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Shelf-Stable Sustainable Shrimp Thermally Processed With Reciprocal Agitation, William R. Dixon, Evelyn G. Watts, John A. King, Xing Fu, Louise Wicker Oct 2020

Shelf-Stable Sustainable Shrimp Thermally Processed With Reciprocal Agitation, William R. Dixon, Evelyn G. Watts, John A. King, Xing Fu, Louise Wicker

Faculty Publications

Shelf-stable, ready-to-eat shrimp offer a convenient, portion-controlled option for a highly desirable seafood commodity. The perishability of shrimp requires tight cold-temperature control during distribution and handling. Thermal processing of shrimp was evaluated in a multimode retort with automated control of come-up, heat, and cool times and with addition of high-speed reciprocal agitation. Reciprocal agitation was compared with static retort for thermal process and quality parameters, including cook time, process time to achieve target lethality (F0), cook yield, texture, and appearance of shelf-stable shrimp. Total retort thermal processing times decreased from 30 min at 0 shakes per minute (SPM) to 17.1 …

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The Dynamic Trophic Niche Of An Island Bird Of Prey, Ulises Balza, Nicolas A. Lois, Michael J. Polito, Klemens Puetz, Amira Saalom, Andrea Raya Rey Oct 2020

The Dynamic Trophic Niche Of An Island Bird Of Prey, Ulises Balza, Nicolas A. Lois, Michael J. Polito, Klemens Puetz, Amira Saalom, Andrea Raya Rey

Faculty Publications

Optimal foraging theory predicts an inverse relationship between the availability of preferred prey and niche width in animals. Moreover, when individuals within a population have identical prey preferences and preferred prey is scarce, a nested pattern of trophic niche is expected if opportunistic and selective individuals can be identified. Here, we examined intraspecific variation in the trophic niche of a resident population of striated caracara (Phalcoboenus australis) on Isla de los Estados (Staten Island), Argentina, using pellet and stable isotope analyses. While this raptor specializes on seabird prey, we assessed this population's potential to forage on terrestrial prey, especially invasive …

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The Central Role Of Taxonomy In The Study Of Neotropical Biodiversity1, Laura P. Lagomarsino, Laura A. Frost Oct 2020

The Central Role Of Taxonomy In The Study Of Neotropical Biodiversity1, Laura P. Lagomarsino, Laura A. Frost

Faculty Publications

© 2020 Missouri Botanical Garden. All rights reserved. The Neotropics are the most species-rich area of the planet. Understanding the origin and maintenance of this diversity is an important goal of ecology and evolutionary biology. Success in this endeavor relies heavily on the past work of taxonomists who have collected specimens and produced the floras and monographs that constitute the foundation for the study of plant diversity. To illustrate this, we visualize collecting efforts through time and identify the importance of past taxonomic and collection efforts in generating the bulk of specimen data that broad-scale analyses rely on today. To …

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Abundance Of The Species Clostridium Butyricum In The Gut Microbiota Contributes To Differences In Obesity Phenotype In Outbred Sprague-Dawley Cd Rats, Diana N. Obanda, Claudia Husseneder, Anne M. Raggio, Ryan Page, Brian Marx, Rhett W. Stout, Justin Guice, Diana Coulon, Michael J. Keenan Oct 2020

Abundance Of The Species Clostridium Butyricum In The Gut Microbiota Contributes To Differences In Obesity Phenotype In Outbred Sprague-Dawley Cd Rats, Diana N. Obanda, Claudia Husseneder, Anne M. Raggio, Ryan Page, Brian Marx, Rhett W. Stout, Justin Guice, Diana Coulon, Michael J. Keenan

Faculty Publications

© 2020 Elsevier Inc. Objectives: Gut microbiota profiles contribute to differences in obesity phenotype. We examined the abundance of the species Clostridium butyricum in relation to obesity phenotype. Methods: In outbred Sprague -Dawley rats we examined effects of dietary fat, resistant starch (RS), and a microbiota transplant on obesity phenotype. Using targeted qPCR, we examined the abundance of total gut bacteria and C. butyricum in relation to the propensity of obesity prone and obesity resistant rats to accumulate abdominal fat. Results: Before inclusion of dietary RS, obesity resistant (OR) rats had higher amounts of total bacteria, and C. butyricum compared …

