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A Distribution Kinetics Approach For Polymer Crystallization And Phase Separation, Jiao Yang
A Distribution Kinetics Approach For Polymer Crystallization And Phase Separation, Jiao Yang
LSU Doctoral Dissertations
The mechanism of polymer crystallization is extensively studied and still far away from consensus. This research adopted cluster size distribution kinetics approach to explore the kinetics of polymer crystallization and phase separation within spinodal region. The kinetics of polymer crystallization is studied by integrating nucleation, crystal growth and ripening. Population balance equations based on crystal size distribution and concentration of amorphous polymer segments are solved numerically and the related differential moment equations are also solved. The model accounts for nucleation and crystal growth. Different mass dependences of growth and dissociation rate coefficients are proposed to investigate the fundamental features of …
Ecology Of Lesser Scaup Amphipods In The Upper-Midwest: Scope And Mechanisms Of The Spring Condition Hypothesis And Implications For Migration Habitat Conservation, Michael Jason Anteau
Ecology Of Lesser Scaup Amphipods In The Upper-Midwest: Scope And Mechanisms Of The Spring Condition Hypothesis And Implications For Migration Habitat Conservation, Michael Jason Anteau
LSU Doctoral Dissertations
I tested the scope of the Spring Condition Hypothesis in explaining the continental population decline of lesser scaup (Aythya affinis; hereafter scaup) and explored potential mechanisms affecting female body condition to assist conservation efforts for population recovery. Lipid reserves of females currently are lower than historical values during spring migration throughout Iowa, Minnesota, and North Dakota; females catabolized lipids throughout this area (indexed by concentrations of plasma-lipid metabolites, which accounted for 75% of the variation in mass change). My results indicate that a large segment of the continental scaup population likely is affected by decreased lipid reserves, which could cause …
Factors That Influence Traditional-Age, High-Achieving Students To Enroll At A Research-Extensive University In The Southern Region Of The United States, Roy Cleveland Brooks, Jr.
Factors That Influence Traditional-Age, High-Achieving Students To Enroll At A Research-Extensive University In The Southern Region Of The United States, Roy Cleveland Brooks, Jr.
LSU Doctoral Dissertations
The primary purpose of this study was to determine if a model existed that significantly increased the researcher's ability to accurately explain the enrollment status of high-achieving freshmen based on the influence of selected demographic and academic characteristics. Since World War II, the need for students to obtain an outstanding postsecondary education in order to compete for the best positions in today's job market has become increasingly important. Thus, the need exists for higher education institutions to offer competitive academic programs that will attract top students and faculty. Since the number of graduating high school students is predicted to decline …
Experimental And Computational Analysis Of Random Cylinder Packings With Applications, Wenli Zhang
Experimental And Computational Analysis Of Random Cylinder Packings With Applications, Wenli Zhang
LSU Doctoral Dissertations
Random cylinder packings are prevalent in chemical engineering applications and they can serve as prototype models of fibrous materials and/or other particulate materials. In this research, comprehensive studies on cylinder packings were carried out by computer simulations and by experiments. The computational studies made use of a collective rearrangement algorithm (based on a Monte Carlo technique) to generate different packing structures. 3D random packing limits were explored, and the packing structures were quantified by their positional ordering, orientational ordering, and the particle-particle contacts. Furthermore, the void space in the packings was expressed as a pore network, which retains topological and …
Adaptive Scalable Protocols For Heterogeneous Wireless Networks, Vamsi Krishna Paruchuri
Adaptive Scalable Protocols For Heterogeneous Wireless Networks, Vamsi Krishna Paruchuri
LSU Doctoral Dissertations
The focus of this dissertation is to propose analytical models to study the impact of collisions and interference in heterogeneous wireless networks and propose simple scalable and lightweight protocols that use these models to adapt to network conditions thus increasing efficiency, decreasing energy consumption and prolonging network lifetime. The contributions of this dissertation are multifold and are summarized as follows: - Analytical models to study the impact of collisions and interference on both broadcast and unicast messages. These analytical models are incorporated into the proposed protocols to adapt to the prevailing network conditions to improve their performance. - Optimized Flooding …
Nutrient Constraints On Plant Community Production And Organic Matter Accumulation Of Subtropical Floating Marshes, Guerry O., Jr. Holm Jr.
