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Studying The Chemistry-Property Relationship In Magnetic And Optical Materials: Spin S = 3/2 Systems Of Neodymium, Manganese, And Cobalt Oxyanions, Xudong Huai

All Dissertations

This dissertation describes the design and tunability of new magnetic and optical materials, emphasizing the intricate relationship between their crystal structures and their optical, electronic, and magnetic properties.

Two new frustrated magnets, ANd(SO₄)₂ (A = Rb, Cs), were designed and synthesized to examine the influence of the the counter cation A site in Nd lanthanide materials featuring a distorted triangular magnetic lattice with S = 3/2. This work demonstrates how the tunability of magnetic and photoluminescent properties can be achieved through the A sites, with findings validated through density functional theory calculations.

AMnTeO₆ (A = Ca, …

Capillary Phenomena In Flow Down Fibers: Beads, Bridges, Sheets, And Threads, Chase Tyler Gabbard

All Dissertations

Capillary phenomena are ubiquitous in everyday life with surface tension responsible for shaping liquids and deforming slender structures on length scales smaller than the capillary length, as seen in the formation of drops from a leaky faucet and in the coalescence of wet hair, respectively. Recently, thin film flow down fibers have received significant attention for their ability to produce bead-on-fiber patterns with associated high surface area-to-volume ratios that optimize retention times in heat and mass transfer applications. The presence of a base flow gives rise to complex dynamics including absolute and convective instabilities. The parallelization of these processes through …

Microwave Spectroscopy And Large Amplitude Motion Of Chlorosulfonic Acid (Clso2oh), Aaron J. Reynolds, Diego E. Rodriguez, Wei Lin, Kenneth R. Leopold

Physics & Astronomy Faculty Publications

The high-resolution rotational spectrum of chlorosulfonic acid (ClSO2OH) has been studied using both broadband and cavity-based Fourier transform microwave spectrometers over the frequency range of 5–18 GHz. a-, b-, and c-type transitions have been recorded for both the 35Cl and 37Cl isotopologues. The observation of c-type lines establishes that the molecule lacks a plane of symmetry and suggests that the OH group can undergo large amplitude motion between equivalent structures. Interconversion between these structures can be achieved via internal rotation through two inequivalent barriers occurring at Cl-S-O-H torsional angles of 0 or 180 degrees. As in …

Implementing General Moment Equations For Parallel Closures In Nimrod, Hankyu Lee

All Graduate Theses and Dissertations, Fall 2023 to Present

Understanding how magnetic fields impact plasma transport is essential for improving the efficiency of thermonuclear fusion power plants. To address the transport problem, both plasma fluid equations and Maxwell’s equations must be solved. To solve these equations, it is necessary to derive closure relations that allow the system to be closed. Previous closure models are useful for describing the behavior of high-collisionality plasma but are not effective at low collisionality. To obtain closure relations valid for low collisionality, the first-order drift kinetic equation must be solved.

This study presents methods for numerically obtaining parallel closures for NIMROD code by deriving …

Md Simulations Of Collision Effects For A Strongly Coupled Plasma, Jawon Jo

All Graduate Theses and Dissertations, Fall 2023 to Present

Studying strongly coupled plasmas can be effectively accomplished using molecular dynamics (MD) simulations. We have developed an advanced MD simulation code that can analyze plasmas with various coupling parameters. This code employs a spherically symmetric cut-off Coulomb force verified through convergence tests by modulating the cut-off and minimum force ranges. Additionally, it incorporates a new algorithm for optimizing the initial positions of particles at a given temperature. This method maintains the temperature constant and the velocity distribution unchanged. As a result, we eliminate the unphysical initial rises and oscillations in temperature that a random distribution of positions causes. The code …

Determining Heterogeneous Growth Rates Of Brucite On Magnesia Using Multiharmonic Qcm-D And X-Ray Scattering Methods, Pedro Josue Hernandez Penagos