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Abundance Of The Species Clostridium Butyricum In The Gut Microbiota Contributes To Differences In Obesity Phenotype In Outbred Sprague-Dawley Cd Rats, Diana N. Obanda, Claudia Husseneder, Anne M. Raggio, Ryan Page, Brian Marx, Rhett W. Stout, Justin Guice, Diana Coulon, Michael J. Keenan Oct 2020

Abundance Of The Species Clostridium Butyricum In The Gut Microbiota Contributes To Differences In Obesity Phenotype In Outbred Sprague-Dawley Cd Rats, Diana N. Obanda, Claudia Husseneder, Anne M. Raggio, Ryan Page, Brian Marx, Rhett W. Stout, Justin Guice, Diana Coulon, Michael J. Keenan

Faculty Publications

© 2020 Elsevier Inc. Objectives: Gut microbiota profiles contribute to differences in obesity phenotype. We examined the abundance of the species Clostridium butyricum in relation to obesity phenotype. Methods: In outbred Sprague -Dawley rats we examined effects of dietary fat, resistant starch (RS), and a microbiota transplant on obesity phenotype. Using targeted qPCR, we examined the abundance of total gut bacteria and C. butyricum in relation to the propensity of obesity prone and obesity resistant rats to accumulate abdominal fat. Results: Before inclusion of dietary RS, obesity resistant (OR) rats had higher amounts of total bacteria, and C. butyricum compared …

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All-Atomic Molecular Dynamic Studies Of Human And Drosophila Cdk8: Insights Into Their Kinase Domains, The Lxxll Motifs, And Drug Binding Site, Wu Xu, Xiao-Jun Xie, Ali K. Faust, Mengmeng Liu, Xiao Li, Feng Chen, Ashlin A. Naquin, Avery C. Walton, Peter W. Kishbaugh, Jun-Yuan Ji Oct 2020

All-Atomic Molecular Dynamic Studies Of Human And Drosophila Cdk8: Insights Into Their Kinase Domains, The Lxxll Motifs, And Drug Binding Site, Wu Xu, Xiao-Jun Xie, Ali K. Faust, Mengmeng Liu, Xiao Li, Feng Chen, Ashlin A. Naquin, Avery C. Walton, Peter W. Kishbaugh, Jun-Yuan Ji

Faculty Publications

Cyclin-dependent kinase 8 (CDK8) and its regulatory partner Cyclin C (CycC) play conserved roles in modulating RNA polymerase II (Pol II)-dependent gene expression. To understand the structure and function relations of CDK8, we analyzed the structures of human and Drosophila CDK8 proteins using molecular dynamics simulations, combined with functional analyses in Drosophila. Specifically, we evaluated the structural differences between hCDK8 and dCDK8 to predict the effects of the LXXLL motif mutation (AQKAA), the P154L mutations, and drug binding on local structures of the CDK8 proteins. First, we have observed that both the LXXLL motif and the kinase activity of CDK8 …

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Dietary Methionine Restriction Signals To The Brain Through Fibroblast Growth Factor 21 To Regulate Energy Balance And Remodeling Of Adipose Tissue, Laura A. Forney, Han Fang, Landon C. Sims, Kirsten P. Stone, Leighann Y. Vincik, Alicia M. Vick, Amanda N. Gibson, David H. Burk, Thomas W. Gettys Oct 2020

Dietary Methionine Restriction Signals To The Brain Through Fibroblast Growth Factor 21 To Regulate Energy Balance And Remodeling Of Adipose Tissue, Laura A. Forney, Han Fang, Landon C. Sims, Kirsten P. Stone, Leighann Y. Vincik, Alicia M. Vick, Amanda N. Gibson, David H. Burk, Thomas W. Gettys

Faculty Publications

© 2020 The Obesity Society. Objective: Restricting dietary methionine to 0.17% in mice increases energy expenditure (EE), reduces fat deposition, and improves metabolic health by increasing hepatic fibroblast growth factor 21 (FGF21). The goal of this study was to compare each of these responses in mice with the coreceptor for FGF21 deleted in either adipose tissue or the brain. Methods: Methionine-restriction (MR) diets were fed to age-matched cohorts of mice with the coreceptor for FGF21 deleted in either adipose tissue or the brain. The physiological and transcriptional responses to MR were compared in the respective cohorts. Results: Tissue-specific deletion of …