Nutrient Constraints On Plant Community Production And Organic Matter Accumulation Of Subtropical Floating Marshes, Guerry O., Jr. Holm Jr.
LSU Doctoral Dissertations
In the cycle of delta growth and decay, peat-forming wetlands span a time and space continuum. Later in the delta cycle, freshwater floating marshes become increasingly removed from external sediment subsidy and internal nutrient cycling controls plant productivity and organic matter accumulation. An interesting question is whether increased external nutrient loading can affect the basic processes that lead to peat formation—plant production and organic matter decomposition. I conducted several field studies to understand whether belowground organic matter accumulation and decomposition were affected with increased nutrient exposure; in addition, the plant community was monitored over three years. A laboratory soil respiration …
Spectral Analysis Of Total Suspended Solids Mixtures For Solids Composition Determination, Curtis W. Sutherland
Spectral Analysis Of Total Suspended Solids Mixtures For Solids Composition Determination, Curtis W. Sutherland
LSU Doctoral Dissertations
Total Suspended Solids (TSS) analysis provides an initial and very basic measure for study and characterization of water quality. The present tedious procedures used for the identification of different solids constituents present in TSS and for the classification or insight into the origins of those solids are time-consuming and expensive. The research reported herein investigates the use of instrumental analysis using reflectance spectra of TSS as an attractive alternative to sufficiently characterize and identify TSS in a more rapid and economical method that could be used to study TSS transport and to identity TSS points of origin. For this investigative …
Tropical Pyramids: Dung Beetle Richness, Abundance, And Biomass, Meghan Gabrielle Radtke
Tropical Pyramids: Dung Beetle Richness, Abundance, And Biomass, Meghan Gabrielle Radtke
LSU Doctoral Dissertations
Volume is a proxy for biomass in hard bodied arthropods (P < 0.0001). I constructed biomass-volume equations for Neotropical (P < 0.0001), temperate (P < 0.0001) and 12 Neotropical genera of scarabs, of which 11 were highly significant. The effect of short term (< 1 year) alcohol storage on volume was negligable. I found scarab volume on geologically old soils in the Amazon was one-third that of the geologically young Amazon (P < 0.0001). Species richness (P = 0.0002), Chao 1 (P = 0.0003), Fisher’s (P = 0.008) and Margalef indices (P = 0.0003) were greater on young soils. Menhinick (P = 0.54), Simpson (P = 0.54) and rarefied species richness (P = 0.24), which correct for sample size differences, indicated no difference in diversity. Young Amazonian soils likely support a higher volume and abundance of scarabs than old soils, but diversity across Amazonia may be similar. I compared beta-diversity of scarab communities across Amazonia. Species rank-abundance curves did not differ among sites whereas volume-abundance distributions and volume-rank abundance curves indicated a larger range of scarab sizes in Brazil than Ecuador. At local levels (<62 km), communities were similar whereas at large distances (>1750 km), they were different. Differences between Brazil and Ecuador may be explained by varied soil age and productivity. I examined the effects of tropical forest fragmentation on scarabs, comparing my results with three other studies from the same site. Among 1, 10, and 100-ha fragments and continuous forest, I found two important trends; beetle biomass and species richness increased with fragment area per sampling effort. Comparing all four studies, diversity increased with fragment size, and by my rarefaction analyses, two studies demonstrated beetle volume increased with fragment size. …
Population Boundaries And Gravitational-Wave Templates For Evolving White Dwarf Binaries, Ravi Kumar Kopparapu
Population Boundaries And Gravitational-Wave Templates For Evolving White Dwarf Binaries, Ravi Kumar Kopparapu
LSU Doctoral Dissertations
We present results from our analysis of double white dwarf (DWD) binary star systems in the inspiraling and mass-transfer stages of their evolution. Theoretical constraints on the properties of the white dwarf stars allow us to map out the DWD trajectories in the gravitational-wave amplitude-frequency domain and to identify population boundaries that define distinct sub-domains where inspiraling and/or mass-transferring systems will and will not be found. We identify for what subset of these populations it should be possible to measure frequency changes and, hence, directly follow orbit evolutions given the anticipated operational time of the proposed space-based gravitational-wave detector, LISA. …
