Digital Commons Network^™

Framing Wildlife Conservation: Exploring Political Bias In States' Wildlife Action Plans, Ciara Nelson

Department of Environmental Studies: Undergraduate Student Theses

Climate change affects regions of the United States differently due to factors such as the country's diverse physical landscapes, political environments, and population distributions. This variation leads to varying impacts on humans, wildlife, and ecosystems, with anthropogenic climate change—acknowledging humans as a significant contributor—being a point of contention, especially among some prominent politicians. The relationship between political party affiliation and climate change acknowledgment is evident, with recent political discourse highlighting differing views on the severity of climate change. This political framing influences how environmental policies are perceived and accepted, with the choice of language and framing playing a crucial role …

Vibmilk: Non-Intrusive Milk Spoilage Detection Via Smartphone Vibration, Yuezhong Wu, Wei Song, Yanxiang Wang, Dong Ma, Weitao Xu, Mahbub Hassan, Wen Hu

Research Collection School Of Computing and Information Systems

Quantifying the chemical process of milk spoilage is challenging due to the need for bulky, expensive equipment that is not user-friendly for milk producers or customers. This lack of a convenient and accurate milk spoilage detection system can cause two significant issues. First, people who consume spoiled milk may experience serious health problems. Secondly, milk manufacturers typically provide a “best before” date to indicate freshness, but this date only shows the highest quality of the milk, not the last day it can be safely consumed, leading to significant milk waste. A practical and efficient solution to this problem is proposed …

Electrochemical Modulation Of Surface Plasmon Wave To Investigate Dna-Based Sensing Platforms And Detection Of Sars-Cov2., Anil Sharma

Electronic Theses and Dissertations

This study offers a thorough comparative analysis of optical and electrical signaling strategies for assessing the electrochemical properties of different redox-labeled DNA-based biosensing platforms. In addition, it illustrates the development of an optical interrogation technique with electrochemical modulation of surface plasmon waves (ECM-SPW) as a route for analyzing and implementing DNA-based hybridization sensors. For those quantitative analyses, we chose a model sensing platform composed of a methylene blue (MB)-modified single-stranded DNA (ssDNA) signaling probe and an unlabeled capture ssDNA probe that complements the signaling probe. Two types of signaling probes were employed in this work: one with MB attached to …

Utilizing Metal Ligand Cooperativity To Activate Small Molecules., Christine Burgan

Electronic Theses and Dissertations

The problems created from the excessive use of fossil fuels can be approached from two directions: capture the CO₂ from the atmosphere or develop alternative energy sources. The current industrial standards for these are environmental and/or health hazards and utilize precious metals, respectively. Metal ligand cooperativity (MLC) has emerged as a promising alternative to using precious metals to activate small molecules. In this dissertation, we focus on a series of metal complexes based on the ligand diacetyl-2-(4-methyl-thiosemicarbazone)-3-(2-hydrazinopyridine) (H₂L¹) for either hydrogen evolution or CO₂ capture. The novel complexes were characterized by ¹H NMR, …

Proof-Of-Concept For Converging Beam Small Animal Irradiator, Benjamin Insley

Dissertations and Theses (Open Access)

The Monte Carlo particle simulator TOPAS, the multiphysics solver COMSOL., and

several analytical radiation transport methods were employed to perform an in-depth proof-ofconcept

for a high dose rate, high precision converging beam small animal irradiation platform.

In the first aim of this work, a novel carbon nanotube-based compact X-ray tube optimized for

high output and high directionality was designed and characterized. In the second aim, an

optimization algorithm was developed to customize a collimator geometry for this unique Xray

source to simultaneously maximize the irradiator’s intensity and precision. Then, a full

converging beam irradiator apparatus was fit with a multitude …

Geometric Principles In Architecture Aesthetics, Vincent Gemmiti

Architecture Undergraduate Honors Theses

This study focuses on geometric formalism in three major monuments across different architectural eras in time. The use of three distinct geometric principles to outline the use of pure or manufactured shapes and figures helps to discover and isolate an aesthetic component of architecture within which it is contained. A collection of studies are implemented and are focused on orthographic drawings from each monument in horizontality and verticality, consisting of a dual set of overlay and interpretative drawings for each type of orthographic representation for each monument. A discussion follows and highlights the changes or similarities over time the role …

Evaluating The Epidemiological, Hormonal, And Psychosocial Sex-Based Differences In Sports-Related Concussion Outcomes, Samantha Kanny

