Digital Commons Network^™

Using Landscape Ecology And Spatial Statistics To Examine The Impacts Of Proposed Removals To Natural Heritage System And The Agricultural System Of Ontario’S Greenbelt, Brianna Downey

Theses and Dissertations (Comprehensive)

The 2022 proposed removals from the Greater Toronto Area (GTA), Southern Ontario’s Greenbelt would have resulted in negative impacts including, reductions to the size and functionality of the Agricultural System and Natural Heritage System, which are components of protected Greenbelt area. Several removal sites were located either on or in close proximity to corridor areas of the NHS, reducing connectivity and negatively impacting the surrounding ecological area. The removal of Agricultural land primarily consisted of corn and soybeans, as well as large removals of woodland, wetland, and shrubland class areas. The removal sites on local Agricultural composition and configuration were …

Comprehensive Analysis Of Environmental Particulate Matter: Chemical Composition And Microbial Assessment, Uyen T. L. Le

Theses and Dissertations (Comprehensive)

Rapid industrialization and population growth have contributed to a decline in air quality, with particulate matter (PM) posing particular concern. PM originates from both natural and human sources and often contains toxic chemicals and microorganisms, including potential pathogens. Inhalation of PM is linked to respiratory and cardiovascular diseases, underscoring the need to characterize better its chemical and biological composition in understudied region - Waterloo, Ontario, Canada. The present thesis is a culmination of three main parts. Part 1 will describe the use of the dithiothreitol (DTT) assay to quantify the oxidative potential of PM through DTT consumption of redox-active field …

Macroinvertebrate Communities And Food Web Structure In Tundra Streams Are Shaped By Substrate Size And Beaver Impoundments, Mathew K. Mervyn

Theses and Dissertations (Comprehensive)

North American beavers (Castor Canadensis) are expanding their range into the Arctic tundra as climate change drives earlier ice and snowmelt, and increased shrub cover. As ecosystem engineers, beavers build dams that alter water chemistry by creating impoundments within streams, trapping sediment and organic matter, and modifying nutrient cycling. This thesis evaluates how beaver impoundments interact with natural geomorphic variation in tundra streams and how impoundments affect tundra freshwater ecosystems in the western Canadian Arctic.

In Chapter 2, I compared water chemistry and benthic macroinvertebrate (BMI) community composition across 16 stream reaches, including those with and without beaver dams, with …

Crime Modeling Using An Integrated Cnn–Lstm Architecture With Embedded Self-Excitation, Pawandeep Kaur

Theses and Dissertations (Comprehensive)

It is often assumed that natural phenomena occur randomly over time. However, careful analysis reveals that these events typically form some series or sequences and exhibit distinctive temporal patterns. These patterns are not exclusive to nature. They also appear in human activities, often studied under the concept of bursty human dynamics. The statistical methods analyzing bursty human dynamics not only capture overall trends or seasonality but also explore how past events influence future ones. It makes the analysis more realistic and the results more closely aligned with reality. Bursty human dynamics can be studied at two levels: the individual level …

Integrating Indigenous Values And Community Strengths To Achieve Indigenous Food Sovereignty And Community Well-Being In The Ka’A’Gee Tu First Nation, Northwest Territories, Jennifer K. Temmer

Theses and Dissertations (Comprehensive)

Northern Indigenous communities face disproportionate impacts from interconnected challenges related to climate change, food security, health, and cultural preservation, that threaten traditional food systems and practices. While there is a growing recognition of the importance of community-driven solutions, existing frameworks fail to integrate Indigenous values and local priorities effectively. This research addresses this gap by exploring how the Ka’a’gee Tu First Nation (KTFN) is responding to these crises through climate change adaptation efforts focused on food system sustainability as a pathway to self-sufficiency and community well-being. To contribute to these efforts, this dissertation uses Participatory Action Research to facilitate community-driven …

Functional Design Of Dissymmetric Ligands For Coordination Systems, Kaitlyn R. Brown

Theses and Dissertations (Comprehensive)

Herein, the functional design of dissymmetric ligands for coordination systems is explored with a focus on their synthesis and structural characterization. The design strategy of these ligands incorporates the ability to coordinate both metal cations and anions along with a ligand site for other functionalization. Their synthesis, structural and other characterization, Hirshfeld surface analysis, and some metal-coordinated complexes are discussed. Chapter 1 introduces supramolecular and coordination chemistry, along with relevant literature that supports this research and outlines the thesis objective. Chapter 2 investigates the hydrogen bonding of a dissymmetric pyrimidine thioether ligand in its neutral form, water solvate, protonated nitrate …

