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Supercritical Fluid Extraction Of Rice Bran With Adsorption On Rice Hull Ash, Paresh Manilal Patel
Supercritical Fluid Extraction Of Rice Bran With Adsorption On Rice Hull Ash, Paresh Manilal Patel
LSU Doctoral Dissertations
Rice bran oil was extracted using environmentally-friendly supercritical carbon dioxide at varying conditions. Experimental treatments included pressure (27.6, 41.4 and 55.2 MPa), temperature (40 and 60 oC) and flow rates (25, 45 and 65 g/min) of supercritical carbon dioxide. Extracts collected at different time intervals during 4-hour extraction runs in a 3-L extractor were analyzed for oil yield and antioxidants. Normal-phase HPLC was used for analyzing the extract for important antioxidant compounds of oryzanol, tocopherols, tocotrienols. Silica rich rice hull ash adsorbent was also incorporated in combined extraction-adsorption experiments under similar supercritical fluid conditions. Supercritical extraction yields of rice bran …
On The Stability Of Rotor Bearing Systems Based On Hopf Bifurcation Theory, Jianke Wang
On The Stability Of Rotor Bearing Systems Based On Hopf Bifurcation Theory, Jianke Wang
LSU Doctoral Dissertations
This research is aimed to establish instability criteria for a rotor-bearing system which consists of a rotor supported by two fluid-film journal bearings. The static and dynamic characteristics of rotor-bearing systems with consideration of turbulent effects are evaluated by applying the Hopf bifurcation theory (HBT) to the equations of motion. A method is developed for predicting the stability envelope of rotor-bearing systems using HBT. Results are compared with published literature obtained using a trial-and-error method. A method based on HBT is presented for predicting the occurrence of a hysteresis phenomenon, which is observed in experimental results dealing with the instability …
Detection Of Biologically Important Molecules, Kyukwang Kim
Detection Of Biologically Important Molecules, Kyukwang Kim
LSU Doctoral Dissertations
Anions play important roles in biological systems. The design of anion sensors has been of great interest. The selective detection of a specific anion is particularly challenging. In the first chapter, I describe the synthesis of a TBS-protected fluorescein dye (1.1) and its use for the selective detection of fluoride. Solutions of 1.1 either in DCM or in aqueous media at physiological pH show the excellent selectivity towards fluoride to afford color formation while solutions of other interfering anions remain colorless. The monitoring of homocysteine (Hcy) and cysteine (Cys) levels is important since they are biomarkers associated with Alzheimer’s and …
Stability In Dynamical Polysystems, George Cazacu
Stability In Dynamical Polysystems, George Cazacu
LSU Doctoral Dissertations
A dynamical polysystem consists of a family of continuous dynamical systems, all acting on a given metric space. The first chapter of the present thesis shows a generalization of control systems via dynamical polysystems and establishes the equivalence of the two notions under certain lipschitz condition on the function defining the dynamics. The remaining chapters are focused on a basic theory of dynamical polysystems. Some topological properties of limit sets are described in Chapter 2. Chapters 3 and 4 provide characterizations for various notions of strong stability. Chapter 5 makes use of the theory of closed relations to study Lyapunov …
Macroinvertebrate Community Of Ecology Of Lowland, Subtropical Streams In Louisiana, Michael Douglas Kaller
Macroinvertebrate Community Of Ecology Of Lowland, Subtropical Streams In Louisiana, Michael Douglas Kaller
LSU Doctoral Dissertations
