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Full-Text Articles in Entire DC Network
The One-Shot Ceiling: Comparing Rag And Fine-Tuning Architectures For Ai-Assisted Math Mentoring, Michael J. Cummins
The One-Shot Ceiling: Comparing Rag And Fine-Tuning Architectures For Ai-Assisted Math Mentoring, Michael J. Cummins
Computer Science Honors Papers
Providing individualized feedback to math students is a resource-intensive bottleneck in STEM education. We present Mentir-AI, a tool designed to elevate teacher capacity by generating high-quality mathematical feedback using the Mathforum's "Problem of the Week" archive. By analyzing a corpus of nearly one million interactions, we compare the efficacy of Retrieval-Augmented Generation (RAG) and Fine-Tuning (FT) architectures. This study details the development of an automated grading pipeline, the evolution of a multi-component system prompt, and the implementation of an automated mentor grading system in AI-led evaluation. While Fine-Tuning demonstrates superior instructional judgement, our results identify persistent failure modes in mathematical …
Friedel–Crafts Addition Of 3-Alkylated Indoles To Aldehydes: 2-Hydroxyalkylation Promoted By Trimethylsilyl Trifluoromethanesulfonate, Eric Zhou, Helen Xia, C. Wade Downey
Friedel–Crafts Addition Of 3-Alkylated Indoles To Aldehydes: 2-Hydroxyalkylation Promoted By Trimethylsilyl Trifluoromethanesulfonate, Eric Zhou, Helen Xia, C. Wade Downey
Chemistry Faculty Publications
In the presence of trimethylsilyl trifluoromethanesulfonate (TMSOTf) and 2,6-lutidine, 3-alkylated indoles undergo Friedel–Crafts silyloxyalkylation when treated with nonenolizable aldehydes. The reaction is general across a wide range of aromatic aldehydes and tolerates a variety of N-alkylated indoles. Deprotection of the silylated product occurs under standard conditions, and in certain cases the initial TMS-protected product can be isolated in high yield.
Synthesis Of A Halogenated Glyoxime For Cobalt Deposition Suppression, Liam S. Allen
Synthesis Of A Halogenated Glyoxime For Cobalt Deposition Suppression, Liam S. Allen
Honors Theses
Dr. Qiang Huang at the University of Alabama is a chemical engineering professor and works on the electrodeposition of metals to create circuitry. During this process suppressive molecules may be added to control help the process. This project focuses on synthesizing an alpha-halogenated glyoxime to test whether the compound is a more effective suppressant in comparison to regular glyoximes. More specifically the target chemical is called bromo-dimethylglyoxime which is created in a two-stage reaction. The starting material, diacetyl monoxime, is brominated at the alpha carbon position. The product of this reaction, officially called bromodimethylglyoxalmonoxime, is then reacted with hydroxylammonium chloride …
How Ai Governance Differs Between Regime Type, Jackson T. Guillou
How Ai Governance Differs Between Regime Type, Jackson T. Guillou
Honors Theses
This thesis will examine how artificial intelligence (AI) regulation and development differ across political regime types, arguing that governance outcomes are fundamentally shaped by institutional political structures. This thesis will draw on comparative frameworks analyzing democratic and authoritarian systems. This thesis will also include case studies of the European Union, the United States of America, China, and Russia. The study finds that democratic regimes tend to emphasize transparency, accountability, and rights-based regulation of AI. This often results in slow regulation of AI, but it is more ethically legitimate and constrained. In contrast, authoritarian regimes prioritize centralized control, strategic coordination, and …
Butte Priority Soils Operable Unit (Bpsou) 2026 Monthly Progress Report. Consent Decree For The Butte Priority Soils Operable Unit. Civil Action No. Cv 89-039-Bu-Seh, Josh Bryson
Silver Bow Creek/Butte Area Superfund Site
No abstract provided.
Re: Conditional Approval Letter For The Butte Priority Soils Operable Unit (Bpsou) Clark Tailings Consolidated Waste Management Area (Ctcwma) Site Investigation Quality Assurance Project Plan (Qapp) (Dated April 16, 2026), Emma Rott
Silver Bow Creek/Butte Area Superfund Site
No abstract provided.
Draft Final Butte Mine Waste Repository Operation And Maintenance (O&M) Plan, Pioneer Technical Services, Inc.
Draft Final Butte Mine Waste Repository Operation And Maintenance (O&M) Plan, Pioneer Technical Services, Inc.
Silver Bow Creek/Butte Area Superfund Site
No abstract provided.
