by Scholars. Published by Universities.®
- Discipline
-
- Physical Sciences and Mathematics (3676)
- Engineering (976)
- Mathematics (804)
- Chemistry (626)
- Analysis (604)
-
- Other Mathematics (593)
- Environmental Sciences (536)
- Earth Sciences (427)
- Oceanography and Atmospheric Sciences and Meteorology (377)
- Social and Behavioral Sciences (360)
- Computer Sciences (272)
- Civil and Environmental Engineering (263)
- Education (258)
- Life Sciences (250)
- Arts and Humanities (247)
- Applied Mathematics (232)
- Chemical Engineering (199)
- Electrical and Computer Engineering (199)
- Mechanical Engineering (175)
- Physics (168)
- Geology (131)
- Oceanography (121)
- Psychology (107)
- Petroleum Engineering (98)
- Astrophysics and Astronomy (88)
- Business (83)
- Music (73)
- Agriculture (66)
- Medicine and Health Sciences (64)
- Philosophy (60)
- Keyword
-
- Education (322)
- Engineering (271)
- Mathematics (231)
- General (113)
- Chemistry (89)
-
- Louisiana (87)
- Physics (78)
- Chemical (73)
- Business administration (69)
- Economics (62)
- Psychology (62)
- Biology (57)
- Agriculture (54)
- Machine learning (54)
- Gulf of Mexico (45)
- Gravitational waves (42)
- Curricula (38)
- Modeling (38)
- Course catalogs (37)
- General catalogs (37)
- Gumbo (37)
- Gumbo yearbook (37)
- La.) (37)
- Louisiana State University (Baton Rouge (37)
- Louisiana state university (37)
- Lsu yearbook (37)
- Physical (37)
- University archives (37)
- Yearbook (37)
- Computer science (36)
- Publication Year
- Publication
-
- Faculty Publications (2672)
- LSU Doctoral Dissertations (2330)
- LSU Master's Theses (1895)
- LSU Historical Dissertations and Theses (1613)
- Communications on Stochastic Analysis (432)
-
- Honors Capstones (265)
- Journal of Stochastic Analysis (160)
- Seminar on Continuity in Semilattices (102)
- LSU General Catalog (53)
- 1650-1850: Ideas, Aesthetics, and Inquiries in the Early Modern Era (46)
- Gumbo Yearbook (37)
- Clinical Research Faculty Publications (35)
- Publications (29)
- LSU Agricultural Experiment Station Reports (27)
- LSU Faculty Senate Publications (26)
- 2026 LSU Symposium on Control, Learning, and Intelligent Systems (17)
- Civil War Book Review (16)
- Population and Public Health Science Faculty Publications (14)
- Taboo: The Journal of Culture and Education (14)
- Division of Basic Science Faculty Publications (11)
- Components (10)
- Louisiana Agriculture (9)
- College of Engineering Patents (7)
- Spark! Innovations in Early Childhood Education: A Research-to-Practice Journal for Educators (7)
- Reports (6)
- LSU AgCenter Bulletins (5)
- Research Magazine (5)
- Student Senate Enrolled Legislation (5)
- Data (4)
- E-Textbooks (4)
- Publication Type
- File Type
Articles 7321 - 7350 of 9887
Full-Text Articles in Entire DC Network
Individual And Landscape-Level Effects Of Selective Herbicides, Mowing, And Prescribed Fire On Habitat Quality For Northern Bobwhite (Colinus Virginianus), Charles Lynn Kitts
Individual And Landscape-Level Effects Of Selective Herbicides, Mowing, And Prescribed Fire On Habitat Quality For Northern Bobwhite (Colinus Virginianus), Charles Lynn Kitts
LSU Master's Theses
Northern bobwhite (Colinus virginianus) populations have been declining throughout their range during the past 30 years primarily because of a result of loss of early successional habitat. Specifically, intensive silviculture practices and reduction in the use of prescribed fire has led to this loss. I studied effects of management practices (selective herbicides, mowing, and prescribed fire) on male and covey distribution, and brood-rearing habitats on Jackson-Bienville Wildlife Management Area (JBWMA). Specifically, I used calling surveys to assess landscape characteristics associated bobwhite distribution. I also measured vegetation and arthropod response, using imprinted bobwhite chicks, pitfalls, and sweep nets, to different habitat …