All Dissertations

Sports-related concussions (SRCs) affect approximately 3.8 million athletes in the United States per year. A multitude of risk factors including age, sex, concussion history and prior medical conditions have been observed to significantly increase sports-related concussion symptom burden. Researchers have posited many reasons to explain sex-based differences in SRC outcomes, often categorized by biological characteristics or sociocultural factors, however, females are vastly underrepresented in sports-related concussion research, making it difficult to understand the true mechanisms underlying SRC sex-based differences. The goal of this dissertation is to help fill the current gap in knowledge on sex-based differences in sports-related concussion outcomes. …

Eco-Anxiety Effects College Students, Alexa Edmundson

Department of Environmental Studies: Undergraduate Student Theses

A survey was conducted on the UNL student population to evaluate whether college students, 18-25 year olds who are currently attending an accredited post-secondary school, are experiencing eco-anxiety and if eco-anxiety affects their pro-environmental behaviors. Climate change is taking a toll not only physically on us but also mentally. The mental health of people, especially college students, is not often studied in relation to climate change, but if we are to understand how to create change in this issue then we need to be looking at the whole picture. The hypothesis is that if college students are experiencing eco-anxiety, then …

Educational Influences On Environmental Perception: A Semester Analysis Of The New Ecological Paradigm Scale In Undergraduates, Zoe Zingler

Department of Environmental Studies: Undergraduate Student Theses

This study evaluated the impact of a geography course, GEOG 181: Global Environmental Issues, at the University of Nebraska-Lincoln on students’ endorsement of the New Ecological Paradigm (NEP) using a pre-course and post-course NEP scale survey. Analyzing paired responses (n = 40) through t-tests and z-scores, only four of 15 statements had statistically significant shifts observed for the entire sample. However, a targeted analysis of students initially possessing lower endorsement of the NEP—early deniers—revealed significant paradigm shifts post-course. While women initially showed stronger NEP endorsement, men demonstrated notable changes following the course towards endorsement of the NEP. Academic majors, whether …

Development Of Novel Immobilized Copper–Ligand Complex For Click Chemistry Of Biomolecules, Rene Kandler, Yomal Benaragama, Manoranjan Bera, Caroline Wang, Rasheda Aktar Samiha, W.M.C. Sameera, Samir Das, Arundhati Nag

Chemistry

Copper-catalyzed azide–alkyne cycloaddition click (CuAAC) reaction is widely used to synthesize drug candidates and other biomolecule classes. Homogeneous catalysts, which consist of copper coordinated to a ligand framework, have been optimized for high yield and specificity of the CuAAC reaction, but CuAAC reaction with these catalysts requires the addition of a reducing agent and basic conditions, which can complicate some of the desired syntheses. Additionally, removing copper from the synthesized CuAAC-containing biomolecule is necessary for biological applications but inconvenient and requires additional purification steps. We describe here the design and synthesis of a PNN-type pincer ligand complex with copper (I) …

Do You Know The Pangolin?: Analyzing Biodiversity Awareness And Attitudes, Ariel "Jazz" Holcomb

Honors Theses

Understanding the impact education has on environmental knowledge and values is critical for knowing how we can promote pro-environmental awareness and attitudes. Thus, this study investigated how environmental education level influences awareness and attitudes on environmental issues, specifically the Biodiversity Crisis. Through a survey primarily utilizing Likert scale statements, the researcher evaluated the differences in knowledge and care levels between classes taking an introductory environmental science course, one class of environmental science majors and one for non-majors. One focus point of the course is the world’s most trafficked mammal, the pangolin, so this species was used as a focus species …

The Mathematics Of Financial Portfolio Optimization Incorporating Environmental, Social, And Governance Score Information, Ian Driskill

Master's Theses

We numerically investigate the effects that Environmental, Social, and Governance (ESG) scores have on portfolio optimization with Modern Portfolio Theory assumptions and how ESG scores correlate with the market returns of a rated company's stock. Additionally, we review and analyze a research paper published in the Journal of Financial Economics regarding ESG investing titled “Responsible investing: The ESG-efficient frontier” by Pedersen, Fitzgibbons, and Lukasz. Our overall goal is provide insight for socially responsible inclined investors, to help them understand what ESG scores tell us and how those scores may effect their overall investment returns."

