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Heat Flux Measurement By Miniature Calorimeters, Gary Rex Coffin Aug 1963

Heat Flux Measurement By Miniature Calorimeters, Gary Rex Coffin

Theses and Dissertations

During recent years an increasing number of technical firms and manufacturers have begun to specify heat flux, energy input per unit area per unit time, as a testing and designing criteria. This change in the boundary condition (to heat flux from temperature excess or others) evolved from the idea that each material has a characteristic burning temperature. Therefore, the rate of ablation or burning depends mainly upon the rate of energy input into the specimen, and not its temperature. Thus, the need for a flux measuring device became more acute.

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Radiant Flux Distribution From Concave Radiation Sources, Richard K. Duke Aug 1963

Radiant Flux Distribution From Concave Radiation Sources, Richard K. Duke

Theses and Dissertations

In order to analyse the radiant heat transfer characteristics of a concave source, two vital concepts must be clearly understood. The first is called the apparent emissivity Ea and is a function of both the local total emissivity E and of the geometry of the source. Although the total emissivities of ordinary substances range between zero and one, the two extremeties never occur. Surface emissivities which approach these values in the limit, must be created mechanically from materials in the range 0

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Thermodynamics Of I) Metal Cyanide Coordination, Ii) Water Formation, And Iii) Metal Halide Coordination, John Dewey Hale Jul 1963

Thermodynamics Of I) Metal Cyanide Coordination, Ii) Water Formation, And Iii) Metal Halide Coordination, John Dewey Hale

Theses and Dissertations

ΔH values for the formation of Ni(CN)4(aq)= have been determined calorimetrically at 25° using a simple calorimeter and a thermometric titration procedure at high and low ionic strengths, respectively. Extrapolation of these ΔH values to infinite dilution resulted in a ΔH° value of -42.7 kcal./mole. Combination of ΔH° and ΔF° values gives a ΔS° value of -5.5 e.u. for Ni(CN)4(aq)= formation. A value of +70 e.u. is calculated for the ionic entropy of Ni(CN)4(aq)=. A preliminary investigation of the Zn(CN)4(aq)= system indicated the existence of zinc cyanide complexes other than Zn(CN)4= and allowed calculation of an approximate ΔH° value of …

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A Study Of The Vibration Characteristics Of A Thin Shell Hyperbolic Paraboloid, Farrin W. West May 1963

A Study Of The Vibration Characteristics Of A Thin Shell Hyperbolic Paraboloid, Farrin W. West

Theses and Dissertations

Recent progress in structural engineering has been marked by the increased use of thin shells as load carrying members. In particular, shells of revolution have been widely utilized in the missile industry whereas shells of arbitrary shape have been incorporated in the architectural design of today's modern buildings. Missile applications have been extensively studied both statically and dynamically. However, architechural applications have generally been limited to the statics problem with little consideration being given to the dynamic behavior of these unique structures.

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Molecular Addition Compounds :|Bi. Systems Of P-Dioxane With Alkyl Halides, Anisole, And Silicon Tetrachloride ; Ii. Titanium Tetrachloride Chargetransfer Complexes Of Benzene, P-Xylene, And Pseudocumene, Nolan F. Mangelson May 1963

Molecular Addition Compounds :|Bi. Systems Of P-Dioxane With Alkyl Halides, Anisole, And Silicon Tetrachloride ; Ii. Titanium Tetrachloride Chargetransfer Complexes Of Benzene, P-Xylene, And Pseudocumene, Nolan F. Mangelson

Theses and Dissertations

Freezing-point diagrams were detennined tor a number or p-dioxane systems. The system, p-dioxane:carbon tetrachloride, was found to contain a 1:2 complex with a congruent melting point of 255.71 °K. This confirmed work reported in the literature. Solid solutions in the region between 0.0000 and 0.4796 mole fraction of p-dioxane were found in the present study. The system, p-dioxane:chloroform, was found to contain a 1:2 complex with a congruent melting point of 215.65 °K. It was determined that no other complexes formed in the solid state. This information resolved contradicting reports in the literature. The system, p-dioxane:dichloromethane, was found to contain …

