Digital Commons Network^™

The Potential Of Iron Electrodes In Electrochemical Cells For The Stabilization Of Synthetic Urine, Skyler Voisin

All Theses

Source separation and urine treatment present the opportunity to significantly reduce influent concentrations of nitrogen and phosphorus in wastewater treatment plants and to capture those minerals for reuse. This study aims to use electrochemical cells with a sacrificial iron electrode to produce hydrogen peroxide in situ for the stabilization of urea while dissolving ferrous iron ions to promote the precipitation of phosphate into compounds such as vivianite (Fe₃ (PO₄)₂ ∙ 8 H₂O), a precipitate with potential uses in agriculture and manufacturing. Synthetic urine samples were treated as anolyte, then were given time to form …

Utilizing The Land-Based Learning Model For The Clemson Agricultural Safety, Growing Safe Tigers Program, Maryann Lovern

All Theses

The Clemson Agricultural Safety, Growing Safe Tigers program was developed in 2019 with the goal of increasing the awareness of agricultural safety in South Carolina. By utilizing the land-based learning model, a need for agricultural safety education was identified through incident surveillance strategies. Agricultural incidents were quantified using AgInjuryNews.org and recommendations were made for the program to provide more tailored information to the four regions of South Carolina, based on the primary cause of incident for each region.

Educators’ understanding of place and interconnected systems was determined pertaining to agricultural safety to provide a baseline for how agricultural education teachers …

Impact Of Granular Activated Carbon On In-Situ Reductive Dechlorination Of Chlorinated Solvents, Reagan Gregory

All Theses

Treatment of chlorinated solvent-contaminated aquifers with in-situ activated carbon offers a simple yet cost-effective treatment opportunity, yet the interactions between activated carbon and the chlorinated solvents and their daughter products are not well understood.

The objective of this research is to demonstrate the impacts of in situ activated carbon on complete reductive dechlorination of chlorinated solvents in contaminated aquifer material with mixed dehalogenating cultures. This research seeks to characterize the sorption of trichloroethene and its daughter products cis-dichloroethene, vinyl chloride, and ethene to granular activated carbon and how that sorption relates to the removal of trichloroethene from contaminated material in …

A Study Of 5g Cellular Connectivity To Unmanned Aerial Vehicles, Jackson Murrin

All Theses

The market of unmanned aerial vehicles (UAVs) has seen significant growth in the past ten years on both the commercial and military sides. The applications for UAVs are endless and options by manufacturers allow users to modify their drones for their specific goals. This industry has opened up the excitement of piloting vehicles in the air, photography, videography, exploration of nature from a different point of view and many other hobbies assisted by the emergence of UAVs. The growth of this industry coincides with the roll out of new 5G cellular network technology. This upgrade in cellular network infrastructure allows …

Resistive And Capacitive Behavior In Self-Healing Poly(Ionic Liquid) Copolymers, Jaylan Fraser-Mines

All Theses

This thesis elucidates the origin of molecular events during the damage-repair cycle in a new class of copolymers composed of ionic liquids (ILs) and acrylic-based monomers. In these studies, (1-[(2-methacryloyloxy)ethyl]-3- butylimidazolium bis(trifluoromethyl-sulfonyl)imide) (MEBIm-TFSI) was copolymerized with methyl methacrylate (MMA) and n-butyl acrylate (nBA) to form poly((1-[(2-methacryloyloxy)ethyl]-3- butylimidazolium bis(trifluoromethyl-sulfonyl)imide)-co-methyl methacrylate-co-n butyl acrylate) (p(MEBIm-TFSI/MMA/nBA)) and its mechanical and electrical properties were examined. Following the introduction to this work, Chapter 1 provides an overview of the continuously growing field of ILs and focuses on the structure-property relationships between ILs and their properties as single molecules and monomers in poly(ionic liquid)s (PILs). Chapter 2 …

The Effect Of Package Types On Fresh Peaches In The Direct-To-Consumer Distribution Environment, Brennan Lytle