Changes In Zooplankton Community Structure In A Wetland Metacommunity Following Homogenization From Flooding, Kevin Peteroy

Theses, Dissertations and Culminating Projects

Wetlands in urban areas provide ecosystem services that benefit the environment and society. Through these services, wetlands are able to help mitigate consequences of human activities such as flooding by increasing permeable surface coverage and contaminant filtering from polluted runoff. One such type of wetland, vernal pools, provide important temporary habitat for many organisms, including myriad zooplankton species. For planktonic organisms, flooding events might be disruptive or allow them to disperse to areas that would be otherwise inaccessible. I observed changing abiotic conditions and zooplankton communities in 20 vernal pools at a wetland in Wayne, New Jersey, USA over a …

Tpm^Ph Derivative Of Tungsten; Hydrogen-Bonding In 7-Coordinate Cation Complex, Olivia Ryon Simcox

Undergraduate Honors Thesis Collection

Tpm^Ph, or tris(3-phenylpyrazolyl)methane reacts with tungsten hexacarbonyl to form the ligand-metal complex tris(3-phenylpyrazolyl)methane tungsten tricarbonyl, or Tpm^PhW(CO)3. The further complexes of Tpm^PhW(CO)3 and Tpm^PhMo(CO)3 are not known. This project aims to explore how the addition of a phenyl substituent to the pyrazole ring on Tpm impacts the synthesis of [Tpm^PhW(CO)3I]+X– and [Tpm^PhW(CO)3H]+X–. The inclusion of this phenyl substituent may impact the possible hydrogen bonding of then hydrogen contained in the carbon-hydrogen bond. This work aims to explore the extent of hydrogen-bonding of the carbon-hydrogen bond of the Tpm^Ph ligand in cationic metal complexes.

Atmospheric Deposition Trends Are Primarily Decreasing In Arkansas And Tennessee, Anna Mccarty

Crop, Soil and Environmental Sciences Undergraduate Honors Theses

Atmospheric deposition has likely changed with the influence of increasing global temperatures and subsequent changes in precipitation across the United States and globally. The objective of this project was to analyze atmospheric deposition across northern Arkansas and Tennessee. The three specific objectives were to: i) evaluate trends in atmospheric deposition of various element/compounds, ii) assess the relationship between atmospheric deposition and rainfall, and iii) evaluate if rainfall-adjusted atmospheric deposition is changing over time. Six sites were analyzed from 1980 to 2022, including AR16, AR27, TN00, TN04, TN11, and TN14, which span over northern Arkansas and across Tennessee. The Mann-Kendall Test …

Reconnecting With Nature One Classroom At A Time, Bianca Apuzzo

Senior Honors Projects

Environmental science is more important to today’s society than it has ever been, and developing basic ecoliteracy is the easiest way we can work towards a more sustainable future. Ecoliteracy allows us to connect deeper to nature and provides us with the information needed to protect and restore our beautiful planet. We are rolling downhill, picking up speed as we go, through a silent mass extinction. The scariest part of it all: nobody seems to care.

In response to the lack of environmental education provided to today’s students, I have created a syllabus for a high school level science course …

A Copper-Selective Sensor And Its Inhibition Of Copper-Amyloid Beta Aggregation, Ngoc Kim Nguyen, Bella Poduska, Mia Franks, Manoranjan Bera, Ian Maccormack, Guoxing Lin, Alexander P. Petroff, Samir Das, Arundhati Nag

Chemistry

Copper is an essential trace metal for biological processes in humans and animals. A low level of copper detection at physiological pH using fluorescent probes is very important for in vitro applications, such as the detection of copper in water or urine, and in vivo applications, such as tracking the dynamic copper concentrations inside cells. Copper homeostasis is disrupted in neurological diseases like Alzheimer’s disease, and copper forms aggregates with amyloid beta (Ab42) peptide, resulting in senile plaques in Alzheimer’s brains. Therefore, a selective copper detector probe that can detect amyloid beta peptide-copper aggregates and decrease the aggregate size has …

Relationship Between Marine Heatwaves And Diadema Antillarum Settlement In The Florida Keys, David Ogando Jr.

Theses, Dissertations and Culminating Projects

Ocean warming can have profound impacts on benthic marine invertebrates through direct physiological effects. Yet, the impacts of ocean warming on the long-spined sea urchin (Diadema antillarum), a keystone grazer on western Atlantic and Caribbean coral reefs, has received little attention. In the summer of 2023, the Caribbean basin experienced a strong marine heatwave event with sea temperatures ~1–3°C above average and the warmest on record in southern Florida. An ongoing field settlement sampling program for D. antillarum in the Florida Keys provided an opportunity to examine the correlative relationship between thermal exposure and larval settlement. Thermal exposure was quantified …