Re: Comment Letter For Old Butte Silver Bow Landfill/Clark Tailings Consolidated Waste Management Area (Ctcwma) Remedy Effectiveness Evaluation Phase I (Conceptual Site Model) (Dated February 27, 2026), Emma Rott
Silver Bow Creek/Butte Area Superfund Site
No abstract provided.
Stridevision: Automated Detection Of Running Form Deviations From 2d Pose Estimation And Machine Learning, Paulina Eguibar Ortega
Stridevision: Automated Detection Of Running Form Deviations From 2d Pose Estimation And Machine Learning, Paulina Eguibar Ortega
Honors Theses
Running gait analysis plays a critical role in injury prevention and performance optimization, however, existing approaches often rely on specialized laboratory equipment or wearable sensors with limited interpretability. Recent advances in computer vision, particularly 2D human pose estimation, enable markerless motion analysis from standard video. However, progress remains constrained by the lack of publicly available datasets designed for running form analysis.
In this work, we introduce a preliminary dataset and benchmark for stride-level running gait analysis. The dataset consists of 73 treadmill running videos from 15 participants with varying experience levels, annotated with over 4,600 stride-level labels across multiple biomechanical …
The Role Of Peat Matrix Structure In The Accumulation, Storage, And Release Of Biogenic Gases From A Variety Of Peat Soils Across A Latitudinal Gradient, Md Rajeun Islam
The Role Of Peat Matrix Structure In The Accumulation, Storage, And Release Of Biogenic Gases From A Variety Of Peat Soils Across A Latitudinal Gradient, Md Rajeun Islam
Electronic Theses and Dissertations
Peatlands store about a third of the global soil carbon pool and are among the most important natural sources of biogenic greenhouse gases, including methane (CH4) and carbon dioxide (CO2). While biogenic gas production in peatlands has been studied extensively over the last few decades, the physical controls that regulate how these gases accumulate within the soil matrix and their influence on gas dynamics as they get released to the atmosphere still remain uncertain. Most studies investigating biogenic gas dynamics in peatlands have inferred in-situ gas distribution either exclusively from measurements of gas flux releases, or …
Badlands And Bison, Andrew Ressler
Badlands And Bison, Andrew Ressler
The Cicadian
“Badlands and Bison” is a fragmentary travel-fiction hybrid set in the mythic badlands of North Dakota. It merges reportage with invention, parody with elegy: a narrator half pilgrim, half comedian drifts from piano keys to prairie herds, searching for sincerity in a landscape that resists it. The form bends between essay and story, using humor, lyric observation, and shifting registers to question how we mythologize place.
Private Assistant Agent, Bao Le '26
Private Assistant Agent, Bao Le '26
Senior Scholarly and Creative Symposium
Our brain has limited fuel: every time we make a decision, it costs fuel. A Personal Artificial Assistant will help preserve that fuel by handling secretarial tasks and scheduling a daily timetable for its user. Personal Assistant Agent (PAA) is an AI assistant running as a text-based Windows desktop application to help users in scheduling and give reminders like a secretary. Users interact with the PAA conversationally. This project is a system of reasoning and a modular memory pipeline that makes any Large Language Model (LLM) behave like a personal assistant. The Language model is isolated inside a function to …
Hormonal Seed Primimg As A Sustainable Alternative To Pesticides, Oyekemi Oyetoro, Swayamjit Ray
Hormonal Seed Primimg As A Sustainable Alternative To Pesticides, Oyekemi Oyetoro, Swayamjit Ray
Research and Creative Works Expo
This study investigates the use of hormonal seed priming with Methyl Jasmonate (MeJA) and Methyl Salicylic Acid (MeSA) as a sustainable alternative to synthetic pesticides. By inducing Systemic Acquired Resistance (SAR) and Induced Systemic Resistance (ISR), these treatments aim to prepare plant defenses for rapid response to future herbivory with reduced reliance on chemical applications. The research specifically explores the growth-defense trade off, evaluating how various hormonal concentrations impact both pest resistance and seedling vigor. The findings identify optimal priming protocols that balance robust protection against herbivores with the maintenance of primary vegetative growth
High-Frequency Vr-Native Eye Tracking: From Data Collection To Machine Learning Models, Meherun Nesa Shraboni, Aryabrata Basu
High-Frequency Vr-Native Eye Tracking: From Data Collection To Machine Learning Models, Meherun Nesa Shraboni, Aryabrata Basu
Research and Creative Works Expo
No abstract provided.