All Theses

The direct-to-consumer (DTC) shipping mode presents new opportunity for fresh peach sales in North America where demand over the past four decades has steadily declined. The hazards in this distribution mode are severe, and fresh peaches are fragile emphasizing the need for proper protection. A full analysis that not only encompasses the effects of the direct-to-consumer distribution environment, but also incorporates analyses of the environmental and economic impact of the packages utilized for transit of peaches is necessary. In this study, we use the metrics of peach grade, firmness, soluble solids concentration, and percent softness before and after the distribution …

The Effects Of Compression Wrapping Techniques And Primary Wound Dressings On Leg Skin Interface Pressure, James Cox

All Theses

Peripheral edema affects approximately 20% of people in the US over the age of 50 and is frequently encountered among individuals with conditions such as heart disease, prolonged immobility, and venous insufficiency.¹ Compression is an established therapeutic tool utilized for the management of several chronic edema presentations including lymphedema and venous leg ulcers.^2,3 Therapeutic efficacy of compressive applications can be evaluated by defining interface pressure (IP) and IP distributions associated with specific textile combinations.² During compressive applications where an open wound is present, primary wound dressings should be used in combination with compressive wraps. Primary wound dressings …

The Extent Of Drone Education Being Taught In Asc Schools To 4-Year Construction Students, Cheran Teja Dumpati

All Theses

The technology of Unmanned Aircraft Systems (UAS) is growing rapidly in many fields and has become one of the skills in demand in the industry. Universities are one of the primary sources of teaching drone technology with a career-oriented approach. The goal of this study is to investigate the content of the drone curriculum being taught in Associated Schools of Construction (ASC) schools. This includes the topics covered, practical training offered, and the key deliverables taught. This information serves as a foundation for the schools that are looking forward to start drone courses in their department. The research found that …

Characterization Of Mechanically Recycled Polylactic Acid (Pla) Filament For 3d-Printing By Evaluating Mechanical, Thermal, And Chemical Properties And Process Performance, Mahsa Shabani Samghabady

All Theses

Polylactic acid (PLA) is a biopolymer made from renewable resources such as sugar and corn. PLA filament is a popular material used in Fused Deposition Modeling (FDM) 3D-printing. While this material has many advantages, all the failed parts, support structures, rafts, nozzle tests, and the many prototype iterations during the 3D-printing process contribute to the plastic pollution and release of greenhouse gases. Although PLA is biodegradable, it can take years to degrade in landfills. Instead of throwing away PLA waste and buying new filaments, PLA can be recycled. Amongst the different recycling technologies, mechanical recycling is the most environmentally friendly. …

Tandem Peptides Targeting Her2 For Delivery Of Cd44 Sirna Into Her2+ Breast Cancer Cells In Vitro, James Kalogeros

All Theses

More than 300,000 women will be diagnosed with breast cancer, and approximately 48,000 women will die this year due to the disease in the United States. HER2+ breast cancer accounts for 20-25% of invasive breast cancer, and it has a worse prognosis and higher early-stage mortality rate than other breast cancer subtypes. Common treatments for HER2+ breast cancer involve surgical removal of the breast or systemic therapy with chemotherapeutic drugs, both of which cause damage to healthy tissue. Due to the lack of a natural ligand for the HER2 receptor, there is a need for improved targeting strategies for the …

Water Scarcity: Impact On Water Rights, Institutions, And An Irrigated Agriculture, Nataly Medina

All Theses

This thesis combines two papers to provide a better understanding of the effects and management of water scarcity during periods of water shortage. The first manuscript discusses the evolution of water rights across the southeastern United States in response to increasing demands and droughts, while the second manuscript studies the effects of water scarcity on agriculture production in the western US.

The southeastern United States has historically benefited from abundant water supplies, allowing them to apply the riparian doctrine with little regulation. However, in the past few decades, the region has undergone major shifts in water policy. In the first …

Vibration Fatigue Of Leaded Solder Joint Interconnects For Pcb Electronics, John Crowder

All Theses

With the increasing prevalence of electronic equipment worldwide, there is also a decrease in the size of the components on their printed circuit boards (PCBs), leading to an increase in the density of these components. A significant amount of failure in electronic equipment is vibration fatigue of solder joints and their attachments. However, the complexity of these PCBs and their components has made finite element modeling (FEM) more complex, adding considerable time to create and analyze a model.