Evaluating The Long-Term Effectiveness Of Marsh Terracing For Conservation With Integrated Geospatial And Wetland Simulation Modeling, Nick Carpenter, Laura Costadone, Thomas R. Allen

ODU Articles

Coastal marshes provide essential ecosystem services, yet they are vulnerable to anthropogenic stressors and climate change, particularly sea level rise (SLR). Restoration approaches like marsh terracing have emerged as nature-based strategies to enhance resilience and reduce habitat loss. This study applies the Sea Level Affecting Marshes Model (SLAMM) to assess the potential of marsh terraces to mitigate future losses, while also examining the model’s limitations, including its assumptions and capacity to reflect complex marsh processes. A geospatial approach was used to generate 3D representations of terraces through morphostatic modeling within digital elevation models (DEMs). Under a no-restoration scenario, SLAMM projections …

Advances In Bacterial Cellulose-Based Scaffolds For Tissue Engineering: Review, Rewati Raman Ujjwal, Gymama Slaughter

Center for Bioelectronics Publications

Bacterial cellulose (BC) has emerged as a highly versatile and promising biomaterial in tissue engineering, with potential applications across skin, bone, cartilage, and vascular regeneration. Its exceptional properties like high mechanical strength, superior biocompatibility, excellent moisture retention, and inherent ability to support cell adhesion and proliferation, make BC particularly effective for wound healing and skin regeneration. These attributes accelerate tissue repair and foster new tissue formation, highlighting its value in skin-related applications. Additionally, BC's capacity to support osteogenic differentiation, combined with its mechanical robustness, positions it as a strong candidate for bone tissue engineering, facilitating regeneration and repair. Recent advancements …

Fabrication Of Thylakoid Membrane-Based Photo-Bioelectrochemical Bioanode For Self-Powered Light-Driven Electronics, Amit Sarode, Gymama Slaughter

Center for Bioelectronics Publications

The transition toward sustainable and decentralized energy solutions necessitates the development of innovative bioelectronic systems capable of harvesting and converting renewable energy. Here, we present a novel photo-bioelectrochemical fuel cell architecture based on a biohybrid anode integrating laser-induced graphene (LIG), poly(3,4-ethylenedioxythiophene) (PEDOT), and isolated thylakoid membranes. LIG provided a porous, conductive scaffold, while PEDOT enhanced electrode compatibility, electrical conductivity, and operational stability. Compared to MXene-based systems that involve complex, multi-step synthesis, PEDOT offers a cost-effective and scalable alternative for bioelectrode fabrication. Thylakoid membranes were immobilized onto the PEDOT-modified LIG surface to enable light-driven electron generation. Electrochemical characterization revealed enhanced redox …

A Happy Medium?: Using Image Generators To Explore Solution-Focused Art Therapy’S Miracle Question, Daniel A. Hernried

Art Therapy | Master's Theses

This mixed methods, randomized, single-session study tested whether integrating text-to-image generations into Solution-Focused Brief Art Therapy alters therapeutic rapport and short-term outcomes relative to traditional artmaking materials. Participants were assigned by coin flip to create using either a text-to-image generator or convention media (23 per group), completing immediate and three-day follow-ups. Alliance was measured using DREAM (Dimensions of Regard, Empathy, and Authenticity Metric), and problems were rated pre/post; groups did not differ significantly on DREAM total or facets, and both modalities produced reliable pre-to-post reductions in problem severity. At the same time, process differences were pronounced: the AI condition showed …

The Geography Of Rock Glaciers In The American West, Allison Reese Trcka, Andrew G. Fountain, Bryce Allen Glenn

Geology Faculty Publications and Presentations

Rock glaciers are relatively common in conterminous United States west of the 100° meridian, yet their distribution and number are not well known. Using aerial and satellite imagery, we inventoried the population of rock glaciers, yielding 2,257 rock glaciers totaling 234.28 km² with an area of uncertainty of 7 percent. Of these, 1,561 (155.44 km²) are considered intact (moving) and 696 (76.84 km²) relict. Based on published estimates of ice content, total water-equivalent volume is roughly 2.52 km³. Rock glacier elevations increase from the northwest (Washington) to the southeast (Colorado), following a spatial …

Drag Reduction In Ground Vehicles Using A Model Porous Medium, Abdullah Ikram Nabi

