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Pressure Calibration To 100 Kbar Based On The Compression Of Nacl, R. N. Jeffrey, J. Dean Barnett, H. B. Vanfleet, H. Tracy Hall Jul 1966

Pressure Calibration To 100 Kbar Based On The Compression Of Nacl, R. N. Jeffrey, J. Dean Barnett, H. B. Vanfleet, H. Tracy Hall

Faculty Publications

An independent determination has been made of the transformation pressures assigned to the high-pressure transformations in Ba and Bi which are generally used for calibration points. The metals were imbedded in NaCl, and the transitions were detected by the resistance change of the metal while the NaCl lattice parameter was simultaneously measured by x-ray diffraction. The NaCl compression values determined at the fixed points were related to pressure by reference to the semiempirical compression curve of Decker. The Ba I-II and Bi III-V transformations at room temperature were assigned thermodynamic equilibrium values of 53.3 ±1.2 kbar and 73.8 ±1.3 kbar, …

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Refinements In The Isomer Distribution And Relative Rate Of Sulfonation Of Toluene And Hydrochlorination Of Olefins With Stannic Chloride Catalyst, David George Guillot May 1966

Refinements In The Isomer Distribution And Relative Rate Of Sulfonation Of Toluene And Hydrochlorination Of Olefins With Stannic Chloride Catalyst, David George Guillot

Theses and Dissertations

The sulfonation of toluene at -12.5° C. with sulfur trioxide in liquid sulfur dioxide was found to give 10.03 ± 0.20 % ortho, 0.73 ± 0.20 % meta and 89.24 ± 0.20 % para isomers. This isomer distribution was determined by isotope dilution analysis using sulfur-35 enriched sulfur trioxide. After dilution of aliquots of the neutralized sulfonation mixture with pure sodium salts of each of the isomers prepared from the corresponding toluidines, the isomers were converted to the p-toluidine salts, purified by recrystallization, and counted by liquid scintillation counting. The relative rate of sulfonation of toluene compared to benzene was …

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X-Ray Diffraction Studies On Tin To 100 Kilobars, J. Dean Barnett, Vern E. Bean, H. Tracy Hall Feb 1966

X-Ray Diffraction Studies On Tin To 100 Kilobars, J. Dean Barnett, Vern E. Bean, H. Tracy Hall

Faculty Publications

The high-pressure equilibrium phase diagram of tin is investigated, and the crystal structure of Sn II at 98 kbar and 25degrees C is shown to be body-centered tetragonal with a=3.70 Angstroms, c=3.37 Angstroms, c/a=0.91, and with two atoms per unit cell. The linear compressibility of white tin is given at 25degrees C up to the high-pressure transformation at 92 kbar, and the latent heat of the transformation is measured as 225 cal/g-atom.

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Drag Forces On Magnetically Accelerated Particles, Darrell Winterton Walker Sep 1965

Drag Forces On Magnetically Accelerated Particles, Darrell Winterton Walker

Theses and Dissertations

The object of this investigation was to determine the effect of acceleration on the drag of spheres as it differs from the steady state case. Steady state drag applies to the force acting on a single sphere moving at constant velocity through an infinite, continuous, incompressible, turbulence free fluid. Extensive experimentation has quite thoroughly documented the steady state drag characteristics of spheres. A dimensionless parameter associated with the drag force is sometimes used to correlate drag characteristics.

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The Role Of Thiamine Pyrophosphate In Regulating The Level Of Gamma-Aminobutyric Acid In The Central Nervous System, Bryant L. Adams Aug 1965

The Role Of Thiamine Pyrophosphate In Regulating The Level Of Gamma-Aminobutyric Acid In The Central Nervous System, Bryant L. Adams

Theses and Dissertations

The level of gamma-aminobutyric acid in the brains of white rats suffering from thiamine deficiency symptoms resulting from pyrithiamine or oxythiamine antagonism of thiamine or from thiamine deprivation was measured. The level of this amino acid was 17.5% lower in the brains of pyrithiamine-treated rats and 20.0% lower in the brains of thiamine-deprived rats than in the control rats. Daily injections of ten times the required amounts of vitamin B6 in rats treated with pyrithiamine or oxythiamine or by thiamine deprivation had no effect on the level of brain gamma-aminobutyric acid or on the psiological behavior of these rats. The …