This paper aims to provide a literature review for the vibration fatigue of leaded solder components, create a test setup, and validate …

Generalizable Deep-Learning-Based Wireless Indoor Localization, Ali Owfi

All Theses

The growing interest in indoor localization has been driven by its wide range of applications in areas such as smart homes, industrial automation, and healthcare. With the increasing reliance on wireless devices for location-based services, accurate estimation of device positions within indoor environments has become crucial. Deep learning approaches have shown promise in leveraging wireless parameters like Channel State Information (CSI) and Received Signal Strength Indicator (RSSI) to achieve precise localization. However, despite their success in achieving high accuracy, these deep learning models suffer from limited generalizability, making them unsuitable for deployment in new or dynamic environments without retraining. To …

Exploring The Necessity Of Technology In Architectural Design: Moving Beyond Showcasing, Ertunc Hunkar

All Theses

Advancements in technology, particularly computational design tools, have transformed the field of architectural design. However, it is crucial to evaluate the impact of technology on the core principles of problem-solving and the design process within architecture. This study aims to examine the consequences and opportunities associated with the integration of technology in architectural design, focusing on the necessity of maintaining a strong problem-solving foundation. Architectural problem-solving involves spatial organization, functional requirements, contextual integration, and user experience. These principles guide architects in addressing design challenges and achieving successful outcomes. The design process comprises stages such as research, analysis, concept development, and …

The Influence Of Premium Finished Paper Packaging On Consumer Behavior, Sahil Bhayani

All Theses

Companies face the challenge of determining the return on investment of premium paper packaging features, such as substrate thickness and finishing options. If companies can better understand how consumers perceive “premium,” they could channel their focus on specific design elements and maximize their returns (Dwivedi & Nayeem, 2018). Touch is a critical factor in driving consumer behavior and purchase decisions and influencing trust between brands and consumers (Krishna et al. 2017). While previous studies have explored the impact of design elements like size, shape, color, and font on consumer behavior, this research investigates the influence of touch, substrate, print finishes …

An Assessment Of Clemson Cooperative Extension Agents’ Perceptions Of Work-Related Factors Leading To Burnout, Erika Hwang

All Theses

Turnover and employee burnout are problems the Cooperative Extension System is facing nationwide, and the Clemson University Cooperative Extension System is no exception. There has been previous research done within the Extension system to identify the factors contributing to turnover and burnout, however, both remain an issue. Yet, there has been no research done to examine the Clemson University Cooperative Extension System individually. To further investigate factors contributing to burnout, this pilot study was conducted with Clemson University Clemson Extension agents using a burnout assessment that has not previously been used in Extension research. This study described Clemson University Cooperative …

Design And Fabrication Of An Optical Blade Tip Timing Sensor, Nick Tomlinson

All Theses

Electricity is a vital energy source that powers modern technology. Turbines are heavily relied on in the electric power industry for the conversion of natural energy sources into electricity. These turbines operate under harsh conditions which increase the likelihood of blade damage. Structural health monitoring of a turbine’s blades is important to detect problems before a blade experiences failure. The blade tip timing method can be used to monitor blade vibrations and determine if damage has occurred. An optical blade tip timing sensor is designed and fabricated to advance the field of sensing in the power industry.