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Effect Of Conjugated Estrogens And Bazedoxifene On Glucose, Energy And Lipid Metabolism In Obese Postmenopausal Women, Kara L. Marlatt, Dragana Lovre, Robbie A. Beyl, Chandra R. Tate, Evelyn K. Hayes, Charles F. Burant, Eric Ravussin, Franck Mauvais-Jarvis Oct 2020

Effect Of Conjugated Estrogens And Bazedoxifene On Glucose, Energy And Lipid Metabolism In Obese Postmenopausal Women, Kara L. Marlatt, Dragana Lovre, Robbie A. Beyl, Chandra R. Tate, Evelyn K. Hayes, Charles F. Burant, Eric Ravussin, Franck Mauvais-Jarvis

Clinical Research Faculty Publications

Objective: Combining conjugated estrogens (CE) with the selective estrogen receptor modulator bazedoxifene (BZA) is a novel, orally administered menopausal therapy. We investigated the effect of CE/BZA on insulin sensitivity, energy metabolism, and serum metabolome in postmenopausal women with obesity. Design: Randomized, double-blind, crossover pilot trial with washout was conducted at Pennington Biomedical Research Center. Eight postmenopausal women (age 50-60 years, BMI 30-40 kg/m2) were randomized to 8 weeks CE/BZA or placebo. Primary outcome was insulin sensitivity (hyperinsulinemic-euglycemic clamp). Secondary outcomes included body composition (DXA); resting metabolic rate (RMR); substrate oxidation (indirect calorimetry); ectopic lipids (1H-MRS); fat cell size, adipose and …

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Testosterone Supplementation Upregulates Androgen Receptor Expression And Translational Capacity During Severe Energy Deficit, Emily E. Howard, Lee M. Margolis, Claire E. Berryman, Harris R. Lieberman, J. Philip Karl, Andrew J. Young, Monty A. Montano, William J. Evans, Nancy R. Rodriguez, Neil M. Johannsen, Kishore M. Gadde, Melissa N. Harris, Jennifer C. Rood, Stefan M. Pasiakos Oct 2020

Testosterone Supplementation Upregulates Androgen Receptor Expression And Translational Capacity During Severe Energy Deficit, Emily E. Howard, Lee M. Margolis, Claire E. Berryman, Harris R. Lieberman, J. Philip Karl, Andrew J. Young, Monty A. Montano, William J. Evans, Nancy R. Rodriguez, Neil M. Johannsen, Kishore M. Gadde, Melissa N. Harris, Jennifer C. Rood, Stefan M. Pasiakos

Clinical Research Faculty Publications

Testosterone supplementation during energy deficit promotes whole body lean mass accretion, but the mechanisms underlying that effect remain unclear. To elucidate those mechanisms, skeletal muscle molecular adaptations were assessed from muscle biopsies collected before, 1 h, and 6 h after exercise and a mixed meal (40 g protein, 1 h postexercise) following 14 days of weight maintenance (WM) and 28 days of an exercise- and diet-induced 55% energy deficit (ED) in 50 physically active nonobese men treated with 200 mg testosterone enanthate/wk (TEST) or placebo (PLA) during the ED. Participants (n = 10/group) exhibiting substantial increases in leg lean mass …

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Louisiana Agriculture Fall, 2020 Oct 2020

Louisiana Agriculture Fall, 2020

Louisiana Agriculture

No abstract provided.

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Northeast- Fall 2020, Lsu Agcenter Oct 2020

Northeast- Fall 2020, Lsu Agcenter

Horticulture Hints

No abstract provided.

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Southwest- Fall 2020, Lsu Agcenter Oct 2020

Southwest- Fall 2020, Lsu Agcenter

Horticulture Hints

No abstract provided.

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Lsu Research Fall 2020, Louisiana State University And Agricultural And Mechanical College Oct 2020

Lsu Research Fall 2020, Louisiana State University And Agricultural And Mechanical College

Research Magazine

LSU Research is published annually by the Office of Research & Economic Development, Louisiana State University.

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Fall 2020 Catalog, Lsu Press Oct 2020

Fall 2020 Catalog, Lsu Press

LSU Press Seasonal Catalogs

No abstract provided.