Open Access Theses & Dissertations

The Earth’s temperature has increased in the last six decades mainly due to the emissions of greenhouse gases, including carbon dioxide (CO2). Mineral looping using magnesium oxide (MgO) is a promising approach for direct air capture (DAC) of CO2 from the atmosphere at the GtCO2/yr scale. The presence of humidity during the carbonation process will lead to a reaction between the MgO and water resulting in magnesium hydroxide formation, Mg(OH)2, growing over the MgO surface forming a shell-like structure. The influence of temperature and relative humidity variation on heterogeneous nucleation and crystal growth kinetics of Mg(OH)2 on MgO is not …

Investigation Of Seasonal Trends And Source Apportionment Of Particulate Matter (Pm2.5) In El Paso-Juarez Airshed, Fatema Tuz Zohora

Open Access Theses & Dissertations

Using the data from Texas Commission on Environmental Quality (TCEQ) for the El Paso city throughout the years from 2021 to 2024 Particulate Matter (PM2.5) was measured to examine the seasonal distribution and sources. This study aims to understand the seasonal variability of PM2.5 concentrations, identify the significant impact of wildfire events on this and source apportionment.The analysis begins with a comprehensive examination of PM2.5 data from TCEQ highlighting the seasonal pattern, it was found that fine particulate matter was more prevalent in winter and tends to be down in spring, and in summer it is relatively lower, subsequently in …

Quantum Circuit Optimization Leveraging Multi-Qubit Exchange Interactions In Spin Qubits, Miguel Gonzalo Rodriguez

Open Access Theses & Dissertations

This thesis looks into how multi-qubit exchange interactions can be used to improve quantumcircuits in semiconductor quantum devices. Pairwise interactions between qubits are a common tenet of traditional quantum computing paradigms, although they can impose complexity and depth constraints on circuits. In order to improve the efficiency and scalability of quantum circuits, this research explores the theoretical underpinnings and practical uses of multi-qubit interactions. A thorough theoretical framework is formulated, outlining the mathematical equivalence of a unitary matrix representing interactions between multiple qubits. We obtain the timeevolution operator by analyzing the Hamiltonian of three spin-1/2 particles. A number of quantum …

Understanding And Control Of Frustration And Topological Defects In Ferroic Matter, Suyash Rijal

Graduate Theses and Dissertations

Ferroic matter are of great importance as they provide a platform to extend the understanding of many-body physics and also for their amazing functional properties relevant for technological advancements. The work in this dissertation is dedicated to two of such ferroic materials.

First is CrGeTe₃ (CGT), a two dimensional (2D) magnet discovered in 2017. The discovery of two-dimensional magnetism has invigorated the research community as their low dimensionality offers a unique avenue to understand and investigate the origin of magnetism in these atomically thin systems and harvest diverse application such as information processing, storage and transfer using their magnetic …

Temperature-Dependent Optical Constants Of Vanadium Dioxide Thin Films Deposited On Polar Dielectrics, Imtiaz Ahmad, Satya R. Kachiraju, Sundar Kunwar, Zachary M. Brown, Pinku Roy, Matthew Gaddy, Vladimir Kuryatkov, Yejin Kwon, Ayrton A. Bernussi, Myoung-Hwan Kim

Physics & Astronomy Faculty Publications

Coating polar dielectrics with thin film vanadium dioxide (VO2) enables one to exploit the temperature-dependent phase transition within VO2 to actively tune and modulate surface phonon polaritons at mid-infrared. However, controlling the behavior of such systems requires intimate knowledge of the temperature-dependent optical constants of VO2, which depend greatly on the growth conditions and substrate material. Here, we accurately determine the complex optical constants of VO2 on polar dielectrics across the insulator-to-metal phase transition (IMT) using only normal incident reflectance spectra by analyzing the reflectance with Kramers–Kronig relations and thin film Fresnel equations. This non-ellipsometry technique offers an …

Observation Of Gravitational Waves From The Coalescence Of A 2.5–4.5 M⊙ Compact Object And A Neutron Star, A. Abac, R. Abbott, I. Abouelfettouh, F. Acernese, Teviet Creighton, Mario C. Diaz, Francisco Llamas, Soma Mukherjee, Volker Quetschke, Wenhui Wang