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Directive Effects In The Sulfonation Of Toluene ; Synthesis And Attempted Rearrangement Of Some Anilinoketones ; The Kinetics And Mechanism Of The Addition Of Bromine To Cyclohexene In Dichloromethane. Solution, John Joseph Duvall Feb 1963

Directive Effects In The Sulfonation Of Toluene ; Synthesis And Attempted Rearrangement Of Some Anilinoketones ; The Kinetics And Mechanism Of The Addition Of Bromine To Cyclohexene In Dichloromethane. Solution, John Joseph Duvall

Theses and Dissertations

The pure sodium salts of the toluenesulfonic acids were prepared by one of two ways. Both methods started with diazotization of the toluidine. In the first method, the diazonium solution was treated with sulfur dioxide and copper powder, and the resulting sulfinic acid was oxidized to the sulfonic acid with potassium permanganate. In the second method, the diazonium solution was treated with cuprous chloride and sulfur dioxide to give the sulfonyl chloride which was hydrolyzed to the sulfonate. Toluene was sulfonated by SO3 (enriched with S-35) in refluxing SO2 solution. The isotope dilution technique was used to determine the isomer …

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An Analysis Of The Theory And Practice Of Worship In The Church Of Jesus Christ Of Latter-Day Saints, John Franklin Heidenreich Jan 1963

An Analysis Of The Theory And Practice Of Worship In The Church Of Jesus Christ Of Latter-Day Saints, John Franklin Heidenreich

Theses and Dissertations

The concept of worship projected in this study is the broad Isaiah pattern of worship of awareness of God, restructuring of the life of the individual, and dedication of the worshiper in service. From this concept, standards of worship are set forth by which Latter-day Saint worship is evaluated.

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A Parametric Study Of The Heat Transfer Characteristics Of A Moving Band Heat Exchanger, Larry Hyde Brim Sep 1962

A Parametric Study Of The Heat Transfer Characteristics Of A Moving Band Heat Exchanger, Larry Hyde Brim

Theses and Dissertations

In recent years much attention has been devoted to the development of efficient heat exchangers. The regenerative or moving matrix heat exchanger is one type which has been considered. Most regenerative heat exchangers use one of the conventional types of high area matrices mounted in a drum or disk in such a manner that it can be moved in a continuous cycle from a cold fluid stream to a hot fluid stream and back again. A rather different approach to the design of a regenerative heat exchanger which has been patented in this country is a set of flexible moving …

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Kinetic Investigation Of The Hydrochlorination Of Olefins In Aprotic Solvents And Sulfonation Of Idobenzene And The Selectivity Relation, Thomas Glen Davies Sep 1962

Kinetic Investigation Of The Hydrochlorination Of Olefins In Aprotic Solvents And Sulfonation Of Idobenzene And The Selectivity Relation, Thomas Glen Davies

Theses and Dissertations

Kinetic investigation of the hydrochlorination of cyclohexene and cis-2-butene in n-heptane with SnCl4 as catalyst shows that the reaction is second order with respect to both olefin and catalyst. The specific rate constants at 25° , 0° and -23.8°C and the activation parameters were determined. Investigation of the Ga2Cl6 catalyzed hydrochlorination of cyclohexene and cis-2-butene in dichloromethane indicates that alkylation and polymerization compete with the hydrochlorination reaction in the presence of the solvent. The relative reaction rates and the isomer distribution for the sulfonation of iodobenzene by S35O3 have been determined in refluxing SO2 at -10°C. The reaction resulted in …

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Sulfonation Of Chlorobenzene And The Selectivity Relation ; Bromine Addition To Cyclohexene In Dichloromethane ; Thorpe's Synthesis Of The Caged Acid, 4-Methyltricyclo[1.1.0.0[Superscript 2-4]] Butane-1,2,3-Tricarboxylic Acid, John A. Gurney Aug 1962

Sulfonation Of Chlorobenzene And The Selectivity Relation ; Bromine Addition To Cyclohexene In Dichloromethane ; Thorpe's Synthesis Of The Caged Acid, 4-Methyltricyclo[1.1.0.0[Superscript 2-4]] Butane-1,2,3-Tricarboxylic Acid, John A. Gurney