Master’s Theses

This research investigates aerodynamic drag reduction on a 25° Slanted Ahmed Body (SAB) by integrating porous media model rods through combined experimental and computational methods at a Reynolds number of 1.16×10⁴. Two porous media configurations: short rods (6.75% of the model height) and long rods (20.0% of the model height), both featuring cylindrical rods with 80% porosity, were systematically compared against a baseline SAB. In-depth analyses were performed to investigate the wake flow topology, recirculation region characteristics, pressure coefficient distribution, Reynolds stress distributions and drag coefficient. Experimental investigations employed particle image velocimetry for precise flow visualization, while Reynold Averaged Navier-Stokes …

Using Post-Supercritical Co2-Assisted Method To Deposit Niep Alloy Coating On The Micro-Arc Oxidation Layer Of Az31 Magnesium Alloy And Its Corrosion Behavior Analysis, Kang-Yu Liao, Hung-Hua Sheu, Ming-Yuan Lin, Ming-Chih Kuo, Po-Hsun Wu, Hung-Bin Lee

Journal of Marine Science and Technology–Taiwan

In this study, a Ni-P alloy coating was deposited on the micro arc oxidation (MAO) layer of AZ31 magnesium alloy to improve its corrosion resistance. The MAO layers were prepared under different operated voltages from 300 to 400 V. The results indicated that the optimize operated parameters for MAO layer is at 350 V, the MAO coatings had the most compact microstructure and superior corrosion resistance. In order to improve the corrosion resistance of MAO coating, this study chose to deposit Ni-P alloy coating on the surface of MAO coating via the post supercritical CO₂-assisted electroless plating (PSC-CO …

The Effect Of Feedback On A Remote Operator’S Maneuvering Control For Mass Remote Navigation Competency, Hyoseon Hwang, Ik-Hyun Youn

Journal of Marine Science and Technology–Taiwan

The rapid advancement of Maritime Autonomous Surface Ships (MASS) technology has highlighted the growing need for Remote Operators (ROs) to manage MASS effectively. ROs possess specialized competencies in areas such as situational awareness, crisis management, and system operation. Despite the introduction of competency-based training and assessment in the maritime sector through the international convention on standards of training, certification, and watchkeeping for seafarers convention, the framework's implementation remains incomplete, particularly in remote operator training for MASS. This study is purpose to identify which competencies improve rapidly with performance feedback and which improve slowly. This study conducted an experiment to quantitatively …

Evaluation Of Carbon Sequestration In Seagrass Meadows Of Kenting: A Comparative Study With Penghu And Dongsha Island, Zih-Wei Tang, Huei-Fen Chen, Jordi Mahardika Puntu, Ping-Yu Chang, Li Lo, Jian-Jhih Chen, Wen-Chen Chou, Lan-Feng Fan, Ying-Ju Chang

Journal of Marine Science and Technology–Taiwan

This study investigates the controlling factors of carbon sequestration (CS) in seagrass bed sediments across three distinct environments in Taiwan: the Kenting (KT) coastal area, the Penghu (PH) open inner bay, and the Dongsha (DS) Atoll lagoon. Actual measurements of the substrate depth beneath the sediment and ground-penetrating radar (GPR) scans of the beach reveal that the coral reef bedrock in KT slopes landward. A field survey of the seagrass area in KT was conducted, and three cross-sectional profiles were analyzed to determine their topography, yielding a median sediment thickness of 88.2cm. Based on these measurements, the sediment volume was …

Calculation Of Aquifer Transmissivity From Borehole Resistance Measurements And Pumping Test Results, Fen-Rong Yang, Chien-Wei Huang, Tien-Kuen Huang

Journal of Marine Science and Technology–Taiwan

Transmissivity is a crucial hydrogeological parameter for evaluating groundwater resources. This parameter is conventionally evaluated using pumping tests; however, these tests are costly and can be conducted at few sites. Many researchers have used ground resistance and pumping test data to estimate various hydrogeological parameters. In this study, borehole resistance survey and pumping test data collected by the Taiwan Groundwater Monitoring Network were used to establish the relationship between transmissivity and formation factor for aquifers in the Zhuoshui River alluvial fan. This relationship was then used to estimate the water output of the aforementioned aquifers in a cost-effective manner from …

A Neural Network-Based Sliding Mode Adaptive Control System For Unmanned Surface Vehicles, Sun Qiaomei, An Liang, Jiang Linglin

Journal of Marine Science and Technology–Taiwan

Over the past decades, numerous studies have explored the use of autonomous unmanned surface vehicles (USVs). Successful USV operation requires a robust tracking control system to perform a range of tasks. However, USV dynamics are uncertain, time-varying, and nonlinear. This paper presents a neural network-based sliding mode adaptive control (NNSMAC) system to enhance USV tracking performance. Trajectories were generated using spline and polynomial interpolation based on a set of N predefined waypoints. Simulation results show that the proposed method outperforms traditional sliding mode control in error reduction, enabling more effective tracking.