Application Of Stochastic Downscaling Techniques To Global Climate Model Data For Regional Climate Prediction, Suchita Potta
Application Of Stochastic Downscaling Techniques To Global Climate Model Data For Regional Climate Prediction, Suchita Potta
LSU Master's Theses
Global warming is the most important issue of the present day that affects the climate drastically. This research was carried out to find out the effects of Global warming on Louisiana in future on a very finer spatial and temporal scale. For this purpose spatial downscaling technique is used, where finer resolution climate information is derived from a coarser resolution Global Climate Model (GCM) output. Empirical/statistical downscaling method is used in which sub grid scale changes are calculated as a function of large scale climate. For this purpose a stochastic weather generator and two Global models are considered. The two …
Overlap Zones, Growth Faults, And Sedimentation: Using High Resolution Gravity Data, Livingston Parish, La, Carrie Alison Cazes
Overlap Zones, Growth Faults, And Sedimentation: Using High Resolution Gravity Data, Livingston Parish, La, Carrie Alison Cazes
LSU Master's Theses
In south Louisiana, parallel to the coast of the Gulf of Mexico, are belts of east-to-west trending, listric-normal faults with associated contemporaneous sedimentation and fault movement. The Tepetate-Baton Rouge Fault system in south-central Louisiana contains individual fault segments which are arcuate and overlap each other in map view, as seen on LiDAR data. Gravity survey data, with a sample spacing of 20 to 50 m, was collected across normal fault scarps. Structural ramps may form in the area between overlapping normal fault segments creating an east-to-west gradient. This gradient change may divert streams and provide areas for coarse-grained sediments to …
Query Of Image Content Using Wavelets And Gibbs-Markov Random Fields, Imtiaz Hossain
Query Of Image Content Using Wavelets And Gibbs-Markov Random Fields, Imtiaz Hossain
LSU Master's Theses
The central theme of this thesis is the application of Wavelets and Random Processes to content-based image query (on texture patterns, in particular). Given a query image, a content-based search extracts a certain representative measure (or signature) from the query image and likewise for all the target images in the search archive. A good representative measure is one that provides us with the ability to differentiate easily between different patterns. A distance measure is computed between the query properties and the properties of each of the target images. The lowest distance measure gives us the best target match for the …
A Meta-Analysis Of Randomness In Human Behavioral Research, Summer Ann Armstrong
A Meta-Analysis Of Randomness In Human Behavioral Research, Summer Ann Armstrong
LSU Master's Theses
This work analyzes the concept of randomness in binary sequences from three different perspectives: mathematically, statistically, and psychologically and examines the research on human perception of randomness and the question of whether or not humans can simulate random behavior. Generally, research shows that human subjects have great difficulty producing random sequences, even when they are instructed and motivated. We survey some of the literature and present some leading theoretical proposals. Finally, we present some basic statistical tests that can be used to evaluate randomness in a given binary sequence.