Freshwater ecosystems, particularly streams and rivers, have been the subject of prodigious research. Unfortunately, in comparison to neighboring regions, the Gulf of Mexico coastal plain has not received as much attention. Therefore, I collected data on the macroinvertebrates of these streams to begin the understanding of the relationships between community structure and environmental characteristics. In contrast to the hypothesized ancestral streams of these macroinvertebrates, coastal plain streams are commonly devoid of rocks leaving only woody debris as usable hard substrates and are typically lower in dissolved oxygen. I examined habitat selection by colonization of woody debris with large and small …
Effects Of Body Size On Goose Behavior: Lesser Snow Goose And Ross's Goose, Jon Einar Jonsson
Effects Of Body Size On Goose Behavior: Lesser Snow Goose And Ross's Goose, Jon Einar Jonsson
LSU Doctoral Dissertations
Body size is highly variable among geese, both at intra- and interspecific levels. Interspecific variation in several behaviors has been attributed to differences in body size in geese: incubation constancy, tendency to maintain family units, and time spent foraging. Body size has important physiological implications for birds, mostly because mass-specific metabolic rate is greater for birds of smaller mass. The Body-size Hypothesis predicts that smaller species deplete their energy reserves at relatively faster rates than do larger species. Hypotheses and conclusions concerning effects of body size on waterfowl behavior often are based on comparisons of species that confront different climates, …
Active Security Mechanisms For Wireless Sensor Networks And Energy Optimization For Passive Security Routing, Lydia Ray
LSU Doctoral Dissertations
Wireless sensor networks consisting of numerous tiny low power autonomous sensor nodes provide us with the remarkable ability to remotely view and interact with the previously unobservable physical world. However, incorporating computation intensive security measures in sensor networks with limited resources is a challenging research issue. The objective of our thesis is to explore different security aspects of sensor networks and provide novel solutions for significant problems. We classify security mechanisms into two categories - active category and passive category. The problem of providing a secure communication infrastructure among randomly deployed sensor nodes requires active security measurements. Key pre-distribution is …
Host-Parasite Cophylogeny And Rates Of Evolution In Two Rodent-Louse Assemblages, Jessica E. Light
Host-Parasite Cophylogeny And Rates Of Evolution In Two Rodent-Louse Assemblages, Jessica E. Light
LSU Doctoral Dissertations
Studies of cophylogeny greatly increase understanding of associations between hosts and their parasites. This study uses molecular data to test the hypothesis that members of two rodent families (Geomyidae and Heteromyidae) and their associated lice (Geomydoecus and Fahrenholzia, respectively) show a statistically significant pattern of cophylogeny. Both host groups are generally solitary organisms and both louse groups are obligate ectoparasites, often exhibiting extreme degrees of host specificity. This intimate and potentially long-term association likely has resulted in coevolutionary adaptations and counter adaptations on the part of both symbiotic partners. Phylogenetic analysis of chewing lice (Geomydoecus) reveals two major clades corresponding …
Zeta Functions Of Finite Graphs, Debra Czarneski
Zeta Functions Of Finite Graphs, Debra Czarneski
LSU Doctoral Dissertations
Ihara introduced the zeta function of a finite graph in 1966 in the context of p-adic matrix groups. The idea was generalized to all finite graphs in 1989 by Hashimoto. We will introduce the zeta function from both perspectives and show the equivalence of both forms. We will discuss several properties of finite graphs that are determined by the zeta function and show by counterexample several properties of finite graphs that are not determined by the zeta function. We will also discuss the relationship between the zeta function of a finite graph and the spectrum of a finite graph.