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Thermodynamics Of Proton Ionization In Aqueous Solution I. A Precision Thermometric Titration Calorimeter ; Ii. Entropy Titration : A Calorimetric Method For Equilibrium Constant Determinations ; Iii. H And S Values For Carboxylic Acid Proton Ionization At 25c ; Iv. Site Of Proton Ionization From Adenosine, Lee D. Hansen Aug 1965

Thermodynamics Of Proton Ionization In Aqueous Solution I. A Precision Thermometric Titration Calorimeter ; Ii. Entropy Titration : A Calorimetric Method For Equilibrium Constant Determinations ; Iii. H And S Values For Carboxylic Acid Proton Ionization At 25c ; Iv. Site Of Proton Ionization From Adenosine, Lee D. Hansen

Theses and Dissertations

The design, construction, and calibration of a precision thermometric titration calorimeter is described. This calorimeter was tested by determining the enthalpy change for ionization of water. The result, 13.34 ±0.03 kcal/mole (standard deviation), is in exact agreement with the best literature values. This standard deviation indicates that, using this calorimeter, ΔH values can be determined with an accuracy of ±0.0.5 kcal/mole. A calorimetric procedure has been developed for the, simultaneous determination of the equilibrium constant, the enthalpy change, and the entropy change for a chemical reaction from a single titration (Entropy Titration). This procedure has been tested by determining pK, …

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Studies Of Rat Brain Thiamine Pyrophosphokinase, Lavell Rolfson Johnson Aug 1965

Studies Of Rat Brain Thiamine Pyrophosphokinase, Lavell Rolfson Johnson

Theses and Dissertations

The enzyme ATP:thiamine pyrophosphotransferase (thiamine pyrophosphokinaseJ was purified from acetone powders which were prepared from rat brains up to the chromatography on alumina C_γ step by a modified procedure that Mano (Y. Mano, J. Biochem., 42, 283 (1960)] developed for the purification of the rat liver thiamine pyrophosphokinase. The enzyme was purified 12 fold over that in the original extract of the acetone powder. A spectrophotometric assay for the brain thiamine pyrophosphokinase was developed utilizing brewer's yeast apotransketolase. The transketolase assay was able to detect less than 10^-11 moles of thiamine diphosphate, which was synthesized by the kinase, in the …

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The Vibration Response Of Laminated Orthotropic Plates, Max E. Waddoups Jr. Aug 1965

The Vibration Response Of Laminated Orthotropic Plates, Max E. Waddoups Jr.

Theses and Dissertations

The behavior of anisotropic materials has been the object of much recent research® The high strength to weight ratio needed by aerospace structures has necessitated the use of exotic, composite materials which generally exhibit anisotropic behavior® These materials cannot be fully utilized unless analytical techniques are used which take maximum advantage of their anisotropic behavior.

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Liquid Particle Interaction With A Normal Shock Wave, Victor George Forsnes Jul 1965

Liquid Particle Interaction With A Normal Shock Wave, Victor George Forsnes

Theses and Dissertations

The atomization of a liquid by an air stream has been an item of much concern in the past, and there have been numerous experimental studies of the process made in an effort to correlate liquid and air- stream physical properties into a general model which will predict the degree of and the time required for atomization for a given physical situation. The breakup of liquid drops, a major portion of the atomization process, finds application in the field of meteorology, where the formation, breakup, and shape of raindrops is an item of much concern; in the field of internal …

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Properties Of Chlorophyll Derivatives Bonded To Polymers, Richard Grant Jensen May 1965