Loading And Recovery Behavior Of The Human Lumbar Spine Under Static Flexion, Guntulu Selen Hatipkarasulu
Loading And Recovery Behavior Of The Human Lumbar Spine Under Static Flexion, Guntulu Selen Hatipkarasulu
LSU Doctoral Dissertations
Musculoskeletal disorders account for 32 percent of work related injuries and illnesses. Extensive studies have been conducted to understand and explore the factors that affect the development of musculoskeletal disorders to provide effective control strategies. One of the most important factors that allow effective control strategies is the biomechanical factors. Among the biomechanical risk factors, exposures to repetitive static and vibratory activities are known to result in musculoskeletal disorders. A ligamento–muscular reflex activity exists in humans and animals to stabilize the knee, shoulder, elbow, ankle joints, and spine. This reflex activity decreases over time when static loading is applied, which …
Detecting The Socioeconomic Conditions Of Urban Neighborhoods Through Wavelet Analysis Of Remotely Sensed Imagery, Guiyun Zhou
Detecting The Socioeconomic Conditions Of Urban Neighborhoods Through Wavelet Analysis Of Remotely Sensed Imagery, Guiyun Zhou
LSU Doctoral Dissertations
Wavelet analysis is an efficient approach to studying textural patterns at different scales. Artificial neural networks can learn very complex patterns in the data and could be an efficient classifier. However, whether wavelet analysis, in combination with artificial neural networks or other classifiers, can be used to detect the social-economic conditions of urban neighborhood is a key research question that needs further study. The hypotheses of this study were: 1) neural networks yielded higher classification accuracy than linear discriminant analysis and the minimum-distance classifier based on wavelet measures of urban land covers; 2) wavelet textural measures could be used to …
Louisiana Cotton, Rice, Soybean And Sugarcane Farmer Stakeholders: Who Are They And What Are Their Perceptions Of Farming Practices As Related To The Environment, Robert James Soileau
Louisiana Cotton, Rice, Soybean And Sugarcane Farmer Stakeholders: Who Are They And What Are Their Perceptions Of Farming Practices As Related To The Environment, Robert James Soileau
LSU Doctoral Dissertations
This study identified the stakeholders of Louisiana plant commodity farmers and rated them in terms of importance. Findings of this study show that farmers/ranchers, LSU AgCenter Experiment Station Research personnel, family, consumers, farm labor and agriculture chemical, fertilizer and seed dealers are the most important stakeholders. The second aspect of this study was to discover the stakeholder perceptions of agricultural practices and their relationship to the environment. An environmental perceptions survey was conducted with two of the most important stakeholder groups identified – Experiment Station Research Faculty associated with plant commodities and Louisiana consumers. LSU AgCenter Experiment Station Research Faculty …
High Harmonic Generation By Short Laser Pulses: Time-Frequency Behavior And Applications To Attophysics, Mitsuko Murakami
High Harmonic Generation By Short Laser Pulses: Time-Frequency Behavior And Applications To Attophysics, Mitsuko Murakami
LSU Doctoral Dissertations
High harmonic generation (HHG) is a process in which noble gas atoms excited by an intense laser field at frequency ω1 emit radiation of higher frequencies that are odd integer multiples of ω1. Driven by an infrared laser, high harmonic radiation can span from the optical into the extreme ultraviolet (XUV) frequency range. In this thesis, I study HHG using short laser pulses by solving the time-dependent Schrödinger equation (TDSE). In particular, I will focus on calculating and controlling the time-dependent instantaneous frequency (chirp) of high harmonics. The harmonic chirp is a direct consequence of the atom-field …
How Cue-Dependent Is Memory?: Internal Reinstatement And Cueing Effects In Recognition And Source Memory, Jeffrey Joseph Starns
How Cue-Dependent Is Memory?: Internal Reinstatement And Cueing Effects In Recognition And Source Memory, Jeffrey Joseph Starns
LSU Doctoral Dissertations
This study explored the role of internal context reinstatement in masking the effects of external context cues on recognition and source memory. Participants studied words paired with pictures of male and female faces. Following the study phase, participants completed either a source test in which they decided whether each test word was studied with a male or female face (Experiments 1, 3, and 4) or a recognition test in which they decided whether each test word appeared in the study phase (Experiment 2). On selected trials, a studied face was reinstated at test to serve as a cue for the …
