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Development Of Remote Hydroxylation Via Redox Catalysis And Mild Activation Of Thioglycosides For O-Glycosylation, Kristina Deveaux

LSU Doctoral Dissertations

The focus of this dissertation is the development of a C-H functionalization method using redox catalysis and the synthesis of saccharides using thioglycosides. Chapter 1 is a review of C-H functionalization and visible-light photoredox catalysis. Over the years there have been many significant contributions to the field of C-H functionalization. Select examples have been discussed and a foundation for the method developed in chapter 2 has been outlined. Chapter 2 discusses the development and optimization of a C-H functionalization method. This approach uses the Tz^o directing group and Ir(ppy)₃ to activate a remote C-H bond via 1,6- and …

Multimode Approach To Classical And Quantum Diffraction, Zhihao Xiao

LSU Doctoral Dissertations

I have investigated classical diffraction of optical beams with multimode approach, which is a significant improvement upon the traditional Huygens–Fresnel principle based diffraction theory. I have also investigated quantum diffraction with multimode approach, which describes the behavior of multimode quantum state. Multimode approach to classical and quantum diffraction provides a clear mathematical formalism and is verified by numerical simulations. In addition, I present the work on superconducting qubit and oscillator with time-dependent coupling coefficient, with first order correction with finite qubit energy and schemes based on and π pulses.

A Performer's Guide To Iosif Andriasov's "Concertino For Trumpet", Andrew K. Gerbitz

LSU Doctoral Dissertations

Iosif Andriasov’s Concertino for Trumpet is an excellent candidate for study and assimilation into the standard trumpet repertoire. A significant composer of Armenian descent from the former Soviet Union, Andriasov wrote his Concerto for Trumpet in 1960 and dedicated it to Yuri Usov. Timofei Dokshizer performed it on an album released in 1978 under the Melodya label. After immigrating to the United States in 1979, the composer revised the work and retitled it as Concertino for Trumpet in 1995. IMMA Publishing Company in New York made the revised work commercially available in 2001. This paper is presented to increase awareness …

Paleoenvironmental Reconstruction Using Coral Microatolls (Sp. Siderastrea Siderea) From The Gulf Of Gonâve, Haiti, Gilman Reno Ouellette Jr.

LSU Doctoral Dissertations

Natural and anthropogenic climate changes present unique and serious risks to society. In order to plan and implement adaptation and mitigation strategies successfully, regional manifestations of broad-scale climate changes must be understood robustly. The Caribbean region contains part of the Western Hemisphere Warm Pool (WHWP), a major sea surface temperature (SST) feature that plays a key role in North Atlantic climate. Climate variability in the Caribbean is captured poorly by climate models, due in part to a lack of continuous, multidecadal instrumental climate records from the region. I explored three research questions in this dissertation: Does non-systematic bias exist in …

Electromagnetic Resonant Scattering In Layered Media With Fabrication Errors, Emily Anne Mchenry

LSU Doctoral Dissertations

In certain layered electromagnetic media, one can construct a waveguide that supports a harmonic electromagnetic field at a frequency that is embedded in the continuous spectrum. When the structure is perturbed, this embedded eigenvalue moves into the complex plane and becomes a “complex resonance” frequency. The real and imaginary parts of this complex frequency have physical meaning. They lie behind anomalous scattering behaviors known collectively as “Fano resonance”, and people are interested in tuning them to specific values in optical devices. The mathematics involves spectral theory and analytic perturbation theory and is well understood [16], at least on a theoretical …

Evidence Of Subglacial Brine Inflow And Wind-Induced Mixing From High Resolution Temperature Measurements In Lake Bonney, Antarctica, Jade Lawrence

LSU Master's Theses

Hypersaline brine beneath Taylor Glacier enters proglacial West Lobe Lake Bonney (WLB) subglacially as well as from Blood Falls, a surface discharge point at the Taylor Glacier terminus. The brine strongly influences the water column of WLB. Because of the extremely high salinities below the chemocline in WLB, density is determined almost entirely by salinity and temperature can be used as a passive tracer. Cold brine intrusions enter WLB at the glacier face and intrude in to the water column at the depth of neutral buoyancy, where they can be identified by anomalously cold temperatures at that depth. This study …

Combining Downhole And Sediment Logging To Understand Spatial Variability In Grain-Size, Facies, And Reservoir Quality Of A Large-Scale Mississippi River Point Bar, False River, Louisiana, Elizabeth D. Olson