Properties Of Chlorophyll Derivatives Bonded To Polymers, Richard Grant Jensen

Theses and Dissertations

Two types of water-soluble complexes of chlorophyll a with organic polymers have been investigated: chlorophyll a coordinately bonded to poly 4-vinylpyridine and a chlorophyll derivative, Mg-chlorin e_6 phytyl methyl ester, covalently bonded to GANTREZ AN (poly (methyl vinyl ether/maleic anhydride) ). The first complex was observed upon dissolving chlorophyll a and poly 4-vinylpyridine in aqueous ethanol solutions. The Mg-chlorin e_6 diester-GANTREZ AN complex (chlorophyll a/polymer) was made by aminolysing the chlorophyll ring V with 1, 6-hexanediamine to give an intermediate product, Mg-chlorin e_6 -6-N-(6' -aminohexyl) carboxamide, phytyl methyl ester. This was attached to GANTREZ AN by linkage of the 6'-amine …

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Thermodynamics Of Charge Transfer Complexes, Reed J. Jensen May 1965

Thermodynamics Of Charge Transfer Complexes, Reed J. Jensen

Theses and Dissertations

Charge transfer complexes were studied spectrophotometrically in the liquid state by a modified Benesi-Hildabrand method. TiCl_4 - Benzene and TiCl_4 - diphenyl ether solutions were found to form contact charge transfer complexes, that is complexes with very weak and non-directional interactions. The systems TiCl_4 - anisole and TiCl_4 - diethyl ether form complexes of the types AD and AD_2 where A stands for TiCl_4 and D stand s for the organic donor. The formation constants for the complexes were, for the TiCl_4 - anisole, K_1 = 0.077, K_2 = 0.01; and TiCl_4 - diethyl ether, K_1= 3.0, K_2 = 1.0. …

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A Thermodynamic Study Of (1) Ligand Replacement Reactions And (2) The Interaction Of Hgcl[Subscript 2](Aq) With Hydroxide Ion, Ethylenediamine, Glycinate Ion, And Methylamine, Jerry Alvin Partridge Apr 1965

A Thermodynamic Study Of (1) Ligand Replacement Reactions And (2) The Interaction Of Hgcl[Subscript 2](Aq) With Hydroxide Ion, Ethylenediamine, Glycinate Ion, And Methylamine, Jerry Alvin Partridge

Theses and Dissertations

A method is reported for determining the species formed in solution by ligand replacement reactions. Reactions in dilute aqueous solution were studied in which the Cl^- on HgCl_2(aq) was replaced by hydroxide ion, ethylenediamine, glycinate ion, and methylamine. The species formed by the replacement reactions were established through computer analysis of pH titration data. Various reaction sequences were proposed for each system and log K values were calculated for each sequence. The selection of the correct reaction sequence for each system was based on the premise that only when the correct sequence is proposed will consistent log K values be …

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Hydrogenation Of 4-Methylcinnoline, William E. Maycock Mar 1965

Hydrogenation Of 4-Methylcinnoline, William E. Maycock

Theses and Dissertations

The rapid expansion of knowledge of cinnoline chemistry since 1941 has not included the hydrocinnolines. Not one catalytic hydrogenation of a fully aromatic cinnoline had been reported. This thesis is an effort to enlarge knowledge of this particular area of cinnoline chemistry. The work is a natural outgrowth of that done at Brigham Young University on decahydroquinoxaline, both the cis- and trans- isomers having been prepared and characterized. 4-Methylcinnoline, prepared by the method of Jacobs, et.al., was hydrogenated in neutral and acidic ethanolic solutions at 2000-3000 psig. hydrogen pressure and 100-266°. The catalysts used were 5% palladium on alumina, ruthenium …

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Adam Samuel Bennion, Educator, Businessman And Apostle, John Andrew Braithwaite Jan 1965

Adam Samuel Bennion, Educator, Businessman And Apostle, John Andrew Braithwaite

Theses and Dissertations

The purpose of this study was to provide a biography of Adam Samuel Bennion. Special emphasis has been given to his contributions in the fields of education, business, civic affairs, and church responsibilities.