Heroic Individualism: The Hero As Author In Democratic Culture, Alan I. Baily
Heroic Individualism: The Hero As Author In Democratic Culture, Alan I. Baily
LSU Doctoral Dissertations
My study focuses on the literature of democratic morality, with specific reference to the question of "heroic individualism." I attempt to elucidate the notion of heroic individualism by examining three modern democratic moralists whose work occupies the space between politics and literature: Jean Jacques Rousseau, Thomas Carlyle and Friedrich Nietzsche. In brief, I conclude that the central aspiration of heroic individualism is to bridge the gap between writing and action, the Text and the Voice. The dialogue among Rousseau, Carlyle, and Nietzsche reveals that the problem of writing as action is central to heroic-individualist morality. Each of these authors demonstrates …
Topics In Quantum Topology, Khaled Moham Qazaqzeh
Topics In Quantum Topology, Khaled Moham Qazaqzeh
LSU Doctoral Dissertations
In chapter 1, which represents joint work with Gilmer, we define an index two subcategory of a 3-dimensional cobordism category. The objects of the category are surfaces equipped with Lagrangian subspaces of their real first homology. This generalizes the result of [9] where surfaces are equipped with Lagrangian subspaces of their rational first homology. To define such subcategory, we give a formula for the parity of the Maslov index of a triple of Lagrangian subspaces of a skew symmetric bilinear form over R. In chapter 2, we find two bases for the lattices of the SU(2)-TQFT-theory modules of the torus …
Reflections On Teaching A Mathematics Education Course, Sarah Elizabeth Smitherman
Reflections On Teaching A Mathematics Education Course, Sarah Elizabeth Smitherman
LSU Doctoral Dissertations
Teaching and learning involve reflexive actions and should be chosen thoughtfully and deliberately, not because someone has decided “what works.” In this study, I examine how complex conversations might offer pedagogical and theoretical (re)considerations in a teacher education course on mathematics. The term “math methods” is a doubly weighted phrase, for both mathematics and methods connote particular ideologies prevalent in current educational rhetoric. In order to unpack the impact of these words, I engage in research based on inquiry, historical analysis, and personal reflections, all of which I use in an eclectic, thoughtful, and explorative manner. The two main research …
A Generalized Approach For The Control Of Micro-Electromechanical Relays, Mohamed Abdelrahman Younis
A Generalized Approach For The Control Of Micro-Electromechanical Relays, Mohamed Abdelrahman Younis
LSU Master's Theses
MEMS (Micro-Electromechanical Systems) is an area of research and applications that is becoming increasingly popular. It's mainly concerned with integrating micro-mechanical transducers with micro-electronic circuits on common substrates, traditionally silicon, through micro-fabrication. Instead of traditionally having the transducer and the communicating (or control) circuit as two separate entities, MEMS miniaturizes and combines them on a single chip, giving it several advantages, saving space, money, and increasing the sensitivity and accuracy of the integrated system. A micro-electromechanical relay is a type of MEM devices that is becoming increasingly important in a wide range of industries such as the computer industry, the …
Genetic Effects Influencing Salinity And Cold Tolerance In Tilapia, Alvaro M. Armas-Rosales
Genetic Effects Influencing Salinity And Cold Tolerance In Tilapia, Alvaro M. Armas-Rosales
LSU Master's Theses
Genetic effects influencing salinity tolerance (ST) and cold tolerance (CT) were evaluated in two full diallel mating designs using six tilapia varieties: Oreochromis aureus (BL), O. mossambicus (MO), O. niloticus (NI), O. niloticus crossbreds (RE), Mississippi commercial strain (MC) and Florida red tilapia (FL). Statistical analyses provided estimates of direct heterosis (hi), cross heterosis (hij), maternal effects (mi), line effects (li), reciprocal and specific reciprocal effects (rij and r**ij), and general and specific combining abilities (GCA and Sij). Analysis of genetic effects for ST indicated that FL …
Caliche As A Geologic Repository For Atmospheric Sulfate, Katie Jane Howell
Caliche As A Geologic Repository For Atmospheric Sulfate, Katie Jane Howell
LSU Master's Theses