Theses and Dissertations

Aromatic sulfonation and some substitution reactions of chlorobenzene show deviations in the selectivity relation. A determination of chlorobenzene sulfonation provided the following rate ratio relative to benzene and partial rate factors: 1.0, [---] of 0.064 , mf 1.7 and pf 4. 2. Our work, Olah's nitration, Ferguson's bromination and Stock's chlorination define a new relation that can be express by adding an entropy term (A) to the selectivity relation. We determined the rate of bromine-cyclohexene addition in dichloro-methane at 0° to provide a basis for a systematic variation of solvents at low temperature. An unusual zero-order reaction was encountered. The …

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Dissertation In Organic Chemistry. Part I, The Fate Of The Anilino Moiety In The Rearrangement Of Α-Anilonoketones. Part Ii, Partial Rate Factors For Sulfonation Of Bromebenzene With Sulfur Trioxide. Part Iii., Preliminary Survey On The Effect Of High Pressure On Ferrocene And Cycloöctatetraene, Jerold Carter Robertson Aug 1962

Dissertation In Organic Chemistry. Part I, The Fate Of The Anilino Moiety In The Rearrangement Of Α-Anilonoketones. Part Ii, Partial Rate Factors For Sulfonation Of Bromebenzene With Sulfur Trioxide. Part Iii., Preliminary Survey On The Effect Of High Pressure On Ferrocene And Cycloöctatetraene, Jerold Carter Robertson

Theses and Dissertations

Part I. The rearrangement of α-anilinoketones was studied in an effort to determine the mode of movement of the nitrogen moiety. A crossover experiment was carried out with an equimolar mixture of 2-(4- bromoanilino)-1-(4-bromophenyl)-2-(4-methoxyphenyl) ethanone and 2-(4-chloroanilino)-1-(4-chlorophenyl) -2-(4-methoxyphenyl)ethanone with γ- picoline hydrobromide as the catalyst. The reaction product was analysed by means of a mass spectrograph. The results of the analysis indicate a crossover of the nitrogen moiety during rearrangement. This indicates that the nitrogen moiety moves in an intermolecular manner during the rearrangement. Part II. The isomer distribution from the sulfonation of bromobenzene with sulfur trioxide was determined by …

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Stress Analysis Of An Infinite Cylinder With An Irregular Shaped Cavity Using Complex Variable Techniques, Gerald H. Lindsey Aug 1962

Stress Analysis Of An Infinite Cylinder With An Irregular Shaped Cavity Using Complex Variable Techniques, Gerald H. Lindsey

Theses and Dissertations

The advancement of modern technology has brought with It a demand upon the engineer for more thorough analysis techniques. This has been precipitated by the advent of missiles and space-craft that do not permit regular inspections to determine causes of failure, crack propagation, design weaknesses, etc. Thus, a more complete analytical work must be performed to facilitate a foreknowledge of reaction and performance of a particular design to its environment.

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A Literature Review Covering The Effect Of Residual Stresses On Fatigue Strength Of Steel, Clarence A. Calder Aug 1962

A Literature Review Covering The Effect Of Residual Stresses On Fatigue Strength Of Steel, Clarence A. Calder

Theses and Dissertations

Fatigue fracture usually is defined as the failure of a part at a stress below its breaking stress due to repetitive loading conditions. It is now a well known fact that a part, designed for a maximum stress well below the yield point of the material, may be very apt to fail under cyclic loading conditions over a period of time. The metal appears to "wear out" after a time just like humans do and fatigue failure occurs. Metal fatigue may be contrasted to animal fatigue in that l) its detection before the latter stages is normally difficult if not …

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Diffraction Of Spherical Scalar And Vector Waves At Axial Points Of A Circular Aperture And Disk, Keith Leon Mcdonald Jun 1962

Diffraction Of Spherical Scalar And Vector Waves At Axial Points Of A Circular Aperture And Disk, Keith Leon Mcdonald

Faculty Publications

The following work treats Kottler's saltus problem of diffraction of electromagnetic waves emitted by a Hertzian oscillator source and the analogous Kirchhoff's scalar problem of waves emitted by a point source. The medium is a homogeneous isotropic dielectric. In the vector case a new exact solution of the basic integrals is presented, at axial points only, (a) behind a circular aperture in a "black'' screen, and (b) behind its complementary "black'' disk. The relative time-averaged intensity of energy flow is plotted for the disk only. It is shown that the scalar theory predicts considerably larger values than the electromagnetic theory …