Practical Guidelines For Pump Testing Of Ccr: Workflow, Design, And Lessons Learned., Nathanial Keller, Brian Hennings, Vic Modeer, Katie Moran
Practical Guidelines For Pump Testing Of Ccr: Workflow, Design, And Lessons Learned., Nathanial Keller, Brian Hennings, Vic Modeer, Katie Moran
World of Coal Ash Proceedings
This session presents a streamlined approach for pump testing of coal combustion residuals (CCR) to maximize hydraulic information with limited well installations, variable pumping rates, and short tests. Pre-test forward modeling identifies well offsets (typically 5–10 ft) and test durations (~2–6 hours) to yield measurable and analyzable drawdown at observation wells despite low pumping rates. Field execution consists of short step-drawdown testing to evaluate well specific capacity and select pumping rates for a constant rate test with one or more observation wells. Test results facilitate analysis of transmissivity and storativity of the CCR. Applied at two Midwestern sites with different …
Brine Solidification And Metals Sequestration Using Lignocellulosics, Frank Kvietok
Brine Solidification And Metals Sequestration Using Lignocellulosics, Frank Kvietok
World of Coal Ash Proceedings
Coal ash has historically been used as a convenient, on-site solidification material for brines generated from flue gas desulfurization at power plants. As alternate utilization scenarios are developed for coal ash, lignocellulosic (wood-based) sorbents can serve as a highly efficient substitute for the solidification process. Results will be shared for a variety of different brine types: thermally reduced, thermally reduced and neutralized, and reverse osmosis. In addition to solidification performance, which demonstrated a 3-4x mass of liquid vs mass of sorbent factor, studies were conducted to quantify the strength of binding to the wood-based sorbent for a broad range of …
Simplified Approximate Procedure For Assessing The Implications Of Updated Usgs Seismic Hazard Models On Seismic Stability Assessments Of Ccr Impoundment Facilities, Nick Mcclung, Matt Bishop, Adrian Pena-Iguaran, Seda Gokyer-Erbis
Simplified Approximate Procedure For Assessing The Implications Of Updated Usgs Seismic Hazard Models On Seismic Stability Assessments Of Ccr Impoundment Facilities, Nick Mcclung, Matt Bishop, Adrian Pena-Iguaran, Seda Gokyer-Erbis
World of Coal Ash Proceedings
Selection of appropriate seismic design ground motions remains a key challenge for seismic stability assessments of coal combustion residual (CCR) impoundment facilities, particularly where regulatory guidance does not specify a required hazard model. This paper examines the implications of using Uniform Hazard Spectra (UHS) derived from the 2014 versus the 2018 U.S. Geological Survey (USGS) National Seismic Hazard Model (NSHM) for seismic amplification and stability evaluations of the Tennessee Valley Authority (TVA) Widows Creek Fossil (WCF) Plant CCR Management Units. The 2018 NSHM incorporates updated understanding of seismicity in the central and eastern United States and generally predicts higher ground …
Integrating Advanced Geochemical Workflows With Modern Statistical Tools To Improve The Decision-Making Process At Ccr Sites, A Case Study, Glenna Thomas
World of Coal Ash Proceedings
While statistical assessment provides the foundation for CCR compliance reporting, incorporating a holistic geochemical framework transforms statistics from a compliance requirement into a powerful predictive tool. Strategic geochemical insight established the basis of understanding needed to support successful statistical approaches and to ensure that statistical outcomes reflect actual groundwater behavior. Whether it is trend analysis, delineating source mechanism, or updating geochemical conceptual site models (GCMs), geochemical context provides the technical foundations for statistical outputs and methods. A continuously refined GCSM enhances the ability to anticipate how groundwater chemistry should evolve, improving interpretation and predictive capability. This allows practitioners to understand …
Before The Limit Hits: Lessons From A Proactive Construction Air Monitoring Program, Brian Egan, Nicholas Golden, Wendy Depp
Before The Limit Hits: Lessons From A Proactive Construction Air Monitoring Program, Brian Egan, Nicholas Golden, Wendy Depp
World of Coal Ash Proceedings
This presentation describes a comprehensive air monitoring program designed to protect workers and nearby neighborhoods during ash pond closure work. The program uses three main components: project (or boundary) monitoring at the site perimeter to track dust near the project boundaries, work area monitoring placed near active construction zones, and personal sampling on individual workers at regular intervals. Together, these approaches provide data on both community impacts and worker exposures, helping the team respond quickly when levels approach action limits. The Teams actions prior to exceedance of regulatory limits has helped prevent exposures. The talk will explain how monitors are …