Recent studies demonstrate that important information on sulfur source, oxidation pathway, transport pattern, and reaction kinetics of the oxidation reactions of reduced sulfur gases in the atmosphere may be uncovered by measuring multiple sulfur and oxygen isotope compositions of the oxidation product — secondary atmospheric sulfate (SAS). SAS from Earth’s distant past, however, is rarely preserved in the rock record because of its high solubility and small quantity. Caliche, a pedogenic carbonate formed in arid to semi-arid continental settings and common in the geologic record, could serve as a repository for ancient SAS. Two major groups of caliche samples: 1) …
Nutrient-To-Cost Comparisons Of Daily Dietary Intake, Food Security Status, And Body Mass Index In Female Food Stamp Recipients Residing In Southeast Louisiana, Shanna Lundy
LSU Master's Theses
Diets are typically poorer and risk of chronic disease is greatest in low-income populations. A relationship has been established in the literature between food costs and diet quality, where lower cost diets are generally those of the poorest quality. Food group intake, energy/nutrient intake, and diet cost were assessed in 64 female food stamp recipients in Southeast Louisiana. From one 24-hour dietary recall collected at the beginning of the monthly resource cycle (Day 1) and one at the end (Day 2), nutrient intakes and diet costs were able to be analyzed between different time frames. Participants were divided among food …
Ab Initio Molecular Dynamics Simulations Of Methylaluminoxane (Mao) Synthesis By Hydrolysis Of Trimethylaluminum, Lacramioara Negureanu
Ab Initio Molecular Dynamics Simulations Of Methylaluminoxane (Mao) Synthesis By Hydrolysis Of Trimethylaluminum, Lacramioara Negureanu
LSU Doctoral Dissertations
MAO is the co-catalyst in the metallocene catalytic systems, which are widely used in single site olefin polymerization due to their high stereoselectivity. To date, the precise structure of MAO, the particular compound or compounds catalytically active in MAO, have eluded researchers. MAO, a white amorphous powder, is not a good sample for a direct spectroscopic characterization, and its NMR spectra are broad and almost featureless. Many structural models have been proposed but none are generally accepted. In the first part of this work the MAO formation mechanism was addressed. Molecular dynamics simulations at MP2 configuration interaction theory level have …
An Inverse Homogenization Design Method For Stress Control In Composites, Michael Stuebner
An Inverse Homogenization Design Method For Stress Control In Composites, Michael Stuebner
LSU Doctoral Dissertations
This thesis addresses the problem of optimal design of microstructure in composite materials. The work involves new developments in homogenization theory and numerical analysis. A computational design method for grading the microstructure in composite materials for the control of local stress in the vicinity of stress concentrations is developed. The method is based upon new rigorous multiscale stress criteria connecting the macroscopic or homogenized stress to local stress fluctuations at the scale of the microstructure. These methods are applied to three different types of design problems. The first treats the problem of optimal distribution of fibers with circular cross section …
Development Of Analytical Techniques For The Analysis Of Submicron Particles And Protein Aggregates, Yohannes H. Rezenom
Development Of Analytical Techniques For The Analysis Of Submicron Particles And Protein Aggregates, Yohannes H. Rezenom
LSU Doctoral Dissertations
The goal of the research presented in this dissertation is to develop analytical techniques for the analysis of heterogeneous mixtures of submicron particles and protein aggregates. In Chapter 2, a simple and reproducible technique for constructing perfectly aligned gaps in fused-silica capillaries has been developed for postcolumn reagent addition with capillary electrophoresis (CE) to take advantage of laser-induced fluorescence (LIF) detection. This technique uses laser ablation with a Nd:YAG laser to create gaps of 14.0 ¡Ó 2.2 ƒÝm. These structures have been used for reagent addition for postcolumn derivatization with LIF detection and have been tested for the separation of …
Investigation Into The Dirhodium-Catalyzed Hydroformylation Of 1-Alkenes And Preparation Of A Novel Tetraphosphine Ligand, Alexandre R. Monteil
Investigation Into The Dirhodium-Catalyzed Hydroformylation Of 1-Alkenes And Preparation Of A Novel Tetraphosphine Ligand, Alexandre R. Monteil
LSU Doctoral Dissertations