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Enhancing Evaluation Of Wildlife Detection Systems, Nick N. Ferenchak Ph.D Oct 2020

Enhancing Evaluation Of Wildlife Detection Systems, Nick N. Ferenchak Ph.D

Data

Every year in the United States, wildlife-vehicle collisions (WVCs) cause 200 human fatalities, 26,000 human injuries, and substantial harm to wildlife populations, resulting in approximately $8.4 billion in total costs. The research team examined two US 64 bridges located near Lumberton, New Mexico that were designed to allow wildlife to cross underneath. Monitoring stations were positioned at each of the crossings so that both wildlife approaches and passages were observed. Special mounting brackets were designed and fabricated to allow for the installation of monitoring equipment. Wildlife observations were supplemented with WVC counts. Over seven months of study, nearly 100,000 wildlife …

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Metabolic And Energetic Benefits Of Microrna-22 Inhibition, Marc Thibonnier, Christine Esau, Sujoy Ghosh, Edward Wargent, Claire Stocker Oct 2020

Metabolic And Energetic Benefits Of Microrna-22 Inhibition, Marc Thibonnier, Christine Esau, Sujoy Ghosh, Edward Wargent, Claire Stocker

Division of Basic Science Faculty Publications

INTRODUCTION: We previously demonstrated in primary cultures of human subcutaneous adipocytes and in a mouse model of diet-induced obesity that specific microRNA-22-3p antagomirs produce a significant reduction of fat mass and an improvement of several metabolic parameters. These effects are related to the activation of target genes such as KDM3A, KDM6B, PPARA, PPARGC1B and SIRT1 involved in lipid catabolism, thermogenesis, insulin sensitivity and glucose homeostasis. RESEARCH DESIGN AND METHODS: We now report a dedicated study exploring over the course of 3 months the metabolic and energetic effects of subcutaneous administration of our first miR-22-3p antagomir drug candidate (APT-110) in adult …

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Exercise Training Impacts Skeletal Muscle Clock Machinery In Prediabetes, Melissa L. Erickson, H. U.I. Zhang, Jacob T. Mey, John P. Kirwan Oct 2020

Exercise Training Impacts Skeletal Muscle Clock Machinery In Prediabetes, Melissa L. Erickson, H. U.I. Zhang, Jacob T. Mey, John P. Kirwan

Division of Basic Science Faculty Publications

Purpose Disruption of the skeletal muscle molecular clock leads to metabolic disease, whereas exercise may be restorative, leading to improvements in metabolic health. The purpose of this study was to evaluate the effects of a 12-wk exercise intervention on skeletal muscle molecular clock machinery in adults with obesity and prediabetes, and determine whether these changes were related to exercise-induced improvements in metabolic health. Methods Twenty-six adults (age, 66 ± 4.5 yr; body mass index (BMI), 34 ± 3.4 kg·m-2; fasting plasma glucose, 105 ± 15 mg·dL-1) participated in a 12-wk exercise intervention and were fully provided isoenergetic diets. Body composition …

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International Reverse Transfer Students: A Critical Analysis Based On Field, Habitus, And Social And Cultural Capital, Yu “April” Chen, Ran Li, Linda Serra Hagedorn Oct 2020

International Reverse Transfer Students: A Critical Analysis Based On Field, Habitus, And Social And Cultural Capital, Yu “April” Chen, Ran Li, Linda Serra Hagedorn

Faculty Publications

Objective: International reverse transfer students are international students who begin their postsecondary journey at a four-year institution but subsequently transfer to a community college. In this qualitative study, we examine the lived experiences of international reverse transfers to understand the reasons for reverse-transfer and to understand the students’ learning experiences. Methods: Using a phenomenological approach, we recruited 10 international reverse transfer students attending one four-year university or one of the two community colleges. We conducted individual interviews with all participants and analyzed transcript data through Bourdieu’s sociological theory of field, habitus, and social and cultural capital. Results: We identified three …

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Toward A Visual History Of Smell In Eighteenth-Century France, Cameron C. Emamdjomeh Oct 2020

Toward A Visual History Of Smell In Eighteenth-Century France, Cameron C. Emamdjomeh

Honors Capstones

No abstract provided.