Migmatization Of Archean Aluminous Metasediments From The Eastern Beartooth Mountains, Montana, U.S.A., Andrew T. Maas
Migmatization Of Archean Aluminous Metasediments From The Eastern Beartooth Mountains, Montana, U.S.A., Andrew T. Maas
LSU Master's Theses
Geothermobarometry, mineral compositions and textures, and thermodynamic models suggest biotite dehydration melting occurred in the peraluminous rocks of the eastern Beartooth Mountains. These Archean metapelitic migmatites are metatexites and diatexites, and have typical metamorphic assemblages of Qtz + Pl + Kfs + Bt + Sil +/- Grt +/- Crd. The subsequent in situ crystallization of the magma derived from the biotite dehydration created migmatitic leucosomes in the rocks. These leucosomes are primarily composed of quartz, plagioclase and potassium feldspar. Water derived from the dehydration of biotite was dissolved in the melted phase. Crystallization of the magma reintroduced this water to …
A Comparison Of A High-Resolution Survey And A Three-Dimensional Seismic Survey In A Feature-Rich Region Of The Green Canyon Area, Gulf Of Mexico, Bruce Miles Samuel
A Comparison Of A High-Resolution Survey And A Three-Dimensional Seismic Survey In A Feature-Rich Region Of The Green Canyon Area, Gulf Of Mexico, Bruce Miles Samuel
LSU Master's Theses
Recent advances in Autonomous Underwater Vehicle (AUV) technology have revolutionized the positioning and accuracy of high-resolution deep sea mapping tools. Geologic hazard and engineering surveys by AUV’s are producing high-resolution data sets of a quality that has never before been seen. Three-dimensional (3D) seismic data, though traditionally used for only deep subsurface mapping of large areas, is now being reprocessed at a higher resolution and utilized in well site investigations and geologic hazard assessments. This study makes a comparison between a 3D seismic survey and an AUV high-resolution survey in order to determine the strengths and weaknesses of both of …
The Portrayals Of Minority Characters In Entertaining Animated Children's Programs, Siobhan Elizabeth Smith
The Portrayals Of Minority Characters In Entertaining Animated Children's Programs, Siobhan Elizabeth Smith
LSU Master's Theses
The purpose of this study is to note, categorize, and discuss the stereotypes of African Americans in animated children’s cartoons. The purpose is also to compare them to see how they changed. A content analysis of two cartoons finds that characters do act in stereotypical ways. A quantitative analysis of 76 cartoons supports these findings. Overall, The Proud Family, a cartoon of the 21st century, is more stereotypical than Fat Albert and the Cosby Kids, a cartoon from 30 years ago. Though primary characters display the same amount of stereotypical behavior, secondary characters show an increase in the amount of …
Freshwater And Nutrient Inputs To A Mississippi River Deltaic Estuary With River Re-Introduction, Emily Christina Grace Hyfield
Freshwater And Nutrient Inputs To A Mississippi River Deltaic Estuary With River Re-Introduction, Emily Christina Grace Hyfield
LSU Master's Theses
In this study, I quantified freshwater and nutrient inputs in the Breton Sound estuary which is receiving freshwater reintroduction in an effort to restore deteriorating wetlands. Almost all wetlands of the Mississippi deltaic plain are isolated from riverine input due to flood control levees along the Mississippi River. This has altered water and nutrient budgets and is a primary cause of the massive wetland loss in the delta. Maintenance of the delta depends on a healthy, functioning ecosystem which includes riverine input. The Breton Sound estuary is located southeast of New Orleans and until recently was hydrologically isolated from direct …
Tissue Interactions With Lasers And Liquid Nitrogen: A Novel Cryopreservation Method, Deepak Kandra
Tissue Interactions With Lasers And Liquid Nitrogen: A Novel Cryopreservation Method, Deepak Kandra
LSU Master's Theses
The importance of the imposed cooling rate in cryopreserving native cells and tissues has been long recognized in the field of cryobiology. When biological tissues are subjected to cooling rates in excess of thousands of degree C per minute, the characteristic structural and physical manifestations of the ice formed are such that the traditional damage due to ice formation at lower cooling rates are suppressed. Hence, achieving high cooling rates in tissues and cells of biologically relevant sizes (mm’s and cm’s) has been a long standing research problem. In the present study, we present a novel technique to achieve high …
Characteristics Of Hurricane Lili's Intensity Changes, Adele Marie Babin
Characteristics Of Hurricane Lili's Intensity Changes, Adele Marie Babin
LSU Master's Theses
Rapid intensity changes of Hurricane Lili in the Gulf of Mexico (GOM) were studied in three distinct ways: climatology, satellite remote sensing, and surface meteorological and oceanographic measurements. Each research methodology provided insight about Hurricane Lili's intensity behavior. A climatology of rapid and explosive intensifications of hurricanes was developed using minimum central pressure observations for the Atlantic tropical cyclone record. Results showed these events were frequent, especially in the GOM. The majority of intensification events occurred ≤ 24 h before landfall, with a third to one-half ≤ 12 h. Lili emerged anomalous as the only hurricane to weaken at a …
Elemental: Promise Of Plenty, Bill Wolff
Elemental: Promise Of Plenty, Bill Wolff
LSU Master's Theses
This body of work is about human nature, and centers on issues of aggression, consumption and collapse. Five materials make up the exhibition, and each carries a specific metaphor: wood is flesh, brick represents collective history, rope is a metaphor for human activity, metal is control and salt is a quintessential commodity. Craft is used as a means to explore the boundary between natural and synthetic phenomena, as well as elevating the status of the base materials. The work is arranged to provide an environment and context for the viewer to respond.