LSU Master's Theses

Although the general processes by which meandering river point bars are constructed have been known for some time, there is a lack of clarity regarding why small-scale heterogeneities develop. This is especially true in the largest meandering river systems, which are equivalent to some of the most important hydrocarbon reservoirs in the world. In this study, we evaluate the stratigraphic architecture of the 80 km² False River Point Bar System on the Lower Mississippi River and use the knowledge gained to better comprehend point bar construction at different phases. Previous studies of small to medium-scale systems have been unable …

Development Of Artificial Intelligence Approach To Nowcasting And Forecasting Oyster Norovirus Outbreaks Along The U.S. Gulf Coast, Shima Shamkhali Chenar

LSU Doctoral Dissertations

Oyster norovirus outbreaks pose increasing risks to human health and seafood industry worldwide. This study presents an Artificial Intelligence (AI)-based approach to identifying the primary cause of oyster norovirus outbreaks, nowcasting and forecasting the growing risk of oyster norovirus outbreaks in coastal waters. AI models were developed using Artificial Neural Networks (ANNs) and Genetic Programming (GP) methods and time series of epidemiological and environmental data. Input variable selection techniques, including Random Forests (RF) and Forwards Binary Logistic Regression (FBLR), were used to identify the significant model input variables among six independent environmental predictors including water temperature, solar radiation, gage height, …

Disproportionality In Discipline Practices: Assessing The Impact Of Unique Contextual Factors Resulting From School Reforms On Discipline, Stephanie Marie Grant

LSU Doctoral Dissertations

With the implementation of the No Child Left Behind act (NCLB, 2001) sweeping school accountability reforms were instituted across the country. Failure to meet the accountability expectations set forth in the law resulted in punitive measures including school closure, restructuring, and chartering. The impact of the NCLB school reforms on student discipline outcomes at the school level, were assessed. Schools in the state of Louisiana were compared along two dimensions of reform, school type, (Charter vs Traditional) and school governance (Local vs State Run). Analyses indicated differences in student discipline outcomes based on reform variables.

School reforms impacted student outcomes, …

Sustained Flow Index: A Stochastic Measure Of Freeway Performance, Siavash Shojaat

LSU Doctoral Dissertations

The capacity of a road addresses its quantitative traffic carrying ability. The estimation of capacity as a parameter to assess traffic flow performance on freeway facilities has received considerable attention in the literature. Research into the traffic operation at high volumes reveals that the capacity of freeways is not a fixed number, but rather a random variable. Thus, in a stochastic approach to freeway capacity of estimation, the capacity is treated as a random variable generated from a population of flow observations, stemmed from a certain distribution function. Since the type of capacity distribution function is generally not known with …

A Multi-Scale Approach For Modeling Shock Ignition And Burn Of Granular Hmx, Pratap Thamanna Rao

LSU Doctoral Dissertations

Deflagration-to-detonation transition (DDT) in confined, low-density granular HMX (65%-85% Theoretical Maximum Density, TMD) occurs by a complex mechanism that involves compaction shock interactions within the material. Piston driven DDT experiments indicate that detonation is abruptly triggered by the interaction of a strong burn-supported secondary shock and a piston-supported primary (input) shock, where the nature of the interaction depends on initial packing density and primary shock strength. These interactions influence transition by affecting hot-spot formation within the micro-structure during pore collapse. In this study, meso-scale simulations of hot-spot formation in shock loaded granular HMX are used to guide the development of …

Floodplain Impacts On Water Quality: A Case Study In Southern Louisiana, Emily Delduco

LSU Master's Theses

The quantity and quality of dissolved carbon delivered to coastal margins by rivers is an important component of global carbon cycling. The Atchafalaya River (AR) discharges ~25% of the flow of the Mississippi River (MR) and the total flow of the Red River (RR) into the Gulf of Mexico (GoM) annually while flowing through the largest bottomland swamp in North America. This provides a unique opportunity to study floodplain impacts on dissolved carbon processes in a large river system. The research aimed to: (1) determine DIC and DOC transport and processing by a river swamp basin under varied seasons and …

Nanopatterns Of Zinc Phthalocyanines, Gold Nanoparticles, And Porphyrins Prepared Using Particle Lithography: Characterization Of Patterning Steps With Scanning Probe Microscopy, Ashley Marie Taylor

LSU Doctoral Dissertations

The growth and self-assembly of molecules on surfaces can be directly visualized at the molecular level using studies which combine nanoscale lithography and high-resolution imaging. Nanopatterning provides a unique and practical approach for direct views of surface changes after the key chemical steps of nanopatterning, providing landmarks and baselines for measuring growth in vertical and lateral dimensions. Controlling the arrangement of materials on surfaces at the nanoscale can be achieved using particle lithography. Arrays of well-defined nanostructures can be prepared with reproducible geometries and arrangement. Results for the preparation of nanopatterns produced with particle lithography are presented using high resolution …