Physics & Astronomy Faculty Publications

We report the observation of a coalescing compact binary with component masses 2.5–4.5 M⊙ and 1.2–2.0 M⊙ (all measurements quoted at the 90% credible level). The gravitational-wave signal GW230529_181500 was observed during the fourth observing run of the LIGO–Virgo–KAGRA detector network on 2023 May 29 by the LIGO Livingston observatory. The primary component of the source has a mass less than 5 M⊙ at 99% credibility. We cannot definitively determine from gravitational-wave data alone whether either component of the source is a neutron star or a black hole. However, given existing estimates of the maximum neutron star mass, we find …

Particle-Imbalanced Weakly Interacting Quantum Droplets In One Dimension, I. A. Englezos, P. Schmelcher, S. I. Mistakidis

Physics Faculty Research & Creative Works

We explore the formation of one-dimensional two-component quantum droplets with intercomponent particle imbalance using an ab initio many-body method. It is shown that for moderate particle imbalance each component maintains its droplet flat-top or Gaussian-type character depending on the intercomponent attraction. Importantly, large particle imbalance leads to a flat-top shape of the majority component with the minority exhibiting spatially localized configurations. The latter imprint modulations on the majority component which become more pronounced for increasing interspecies attraction. The same holds for larger mass or increasing repulsion of the minority species. Such structural transitions are also evident in the underlying two-body …

Instantons In Φ4 Theories: Transseries, Virial Theorems, And Numerical Aspects, Ludovico T. Giorgini, Ulrich D. Jentschura, Enrico M. Malatesta, Tommaso Rizzo, Jean Zinn-Justin

Physics Faculty Research & Creative Works

We discuss numerical aspects of instantons in two- and three-dimensional φ4 theories with an internal O(N) symmetry group, the so-called N-vector model. By combining asymptotic transseries expansions for large arguments with convergence acceleration techniques, we obtain high-precision values for certain integrals of the instanton that naturally occur in loop corrections around instanton configurations. Knowledge of these numerical properties is necessary in order to evaluate corrections to the large-order factorial growth of perturbation theory in φ4 theories. The results contribute to the understanding of the mathematical structures underlying the instanton configurations.

Doubly Differential Cross Sections For Ionization In Proton Collisions With Atomic Hydrogen: Energy And Angular Distribution Of Emitted Electrons, C. T. Plowman, K. H. Spicer, N. W. Antonio, M. S. Schöffler, Michael Schulz, I. Bray, A. S. Kadyrov

Physics Faculty Research & Creative Works

We use the two-center wave-packet convergent close-coupling approach to ion-atom collisions to calculate the energy and angular distribution of electrons emitted in proton collisions with atomic hydrogen. Results are provided across a wide range of intermediate energies where many competing reaction channels make calculations challenging. The present data consistently agree with the available experimental measurements and improve upon previously available results based on perturbative and classical methods. Furthermore, we extend the range of electron angles and energies over which theoretical data are available for the doubly differential cross section for ionization. This provides strong evidence that at the level of …

Novel Emergent Phases In A Two-Dimensional Superconductor, Simrandeep Kaur, Hemanta Kumar Kundu, Sumit Kumar, Anjana Dogra, Rajesh Narayanan, Thomas Vojta, Aveek Bid

Physics Faculty Research & Creative Works

In this letter, we report our observation of an extraordinarily rich phase diagram of a LaScO₃/SrTiO₃ heterostructure. Close to the superconducting transition temperature, the system hosts a superconducting critical point of the Infinite-randomness type characterized by an effective dynamical exponent ν z that diverges logarithmically. At lower temperatures, we find the emergence of a magnetic field-tuned metallic phase that co-exists with a quantum Griffiths phase (QGP). Our study reveals a previously unobserved phenomenon in 2D superconductors—an unanticipated suppression of the QGP below a crossover temperature in this system. This concealment is accompanied by the destruction of the …