Assessing Landscape-Level Impacts Of Red Imported Fire Ants On Native Faunal Communities In Pine-Dominated Forests, Keri Elizabeth Landry
Assessing Landscape-Level Impacts Of Red Imported Fire Ants On Native Faunal Communities In Pine-Dominated Forests, Keri Elizabeth Landry
LSU Master's Theses
Since the accidental introduction of red imported fire ants (Solenopsis invicta Buren, RIFA) into Mobile, Alabama in the 1930’s, the invasion of this species into other areas across the southeast has increased drastically. RIFA have been implicated in the disruption of ecosystems and decreases in biodiversity. Most research on effects of RIFA on vertebrates and invertebrates have focused on small spatial scales and single species. I examined established populations of RIFA in relation to native ground-dwelling arthropods and small mammal communities in longleaf-pine and pine-hardwood forests. I evaluated the efficacy of using Amdro® to control RIFA and determined the effect …
Towards Automation Of Forensic Facial Reconstruction, Hemant Narendra Khatod
Towards Automation Of Forensic Facial Reconstruction, Hemant Narendra Khatod
LSU Master's Theses
Forensic facial reconstruction is a blend of art and science thus computerizing the process leads to numerous solutions. However, complete automation remains a challenge. This research concentrates on automating the first phase of forensic facial reconstruction which is automatic landmark detection by model fitting and extraction of feature points. Detection of landmarks is a challenging task since the skull orientation in a 3D scanned data cloud is generally arbitrary and unknown. To address the issue, well defined skull and mandible models with known geometric structure, features and orientation are (1) aligned and (2) fit to the scanned data. After model …
Irrationality And Human Reasoning, Michael Aristidou
Irrationality And Human Reasoning, Michael Aristidou
LSU Master's Theses
In his account of intentional interpretation, Donald Davidson assumes that people are mostly rational. Several psychological experiments though, reveal that human beings deviate drastically from the normative standards of rationality. Therefore, some psychologists arrive to the conclusion that humans are mostly irrational. In this thesis, I raise some objections to both points of view. On the one hand, ascribing rationality to humans in an a priori manner seems a suspicious position to adopt, considering the empirical data that show otherwise. On the other hand, the validity of the experiments and what exactly they test can also be put in question, …
Numerical And Experimental Investigation Of Transport Processes In Biological Systems, Yimeng He
Numerical And Experimental Investigation Of Transport Processes In Biological Systems, Yimeng He
LSU Master's Theses
This thesis focuses on optimization techniques for transport process during the cryopreservation of biological systems. In the first part of this thesis, a well established shape independent Differential Scanning Calorimeter (DSC) technique was used to measure the dehydration response during freezing of Pacific oyster sperm cells. Volumetric shrinkage during freezing of diploid and tetraploid pacific oyster sperm cell suspensions was obtained at cooling rates of 5 and 20 ˚C/min in the presence of extracellular ice and CPAs. By fitting a model of water transport to the experimentally obtained volumetric shrinkage data the best fit membrane permeability parameters (Lpg and …
Which Mean Do You Mean?: An Exposition On Means, Mabrouck K. Faradj
Which Mean Do You Mean?: An Exposition On Means, Mabrouck K. Faradj
LSU Master's Theses
The objective of this thesis is to give a brief exposition on the theory of means. In Greek mathematics, means are intermediate values between two extremes, while in modern mathematics, a mean is a measure of the central tendency for a set of numbers. We begin by exploring the origin of the antique means and list the classical means. Next, we present an overview of the theories of binary means and n-ary means. We include a general discussion on axiomatic systems for means and present theorems on properties that characterize the most common types of means.