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Enhancing Evaluation Of Wildlife Detection Systems, Nick N. Ferenchak Ph.D Oct 2020

Enhancing Evaluation Of Wildlife Detection Systems, Nick N. Ferenchak Ph.D

Publications

Every year in the United States, wildlife-vehicle collisions (WVCs) cause 200 human fatalities, 26,000 human injuries, and substantial harm to wildlife populations, resulting in approximately $8.4 billion in total costs. The research team examined two US 64 bridges located near Lumberton, New Mexico that were designed to allow wildlife to cross underneath. Monitoring stations were positioned at each of the crossings so that both wildlife approaches and passages were observed. Special mounting brackets were designed and fabricated to allow for the installation of monitoring equipment. Wildlife observations were supplemented with WVC counts. Over seven months of study, nearly 100,000 wildlife …

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Loss Of Ulk1 Attenuates Cholesterogenic Gene Expression In Mammalian Hepatic Cells, Sangam Rajak, Liliana F. Iannucci, Jin Zhou, B. Anjum, Nelson George, Brijesh K. Singh, Sujoy Ghosh, Paul M. Yen, Rohit A. Sinha Sep 2020

Loss Of Ulk1 Attenuates Cholesterogenic Gene Expression In Mammalian Hepatic Cells, Sangam Rajak, Liliana F. Iannucci, Jin Zhou, B. Anjum, Nelson George, Brijesh K. Singh, Sujoy Ghosh, Paul M. Yen, Rohit A. Sinha

Division of Basic Science Faculty Publications

The hepatic mevalonate (MVA) pathway, responsible for cholesterol biosynthesis, is a therapeutically important metabolic pathway in clinical medicine. Using an unbiased transcriptomics approach, we uncover a novel role of Unc-51 like autophagy activating kinase 1 (ULK1) in regulating the expression of the hepatic de novo cholesterol biosynthesis/MVA pathway genes. Genetic silencing of ULK1 in non-starved mouse (AML-12) and human (HepG2) hepatic cells as well as in mouse liver followed by transcriptome and pathway analysis revealed that the loss of ULK1 expression led to significant down-regulation of genes involved in the MVA/cholesterol biosynthesis pathway. At a mechanistic level, loss of ULK1 …

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177Lu-Labeled Eu-Doped Mesoporous Sio2Nanoparticles As A Theranostic Radiopharmaceutical For Colorectal Cancer, Rodrigo Da Silva Viana, Luciana Amaral De Mescana Costa, Ashlyn C. Harmon, Manoel Adrião Gomes Filho, Eduardo H.L. Falcão, Maria G.H. Vicente, Severino A. Junior, J. Michael Mathis Sep 2020

177Lu-Labeled Eu-Doped Mesoporous Sio2Nanoparticles As A Theranostic Radiopharmaceutical For Colorectal Cancer, Rodrigo Da Silva Viana, Luciana Amaral De Mescana Costa, Ashlyn C. Harmon, Manoel Adrião Gomes Filho, Eduardo H.L. Falcão, Maria G.H. Vicente, Severino A. Junior, J. Michael Mathis

Faculty Publications

Copyright © 2020 American Chemical Society. Colorectal cancer is one of the most significant types of cancer, ranking second in the world's mortality cases. As colorectal cancer is often diagnosed at a late stage of disease progression, effective treatments are necessary. Therefore, radiotherapy has become a fundamental approach in the treatment of colorectal cancer, especially those based on the use of 177Lu. A potential approach to meet this challenge is the use of nanotechnology through the development of radionuclide-based nanomaterials. In this work, we investigated a SiO2-derived class of nanomaterials formed by the insertion of the coordination complex, based on …

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Low Aflatoxin Levels In Aspergillus Flavus-Resistant Maize Are Correlated With Increased Corn Earworm Damage And Enhanced Seed Fumonisin, Subbaiah Chalivendra, Fangneng Huang, Mark Busman, W. Paul Williams, Jong Hyun Ham Sep 2020

Low Aflatoxin Levels In Aspergillus Flavus-Resistant Maize Are Correlated With Increased Corn Earworm Damage And Enhanced Seed Fumonisin, Subbaiah Chalivendra, Fangneng Huang, Mark Busman, W. Paul Williams, Jong Hyun Ham

Faculty Publications

Preharvest mycotoxin contamination of field-grown crops is influenced not only by the host genotype, but also by inoculum load, insect pressure and their confounding interactions with seasonal weather. In two different field trials, we observed a preference in the natural infestation of corn earworm (CEW; Helicoverpa zea Boddie) to specific maize (Zea mays L.) genotypes and investigated this observation. The field trials involved four maize lines with contrasting levels of resistance to Aspergillus flavus. The resistant lines had 7 to 14-fold greater infested ears than the susceptible lines. Seed aflatoxin B1 (AF) levels, in mock- and A. flavus-inoculated ears were …