The Development Of A One Pot, Two Reaction Synthetic Preparation Of 1,2,4-Oxadiazole, And Synthesis Of Ataluren, A Novel Drug In The Fight Against Duchenne Muscular Dystrophy. Efforts Towards The Synthesis Of A Potential Protease Inhibitor Against The Main Protease (3clpro) Of Covid-19, Austin J. Carter

Theses and Dissertations

1,2,4-Oxadiazoles are five-membered heterocyclic structures first synthesized by Tiemann and Krüger in 1884. Recent discoveries suggest an array of useful biological properties.In preparation of 1,2,4-oxadiazoles, the most prevalent precursors are amidoximes, which can be created via the reaction of nitriles with hydroxylamine hydrochloride and a base. The amidoximes are reacted with an activated carboxylic acid to yield an acylated intermediate. This intermediate can be exposed to a base to cyclize into the 1,2,4-oxadiazole. This thesis describes the efforts in combining these three steps into a unified one-pot synthesis.

Currently, there are a significant number of commercially available FDA approved and …

Site-Specific Modification Of Antibodies Utilizing Microbial Transglutaminase For Improved Immunoassay Performance, Emily Beitello

Theses and Dissertations

Immobilization strategies used for fixing antibodies to solid phase surfaces significantly contribute to the antigen capture capacity and influences the performance and sensitivity of immunoassays. Traditional methodologies result in the random orientation and/or the weak attachment of immobilized antibodies. Different formats of immunoassays scope in applicability to many fields of research and everyday use. Improving the efficiency of immobilizing antibodies in immunoassays is a beneficial endeavor to increase assay sensitivity. Here, we investigated the use of enzyme-mediated conjugation of antibodies to facilitate a highly oriented immobilization. Microbial transglutaminase (mTG) catalyzes the covalent bond formation between a plethora of primary amine …

Generational Exposures To Cerium Oxide Nanoparticles And Perfluorooctanesulfonic Acid Affect The Performance Of Daughter Plants, Preston Clubb

Graduate Theses/Dissertations

The effects of parental stress on the performance of next generation exposed to another contaminant were investigated. Wheat was exposed to cerium oxide nanoparticles (CeO2-NPs) in first and second generations and exposed to perfluorooctanesulfonic acid (PFOS) in the third generation. Phenotypic or metabolic responses were assessed at 21-day (short-term exposure) or 90-day (long-term exposure) exposure periods. Biomass production, chlorophyll content, enzyme activity, and membrane damage were measured at short-term exposure, while elemental and PFOS concentrations, and grain metabolites were analyzed in long-term exposure. Results showed that continued exposures to CeO2-NPs and PFOS enhanced chlorophyll content but reduced concentrations of important …

The First Iucn Red List Of Cold-Water Corals Highlights Global Declines, Julia D. Sigwart, A. Louise Allcock, Renata Carolina Mikosz Arantes, Kelsey Archer Barnhill, Narissa Bax, Julia S. Beneti, Saskia Brix, Gudmundur Gudmundsson, Catherine S. Mcfadden, Severin A. Korfhage, Christi Linardich, Declan Morrissey, Pedro De Oliveira Nascimento, Bárbara De Moura Neves, Steinunn H. Ólafsdóttir, Stefán Ragnarsson, Kaveh Samimi-Namin, Íris Sampaio, Mark E. De Wilt

Biological Sciences Faculty Publications

The most well-known species-based conservation tool is the International Union for the Conservation of Nature (IUCN) Red List of Threatened Species. The current coverage of species in the Red List is known to under-represent benthic marine species. Cold-water corals (CWCs) are increasingly recognised as key to deep-water biodiversity and integral to protected vulnerable marine ecosystems (VMEs), but no deep-sea coral species were previously included in the Red List. We selected 22 cold-water coral species in the Northeast Atlantic, including 4 reef-forming stony corals and 18 octocorals including sea pens and gorgonians, and completed the first IUCN Red List global assessments …