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An Investigation Of Coulometric Methods Of Analysis Of 1,1-Dimethylhydrazine, David M. Creighton May 1962

An Investigation Of Coulometric Methods Of Analysis Of 1,1-Dimethylhydrazine, David M. Creighton

Theses and Dissertations

The oxidation of 1,1-dimethylhydrazine by bromine has been studied using a coulometric method of bromine generation, and a dual intermediate system of bromide and cupric ions in solution. The system allowed over-generation of bromine and back-titration by cupric ion. The results of the investigation showed that the mechanism of oxidation is not fixed, but is a function of the concentration of bromine in the solution at any time. Additional studies have been recommended, whereby the mechanisms of the reactions may be determined.

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The Aerodynamic Drag Of Spheres, Leon Rouzelle Scott May 1962

The Aerodynamic Drag Of Spheres, Leon Rouzelle Scott

Theses and Dissertations

A literature survey was conducted to determine the factors which affect aerodynamic drag of spheres. Graphs are presented which show the effect of each variable where such information was available. Equipment was designed and built for the purpose of studying the effects of acceleration on the aerodynamic drag of spheres. Special emphasis was placed on the measurement and control of each of the other variables which can affect the drag. Tests were conducted using large spheres in air and water to show that the method presented can produce a valid determination of the drag coefficients. The numerical values of the …

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William James: Philosopher-Educator, Truman G. Madsen Jan 1962

William James: Philosopher-Educator, Truman G. Madsen

BYU Studies

William James, renowned for his work in philosophy and psychology, was also a highly influential and effective educator. This article explores James's background, his classroom philosophy and teaching style, his intellectual appeal, his depth of knowledge, his individual attention to students, and his attitude toward teaching in order to illuminate the reason behind his great power as a teacher.

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Plato's Trinity As Problem And Promise In University Life, Obert C. Tanner Jan 1962

Plato's Trinity As Problem And Promise In University Life, Obert C. Tanner

BYU Studies

Plato's ideals of goodness, truth, and beauty exist in a precarious balance. Not only are they out of humanity's reach, they cause problems when one overpowers the other two. Universities are in a unique position when it comes to fostering these ideals. If Brigham Young University is to become a great university, its faculty and students need to find the proper balance between its quest for goodness, truth, and beauty.

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A Note On K-Commutative Matrices, D. W. Robinson Nov 1961

A Note On K-Commutative Matrices, D. W. Robinson

Faculty Publications

Let A and B be square matrices over a field in which the minimum polynomial of A is completely reducible. It is shown that A is k commutative with respect to B for some non-negative integer k if and only if B commutes with every principal idempotent of A. The proof is brief, simplifying much of the previous study of k-commutative matrices. The result is also used to generalize some well-known theorems on finite matrix commutators that involve a complex matrix and its transposed complex conjugate.

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A Thermodynamic Study Of Step-Wise Complex Formation In Several Aqueous Copper (Ii)-Amino Acid Systems, Vipin M. Kothari Sep 1961

A Thermodynamic Study Of Step-Wise Complex Formation In Several Aqueous Copper (Ii)-Amino Acid Systems, Vipin M. Kothari

Theses and Dissertations

pK_n values for step-wise dissociation of protons from the protonated ligands (glycine, α-amino isobutyric acid, sarcosine and theonine) were determined potentiometrically with a Beckman Model GS pH meter in aqueous solution at 10, 20, 30 and 40° C. Log K values for step-wise interaction of glycine, α-amino isobutyric acid, sarcosine and threonine with copper(II) ion were also determined potentiometrically with a pH meter at 10, 20, 30 and 40° C. The standard free energy of formation for the step-wise interaction of copper(II) with each of the above ligands was calculated from the values of log K. Enthalpy and entropy changes …