The Genetics Of Speciation By Reinforcement, Daniel Ortiz-Barrientos
The Genetics Of Speciation By Reinforcement, Daniel Ortiz-Barrientos
LSU Doctoral Dissertations
Reinforcement occurs when natural selection strengthens behavioral discrimination to prevent costly interpopulation matings, such as when matings produce sterile hybrids. This evolutionary process can complete speciation, thereby providing a direct link between Darwin’s theory of natural selection and the origin of new species. My dissertation presents the first study on the genetics of reinforcement. This study is framed in a conceptual body that explains how genomic architecture, selection and recombination, interact to facilitate divergence in the presence of gene flow. In addition, in my dissertation I produced a dense recombination map for D. pseudoobscura, which together with the genome sequence …
Aspects Of The Life History, Ecophysiology, Bioenergetics, And Population Dynamics Of The Cownose Ray, Rhinoptera Bonasus, In The Northern Gulf Of Mexico, Julie Ann Neer
LSU Doctoral Dissertations
The cownose ray, Rhinoptera bonasus, is an elasmobranch commonly observed throughout the Gulf of Mexico. Cownose rays appear to be sensitive to water temperature. I performed laboratory experiments and collected field data to obtain basic life history information, and used the information to configure an individual-based bioenergetics model. The bioenergetics model was coupled to a matrix projection model, and the coupled models were used to predict how warmer and cooler water temperatures, compared to current conditions, would affect the growth and population dynamics of the cownose rays. The life history study determined weight at age, maturity by weight, and fecundity …
A Case Study Inquiry Into The Relative Impact Of Balanced Reading Instruction On Hispanic Students In A Highly Culturally Diverse Elementary School, Rita Ramirez
LSU Doctoral Dissertations
This research explores the relative impact of Balanced Reading instruction upon Hispanic students in a highly culturally diverse elementary school. This case study inquiry focuses on Hispanic students learning to read in English in kindergarten, first and third grade, how these Hispanic students are affected by the classroom setting within the context of the Balanced Reading instructional framework of each respective grade, and what are the similarities and differences in the learning methodologies and strategies that impact the learning curve of these Hispanic students. The researcher collects qualitative data to determine the methods and strategies found to be most effective …
The Stable Isotope Stratigraphy And Paleosols Of North America's Most Southern Exposure Of Late Paleocene/Early Eocene Fossiliferous Continental Deposits: Documenting The Initial Eocene Thermal Maximum In Big Bend National Park, Texas, Paul David White
LSU Doctoral Dissertations
A chemostratigraphic section across the Paleocene/Eocene boundary, using the stable isotopes of carbon and oxygen, has been developed for North America's most southern exposure of early Paleogene continental deposits in which the boundary is constrained by fossil mammals. A negative carbon excursion has been identified within C24r. The range in d13C values is from -8.1 to -13.2‰. Until the development of the chemostratigraphic section it was uncertain if the earliest Eocene was recorded in Big Bend. An early Wasatchian (Wa1) fossil site occurs stratigraphically higher than the carbon excursion and has yielded the stratigraphically lowest Hyracotherium in the …
Synthesis, Characterization And Application Of Polymeric Surfactants In Micellar Electrokinetic Chromatography: Use Of Ionic Liquids As Modifiers, Simon M. Mwongela
Synthesis, Characterization And Application Of Polymeric Surfactants In Micellar Electrokinetic Chromatography: Use Of Ionic Liquids As Modifiers, Simon M. Mwongela
LSU Doctoral Dissertations
The goal of the research presented in this dissertation is to synthesize, characterize, and apply a novel chiral amino acid-based surfactant and achiral sulfate-based surfactants for the effective separations of chiral and achiral compounds in micellar electrokinetic chromatography (MEKC). The first part of this research involves novel synthesis, characterization, and application of polysodium oleyl-L-leucyl-valinate (poly-L-SOLV) for the separation of chiral compounds in MEKC. Surface tensiometry, proton nuclear magnetic resonance, infrared spectroscopy, densitometry and analytical ultracentrifugation were used as the characterization techniques. Optimal MEKC separating conditions were established by varying surfactant concentration, buffer concentration and pH, applied voltage, and capillary temperature. …
Dynamical Systems With Time Delay, Norma Ortiz
Dynamical Systems With Time Delay, Norma Ortiz
LSU Doctoral Dissertations