The reaction of the tetraphosphine ligand rac-et,ph-P4 (et,ph-P4 = PEt2CH2CH2(Ph)PCH2P(Ph)CH2CH2PEt2) with 2 equiv. of [Rh(nbd)2]+ (nbd = norbornadiene) generates [rac-Rh2(nbd)2(et,ph-P4)]2+, which is the precursor to a highly active and regioselective hydroformylation catalyst system. The “key” catalyst species generated under H2/CO pressure has been proposed to be the dihydrido complex [rac-Rh2H2(ì-CO)2(et,ph-P4)]2+, and represents one of the most dramatic example of homobimetallic …
Simulating Protein Evolution Via Thermodynamic Models, Yanlong Xu
Simulating Protein Evolution Via Thermodynamic Models, Yanlong Xu
LSU Doctoral Dissertations
Natural proteins are results of evolution and they need to maintain certain thermodynamic stabilities in order to carry out their biological functions. By simulating protein evolution based on thermodynamic rules, we could reconstruct the evolution trajectory and analyze the evolutionary dynamics of a protein population, and further understand the protein sequence-structure-function relationship. In this study, we have used both a simplified lattice model and a high-resolution atomic model to simulate protein evolution processes. With the lattice model, we have investigated general theoretical questions about how protein structural designability would affect protein evolution, particularly how it would affect protein recombination and …
Thermal Management Of Micro Gas Chromatographs, Chetan Ramesh
Thermal Management Of Micro Gas Chromatographs, Chetan Ramesh
LSU Master's Theses
Gas chromatography is an analytical technique for separating and analyzing individual components in a gas mixture. Applications of gas chromatographs (GCs) include chemical analysis, environmental maintenance, green house gases monitoring, and forensic analysis when used in conjunction with mass spectrometry. There has been a tremendous interest in miniaturization of gas chromatograph systems because of significantly reduced size, portability, fast response times, low power consumption and low cost. Isothermal analysis is a chromatographic analysis at one column temperature. In temperature programming, a linear increase of column temperature with time is used during the course of the analysis. Temperature programming facilitates separation …
Effects Of Terraces On Submerged Aquatic Vegetation In Shallow Marsh Ponds In Coastal Southwest Louisiana, Christopher Dean Cannaday
Effects Of Terraces On Submerged Aquatic Vegetation In Shallow Marsh Ponds In Coastal Southwest Louisiana, Christopher Dean Cannaday
LSU Master's Theses
The wetlands of coastal Louisiana are disappearing at a rate of 65 to 80 km2yr-1. Most of the loss is the conversion of emergent marsh to shallow marsh ponds. Terracing is one restoration technique that has been used frequently in recent years. Terraces are small intertidal ridges built in shallow marsh ponds to reduce wave action. It is assumed that this will slow erosion of adjacent emergent marsh and increase Submerged Aquatic Vegetation (SAV) production, a key habitat component for many marsh fauna. Yet both relevant previous studies failed to show that terraces increased SAV abundance. …
Verification Of Direct Brachytherapy Dosimetry For A Single Seed Implant, Jabari Robinson
Verification Of Direct Brachytherapy Dosimetry For A Single Seed Implant, Jabari Robinson
LSU Master's Theses
A new technique using direct post-implant dosimetry, which does not depend explicitly on brachytherapy seed orientation or position, was explored for a prostate and a breast case. This technique, proposed by E Sajo and ML Williams (SW), uses trace amounts of positron emitters placed in the seed capsule and uses the positron emission tomography image in conjunction with a computed tomography image (PET-CT) to compute the therapeutic dose distribution in the patient. The SW technique could reduce errors in the post-implant dose computations associated with seed localization, seed shadowing and medium heterogeneity. Dose point kernels were obtained using Monte Carlo …
The Business Dynamics In Telecommunication Market Consolidation, George Amstad
The Business Dynamics In Telecommunication Market Consolidation, George Amstad
LSU Master's Theses
The Swiss telecommunication market is quite different from the markets in surrounding European countries. The Swiss Market is characterized by a very small number of competitors and relatively high and stable prices. The model in this thesis explains shows how the limited competition enables the mobile telecommunication service providers to keep prices up. This is due to a oligopoly market situation linked to complicated laws that discourage new competitors to join the Swiss market. Later in 2006, the Swiss federal council will pass the new televisor law, which will make it significantly easier to join the Swiss market. This will …