Adam S. Bennion was born in 1886 in Taylorsville, Utah. He became active in educational and Church activities early in his life. He attended Taylorsville public schools, the University of Utah, Columbia University in New Yourk and graduated from the University of California with his Ph.D. degree. He served as Superintendent of the LDS Church Schools and was instrumental in the establishment of the LDS seminary program …

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A Study Of The Concerns Of Eleventh And Twelfth Grade Seminary Students By Sex And Grade In Areas Covered By The Thirty-Five Directional Objectives Of The Lds Seminary System, M. Richard Maxfield Jan 1965

A Study Of The Concerns Of Eleventh And Twelfth Grade Seminary Students By Sex And Grade In Areas Covered By The Thirty-Five Directional Objectives Of The Lds Seminary System, M. Richard Maxfield

Theses and Dissertations

The purpose of this study was to determine the concerns of eleventh and twelfth grade L.D.S. Seminary students in areas covered by each of the thirty-five directional objectives of the L.D.S. Seminary System and to determine whether significant differences occur on the basis of grade and sex. A student inventory was constructed to measure concerns. The question of which directional objectives cause the greatest concern was to be answered for each male and female, junior and senior group. Five null hypotheses were formulated hypothesizing no differences in concerns between juniors and seniors, male and female groups.
The student inventory was …

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Equation Of State Of Nacl And Its Use As A Pressure Gauge In High-Pressure Research, Daniel L. Decker Jan 1965

Equation Of State Of Nacl And Its Use As A Pressure Gauge In High-Pressure Research, Daniel L. Decker

Faculty Publications

The pressure as a function of lattice parameter and temperature has been calculated for NaCl over a pressure range of 0 to 500 kbar for temperatures between 0degrees and 1500degrees C. The calculation used the Mie-Gruneisen equation of state with Born-Mayer type repulsion terms between first and second nearest neighbors. The Gruneisen constant was expanded about its value at room temperature and atmospheric pressure; the first coefficient in the expansion being evaluated by forcing the calculated thermal expansion at atmospheric pressure to fit the experimental results of Enck. The two empirical parameters in the repulsion terms were evaluated using the …

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Marcel Schwob And “The Talking Machine”: A Tale À La Poe—Via Thomas A. Edison, John A. Green Jan 1965

Marcel Schwob And “The Talking Machine”: A Tale À La Poe—Via Thomas A. Edison, John A. Green

BYU Studies

John A. Green gives a brief biographical sketch of French author Marcel Schwob (1867-1905) and describes the historical context of his short story "The Talking Machine." Then Green gives his translation of the story itself.

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Spanish Academies Of The Golden Age, M. Carl Gibson Oct 1964

Spanish Academies Of The Golden Age, M. Carl Gibson

BYU Studies

Lope de Vega, Cervantes, Quevedo, Calderón de la Barca, and Guillén de Castro, among other great writers, artists, and poets, all took part in the academias of the Spanish Golden Age. The article traces the Italian, Arabic, and Jesuit influences on these academies and attributes the richness of the art and poetry of the Golden Age to the perfect blending of these traditions.

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The Anti-Christian Background Of German Literary Naturalism, R. Max Rogers Oct 1964

The Anti-Christian Background Of German Literary Naturalism, R. Max Rogers

BYU Studies

German naturalism flourished in a time when Christianity as a whole was under attack. The philosophies of positivism and materialism, both of which challenged beliefs held by traditional Christianity, had a great impact on naturalist thinking. Charles Darwin's theories also extended beyond the discipline of natural sciences to reach the philosophical, religious, and literary realm. While some tried to reform the Christian church, others attempted to find a connection to God independent of organized religion. Others became indifferent while some became hostile toward Christianity. Each attitude found expression in German naturalism.