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Effect Of Oxidation Level On The Interfacial Water At The Graphene Oxide-Water Interface: From Spectroscopic Signatures To Hydrogen-Bonding Environment, Rolf David, Aashish Tuladhar, Le Zhang, Christopher Arges, Revati Kumar Sep 2020

Effect Of Oxidation Level On The Interfacial Water At The Graphene Oxide-Water Interface: From Spectroscopic Signatures To Hydrogen-Bonding Environment, Rolf David, Aashish Tuladhar, Le Zhang, Christopher Arges, Revati Kumar

Faculty Publications

Copyright © 2020 American Chemical Society. The interfacial region of the graphene oxide (GO)-water system is nonhomogenous due to the presence of two distinct domains: an oxygen-rich surface and a graphene-like region. The experimental vibrational sum-frequency generation (vSFG) spectra are distinctly different for the fully oxidized GO-water interface as compared to the reduced GO-water case. Computational investigations using ab initio molecular dynamics were performed to determine the molecular origins of the different spectroscopic features. The simulations were first validated by comparing the simulated vSFG spectra to those from the experiment, and the contributions to the spectra from different hydrogen bonding …

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Effect Of Oxidation Level On The Interfacial Water At The Graphene Oxide-Water Interface: From Spectroscopic Signatures To Hydrogen-Bonding Environment, Rolf David, Aashish Tuladhar, Le Zhang, Christopher Arges, Revati Kumar Sep 2020

Effect Of Oxidation Level On The Interfacial Water At The Graphene Oxide-Water Interface: From Spectroscopic Signatures To Hydrogen-Bonding Environment, Rolf David, Aashish Tuladhar, Le Zhang, Christopher Arges, Revati Kumar

Faculty Publications

The interfacial region of the graphene oxide (GO)-water system is nonhomogenous due to the presence of two distinct domains: an oxygen-rich surface and a graphene-like region. The experimental vibrational sum-frequency generation (vSFG) spectra are distinctly different for the fully oxidized GO-water interface as compared to the reduced GO-water case. Computational investigations using ab initio molecular dynamics were performed to determine the molecular origins of the different spectroscopic features. The simulations were first validated by comparing the simulated vSFG spectra to those from the experiment, and the contributions to the spectra from different hydrogen bonding environments and interfacial water orientations were …

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Point-Of-Care Devices For Therapeutic, Medical And Environmental Applications, Alisha Prasad Sep 2020

Point-Of-Care Devices For Therapeutic, Medical And Environmental Applications, Alisha Prasad

LSU Doctoral Dissertations

Point-of-care testing (POCT) or Point-of-use (POU) devices or technologies are defined as testing aids that are capable for onsite use or testing. The key advantages of POCT are low sample volume, quick onsite diagnosis, high accuracy, and cost-effectiveness. POCT has the potential and the benefits to facilitate better health care management by rapid routine diagnosis and monitoring. To reach this goal, several researchers as well as the healthcare industry over a few years have conducted cutting edge research to bring science to technology by developing smart diagnostic devices capable of performing as per patient profiles and make personalized health care …

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A Reenvisioned Agricultural System In Thailand: The Growth In Human Capital Experienced By Agriculturalists After Adoption Of The Sufficiency Economic Philosophy, Alexis C. Agard, Richie Roberts Sep 2020

A Reenvisioned Agricultural System In Thailand: The Growth In Human Capital Experienced By Agriculturalists After Adoption Of The Sufficiency Economic Philosophy, Alexis C. Agard, Richie Roberts

Faculty Publications

No abstract provided.

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Machine Intelligence For Nerve Conduit Design And Production, Caleb E. Stewart, Chin Fung Kelvin Kan, Brody R. Stewart, Henry W. Sanicola Iii, Jangwook P. Jung, Olawale A. R. Sulaiman, Dadong Wang Sep 2020

Machine Intelligence For Nerve Conduit Design And Production, Caleb E. Stewart, Chin Fung Kelvin Kan, Brody R. Stewart, Henry W. Sanicola Iii, Jangwook P. Jung, Olawale A. R. Sulaiman, Dadong Wang