Women Building After The Charleston Fire Of 1838 Using “An Act For Rebuilding The City Of Charleston” Loans, Joyce Pope

All Theses

The subject of this thesis is women commissioning buildings using loans they obtained as part of An Act for Rebuilding the City of Charleston. The Act, which passed after the fire of 1838, made $2 million dollars in loans available to all Charlestonians to rebuild the city after the fire wiped out hundreds of buildings on the peninsula. As a result of the way the act was structured, at least ten women, including a formerly enslaved woman, received loans and built houses and commercial buildings using those funds. This thesis examines whether the loan program opened the door for women …

Virtual Prototyping And Validation For Autonomous Assistive Mobility, Amogh Venkataramana Reddy

All Theses

Physical disability in humans is something that no one has control over. It is catastrophic for people to experience it, and sometimes hinders them from enjoying the essence of life. Though disability is something people have no control over, they do have control on how they can go forward and make life beautiful and meaningful. Wheelchairs have helped people with disabilities in mobility, allowing them to move around with the help of others or sometimes on their own. This research will focus on development of an autonomous assistive mobility robot to help the disabled using virtual prototyping tools for development …

Multiphysics Diesel Aftertreatment System Modeling For Reduced Emissions From Hybrid Electric Heavy-Duty Powertrains, Uday Srivastav

All Theses

Hybridization of heavy-duty on-road vehicles presents an opportunity to significantly reduce internal combustion engine emissions in real-world operation. These gains can be realized through the coordination of the electric drive, engine, and aftertreatment systems. Accurate Multiphysics models of all powertrains sub-systems are required to achieve the goal of reduced emissions. This research aims to develop a model of a highly complex diesel engine aftertreatment system. This study focuses on utilizing transient data for calibration and validation of the aftertreatment system and reducing the run time when compared to real-time experiments. The calibration focuses on two physical phenomena, thermal behavior and …

The Effect Of Deployment And Optimal Dispatch Of Shared Electric Shuttles On The Energy Efficiency Of Campus Transit, Robert Smith

All Theses

A problem facing most public transit systems is low energy efficiency and the continued cycling of large transport vehicles such as buses at low occupancy when low demand for transport exists, wasting energy to no benefit. To remedy this issue, we propose a hybrid system consisting of existing diesel buses and automated electric shuttles to augment the system during off-peak hours. Due to their smaller size, higher occupancy, and more efficient powertrains, these shuttles could reduce the system energy used per passenger-mile-traveled. Automation removes the labor cost of drivers and, thus, eliminates the need to employ more drivers for the …

Effects Of Ivd-Like Pressure And Ph On Human Adipose Derived Mesenchymal Stem Cells, Alexandria Pendino

All Theses

Low back pain (LBP) affects approximately 12% of adults in the US, and of these cases, between 26 and 42% are caused by intervertebral disc degeneration (IVDD). Current treatment approaches for LBP and IVDD, such as medication and surgery, mainly focus on reliving pain and do not address current or future degeneration. As a result of reherniation, up to 15% of patients will need a second surgery. As a solution, the use of tissue engineering combining scaffolds and stem cells to regenerate the damaged structures has been proposed. There are several types of stem cells that have shown potential for …

Influence Of Swirl And Turbulence In The Particle Removal Using Fog In A Pipe Flow, Nisarg T. Patel

All Theses

Fog-and-tube scrubbers are employed to remove harmful ultrafine aerosols, such as Diesel particulate matter (DPM), from an airflow. The underlying principle of this removal process involves enlarging the aerosol particles by coagulating them with fog drops, which are subsequently eliminated through inertial impaction onto the tube wall. Previous research conducted by Tabor et al. (2021) demonstrated an increase in scavenging of ultrafine DPM particles, ranging from 11.5 nm to 154 nm, by as large as 45% over the no fog case. This finding is crucial in addressing the challenges associated with conventional filtration methods for capturing ultrafine particles.

The present …

Performance Modeling Of Inline Compression With Software Caching For Reducing The Memory Footprint In Pysdc, Sansriti Ranjan

All Theses

Modern HPC applications compute and analyze massive amounts of data. The data volume is growing faster than memory capabilities and storage improvements leading to performance bottlenecks. An example of this is pySDC, a framework for solving collocation problems iteratively using parallel-in-time methods. These methods require storing and exchanging 3D volume data for each parallel point in time. If a simulation consists of M parallel-in-time stages, where the full spatial problem has to be stored for the next iteration, the memory demand for a single state variable is M ×Nx ×Ny ×Nz per time-step. For an application simulation with many state …