In this dissertation, we study necessary conditions and weak invariance properties of dynamical systems with time delay. A number of results have been obtained recently that refine necessary conditions of optimal solutions for nonsmooth dynamical systems without time delay. In this dissertation, we examine the extension of some of these results to problems with time delay. In particular, we study the generalized problem of Bolza with the addition of delay in the state and velocity variables and refer to this problem as the Neutral Problem of Bolza. We consider the relationship between the generalized problem of Bolza with time delay …
Power And Memory Optimization Techniques In Embedded Systems Design, Atef Khalil Allam
Power And Memory Optimization Techniques In Embedded Systems Design, Atef Khalil Allam
LSU Doctoral Dissertations
Embedded systems incur tight constraints on power consumption and memory (which impacts size) in addition to other constraints such as weight and cost. This dissertation addresses two key factors in embedded system design, namely minimization of power consumption and memory requirement. The first part of this dissertation considers the problem of optimizing power consumption (peak power as well as average power) in high-level synthesis (HLS). The second part deals with memory usage optimization mainly targeting a restricted class of computations expressed as loops accessing large data arrays that arises in scientific computing such as the coupled cluster and configuration interaction …
Ecotoxicology Of Metal-Hydrocarbon Mixtures In Benthic Invertebrates, Kurt A. Gust
Ecotoxicology Of Metal-Hydrocarbon Mixtures In Benthic Invertebrates, Kurt A. Gust
LSU Doctoral Dissertations
Metal-hydrocarbon mixtures are becoming increasingly prevalent in natural environments due to expanding industrial activity and urbanization. The ecotoxicology of metal-hydrocarbon mixtures in benthic environments is of particular concern because both classes of contaminants partition to sediments and can thereby exert toxic effects in benthic organisms. Mixtures of dissimilar chemicals (including metals and hydrocarbons) are broadly hypothesized to elicit independent toxic effects however; this hypothesis has little supporting data. The purpose of this dissertation was to test this hypothesis for metal-hydrocarbon mixtures using environmentally relevant exposures and to determine mechanisms for observed interactive effects. Sediment and water-only bioassays were conducted employing …
Broadcast In Sparse Conversion Optical Networks Using Fewest Converters, Tong Yi
Broadcast In Sparse Conversion Optical Networks Using Fewest Converters, Tong Yi
LSU Doctoral Dissertations
Wavelengths and converters are shared by communication requests in optical networks. When a message goes through a node without a converter, the outgoing wavelength must be the same as the incoming one. This constraint can be removed if the node uses a converter. Hence, the usage of converters increases the utilization of wavelengths and allows more communication requests to succeed. Since converters are expensive, we consider sparse conversion networks, where only some specified nodes have converters. Moreover, since the usage of converters induces delays, we should minimize the use of available converters. The Converters Usage Problem (CUP) is to use …
Dragos Tanasescu's Treaties Of Pianistic Technique, Lucian B. Zidaru
Dragos Tanasescu's Treaties Of Pianistic Technique, Lucian B. Zidaru
LSU Doctoral Dissertations
This study examines Dragos Tanasescu's fingering system and technical exercises presented in Treatise of Pianistic Technique. The Treatise contains four books, each one dedicated to a segment of technical problems. Tanasescu's main contribution to the piano technique is the applications of math permutation formulas to create all possible arrangements of fingering patterns. His treatise continues previous technical approaches of A. Kullak, F. Liszt, J. Pischna and E. Dohnanyi. Earlier methods organize the technical material by one principle: fingerings. The purpose of this study is to illustrate the characteristics of Tanasescu's fingering system presented in Treatise of Pianistic Technique, and provide …
Separation And In Situ Catalytic Testing Of A Dirhodium Tetraphosphine Catalyst, Bobby Lloyd Barker
Separation And In Situ Catalytic Testing Of A Dirhodium Tetraphosphine Catalyst, Bobby Lloyd Barker
LSU Doctoral Dissertations
Attempts to study the asymmetric hydroformylation abilities of [rac-Rh2(nbd)2(et,ph-P4)](BF4)2 were made through the separation of the enantiomers of et,ph-P4 using a chiral HPLC column. Efforts were also made to optimize the NiCl2 separation chemistry for the methyl analogue of et,ph-P4 for use in asymmetric hydroformylation. A study of hydroformylation of olefins using [rac-Rh2(nbd)2(et,ph-P4)](BF4)2 in ionic liquids was also performed, leading directly to the important (and unexpected) effect of increased hydrogen pressure on [rac-Rh2(nbd)2(et,ph-P4)](BF4)2 in the acetone/water system to …