The Influence Of Edaphic Factors On The Growth And Competitiveness Of Loosestrife (Lythrum Spp.), Martha Mahady

Theses, Dissertations and Culminating Projects

Wetlands are important areas in the landscape, providing important ecosystem services. Purple loosestrife (Lythrum salicaria), native to Europe and Asia, invades wetlands in North America, outcompeting native wetland plants and disrupting ecosystem services. While purple loosestrife is invasive in North America, it is not in its native range. Winged loosestrife (Lythrum alatum), a North American native congener, is not invasive in North America. Purple loosestrife from Sussex County, N.J. U.S.A. and purple loosestrife from the United Kingdom, and winged loosestrife were compared in this study. Their response to soil edaphic factors, such as seed vernalization, soil nutrients, soil pH, water, …

A Global Analysis Of Carbon And Nitrogen Stocks In Natural And Anthropogenic Soils, Shih-Chieh Chien

Theses, Dissertations and Culminating Projects

In terrestrial biomes, soils possess the highest amount of carbon and nitrogen stocks that regulate biogeochemical processes and provide ecosystem services. The amount of carbon and nitrogen stored in soils, as a balance of nutrient influxes and outfluxes, is controlled by various environmental and soil factors, while at the same time soil carbon and nitrogen stocks can be subject to anthropogenic impacts, like nutrient storage in urban soils. To inform a better, general understanding of carbon and nitrogen distribution in urban soils, the present dissertation gathers four articles (from Chapters 2 to 5, respectively) addressing different aspects of the issue, …

Evaluation Of Heavy Metal Pollution, Water Quality, And The Effectiveness Of Remedial Sediment Dredging In The Lower Passaic River, New Jersey, Oluwafemi Soetan

Theses, Dissertations and Culminating Projects

Toxic metal pollution is a leading environmental concern for aquatic systems globally and remedial dredging has been widely employed to mitigate its harmful impacts. In terms of the short-term impacts of remedial dredging, mixed results are reported in several studies. Despite its immediate negative impacts including saturation of water with toxic metals, increased turbidity, and sediment resuspension, positive impacts can be recorded over a stabilization period of 6 – 24 months after dredging. Nevertheless, the sustainability of these recorded positive effects cannot be ascertained as some studies have reported long-term regression in remediated sites’ conditions. Evaluation of success determinants, site-measure …

A Multi-Century Reconstruction Of Sea Surface Temperature, Salinity, And Density From A Northern Red Sea Coral., Daliza Nanette Rivera-Matos

Legacy Theses & Dissertations (2009 - 2024)

The Red Sea Outflow Water (RSOW), an intermediate water mass formed in the northern Red Sea, is a primary Red Sea water circulation process. Understanding these water circulation processes gives us an insight into this region's climate dynamics. The intermediate water formation is one of the main processes of the water circulation in the northern Red Sea and feeds the Indian Ocean with saltier and colder water. Despite understanding the RSWO's association with the North Atlantic Oscillation (NAO), its historical response to this climate mode remains unclear. There has not been a long-term record to analyze the relationship between the …

Determining The Time Since Deposition Of Bloodstains Based On Vibrational Spectroscopy For Forensic Purposes, Alexis Renee Weber

Legacy Theses & Dissertations (2009 - 2024)

At the scene of violent crimes, bloodstain evidence is one of the most frequently found and valuable types of evidence. Blood traces discovered at crime scenes can provide crucial information to an investigation. By obtaining a DNA profile from the bloodstain, the profile can be used to link someone to a crime scene, which can corroborate or dispute a witness's statement. However, the current analysis of bloodstains is still not able to answer a key question for investigators: how much time has passed since the criminal event occurred? In addition, an equally important aspect of crime reconstruction is the ability …

Advancing Learning Models For High-Dimensional Data: From Molecular Modeling To Motion Planning, Tuan Nguyen Anh Tran

Legacy Theses & Dissertations (2009 - 2024)

Processing and analyzing high-dimensional data, particularly in domains like protein research and robotics, introduces unique challenges. In protein analysis, high-dimensional data often arises from complex molecular structures and their interactions. Analyzing protein data involves intricate computational models and algorithms that must deal with the large size of molecular datasets and the need to extract biologically relevant information. This makes it challenging to discern significant protein structure-activity relationships, understand complex biological interactions, or predict protein behavior accurately. Similarly, in robotics, high-dimensional data is prevalent when dealing with sensory inputs, the dimensionality of the robot, or the complexity of the operational environments. …

Square Functions For Ritt Operators In L1, Jennifer M. Hults

Legacy Theses & Dissertations (2009 - 2024)