Bringing Vanished Landscapes To The Surface: A Multi-Tool Approach To Unearthing Charleston's Walled City, Alexis Allen

All Theses

The early 18^th century historic fortification system that surrounded the urban town of Charleston has been a focus of excavations and historical research within the past two decades. However, while the outline of early Charleston’s walled city is hypothesized through the analysis of historic maps and plats, very few fortification locations have been visually confirmed. In order to determine their accuracy, this thesis georeferenced eleven historic maps and four plats to the modern landscape. As a result, possible locations of Charleston’s walled city were predicted. These were surveyed as test sites and remote sensing methods were employed that helped …

Dynamics And Steering Of A Vibration-Driven Bristle Bot In A Pipe System, Ian Stewart

All Theses

Soft vibrational robots are robots that incorporate compliant structures into their design and are driven by oscillating actuators. A recent, popular version of a soft vibrational robot is the bristle bot, which uses flexible bristles and a vibration motor to propel itself across surfaces and through pipes. This motion is primarily driven by stick-slip dynamics resulting from asymmetric frictional forces applied at the bristle tips. Depending on the frequency of vibration of the motor, the robot experiences various resonance regions allowing it to maneuver in different directions. Attaching bristles to all sides of the robot and placing it in a …

Integrating Sensor Development, Risk Assessment, And Community Engagement To Support Environmental Justice In The Rural Community Of El Tiple, Colombia, David Bahamon Pinzon

All Dissertations

In Colombia, ethnic communities have traditionally been responsible stewards of natural resources. They recognize the importance of these resources for their livelihood, as well as their ancestral and cultural heritage. El Tiple, a rural Afro-Colombian community, has been affected by the incursion of private corporations that promoted the expansion of sugarcane monocrops in their territory. Since the introduction of the monoculture industry, local freshwater sources have been depleted due to intensive water use for irrigation of the sugarcane crops. Additionally, the intensive usage of agrochemicals has been linked with loss of native flora, damages to family farms, and pollution of …

Development & Validation Of Needle-Based Metrics For Hemodialysis Cannulation Skill Assessment, Ziyang Zhang

All Dissertations

Dialysis is a vital medical treatment for patients with end-stage renal disease. An arteriovenous fistula, a surgically created connection between an artery and a vein, is the preferred vascular access for dialysis due to superior clinical outcomes. However, cannulation complications caused by needle-related errors are common and dangerous, necessitating the need for effective cannulation training. Despite cannulation being a challenging and complex clinical procedure, little is known about the quantitative aspects of needle insertion dynamics necessary for skilled cannulation. The aim of this study was to develop meaningful and instructive needle-based metrics for cannulation skill assessment and training.

Two iterations …

A Framework For Statistical Modeling Of Wind Speed And Wind Direction, Eva Murphy

All Dissertations

Atmospheric near surface wind speed and wind direction play an important role in many applications, ranging from air quality modeling, building design, wind turbine placement to climate change research. It is therefore crucial to accurately estimate the joint probability distribution of wind speed and direction. This dissertation aims to provide a modeling framework for studying the variation of wind speed and wind direction. To this end, three projects are conducted to address some of the key issues for modeling wind vectors.\\

First, a conditional decomposition approach is developed to model the joint distribution of wind speed and direction. Specifically, the …

Generative Neural Network-Based Defense Methods Against Cyberattacks For Connected And Autonomous Vehicles, M Sabbir Salek

All Dissertations

The rapid advancement of communication and artificial intelligence technologies is propelling the development of connected and autonomous vehicles (CAVs), revolutionizing the transportation landscape. However, increased connectivity and automation also present heightened potential for cyber threats. Recently, the emergence of generative neural networks (NNs) has unveiled a myriad of opportunities for complementing CAV applications, including generative NN-based cybersecurity measures to protect the CAVs in a transportation cyber-physical system (TCPS) from known and unknown cyberattacks. The goal of this dissertation is to explore the utility of the generative NNs for devising cyberattack detection and mitigation strategies for CAVs. To this end, the …