Faculty Publications

Nerve guidance conduits (NGCs) have emerged from recent advances within tissue engineering as a promising alternative to autografts for peripheral nerve repair. NGCs are tubular structures with engineered biomaterials, which guide axonal regeneration from the injured proximal nerve to the distal stump. NGC design can synergistically combine multiple properties to enhance proliferation of stem and neuronal cells, improve nerve migration, attenuate inflammation and reduce scar tissue formation. The aim of most laboratories fabricating NGCs is the development of an automated process that incorporates patient-specific features and complex tissue blueprints (e.g. neurovascular conduit) that serve as the basis for more complicated …

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Cyclic Topology Enhancing Structural Ordering And Stability Of Comb-Shaped Polypeptoid Thin Films Against Melt-Induced Dewetting, Naisheng Jiang, Jianxia Chen, Tianyi Yu, Albert Chao, Liying Kang, Ying Wu, Kangmin Niu, Ruipeng Li, Masafumi Fukuto, Donghui Zhang Sep 2020

Cyclic Topology Enhancing Structural Ordering And Stability Of Comb-Shaped Polypeptoid Thin Films Against Melt-Induced Dewetting, Naisheng Jiang, Jianxia Chen, Tianyi Yu, Albert Chao, Liying Kang, Ying Wu, Kangmin Niu, Ruipeng Li, Masafumi Fukuto, Donghui Zhang

Faculty Publications

Copyright © 2020 American Chemical Society. We investigated the effect of cyclic chain topology on the molecular ordering and thermal stability of comb-shaped polypeptoid thin films on silicon (Si) substrates. Cyclic and linear poly(N-decylglycine) (PNDG) bearing long n-decyl side chains were synthesized by ring-opening polymerization of N-decylglycine-derived N-carboxyanhydrides. When the spin-coated thin films were subjected to thermal annealing at temperatures above the melting temperature (T > Tm), the cyclic PNDG films exhibited significantly enhanced stability against melt-induced dewetting than the linear counterparts (l-PNDG). When recrystallized at temperatures below the crystallization temperature (T < Tc), the homogeneous c-PNDG films exhibit enhanced crystalline ordering relative to the macroscopically dewetted l-PNDG films. Both cyclic and linear PNDG molecules adopt cis-amide conformations in the crystalline film, which transition into trans-amide conformations upon melting. A top-down solvent leaching treatment of both l/c-PNDG films revealed the formation of an irreversibly physisorbed monolayer with similar thickness (ca. 3 nm) on the Si substrate. The physisorbed monolayers are more disordered relative to the respective thicker crystalline films for both cyclic and linear PNDGs. Upon heating above Tm, the adsorbed c-PNDG chains adopt trans-amide backbone conformation identical with the free c-PNDG molecules in the molten film. By contrast, the backbone conformations of l-PNDG chains in the adsorbed layers are notably different from those of the free chains in the molten film. We postulate that the conformational disparity between the chains in the physically adsorbed layers versus the free chains in the molten film is an important factor to account for the difference in the thermal stability of PNDG thin films. These findings highlight the use of cyclic chain topology to suppress the melt-induced dewetting in polymer thin films.

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Tropical Cyclone Landfall Frequency And Large-Scale Environmental Impacts Along Karstic Coastal Regions (Yucatan Peninsula, Mexico), Victor H. Rivera-Monroy, Luis M. Farfan, Luis Brito-Castillo, Jorge Cortes-Ramos, Eduardo Gonzalez-Rodriguez, Eurico D'Sa, Jorge I. Euan-Avila Sep 2020

Tropical Cyclone Landfall Frequency And Large-Scale Environmental Impacts Along Karstic Coastal Regions (Yucatan Peninsula, Mexico), Victor H. Rivera-Monroy, Luis M. Farfan, Luis Brito-Castillo, Jorge Cortes-Ramos, Eduardo Gonzalez-Rodriguez, Eurico D'Sa, Jorge I. Euan-Avila

Faculty Publications

Tropical cyclones (TCs) are natural systems that develop over ocean basins and are key components of the atmospheric activity during the warm season. However, there are still knowledge gaps about the combined positive and negative TC impacts on the structure and function of coastal socio-ecosystems. Using remote sensing tools, we analyzed the frequency, trajectory, and intensity of 1894 TCs from 1851-2019 to identify vulnerable "hotspots" across the Yucatan Peninsula (YP), Mexico. A total of 151 events hit the YP, with 96% of landings on the eastern coast. We focused on three major hurricanes (Emily and Wilma, 2005; Dean, 2007) and …

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