Let Y be a Banach space. An operator T ∈ L(Y) is a Ritt operator providedsupn n∥Tn − Tn+1∥ < ∞. For Ritt operators T in Lp, where 1 < p < ∞, the square function (?n2m+1|Tn(I − T)m+1f|2)1/2 is bounded. We show that (?nα|Tn(I − nn T)lf|s)1/s is bounded in L1 for for l > 0 and sl > α+1 and (?nα|Tn(I−Tl)f|s)1/s is n 1 + ?n n+1s1/s boundedinL forl∈Z ands>α+1.Wealsoconsider( nl|T lf−T l f|) l where {nl} is an increasing sequence with increasing gaps. Finally, we investigate the related variational and oscillation norms.

Exploring Nucleic Acid Modifications For Rna-Based Therapeutics: Insights From Molecular Dynamics Simulations, Samantha Biaesch

Legacy Theses & Dissertations (2009 - 2024)

Nucleic acid modifications are pivotal in biological processes due to their multifaceted roles. They regulate gene expression by modulating transcription, with modifications in the nucleic acid, sugar group, or in its phosphate backbone. In our investigation, we explore the use of molecular dynamics simulations to study nucleic acid modifications for potential applications in RNA-based therapeutics. These modifications introduce nonstandard atoms, such as selenium, and new parameterizations must be performed to properly simulate in GROMACS. These parameters govern bonded (strength of bonds, angles and dihedrals) and non-bonded (size and charges) interactions for each of the atoms in the modification. The first …

Barrier Removal Prioritization To Increase Climate Resiliency And Aquatic Connectivity For Communities In The Upper Susquehanna Basin, Cassandra Mae Davis

Legacy Theses & Dissertations (2009 - 2024)

The streams and rivers of the Upper Susquehanna Basin have been heavily modified over centuries through deforestation of nearshore areas and creation of physical barriers, such as dams and culverts. Dams and undersized culverts negatively affect aquatic organisms by modifying habitat conditions and restricting movement of these organisms. In addition, improperly maintained dams and undersized culverts can intensify flooding impacts and negatively affect water quality. A standardized method is needed to determine which barriers should be prioritized for assessment and potential replacement or removal based on multiple ecosystem and societal factors. The goal of this analysis was to have a …

Argonaute 2 Binding Affinity To Determine Repression Of Mirna-Mrna Pairs, Christina M. S. Karadiakos

ALL - Honors Theses

MicroRNAs (miRNA) are a class of small non-coding RNAs that play a key role in gene silencing. miRNAs form an RNA-induced silencing complex (RISC) with the argonaute 2 (AGO2) protein in order to control gene expression through silencing messenger RNAs (mRNA). The ability for a miRNA-mRNA complex to fit into AGO2 and form the RISC is based on the location and characteristics of a central bulge, but the mechanism and interactions that lead to a functional RISC remain unknown. Using available experimental data, we modeled complexes composed of a miRNA (miR-34a) and different mRNA sequences inside of AGO2. The resulting …

Screening Full-Sib And Half-Sib Families Of Chestnut Seedlings For Resistance To Cryphonectria Parasitica Using A Small Stem Assay And A Leaf-Disc Assay, Uma Plambeck

Honors Theses

Cryphonectria parasitica is the ascomycete fungus species that causes chestnut blight disease. Symptoms of chestnut blight include bark cankers and eventually the death of American chestnut, Castanea dentata. However, not all Castanea species are equally affected by the disease, and some Asian species appear highly resistant. The OALDS and SSA in this study aim to assist in screening for resistance to C. parasitica within a year. We investigated the effect of C. parasitica on three North American species, one European species, four East Asian species of Castanea, and nine full-sib families of TACF backcross hybrids. Our study used both a …

Advancement Of Iterative Optimization Technology Algorithms Toward Calibration-Free Process Analytical Technology Applications, Adam Rish

Electronic Theses and Dissertations

The expansion of spectroscopic process analytical technology (PAT) tools within the pharmaceutical industry has the potential to elevate the current state-of-the-art of pharmaceutical manufacturing by offering opportunities for reduced quality testing times, enhanced process control, and greater production flexibility. Spectroscopic PAT tools are dependent on multivariate models to extract the relevant information from the spectral outputs. However, there is a substantial calibration burden for developing and maintaining these multivariate models that discourages the application of PAT, despite the encouragement from regulators. This has led to an interest in calibration-free methods such as iterative optimization technology (IOT) for spectroscopic PAT that …