Innovative Cooling Configurations For Low Emission Gas Turbine Combustors, Ryan Thomas Hebert
Innovative Cooling Configurations For Low Emission Gas Turbine Combustors, Ryan Thomas Hebert
LSU Master's Theses
Presently, effective cooling of modern low NOx combustor liners is achieved through combinations of innovative impingement configurations and other heat transfer enhancement methods. An inherent characteristic of conventional impingement configurations is the occurrence of downstream heat transfer degradation due to increased crossflow effects. In the present study, two different impingement configurations are studied. Both impingement configurations examined in this study aim to increase heat transfer effectiveness by reducing the detrimental effects of spent air crossflow. In Part I, a combination technique wherein impingement is combined with ribs placed in between impingement rows is studied. Three configurations with increased rib placements …
Probabilistic Risk Assessment Method For Prioritization Of Risk Factors, Jay Tarakkumar Shah
Probabilistic Risk Assessment Method For Prioritization Of Risk Factors, Jay Tarakkumar Shah
LSU Master's Theses
Risk management involves assessing the risk sources and designing strategies and procedures to mitigate those risks to an acceptable level. Measurement of risk factors plays an important role in the assessment of risk. This research proposes to develop risk assessment frameworks and mathematical model (Probabilistic Risk Assessment model) identify the risk factors. Quantification and prioritization of risk factors will help to design controls, resource allocation policies and minimize the total cost using the Cost Minimization model. The proposed models are applied to a complex system that is representative of actual business situations.
Microsatellite Instability In Squamous Cell Carcinoma And Lichen Sclerosus Of The Vulva, Sidney Joseph Marlborough
Microsatellite Instability In Squamous Cell Carcinoma And Lichen Sclerosus Of The Vulva, Sidney Joseph Marlborough
LSU Master's Theses
The usefulness of detecting genomic instability in the form of microsatellite instability (MSI) has been examined in a number of cancers. Squamous cell carcinoma (SCC) and adjacent normal and lichen sclerosis (LS) samples were taken from patients with radical vulvectomies. Vulvar SCC samples were compared with adjacent normal samples using four oligonucleotide markers (BAT-25, BAT-26, D10S208 and D10S587) found to be informative with other carcinomas. Using polymerase chain reaction techniques, 30 vulvar SCC DNA samples were examined for MSI. BAT-26 displayed the highest level of MSI and was considered to be the most sensitive marker in studying vulvar SCC. There …
An Analysis Of Cardiovascular And Respiratory Mortality As A Function Of Ambient Ozone And Fine Particulate Matter In The Baton Rouge Air Quality Control Region, Thomas James Wiley Iv
An Analysis Of Cardiovascular And Respiratory Mortality As A Function Of Ambient Ozone And Fine Particulate Matter In The Baton Rouge Air Quality Control Region, Thomas James Wiley Iv
LSU Master's Theses
The Baton Rouge Air Quality Control Region has come under fire due to difficulties in reaching attainment of one-hour daily ozone limitations and its general perception as being a polluted place to live. Ozone is a reactive oxygen species which has been shown to result in damage to biological molecules and is detrimental to human physiology, especially in regards to cardio-respiratory structure and function. In the last decade, fine particulate matter less than 2.5 microns in mean aerodynamic diameter have been identified as a possible pollutant that is affecting public health at levels lower than the EPA’s established limits. PM2.5 …
Effects Of Redox Potential And Ph On The Fate Of Nitroglycerin In A Surface And Aquifer Soil, Sally Yost
Effects Of Redox Potential And Ph On The Fate Of Nitroglycerin In A Surface And Aquifer Soil, Sally Yost
LSU Master's Theses
Nitroglycerin, used in propellant formulations and ignition cartridges in military weapons, has been found as a surface soil contaminant on military installations. Concerns have arisen since the fate and mobility of nitroglycerin is not understood in these natural environments. The objective of this study was to determine the fate of nitroglycerin in natural field soils. Nitroglycerin degradation was examined using a surface soil and an aquifer soil under aerobic and anaerobic conditions at three pH levels. Studies were also performed to determine the influence of a supplemental carbon source on degradation. Radiolabeled 14C-nitroglycerin was used to trace the partitioning between …