Magnetization And Age Of Ca. 544 Ma Syenite, Eastern Canada: Evidence For Renewal Of The Geodynamo, Tinghong Zhou, Mauricio Ibañez-Mejia, Richard K. Bono, Rory D. Cottrell, Wouter Bleeker, Kenneth P. Kodama, Wentao Huang, Eric G. Blackman, Francis Nimmo, Aleksey Smirnov, John A. Tarduno

Michigan Tech Publications

The ca. 565 Ma Ediacaran geodynamo was highly unusual, producing an ultralow field 10 times weaker than present-day value of 8 x 1022 A m2. A ∼5 times rise in field strength is seen in time-averaged single crystal paleointensity data of ca. 532 Ma Early Cambrian anorthosites of Oklahoma (USA). The field increase could record the onset of inner core nucleation predicted by thermal evolution and numerical dynamo models. Here, we examine the renewal of the geodynamo through zircon U-Pb geochronology and single crystal paleointensity studies of plagioclase from the Chatham-Grenville syenite intrusion in the Grenville Province (Canada). U-Pb data …

Qcd Bounds On Leading-Order Hadronic Vacuum Polarization Contributions To The Muon Anomalous Magnetic Moment, Siyuan Li, T. G. Steele, Jason N.E. Ho, R. Raza, K. Williams, R. T. Kleiv

Faculty Work Comprehensive List

QCD bounds on the leading-order (LO) hadronic vacuum polarization (HVP) contribution to the anomalous magnetic moment of the muon [𝑎HVP,LO𝜇, 𝑎𝜇 =(𝑔−2)𝜇/2] are determined by imposing Hölder inequalities and related inequality constraints on systems of finite-energy QCD sum rules. This novel methodology is complementary to lattice QCD and data-driven approaches to determining 𝑎HVP,LO𝜇. For the light-quark (𝑢, 𝑑, 𝑠) contributions up to five-loop order in perturbation theory in the chiral limit, LO in light-quark mass corrections, next-to-leading order in dimension-four QCD condensates, and to LO in dimension-six QCD condensates, we findthat (657.0±34.8) ×10−10 ≤𝑎HVP,LO𝜇 ≤(788.4±41.8) ×10−10, bridging the range between …

Cross-Correlation Increases Sampling In Diffusion-Based Super-Resolution Optical Fluctuation Imaging, Jeanpun Antarasen, Benjamin Wellnitz, Stephanie N. Kramer, Surajit Chatterjee, Lydia Kisley

Faculty Scholarship

Correlation signal processing of optical three-dimensional (x, y, t) data can produce super-resolution images. The second-order cross-correlation function XC2 has been documented to produce super-resolution imaging with static and blinking emitters but not for diffusing emitters. Here, we both analytically and numerically demonstrate cross-correlation analysis for diffusing particles. We then expand our fluorescence correlation spectroscopy super-resolution optical fluctuation imaging (fcsSOFI) analysis to use cross-correlation as a postprocessing computational technique to extract both dynamic and structural information on particle diffusion in nanoscale structures simultaneously. Cross-correlation maintains the same super-resolution as auto-correlation while also increasing the sampling rates to reduce aliasing for …

Answers To Frequently Asked Questions About The Pulsar Timing Array Hellings And Downs Curve, Joseph D. Romano, Bruce Allen

Physics & Astronomy Faculty Publications

We answer frequently asked questions (FAQs) about the Hellings and Downs correlation curve—the ‘smoking-gun’ signature that pulsar timing arrays (PTAs) have detected gravitational waves (GWs). Many of these questions arise from inadvertently applying intuition about the effects of GWs on LIGO-like detectors to the case of pulsar timing, where not all of it applies. This is because Earth-based detectors, like LIGO and Virgo, have arms that are short (km scale) compared to the wavelengths of the GWs that they detect (≈102–104 km). In contrast, PTAs respond to GWs whose wavelengths (tens of light-years) are much shorter than their arms (a …

New Empirical Formulae For Some (P,Γ) Reactions Of Astrophysical S-Factor And Thermonuclear Reaction Rates, Mohammed Issa Hussein