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Analysis And Discussion Of The Effect Of Heat Loss From The "Insulated" Face Of Thin Foil Heat Flux Meters, Mont Johnson Stevens Sep 1964

Analysis And Discussion Of The Effect Of Heat Loss From The "Insulated" Face Of Thin Foil Heat Flux Meters, Mont Johnson Stevens

Theses and Dissertations

The object of this work was to investigate the effect that heat losses from the "insulated" face of thin foil heat flux meters has upon the sensitivity of heat flux meters. In the past it has been characteristic of any analysis done on heat flux meters to assume that the insulation on the back face of the foil was a perfect insulator and thereby neglect the effects of heat losses from this "insulated" face. It is hoped that the information given in this thesis will be of value in determining how the geometric and heat transfer parameters affect the operation …

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Metabolism Of Thiamine And The Effect Of Some Antagonists, Russel M. Bender Aug 1964

Metabolism Of Thiamine And The Effect Of Some Antagonists, Russel M. Bender

Theses and Dissertations

To investigate the possibility that thiamine has more than one vital role in the mammalian system, it was decided to use the antagonists pyrithiamine and oxythiamine, and to utilize carbon-14 labeled compounds to more effectively study the vitamin and the above-named antagonists. To make it more effective, we felt that perhaps differences between the localization of oxythiamine and pyrithiamine could be detected in the brain. We also considered and tested the possibility that either or both of the antagonists would alter the localization of thiamine. Essentially, two procedures were used in this study. One was a counting method and the …

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Evaluation Of Methods Used In The Determination Of Stability Constants Of The Thallium (Iii)-Chloride System At Twenty-Five Degrees, Nelson Kent Dalley Aug 1964

Evaluation Of Methods Used In The Determination Of Stability Constants Of The Thallium (Iii)-Chloride System At Twenty-Five Degrees, Nelson Kent Dalley

Theses and Dissertations

The difficulties encountered in the determination of equilibrium constants in systems with small, not directly rneasureable free ligand concentrations are discussed. These difficulties are illustrated using the determination of the formation constants of the Tl(III)-Cl- system as a specific example. Four methods are used and evaluated in this study. They are (1) the corresponding solutions method, (2) the method of Fronaeus, (3) the solubility of AgCl in Tl(III) solution method and (4) the method of Hugus. A discussion and derivation of each of these methods is given. The first three methods given and free ligand concentration data from which formation …

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The Wealth Of Knowledge, Excerpts From The Writing Of Brigham Young, Brigham Young Apr 1964

The Wealth Of Knowledge, Excerpts From The Writing Of Brigham Young, Brigham Young

BYU Studies

Three short quotations from Brigham Young, second president of the Church of Jesus Christ of Latter-day Saints, show the emphasis he placed on education and the need of every person to seek wisdom.

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A Calorimetric Study Of Metal Amino Acid Complexes In Aqueous Solution. I. The Copper (Ii) Glycine System. Ii. The Nickel (Ii) Glycine, Alanine And Phenylalanine Systems, Wilbur Orme Greenhalgh Apr 1964

A Calorimetric Study Of Metal Amino Acid Complexes In Aqueous Solution. I. The Copper (Ii) Glycine System. Ii. The Nickel (Ii) Glycine, Alanine And Phenylalanine Systems, Wilbur Orme Greenhalgh

Theses and Dissertations

Calorimeter values were obtained for the standard enthalpy change for the following reactions at 10,25, and 40 degrees C.: 1. The dissaciation of the amino acid, glycine, in the zwitterion form (HA) to give the basic form (A-) and a proton. 2. The reactions of copper (II) ion with glycine to form the Cu gly+ and Cu (gly)2 complexes. 3. The reactions of nickel (II) ion with glycine and alanine to form Ni gly+, Ni (gly)2, Ni al+, and Ni (al)2 complexes. For calorimetric enthalpy calculations, the initial and final concentrations of all species in the calorimeter must be known; …

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The Religious Education Program Of The Pacific Board Of Education, V. Lynn Tyler Jan 1964

The Religious Education Program Of The Pacific Board Of Education, V. Lynn Tyler

Theses and Dissertations

The major purposes of this study have been (1) to define and coordinate principles and policies for religious education in Pacific elementary and secondary schools that are operated by the Pacific Board of Education of the Church of Jesus Christ of Latter-day Saints, and (2) to provide a manual of instructions for administrators and teachers which will help them attain the objectives outlined in this study.
Religious education in the Pacific Schools is an integral part of the entire curriculum, receiving emphasis in religion classes. The Church Seminary system, in contrast, is supplemental to public secular education.