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A Thermodynamic Study Of Complex Formation In Aqueous Solution.|Ni.|Pthe Hg(Ii)-, Zn(Ii)-, Cd(Ii)-, Ag(I)-Serine Systems.|Nii.|Pthe Hg(Ii)-, Zn(Ii)-, Cd(Ii)-, In(Iii)- Thioglycollic Acid System :|Ba Study Of The Effect Of D[Pi]-D[Pi] Bonding On These Complexes, Marriner Lee Morrell Aug 1961

A Thermodynamic Study Of Complex Formation In Aqueous Solution.|Ni.|Pthe Hg(Ii)-, Zn(Ii)-, Cd(Ii)-, Ag(I)-Serine Systems.|Nii.|Pthe Hg(Ii)-, Zn(Ii)-, Cd(Ii)-, In(Iii)- Thioglycollic Acid System :|Ba Study Of The Effect Of D[Pi]-D[Pi] Bonding On These Complexes, Marriner Lee Morrell

Theses and Dissertations

Thermodynamic equilibrium constants were obtained potentiometrically using a Beckman pH meter for metal-serine and metal-thioglycolloc acid complexes to study the thermodynamic properties of the complexes and the effect of dπ - dπ bonding on the equilibrium constants. The following calculations were made: 1. The stepwise dissociation of protons from serine at 10, 20, 30, and 40°C and the stepwise dissociation of protons from thioglycollic acid at 20, 30, and 40°C. 2. The thermodynamic formation constants for Zn(II), Cd(II), Hg(II), and Ag(I) with serine at 10, 20, 30, and 40°C and at two ionic strengths. 3. The thermodynamic formation constants for …

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The Influence Of Temperature And Some Other Factors On The Biological And Nonbiological Oxidation Of Chalcopyrite, Pyrite And Copper Sulfide, Ezra Revier Palmer Aug 1961

The Influence Of Temperature And Some Other Factors On The Biological And Nonbiological Oxidation Of Chalcopyrite, Pyrite And Copper Sulfide, Ezra Revier Palmer

Theses and Dissertations

The purpose of this study was: (1) to find the effect of temperature on the wet oxidation of chalcopyrite, pyrite, and copper sulfide over the biological and nonbiological range; (2) to determine the influence of ferrous and ferric iron and free oxygen(air) on the oxidation. The sulfide minerals studied were oxidized over a range of temperatures between 25° to 75° C. The optimum biological oxidation occurred near 35° C. The nonbiological oxidation was very slow at low temperatures but increased with increasing temperature. The effect of solutions used in leaching the various sulfides over the temperature range differred. A synthetic …

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An Historical Study Of The Factors Influencing The Organization Of Education In Washington County, 1852-1915, Robert H. Moss Jan 1961

An Historical Study Of The Factors Influencing The Organization Of Education In Washington County, 1852-1915, Robert H. Moss

Theses and Dissertations

The purpose of this study was to trace the development of education in Washington County from its beginnings as a small district system to its present status as a free public school system within a county administrative unit.

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Application Of The Quasi-Lattice Theory To The Heats Of Mixing Of Some Alcohol-Hydrocarbon Systems, Mar Lynn James Sep 1960

Application Of The Quasi-Lattice Theory To The Heats Of Mixing Of Some Alcohol-Hydrocarbon Systems, Mar Lynn James

Theses and Dissertations

Values for the heats of mixing were obtained calorimetrically for the systems C2H5OH-C6H12, CH3OH-C6H6 and C2H5OH-C6H6 at 25° over the complete range of composition. Analytical equations which summarize these values are: Benzene (1) - Methanol (2) System ΔHxM = x1x2[628.4 + 365.7(x1-x2) + 521.9(x1-x2)3 + 819.8(x1-x2)4 ] Benzene (1) - Ethanol (2) System ΔHxM = x1x2[748.8 + 534.1(x1-x2) + 265.7(x1-x2)2 + 408.7(x1-x2)3 + 434.1(x1-x2)4 ] Cyclohexane (1) - Ethanol (2) System ΔHxM = x1x2[615.0 + 132.4(x1-x2) + 195.9(x1-x2)2 + 251.5(x1-x2)3 + 521.7(x1-x2)4 ] where xi is the mole fraction of component i. The experimental data were satisfactorily interpreted by a …