Polytechnic Journal

The study utilized weighted averages of cross sections in millibarn for (p,γ) reactions of ⁷⁴Ge, ⁸⁸Sr, ⁸⁹Y, ⁹⁰Zr, and ¹⁰⁷Ag medium target elements from the EXFOR nuclear data library and compares them with evaluated from TALYS 1.95 nuclear model code. These averages were employed to develop empirical formulas for the astrophysical S-factor, covering proton energies up to 5 MeV, and thermonuclear reaction rates up to 20×10⁹ K T₉ (T₉ is the temperature in units of 10⁹K). Polynomial formulas have been utilized to accurately model the calculated astrophysical S-factor and thermonuclear …

Proton And Neutron As Coaxial Structures, Polievkt Perov

College of Arts & Sciences Faculty Works

We suggest that a proton and a neutron are coaxial spinning structures. It is assumed that an up-quark and a down-quark composing a proton and a neutron each contain three like charges revolving about the axis where one (in the up-quark) or two (in the down-quark) basic fractional charges reside. In the case of particles with more than one charge on the axis of rotation, for example in a down-quark, the distance between the charges on the axis is determined by the requirement of zero net force on each charge on the axis. In a proton, two up-quark and one …

Electroweak Structure And Reactions In Light Nuclei With Quantum Monte Carlo Methods, Garrett King

Arts & Sciences Graduate Student Theses and Dissertations

Nuclei will play a prominent role in searches for physics beyond the Standard Model as the active material in experiments. In order to reliably interpret new physics signals, one needs an accurate model of the underlying nuclear dynamics. In this thesis, I discuss the validation of the Norfolk two-and three-body model of nuclear interactions along with consistent sets of electroweak transition operators used in conjunction with quantum Monte Carlo approaches to compute electroweak structure and reaction observable in light nuclei. I will provide the salient details of the model and method before presenting calculations of $\beta$-decay rates and spectra, muon …

Robustness Of Aging Transition In Competing Effect Of Heterogeneity And Symmetry Breaking Coupling, Gowthaman I

Theses and Dissertations

The knowledge of emergent dynamics and the mechanisms by which self-organizing complex systems operate is a perennially difficult problem that can be effectively resolved by employing an ensemble of coupled dynamical units as a framework. Several intriguing collective dynamical behaviors, such as synchronization, chimera, clustering, oscillation quenching, etc., have been reported using an ensemble of coupled oscillators. Failure or degradation in the performance of even one of the local oscillators in a network of oscillators can lead to cascading failures resulting in the collapse of the entire network such as power blackouts. Similar dynamics can also be observed among neuronal …

Space Radiation Assessment And Mitigation: Meeting The Growing Demand For Shielding Solutions By Enhancing Models And Exploring Novel Shielding Opportunities, M. Laura Sorgi Johann

Doctoral Dissertations and Master's Theses

The rapid growth of satellite technology and the increasing presence of vulnerable technology and human life in space have highlighted the need for improved shielding materials. Industry standard protocols for shielding are being pushed to their limits as we gain a deeper understanding of the harsh space environment and as chip sizes approach the scale of radiation wavelengths. Furthermore, the commercialization of space is attracting interest from industries such as pharmaceuticals and semiconductor crystal growing, as they explore the potential benefits of zero-gravity production environments. However, the eagerness to develop lighter shielding and the lack of consideration for existing tools …

Freedom As The Physical Notion. Mechanics Of A Material Point, Michael Vigdorowitsch

Karbala International Journal of Modern Science

This is a novel conceptual attempt to introduce freedom as a consistent physical notion. The present consideration is limited to mechanics of a material point. Adapted to physical representation, freedom is tested throughout the paper to conform to its general perception. It is first tried on such physical notions (but not restricted to) as potency of a set, Lagrangian, action, degrees of freedom. Defined as angular and essentially nonlinear variable, it appears to be dual as that the domain affords and that the material point possesses within the domain, not necessarily equal to one another. Freedom has to degrade if …

Glitch Veto Based On Unphysical Gravitational Wave Binary Inspiral Templates, Raghav Girgaonkar, Soumya D. Mohanty