Microgrid Energy Management With Flexibility Constraints: A Data-Driven Solution Method, Okan Ciftci

LSU Master's Theses

Microgrid energy management is a challenging and important problem in modern power systems. Several deterministic and stochastic models have been proposed in the literature for the microgrid energy management problem. However, more accurate models are required to enhance flexibility of the microgrids when accounting for renewable energy and load uncertainties. This thesis proposes key contributions to solve the energy management problem for smart building (or small-scale microgrid). In Chapter 3, a deterministic energy management model is presented taking into account system flexibility requirements. Energy storage systems are deployed to enhance the grid flexibility and ramping capability. The objective function of …

Issues Related To Carbon Dioxide Pipeline Transportation Infrastructure In Louisiana, Michael Allen Layne Iii

LSU Master's Theses

There is no single solution to mitigate anthropogenic climate change; a multifaceted approach with economic incentives is needed. Carbon dioxide (CO₂) enhanced oil recovery (EOR) is one such solution which provides an economic incentive, in the capture and sale of oil, for sequestering CO₂ underground. While carbon capture and subsequent geological injection are both mature technologies, there has been little discussion or appreciation for the role of pipelines. The current CO₂ pipeline infrastructure will need to significantly expand in order to accommodate increasing EOR production. However, pipeline construction costs, and institutional factors impacting development, may be …

Polynomial Regression Analyses Of Parental Desirable Responding, Megan Elizabeth Lilly

LSU Doctoral Dissertations

Child assessments have consistently yielded poor agreement between parent-child self-report measures and considerable research has failed to isolate the underlying source of the discrepancies. Validity testing has successfully been used to differentiate credible from non-credible performance, recognize feigned symptoms, and detect underestimates of ability in adults for decades (Sherman, 2015). Despite these potential benefits, attention to the importance of validity testing in the child assessment literature has been largely neglected. Many psychologists believe children are not capable of feigning or exaggerating their symptoms and lack the underlying motivations and incentives for deception found in adult assessments. Whereas, more research is …

Coupled Plasmon/Molecule Dynamics Near Core-Shell Nanoparticles: Synthesis, Ultrafast Characterization, And Quantum/Classical Modeling, Holden Tyler Smith

LSU Doctoral Dissertations

In this dissertation, the resonance coupling of chromaphoric dyes adsorbed on the surface of plasmonic nanoparticles (NPs) are investigated using a combined theoretical and experi- mental approach. Colloidal gold, gold-silver core-shell, silver-gold core-shell, and gold-silver- gold core-shell-shell NPs are considered. These NPs are thiolated with mercaptosuccinic acid, and malachite green dyes are adsorbed to the surface of the nanoparticle (NP) via elec- trostatic interactions. Second harmonic generation is used to determine the surface to the isotherm of the molecular dyes to the colloidal nanoparticle surface. Adsorption isotherms show that the SHG intensity increases as the concentration of dye increases, reaching …

How Dredge Pits Evolve Over Time: A Look At Their Geomorphologic Evolution And Infilling Processes, Patrick Robichaux

LSU Master's Theses

As coastal environments become more susceptible to land loss through accelerating sea level rise and subsidence, new restoration methods harnessing borrowed sediment are more valuable than ever. Mud-capped dredge pits (MCDPs) are a relatively new source of restoration-quality sediment that has only recently been utilized for beach and barrier island restorations in Louisiana. Because MCDPs have been in use for less than two decades in only a handful sites, little is understood about their evolution over decadal timescales. To improve our understanding of MCDPs after they are dredged, we have conducted a suite of geophysical surveys including bathymetry, sidescan sonar, …

An Enhanced Bridge Weigh-In-Motion Methodology And A Bayesian Framework For Predicting Extreme Traffic Load Effects Of Bridges, Yang Yu

LSU Doctoral Dissertations

In the past few decades, the rapid growth of traffic volume and weight, and the aging of transportation infrastructures have raised serious concerns over transportation safety. Under these circumstances, vehicle overweight enforcement and bridge condition assessment through structural health monitoring (SHM) have become critical to the protection of the safety of the public and transportation infrastructures. The main objectives of this dissertation are to: (1) develop an enhanced bridge weigh-in-motion (BWIM) methodology that can be integrated into the SHM system for overweight enforcement and monitoring traffic loading; (2) present a Bayesian framework to predict the extreme traffic load effects (LEs) …