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George Romney And The Michigan Gubernatorial Compaign - 1962, Richard C. Fuller Jan 1964

George Romney And The Michigan Gubernatorial Compaign - 1962, Richard C. Fuller

Theses and Dissertations

Politics in Michigan had been on a low plane for a number of years. The troubles were many and their roots could be found deep in the structure of the state's government.

In April of 1959, the sagging governmental structure gave way to the extent that the state was unable to meet its payroll. The result was the much publicized "Payless Pay Day" which attracted national and international interest.

Seeing that their elected officials were seemingly powerless to correct even the basic flaws in Michigan's government, many of the state's leading business and industrial leaders decided to apply their considerable …

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A Study Of The Differences Between Seminary And Non-Seminary Students At The Ogden-Weber Seminary 1963-64, Gerald F. Taylor Jan 1964

A Study Of The Differences Between Seminary And Non-Seminary Students At The Ogden-Weber Seminary 1963-64, Gerald F. Taylor

Theses and Dissertations

The major purpose of this study was to discover differences between LDS students enrolled in the Ogden-Weber Seminary and LDS students who are not enrolled in this seminary.
This study proposed to answer the following questions:
1. What are the differences in the responses, to a questionnaire designed to determine attitudes, of Latter-day Saint students who are not enrolled in seminary compared with Latter-day Saint students who are enrolled?
2. What are the differences between Latter-day Saint students who are not enrolled in seminary and Latter-day Saint students who are enrolled in seminary when compared as to mental achievement and …

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A Study Of Lds Seminary Libraries, F. Burton Winters Jan 1964

A Study Of Lds Seminary Libraries, F. Burton Winters

Theses and Dissertations

This paper is devoted to an examination of seminary libraries. The study has a threefold purpose:
1. To determine some basic professional standards for seminary libraries.
2. To make a study among seminary faculties and students to determine library size, operation method, and use.
3. To draw conclusions and make recommendations that may be helpful to seminaries in maintaining adequate libraries.

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I. Preparation And Properties Of Alkyl And Aryl Substituted Thioquinazolines And Sulfoxides ; Ii. An Investigation Of The Quinazoline 3-Oxide--1,4-Benzodiazepine 4-Oxide Rearrangement, Marvin C. J. Kuchar Nov 1963

I. Preparation And Properties Of Alkyl And Aryl Substituted Thioquinazolines And Sulfoxides ; Ii. An Investigation Of The Quinazoline 3-Oxide--1,4-Benzodiazepine 4-Oxide Rearrangement, Marvin C. J. Kuchar

Theses and Dissertations

I. The quinazolines, a branch of the benzodiazine class of aromatic nitrogen hetercycles, do not occur to any great extent in naturally occurring compounds. The discovery of the antimalarial febrifugine and its structure elucidation led to the preparation and investigation of a host of new quinazolines in the search for new and more effective antimalarials. Most of the present body of information governing the quinazolines arose out of these synthetic studies. The present study has been accomplished with a four-fold purpose in mind: (1) to investigate the susceptibility of chloroquinazolines to nucleophilic displacement reactions by thiols or their salts, (2) …

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Analysis Of The Transient Response Of A Flat Rotating Disk By Generalized Transforms, Kenneth Wayne Chase Sep 1963

Analysis Of The Transient Response Of A Flat Rotating Disk By Generalized Transforms, Kenneth Wayne Chase

Theses and Dissertations

The object of this thesis was to lay a foundation for a comprehensive study of the dynamic response of rotating members. This initial phase of the study includes a theoretical investigation and proposes experimental techniques for the determination of the stresses and strains in a thin, rotating disk with a concentric hole, subjected to transient shaft inputs. There are many practical applications of this problem including computor memory storage disks, turbine rotors, grinding wheels, saw blades, gears, optical reflectors, and solar sails for space vehicles.

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