Synthetic Development And Application Of Compounds With Biological Relevance, Jeffery Caleb Clark
Synthetic Development And Application Of Compounds With Biological Relevance, Jeffery Caleb Clark
LSU Doctoral Dissertations
Nature has provided a vast number of compounds that have medicinal application. The use of these compounds provided by nature however, is limited by the amount of a specific compound that nature provides. The synthesis of these molecules and their derivatives provides an even greater number of compounds for biological screening. Various pyrroles, the heterocyclic building blocks of porphyrins, can be prepared synthetically over several steps. The implementation of carboranes on pyrrole rings intrinsically provides substrates that can be converted into porphyrins bearing carborane substituents. The condensation of these carboranylpyrroles with carboranylaldehydes provides carboranylporphyrins bearing a higher order of carborane …
Capillary And Microchip Gel Electrophoresis Using Multiplexed Fluorescence Detection With Both Time-Resolved And Spectral-Discrimination Capabilities: Applications In Dna Sequencing Using Near-Infrared Fluorescence, Li Zhu
LSU Doctoral Dissertations
Increasing the information content obtainable from a single assay and system miniaturization has continued to be important research areas in analytical chemistry. The research presented in this dissertation involves the development of a two-color, time-resolved fluorescence microscope for the acquisition of both steady-state and time-resolved data during capillary and microchip electrophoresis. The utility of this hybrid fluorescence detector has been demonstrated by applying it to DNA sequencing applications. Coupling color discrimination with time-resolved fluorescence offers increased multiplexing capabilities because the lifetime data adds another layer of information. An optical fiber-based fluorescence microscope was constructed, which utilized fluorescence in near-IR region, …
The Effectiveness Of Student Support Services At A Research Extensive University In The South, Eric Lyle Penalber
The Effectiveness Of Student Support Services At A Research Extensive University In The South, Eric Lyle Penalber
LSU Doctoral Dissertations
The primary purpose of this study was to determine the influence of level of participation in services provided by the Student Support Services (SSS) Program on the grade point average, retention, and the six-year graduation rate of first-time entering freshmen who also entered the SSS program at a research extensive university in the South. Participants in the study were one hundred, fifty-two (152) SSS students who entered this university in the fall of 1996 and fall of 1997. Tinto’s (1987) longitudinal model of institutional departure was used as the conceptual framework for this study. Services provided by the SSS program …
Physically Based Multiscale-Viscoplastic Model For Metals And Steel Alloys: Theory And Computation, Farid H. Abed
Physically Based Multiscale-Viscoplastic Model For Metals And Steel Alloys: Theory And Computation, Farid H. Abed
LSU Doctoral Dissertations
The main requirement of large deformation problems such as high-speed machining, impact, and various primarily metal forming, is to develop constitutive relations which are widely applicable and capable of accounting for complex paths of deformation. Achieving such desirable goals for material like metals and steel alloys involves a comprehensive study of their microstructures and experimental observations under different loading conditions. In general, metal structures display a strong rate- and temperature-dependence when deformed non-uniformly into the inelastic range. This effect has important implications for an increasing number of applications in structural and engineering mechanics. The mechanical behavior of these applications cannot …
Automatic Segmentation Of Magnetic Resonance Images Of The Brain, Kirk V. N. Spence
Automatic Segmentation Of Magnetic Resonance Images Of The Brain, Kirk V. N. Spence
LSU Doctoral Dissertations
Magnetic resonance imaging (MRI) is a technique used primarily in medical settings to produce high quality images of the human body’s internal anatomy. Each image is of a thin slice through the body, with the typical distance between slices being a few millimeters. Brain segmentation is the delineation of one or more anatomical structures within images of the brain. It promotes greater understanding of spatial relationships to aid in such tasks as surgical planning and clinical diagnoses, particularly when the segmented outlines from each image slice are displayed together as a surface in three-dimensions. A review of the literature indicates …