Scalability Of Car-Following And Lane-Changing Models In Microscopic Traffic Simulation Systems, Yan Zhang
Scalability Of Car-Following And Lane-Changing Models In Microscopic Traffic Simulation Systems, Yan Zhang
LSU Master's Theses
Microscopic simulation models are more and more widely used to support real-time control and management functions in the field of transportation engineering. However, even with today¡¯s advancement in computing power, microscopic simulation modeling remains a computationally intensive process that imposes limitations on its potential use for modeling large-scale transportation networks. While microscopic features of a simulated system collectively define the overall system characteristics, it is argued here that the simulation process itself is not necessarily free of redundancy which, if reduced, could substantially improve the computational efficiency of simulation processes without substantially compromising the overall integrity of the simulation process. …
Mems Accelerometer: Proof Of Concept For Geotechnical Engineering Testing, Keith Nicholas Hoffman
Mems Accelerometer: Proof Of Concept For Geotechnical Engineering Testing, Keith Nicholas Hoffman
LSU Master's Theses
Geotechnical engineering materials are inherently variable, which leads to many simplifications when trying to model their behavior. The materials must always be characterized prior to any design work so that the engineer knows which direction he must progress to have a reliable design. Although subsurface characterization techniques and geotechnical design steadily improve, they are by no means infallible. The combination of geotechnical subsurface characterization along with geophysical techniques for improved design and construction monitoring has begun to surface as a viable alternative to the standard techniques in geotechnical engineering. This is important because there is a lack of Quality Control/Quality …
Inter-An Evolving Installation, Lyman Landreth Edwards
Inter-An Evolving Installation, Lyman Landreth Edwards
LSU Master's Theses
Inter- An Evolving Installation is an interactive site specific installation designed and constructed in the School of Art Gallery at Louisiana State University. This installation explores the interplay between the ideas of order and change by presenting the visitor with a very structured environment that by nature of its design and materials changes with each footstep. Sand, granulated carbon, and clay cover the floor of the gallery in a geometric pattern inspired by the Fibonacci Sequence and Buddhist sand paintings. As a person enters the installation it immediately changes from its original design simply through disturbance by the visitor's footsteps …
Lattice Boltzmann Simulation Of Flow Around Bluff-Bodies, Kevin Tubbs
Lattice Boltzmann Simulation Of Flow Around Bluff-Bodies, Kevin Tubbs
LSU Master's Theses
In this work, results from a 2-D Lattice Boltzmann (LB) solver are presented simulating flow past rectangular square cylinders at low Reynolds numbers (< 250). The LBGK equation is a hyperbolic equation that approximates the Navier Stokes equations in the nearly incompressible limit. It is a system of 9 one dimensional partial differential Hamiltonian-Jacobian equations, consisting of an advection and diffusive portion. The LB method is an alternative computational fluid dynamics (CFD) method used to numerically predict incompressible viscous flow. The current LB method uses a statistical mechanics formulation to solve the Boltzmann equation. The LB model captures the nonlinear Navier Stokes advection terms using linear streaming operators. In this thesis, the LB model is classified as an explicit, Lagrangian, finite-hyperbolicity and weakly compressible approximation of the Navier Stokes equations. The momentum flux tensor is captured locally as opposed to a pressure field eliminating the need to solve the Poisson equation. This allows the fluid structure interactions (FSI) behavior to be calculated elegantly at the interface through the mesoscopic momentum transfer between the fluid and structure. At this level, the forces are simultaneously calculated. The LB equations are discretized both in time and phase space using a standard D2Q9 lattice model. Validation tests for flow around single square cylinders at different aspect ratio at low Reynolds numbers are presented. Good agreement with other investigators is achieved. Flow past multiple bluff bodies (representing building in a city) is also presented. The vortex shedding simulations presented provide preliminary indications in terms of St that the LB method can be used to simulate high Re flow.