Physics & Astronomy Faculty Publications

Transient signals arising from instrumental or environmental factors, commonly referred to as glitches, constitute the predominant background of false alarms in gravitational wave searches with ground-based detectors. Therefore, effective data analysis methods for vetoing glitch-induced false alarms are crucial to enhancing the sensitivity of a search. We present a veto method for glitches that impact matched filtering-based searches for binary inspiral signals. The veto uses unphysical sectors in the space of chirp time parameters as well as an unphysical extension including negative chirp times to efficiently segregate glitches from gravitational wave signals in data from a single detector. Inhabited predominantly …

Variable Radio Emission Of Neutron Star X-Ray Binary Ser X–1 During Its Persistent Soft State, Eli C. Pattie, Thomas J. Maccarone, Alexandra J. Tetarenko, James C. A. Miller-Jones, Manuel Pichardo Marcano, Liliana E. Rivera Sandoval

Physics & Astronomy Faculty Publications

Ser X–1 is a low-mass neutron star X-ray binary and has been persistently accreting since its discovery in the 1960s. It has always been observed to be in a soft spectral state and has never showed substantial long-term X-ray variability. Ser X–1 has one previous radio observation in the literature in which radio emission was detected during this soft state, which is contrary to the behavior of black hole X-ray binaries. We have recently obtained 10 randomly sampled radio epochs of Ser X–1 in order to further investigate its anomalous soft-state radio emission. Out of 10 epochs, we find 8 …

The Potential Influence Of Immune Modulatory Molecules (Tgf-Βiii And Ctla-4) In Pathogenicity Of Pcos, Mustafa Riyadh Abdullah, Hazima Mossa Alabassi

Karbala International Journal of Modern Science

Polycystic ovary syndrome (PCOS) is characterised by chronic anovulation, hyperandrogenism, polycystic ovaries, and immunological dysregulation. Immune homeostasis and inflammation management require immune functions. T-regulatory cells (Tregs) regulate PCOS's immune system, inflammation, insulin resistance, ovarian function, and homeostasis. Transforming growth factor βIII (TGF-βIII) and Cytotoxic-T-lymphocyte-associated-protein-4 (CTLA-4) receptors on the surfaces of Treg cells are important for controlling the immune system. The study included 68 PCOS patients and 22 non-PCOS women controls aged 20–45. The waist-hip ratio (WHR) determines obesity. We evaluated serum levels and gene expression of TGF-βIII and CTLA-4 via ELISA and real-time PCR. Women with PCOS had significantly higher …

Enhanced Optoelectronics Performance Of Hybrid Self Power Photodetectors Go: Tio2- Ad / N-Si Heterojunctions, Mohammed J. Alsultani, Maysoon F. Alias

Karbala International Journal of Modern Science

A GO:TiO₂/n-Si heterostructure has been submerged in an anthocyanin dye solution that extracted from the red cabbage plant creates a high responsivity, self-powered UV, and visible photodetectors fabricated by the spray pyrolysis technique. The GO concentrations are varied, whereas TiO₂ is fixed. Thin films' structure, shape, and optical characteristics were examined using X-ray diffraction, field emission scanning electron microscopy, and UV-Vis spectrophotometers respectively. Island-like polycrystalline film powders with grain boundaries and granular shapes are created. Two direct energy gaps between 3.33-3.02 and 2.39-2.04 eV exist in all films. J-V characteristics were examined. The saturation current density (J …

Quantum Classical Algorithm For Solving The Hubbard Model Via Dynamical Mean-Field Theory, Anshumitra Baul

LSU Doctoral Dissertations

Modeling many-body quantum systems is widely regarded as one of the most promising applications for near-term noisy quantum computers. However, in the near term, system size limitation will remain a severe barrier for applications in materials science or strongly correlated systems. A promising avenue of research is to combine many-body physics with machine learning for the classification of distinct phases. I present a workflow that synergizes quantum computing, many-body theory, and quantum machine learning (QML) for studying strongly correlated systems. In particular, it can capture a putative quantum phase transition of the stereotypical strongly correlated system, the Hubbard model. Following …