Synthesis Of Symmetric And Asymmetric Water-Soluble Porphyrin Derivatives, Caroline Owendi Ongayi
Synthesis Of Symmetric And Asymmetric Water-Soluble Porphyrin Derivatives, Caroline Owendi Ongayi
LSU Doctoral Dissertations
Novel symmetric and asymmetric water-soluble tetrabenzoporphyrin are synthesized in relatively good yields. These compounds are synthesized by the condensation of butanopyrrole with several aldehydes that contain masked water solubilizing groups followed by metal insertion, oxidation and demetallation and deprotection of the masked solubilizing groups. The biological evaluation (in vitro and in vivo) studies are described in addition to the photophysical evaluations of the corresponding compounds. A novel versatile route to the syntheses of novel free-bases and metallo-benzoylbiliverdin is discussed. The treatment of metal free-dodecasubstituted porphyrin with sodium nitrite and trifluoroacetic acid at room temperature in the presence of oxygen affords …
Infrared And X-Ray Spectroscopic Studies Of The Copper(Ii) Oxide Mediated Reactions Of Chlorinated Aromatic Precursors To Pcdd/F, Steven L. Alderman
Infrared And X-Ray Spectroscopic Studies Of The Copper(Ii) Oxide Mediated Reactions Of Chlorinated Aromatic Precursors To Pcdd/F, Steven L. Alderman
LSU Doctoral Dissertations
Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) are toxic compounds produced in combustion systems such as incinerators, and their emissions are an important environmental issue. Chlorinated phenols and benzenes form PCDD/F through heterogeneous reactions following adsorption onto fly-ash surfaces. Current research implicates transition metals in promoting formation of phenoxyl radicals that react to form PCDD/F, although this has not been studied extensively. This objective of this work is to better understand PCDD/F formation from chlorinated aromatic precursors. Using 2 chlorophenol as a model PCDD/F precursor and silica as a fly-ash surrogate, time-dependent chemisorption of 2 chlorophenol onto silica was studied in situ …
Techniques For Low Power Analog, Digital And Mixed Signal Cmos Integrated Circuit Design, Chuang Zhang
Techniques For Low Power Analog, Digital And Mixed Signal Cmos Integrated Circuit Design, Chuang Zhang
LSU Doctoral Dissertations
With the continuously expanding of market for portable devices such as wireless communication devices, portable computers, consumer electronics and implantable medical devices, low power is becoming increasingly important in integrated circuits. The low power design can increase operation time and/or utilize a smaller size and lighter-weight battery. In this dissertation, several low power complementary metal-oxide-semiconductor (CMOS) integrated circuit design techniques are investigated. A metal-oxide-semiconductor field effect transistor (MOSFET) can be operated at a lower voltage by forward-biasing the source-substrate junction. This approach has been investigated in detail and used to designing an ultra-low power CMOS operational amplifier for operation at …
Denitrification And Greenhouse Gas Emissions From Cultivated And Wetland Alluvial Soils, Sami Ullah
Denitrification And Greenhouse Gas Emissions From Cultivated And Wetland Alluvial Soils, Sami Ullah
LSU Doctoral Dissertations
Agricultural development in the Mississippi River Basin has contributed to an 3-fold increase in NO3 loading of the river. Increased NO3 loading is a primary cause of eutrophication in the northern Gulf of Mexico. Identification of best management practices (BMPs) to reduce NO3 loss and wetlands restoration to remove NO3 through denitrification are critically needed. The objectives of this research were to determine factors controlling denitrification potential of different landscape units in an agricultural watershed and quantify the effects of BMPs and organic C amendments on denitrification rates of cultivated lands and restored forested wetlands. N2O, CH4 and CO2 emissions …
Measurement And Modeling Of Fluid-Fluid Miscibility In Multicomponent Hydrocarbon Systems, Subhash C. Ayirala
Measurement And Modeling Of Fluid-Fluid Miscibility In Multicomponent Hydrocarbon Systems, Subhash C. Ayirala
LSU Doctoral Dissertations
Carbon dioxide injection has currently become a major gas injection process for improved oil recovery. Laboratory evaluations of gas-oil miscibility conditions play an important role in process design and economic success of field miscible gas injection projects. Hence, this study involves the measurement and modeling of fluid-fluid miscibility in multicomponent hydrocarbon systems. A promising new vanishing interfacial tension (VIT) experimental technique has been further explored to determine fluid-fluid miscibility. Interfacial tension measurements have been carried out in three different fluid systems of known phase behavior characteristics using pendent drop shape analysis and capillary rise techniques. The quantities of fluids in …