Development Of A Mode And Destination Type Joint Choice Model For Hurricane Evacuation, Ruijie Bian

LSU Doctoral Dissertations

Since Hurricane Katrina, transit evacuation service has been seen to serve critical needs in affected cities and an increasing number of hurricanes have struck the east coast where more people rely on public transportation to evacuate. Thus, it is important to model mode choice in evacuation for a better estimation of evacuation transit demand. In this study, a joint mode and destination type choice model was estimated based on multiple post-storm behavioral surveys from the northeastern seaboard to the Gulf coast. A Nested Logit model specification was used to estimate this joint choice model. The estimated model showed significant linkage …

Paleoenvironmental Variation And Provenance Records From Neogene Deep Sea Sediment Of The South China Sea, Chang Liu

LSU Doctoral Dissertations

I employed several paleoenvironmental proxies by utilizing deep sea sediment from the largest marginal basin in east Asia, namely the South China Sea (SCS), to reconstruct the long term paleoenvironmental variation in SE Asia since the Neogene. Sediments deposited within the SCS were mainly delivered by several major fluvial systems whose catchment basins cover several geological blocks in SE Asia. By analyzing the sediment’s geochemical and mineralogical characteristics, several indices which are affected by the source of the sedimentary influx, as well as the weathering state could be built and applied to constrain my paleoenvironmental reconstructions

Two deep sea drilling …

A Political Theory Of The Chinese Stock Market, Liang Kong

LSU Doctoral Dissertations

The Chinese stock market crash of 2015 attracted much attention from both the media and academia. Yet it was not a unique incident. The Chinese stock market fluctuates more frequently and drastically than most mature stock markets. The purpose of this work is to explain these unusual stock market fluctuations through a political lens. Traditional financial models and behavioral finance cannot sufficiently explain the unusual fluctuations of the Chinese stock market. Traditional financial models find that economic forces cannot explain all fluctuations in China’s stock market. Behavioral finance attributes the fluctuations to investor’s irrational behavior without explaining why investors behave …

When, How, And Why Did The West Antarctic Ice Sheet Retreat In The Ross Sea Since The Last Glacial Maximum Using Foraminiferal And Porewater Geochemistry, Matthew Decesare

LSU Doctoral Dissertations

The Antarctic Ice Sheets (AIS) began to retreat from their Last Glacial Maximum (LGM) position sometime after 19,000 years ago. However, the corrosive waters circulating around Antarctica has prevented the recovery of radiocarbon-dateable material, hindering the development of deglacial chronologies. During Expedition NBP1502B to the eastern Ross Sea, an unprecedented quantity of fossil foraminifera and bivalves were recovered. Radiocarbon-dated specimens have been used to constrain the timing of West-AIS retreat from Whales Deep basin and Ross Bank. Whales Deep samples show that the WAIS retreated from its LGM position on the continental shelf edge by 14,700 ± 400 calibrated radiocarbon …

Self-Assembly Mechanisms Of Organosilanes And Porphyrins Investigated With Scanning Probe Microscopy, Phillip Charles Chambers Ii

LSU Doctoral Dissertations

This dissertation details the development of new fabrication strategies for the preparation of spatially selective surfaces by combining techniques of particle lithography and scanning probe microscopy (SPM). This combination of lithography and nanoscale surface characterization was applied to study the mechanisms of molecular level surface-assembly of organosilanes and porphyrin on surfaces of Si(111). Particle lithography was used to investigate the surface assembly of 4-chloromethylphenyltrichlorosilane (CMPS) within exposed sites of nanoholes in selected solvents and at selected temperatures to gain insight into the details of self-polymerization. Nanopillars of CMPS were generated under selected conditions of solvent and temperature and characterized with …

Teaching Introductory Statistics To Graduate Students In The Social Sciences: A Mixed Method Investigation Of The Effectiveness Of Simulations In Statistics Education, Liuli Huang

LSU Doctoral Dissertations

The primary purpose of this study is to determine the effectiveness of using simulations as an instructional tool in an introductory doctoral level statistics course. The study focuses on the impacts of simulations on students’ attitudes and understanding of statistical concepts, as well as how the simulations could inspire students’ positive attitudes and improve statistics performance or would fail to help. In addition, since the statistics anxiety has been a primary obstacle to students’ statistics education, and “statistics anxiety” is experienced by as many as 80% of graduate students (Onwuegbuzie, 2004). The researcher is interested to explore the details of …