Monitored Natural Attenuation Evaluation And Additional Characterization Of A Ccr Unit Lithium Groundwater Plume, Matt Barickman, Adam Piestrzeniewicz Pg
Monitored Natural Attenuation Evaluation And Additional Characterization Of A Ccr Unit Lithium Groundwater Plume, Matt Barickman, Adam Piestrzeniewicz Pg
World of Coal Ash Proceedings
Monitored Natural Attenuation (MNA) refers to the reliance on natural attenuation processes (within the context of a carefully controlled and monitored site cleanup approach) to meet groundwater protection standards (GPS) for a CCR unit within a reasonable time frame (USEPA, 1999). MNA is being evaluated as an adaptive management strategy for a CCR unit groundwater plume with statistically significant lithium concentrations above GPS, though with little risk of offsite migration. A previous MNA evaluation was performed for the lithium plume following the United States Environmental Protection Agency (USEPA) “tiered lines of evidence approach” (USEPA, 2015), which determined that there were …
Establishing Groundwater Monitoring Systems Under The Legacy Rule: A Systematic Approach For Utilities, Chris Hoglund
Establishing Groundwater Monitoring Systems Under The Legacy Rule: A Systematic Approach For Utilities, Chris Hoglund
World of Coal Ash Proceedings
The USEPA’s Legacy CCR Rule introduces new requirements for establishing groundwater monitoring systems at Legacy Surface Impoundments (LSIs) and Coal Combustion Residual Management Units (CCRMUs). These requirements present unique challenges for electric utilities, particularly at inactive or historically operated facilities where subsurface data are limited and CCR units may have nontraditional configurations such as linear roadways, elongated embankments, or distributed disposal areas. Utilities must also determine how best to apply single-unit or multi-unit monitoring approaches, integrate newly regulated units into existing monitoring networks, and align monitoring system design with planned closure strategies. This presentation outlines a systematic, defensible framework to …
Risk Evaluation Of Linear Coal Combustion Residual Management Unit (Ccrmu) Fills, Qian Zhang, Andrew Bittner, John Kondziolka, Masoud Arshadi
Risk Evaluation Of Linear Coal Combustion Residual Management Unit (Ccrmu) Fills, Qian Zhang, Andrew Bittner, John Kondziolka, Masoud Arshadi
World of Coal Ash Proceedings
In 2024, the US Environmental Protection Agency (US EPA) established new regulations for coal combustion residual management units (CCRMUs), defined as coal combustion residual (CCR) deposits placed on power plant properties outside of landfills or surface impoundments. US EPA supported the rulemaking with modeling-based risk analyses and established regulatory requirements based on fill size. Linear CCRMU, such as backfill along pipelines or haul roads, have individual segments that may be composed of a small amount of mass below the threshold for regulation, but the cumulative mass over the full linear feature extent may exceed regulatory thresholds. This study applies US …
Application Of Mine Tailings Flow Failure Assessment On Ccr, Zachary Fallert
Application Of Mine Tailings Flow Failure Assessment On Ccr, Zachary Fallert
World of Coal Ash Proceedings
A new geotechnical stability analysis method has been implemented for a CCR surface impoundment to aid in design for temporary cut slopes and final closure grades. Conditions have come to light after significant tailings dam failures occurred across the globe, specifically those exhibiting flow failures (i.e. failures in which tailings behave a liquid and flow out of the facility). These failures have come under intense scrutiny as the failures pose significant risk to public safety and the environment and have been observed in CCR. Additionally, static liquefaction has arisen as another potential but less well understood causative mechanism. As the …
Lessons Learned: Commissioning An Fgd Wastewater Treatment System, Bella Triolet, Mckale Grant, Louis Manigault
Lessons Learned: Commissioning An Fgd Wastewater Treatment System, Bella Triolet, Mckale Grant, Louis Manigault
World of Coal Ash Proceedings
Stantec recently supported commissioning a flue gas desulfurization (FGD) Wastewater Treatment System in accordance with the 2020 Environmental Protection Agency (EPA) Effluent Limitations Guidelines (ELG) Rule, which requires that coal fired power plants meet their more stringent requirements by December 31, 2025. With the addition of the 2024 EPA ELG Rule, coal fired power plants will now be expected to move to zero liquid discharge (ZLD) systems or permanently cease coal combustion by 2034. Due to this change, it is likely that coal fired power plants will be looking to design and install ZLD systems within the next decade. While …
Risk Evaluation Of Linear Coal Combustion Residual Management Unit (Ccrmu) Fills, Qian Zhang, Andrew Bittner, John Kondziolka, Masoud Arshadi
Risk Evaluation Of Linear Coal Combustion Residual Management Unit (Ccrmu) Fills, Qian Zhang, Andrew Bittner, John Kondziolka, Masoud Arshadi
World of Coal Ash Proceedings