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An Investigation Of Solvent Extraction Techniques In The Determination Of Formation Constants Of Complex Species In Aqueous Silver Chloride Solution, David Martin Bodily Jul 1960

An Investigation Of Solvent Extraction Techniques In The Determination Of Formation Constants Of Complex Species In Aqueous Silver Chloride Solution, David Martin Bodily

Theses and Dissertations

Solvent extraction techniques have been used to determine formation constants for molecular silver chloride and dichloro silver (I) ion in unsaturated aqueous solutions. Nitrobenzene was used to extract the molecular silver chloride from the aqueous silver chloride solution. The total concentration of silver in each phase was determined by radioassay techniques and related by an expression involving the equilibrium constants. The reciprocal of the distribution ratio times the activity of the chloride ion was plotted versus the activity of the chloride ion and portions of the curve were analyzed by the method of least squares to obtain values for the …

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The Vitamin B1-Sparing Action Of Sorbitol, Gisela Eleanor Bethsold Jun 1960

The Vitamin B1-Sparing Action Of Sorbitol, Gisela Eleanor Bethsold

Theses and Dissertations

The present study was initiated to determine the effect sorbitol has upon the enzymatic functions of thiamin; specifically, what effect sorbitol bas upon the alpha-ketoglutarate and pyruvate dehydrogenases activities of rat liver mitochondria. In addition, the effect of varying the dietary sorbitol concentration on the development of an athiaminosis was studied, particularly the effect on growth rate.

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An Investigation Of The Formation Constant Of Molecular Silver Chloride Using Ion Exchange Techniques.|Nii.|Pan Investigation Of The Rate Of Precipitation Of Silver Sulfide By Thioacetamide, James W. Pyper May 1960

An Investigation Of The Formation Constant Of Molecular Silver Chloride Using Ion Exchange Techniques.|Nii.|Pan Investigation Of The Rate Of Precipitation Of Silver Sulfide By Thioacetamide, James W. Pyper

Theses and Dissertations

The first part of this work reports on the investigation of the formation constant of molecular silver chloride using ion exchange techniques. In order to determine the formation constant, it was necessary to develop a method of rinsing the sorbed molecular silver chloride from the resin. It was found that desorption with nitrobenzene would remove the sorbed molecular species. However, the formation constant was not calculated since the nitrobenzene used contained hydrogen ion and chloride ion which removed silver ion as well as the molecular species. In the study of the formation of silver sulfide by the reaction between the …

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The United Nations As A Policy Instrument, Robert E. Riggs Apr 1960

The United Nations As A Policy Instrument, Robert E. Riggs

BYU Studies

The author examines how the United Nations is an instrument of United States policy. To varying degrees, within the General Assembly, the Security Council, the Economic and Social Council, the Trusteeship Council, and the Secretariat, the United States exerts its influence. Each UN body serves a unique function in which the United States can further its own foreign policy.

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The Differential Effects Of Bases For Moral Behavior And Major Field Of Study Upon Moral Judgment, Ray Edgar Paskett Jan 1960

The Differential Effects Of Bases For Moral Behavior And Major Field Of Study Upon Moral Judgment, Ray Edgar Paskett

Theses and Dissertations

The purpose of this study was to determine whether the individual's bases for moral behavior and his major field of study are related to his moral judgement. Previous studies have indicated that the effect of certain moral education programs was either negligible or detrimental to the accomplishment of their objectives. Because of the emphasis by the Church of Jesus Christ of Latter-day Saints upon fundamental principles as determinants of moral behavior, it seems appropriate to examine the effects of these concepts upon the individual.

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Early History Of Malad Valley, Glade F. Howell Jan 1960

Early History Of Malad Valley, Glade F. Howell

Theses and Dissertations

The Malad Valley is geographically located in a unique position in the Pacific Northwest. The Bear River and its main affluent, the Malad River, are the only rivers in the Pacific Northwest that drain into the Great Basin, whereas the other streams and rivers of the states of Washington, Idaho, and Oregon empty eventually into the Pacific Ocean. It is also characterized for being the northern end of prehistoric Lake Bonneville, and eventually it was through this valley that an outlet opened to drain the lake. The soil deposits from this lake left a fertile valley, capable of producing most …

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