Comparison Studies Of The Mechanistic Formation Of Polyhalogentaed Dibenzo-P-Dioxins And Furans From The Thermal Degradation Of 2-Bromophenol And 2-Chlorophenol, Catherine Spearing Evans
Comparison Studies Of The Mechanistic Formation Of Polyhalogentaed Dibenzo-P-Dioxins And Furans From The Thermal Degradation Of 2-Bromophenol And 2-Chlorophenol, Catherine Spearing Evans
LSU Doctoral Dissertations
Emissions of polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) and polybrominated dibenzo-p-dioxins and furans (PBDD/Fs) from hazardous waste incinerators, and many other sources for combustion have been considered environmentally hazardous and a major health threat. Recently, a growing number of materials containing brominated hydrocarbons, commonly used flame retardants, have been disposed in municipal and hazardous waste incinerators. This results in the increased potential for formation of PBDD/Fs and other hazardous combustion by-products. In contrast to chlorinated hydrocarbons, the reactions of brominated hydrocarbons have been studied only minimally. In fact, studies have shown that brominated phenols form higher yields of PBDD/Fs than the …
Dynamics Of Complex Polymer Solutions: Putting Diffusion To Work And Exploring Rigid Rod Diffusion, Garrett John Doucet
Dynamics Of Complex Polymer Solutions: Putting Diffusion To Work And Exploring Rigid Rod Diffusion, Garrett John Doucet
LSU Doctoral Dissertations
This dissertation is concerned with random coil and rodlike polymer diffusion in complex solutions. The development of fluorescence photobleaching recovery, FPR, as a technique to determine polymer molecular weight distributions by measuring the diffusion distribution and converting it to a molecular weight distribution using a calibration curve is first covered. Fluorescently tagged probes were individually dissolved in polymer solutions at negligible amounts and measured with FPR to construct the calibration curve of self-diffusion vs. molecular weight. Once calibration curves were constructed, bimodal distributions were separated using the matrices corresponding to the calibration curves. The diffusion of the probes and separation …
Asymptotic Laplace Transforms, Claudiu Mihai
Asymptotic Laplace Transforms, Claudiu Mihai
LSU Doctoral Dissertations
In this work we discuss certain aspects of the classical Laplace theory that are relevant for an entirely analytic approach to justify Heaviside's operational calculus methods. The approach explored here suggests an interpretation of the Heaviside operator ${cdot}$ based on the "Asymptotic Laplace Transform." The asymptotic approach presented here is based on recent work by G. Lumer and F. Neubrander on the subject. In particular, we investigate the two competing definitions of the asymptotic Laplace transform used in their works, and add a third one which we suggest is more natural and convenient than the earlier ones given. We compute …
Synthesis, Separation And Reactivities Of Multidentate Phosphine Ligands And Investigation Into Dirhodium Hydroformylation And Hydrocarboxylation Catalysis, David Aubry
LSU Doctoral Dissertations
A dirhodium homogeneous hydroformylation catalyst based on a tetraphosphine ligand, rac-Et2PCH2CH2P(Ph)CH2P(Ph)CH2CH2PEt2, rac-et,ph-P4, is under investigation. The ligand synthesis produces a racemic mixture and a facile and efficient method of separation of the racemic and meso diastereomers was achieved through reaction of et,ph-P4 with two equivalents of NiCl2 in EtOH to yield an almost quantitatively isolable precipitate of meso-Ni2Cl4(et,ph-P4) and the soluble rac-Ni2Cl4(et,ph-P4). Subsequent cyanolysis of these complexes liberates the et,ph-P4 ligand, and the …