In 2024, the US Environmental Protection Agency (US EPA) established new regulations for coal combustion residual management units (CCRMUs), defined as coal combustion residual (CCR) deposits placed on power plant properties outside of landfills or surface impoundments. US EPA supported the rulemaking with modeling-based risk analyses and established regulatory requirements based on fill size. Linear CCRMU, such as backfill along pipelines or haul roads, have individual segments that may be composed of a small amount of mass below the threshold for regulation, but the cumulative mass over the full linear feature extent may exceed regulatory thresholds. This study applies US …
Site Characterization, Design, Permitting, And Construction For Clean Closure Of A Small But Challenging Legacy Ccr Disposal Impoundment, John Garten, Bob Baker, Lee Lenhart
Site Characterization, Design, Permitting, And Construction For Clean Closure Of A Small But Challenging Legacy Ccr Disposal Impoundment, John Garten, Bob Baker, Lee Lenhart
World of Coal Ash Proceedings
The Lay of Land Area (LOLA) is a 10-acre (40,468 square meters) legacy disposal impoundment containing approximately 55,000 cubic yards (42,000 cubic meters) of sluiced coal combustion residuals (CCRs) produced during startup operations of a former fossil plant. Most of its perimeter is bounded by water, with a river to the north and a cooling water lake to the south. The entire area lies within a 100-year floodplain, is heavily forested, and groundwater is typically encountered within a few feet of the existing ground surface. As part of an overall CCR closure-by-removal and ash beneficiation program, planning, design, permitting, and …
Trimble County Pond Closures, Steven Turner, Shanti Montgomery
Trimble County Pond Closures, Steven Turner, Shanti Montgomery
World of Coal Ash Proceedings
The Trimble County Closure Project is a 5-year project to close the 40-acre (161,900 square meters) Gypsum Storage Pond (GSP) through closure-by-removal and the 100-acre (404,700 square meters) Bottom Ash Pond (BAP) through closure-in-place in accordance with coal combustion residual (CCR) Rule. The excavated gypsum from the GSP was “Beneficially Reused” to fill the BAP to the prescribed grade for drainage through a monitored outfall to the adjacent creek. The daily plant produced CCRs of fly ash, bottom ash, and gypsum were also used for four years to supplement the filling of the BAP as well as several onsite soil/rock …
Building Better Partnerships: Design-Build Lessons From The Ash Pond Closure Front Lines, Brian Egan, Nicholas Golden, Mark Edlebeck
Building Better Partnerships: Design-Build Lessons From The Ash Pond Closure Front Lines, Brian Egan, Nicholas Golden, Mark Edlebeck
World of Coal Ash Proceedings
This presentation shares lessons learned on an ash pond dig-and-haul project delivered by a design-build team with CTI providing engineering and Fisher Contracting delivering construction services. CTI and Fisher Contracting will discuss how they formed their partnership, what makes a good teaming arrangement work, and the challenges that come with working closely together. This team has worked side by side from early design through construction, which has helped cut costs and keep the project on schedule. The talk will show how the partners divide tasks, then adjust roles as needed instead of locking into a fixed plan. In some cases, …
Dewatering System Operations And Modeling Of A Bottom Ash Ccr Surface Impoundment, Craig Schuettpelz, Todd Stong, Ben Sieren
Dewatering System Operations And Modeling Of A Bottom Ash Ccr Surface Impoundment, Craig Schuettpelz, Todd Stong, Ben Sieren
World of Coal Ash Proceedings
Dewatering of coal combustion residual (CCR) surface impoundments is a technically challenging item for sites with CCR units at closure. Generation has ceased at this site where fly ash was mostly sold for beneficial use and bottom ash was sluiced to composite-lined CCR surface impoundments to passively drain prior to landfilling. During site closure and restoration, bottom ash and relatively minor amounts of other permitted waste materials were consolidated into the site’s landfill and bottom ash impoundment. The bottom ash impoundment entered closure 5 years ago with installation of a final cover system and construction of a sump to allow …
Illinois Coal Ash Impoundment Assessment, Randy Locke
Illinois Coal Ash Impoundment Assessment, Randy Locke
World of Coal Ash Proceedings
Coal combustion residuals (CCR) present one of the most significant waste management challenges in the United States. Illinois hosts 72 coal ash impoundments at 23 facilities across 22 counties. In 2019, the state enacted Public Act 101 0171 (Coal Ash Pollution Prevention Act), followed by Illinois Administrative Code Title 35, Part 845, establishing CCR surface impoundment standards. Even with federal and state requirements, significant gaps remain in identifying management options and site-specific risks. Key limitations include: (1) incomplete understanding of ash composition and variability within and among impoundments; and (2) fragmented information on impoundment physical properties, operational status, and geological …