Measurement Of Neutrino And Antineutrino Oscillations By The T2k Experiment Including A New Additional Sample Of Ve Interactions At The Far Detector, K. Abe, J. Amey, C. Andreopoulos, M. Antonova, S. Aoki, A. Ariga, Y. Ashida, S. Ban, M. Barbi, G. J. Barker, G. Barr, C. Barry, M. Batkiewicz, V. Berardi, S. Berkman, S. Bhadra, S. Bienstock, A. Blondel, S. Bolognesi, S. Bordoni, S. B. Boyd, D. Brailsford, A. Bravar, C. Bronner, M. Buizza Avanzini, R. G. Calland, T. Campbell, S. Cao

Faculty Publications

The T2K experiment reports an updated analysis of neutrino and antineutrino oscillations in appearance and disappearance channels. Asample of electron neutrino candidates at Super-Kamiokande in which a pion decay has been tagged is added to the four single-ring samples used in previous T2K oscillation analyses. Through combined analyses of these five samples, simultaneous measurements of four oscillation parameters, j?m2 32j, sin2 ?23, sin2 ?13, and dCP and of the mass ordering are made. A set of studies of simulated data indicates that the sensitivity to the oscillation parameters is not limited by neutrino interaction model uncertainty. Multiple oscillation analyses are …

Internode Morphometrics And Allometry Of Tonkin Cane Pseudosasa Amabilis, Liang Cheng, Cang Hui, Gadi V.P. Reddy, Yu Long Ding, Pei Jian Shi

Faculty Publications

Pseudosasa amabilis (McClure) (Poales: Gramineae) is a typical bamboo species naturally distributed in large area of south China and famous for its culm strength. Although bamboos were found to share the same development rule, the detailed internode morphology of bamboo culm was actually not fully expressed. We explored internode morphology of P. amabilis using 11 different physical parameters in different dimensions (1–4). As Taylor's power law (TPL) is generally applicable to describe relationship between mean and variance of population density, here we used TPL to evaluate the differences between internodes, and further, the relationship between dimension and TPL. Results showed …

Arthropod Development’S Response To Temperature: A Review And New Software For Modeling, Mohammad Ali Mirhosseini, Yaghoub Fathipour, Gadi V.P. Reddy

Faculty Publications

Among environmental factors, temperature has a direct and crucial influence on the key life processes of survival, development, reproduction, and movement of poikilothermic animals and hence their population dynamics. The lower and upper temperature thresholds and optimal temperature have ramifications for all major life processes, where within a specific range, a temperature change results in a proportional rise or fall of the rate of any given process. There are some basic approaches for modeling development response to temperature in arthropods. The oldest and most widely used model is a simple linear description of arthropod development in relation to temperature.The linear …

Comparison Of Thermal Performance Equations In Describing Temperature-Dependent Developmental Rates Of Insects: (Iii) Phenological Applications, Pei Jian Shi, Mei Ling Fan, Gadi V.P. Reddy

Faculty Publications

The developmental times of poikilotherms at different stages are significantly affected by temperature. Most mathematical models describing the temperature-dependent developmental rates of poikilotherms are built according to the experimental data at various constant temperatures. However, these models can also be applied to the developmental rates at variable temperatures. It is more meaningful to use models to predict the occurrence times of pest insects that actually represent the completion for a particular developmental stage (e.g., hatching, pupation, eclosion) under a natural thermal environment. For some developmental stages, insects might experience a period of high temperatures. In this case, skewed bell-shaped nonlinear …

Admixture Mapping In The Hispanic Community Health Study/Study Of Latinos Reveals Regions Of Genetic Associations With Blood Pressure Traits, Tamar Sofer, Leslie J. Baier, Sharon R. Browning, Timothy A. Thornton, Gregory A. Talavera, Sylvia Wassertheil-Smoller, Martha L. Daviglus, Robert Hanson, Sayuko Kobes, Richard S. Cooper, Jianwen Cai, Daniel Levy, Alex P. Reiner, Nora Franceschini

Faculty Publications

Admixture mapping can be used to detect genetic association regions in admixed populations, such as Hispanics/Latinos, by estimating associations between local ancestry allele counts and the trait of interest. We performed admixture mapping of the blood pressure traits systolic and diastolic blood pressure (SBP, DBP), mean arterial pressure (MAP), and pulse pressure (PP), in a dataset of 12,116 participants from the Hispanic Community Health Study/Study of Latinos (HCHS/SOL). Hispanics/Latinos have three predominant ancestral populations (European, African, and Amerindian), for each of which we separately tested local ancestry intervals across the genome. We identified four regions that were significantly associated with …