A Blueprint To Greener Shorelines: Advancing The Effectiveness, Sustainability, And Widespread Adoption Of Coastal Nature-Based Solutions Through Transdisciplinary Research, Taylor M. Sloey, Sierra Hildebrandt, Rebecca L. Morris, Matthew V. Bilskie, Aaron Bland, David Bushek, Gabriella Dipetto, Daniel Elefant, Vincent Encomio, Ramin Familkhalili, Christine Hladik, Danielle Kreeger, Avery B. Paxton, Cindy M. Palinkas, Latina Steele, Andrew Scheld, Daisuke Taira, Jason D. Toft, Armando J. Ubeda, Christine Whitcraft, Donna Marie Bilkovic

Biological Sciences Faculty Publications

Coastal nature-based solutions (NbS) have emerged as powerful tools to enhance sustainable development and ecological restoration goals. As a rapidly growing field spanning across social, political, ecological, economic, and engineering disciplines, it is critical that researchers working in coastal NbS regularly attempt to identify emerging focal areas for scientific inquiry. Following the 27th Biennial meeting of the Coastal and Estuarine Research Federation, we provide a transdisciplinary perspective (including biologists, engineers, oceanographers, geoscientists, economists, and facilitators of workforce training programs) of pertinent research questions that, if answered, will advance the effectiveness, sustainability, and widespread adoption of coastal NbS. These suggestions for …

Thermal Tolerance Limits Of Mesophotic Corals In American Samoa, Daniel Barshis, Veronica Z. Radice, Katherine E. Parker, Nicholas Evensen

Biological Sciences Faculty Publications

We analyzed the thermal tolerances of multiple coral species from an upper mesophotic (38–40m) and a shallow reef (5–10m) with our portable Coral Bleaching Automated Stress System (CBASS). Depth generalist Montipora grisea (deep and shallow) and depth specialists Pachyseris speciosa and Leptoseris sp. (deep only) were assayed from Leone, located on the western coast of Tutuila in American Samoa. Fragments from 10 genotypes of each species were exposed to a 17-hour thermal stress assay reaching four maximum temperatures ranging from 30–38°C under in situ light conditions (150 μmol photons m⁻² s⁻¹ under a Lee Filters “deep …

Carbon Dynamics Across The Mangrove-Tidal Flat Ecotone In A Tropical Seascape, E. S. Yando, I. J.B. Alemu, L. Kiah Eng, T. M. Sloey, M. Van Breugel, Bhatia N. Friess

Biological Sciences Faculty Publications

Mangroves and other blue carbon ecosystems are important for climate through the storage and sequestration of carbon. Most research estimates carbon dynamics by subsampling central portions of the ecosystem and are then upscales using habitat maps to patch, landscape, or regional levels. However, heterogeneity is rarely accounted for - particularly at edges. Further, adjacent tidal flat ecosystems have only recently been considered for carbon storage, but may be undervalued if areas where they transition with vegetated systems are not accounted for. To address the lack of information at coastal ecotones, we examined both soil carbon storage and carbon dioxide flux …

Campesino World-Building: Stories Of Migration, Memory, And Care In The Tension Of The Colonial Frame, Chelsea Ríos Gómez

Cal Poly Humboldt theses and projects

Campesinos, often reduced to the label of “farmworkers”, are too often seen only through the lens of their labor within profit-driven systems. This thesis disrupts that limited narrative by illuminating the rich, expansive nature of vivencias campesinas, ways of being that transcend capitalist measures of value. These vivencias are lived, embodied experiences rooted in campesino lifeways, encompassing cultural, spiritual, and relational practices that nurture and sustain life.

My research is guided by four central questions: (1) In what ways have campesinos in pixley resisted exploitative labor systems, and how can this resistance be understood as a form of care labor? …

An Economic And Production Analysis Of Seaweed Farms In California And The Pacific Northwest, Brian Donovan

Cal Poly Humboldt theses and projects

Since the early 2010s, the seaweed aquaculture industry has steadily expanded in the United States, with states like Alaska, Maine, Hawaii, and Connecticut leading the way in the development of this emerging sector. However, information gaps remain concerning certain aspects of the domestic seaweed aquaculture industry. The purpose of this study was to examine the status of the seaweed aquaculture industry along the West Coast of the United States; specifically in the states of California, Oregon, and Washington. Seaweed farmers in these states were invited to voluntarily complete surveys asking important production, economic, and commercial questions regarding their operations. Data …

Open Path Spectroscopic Detection Of The Hydroxyl Radical: A Comparison Between Broadband Cavity-Enhanced Absorption Spectroscopy (Bbceas) And Bbceas Coupled With A Fabry-Pérot Interferometer (Bbceas-Fp), Callum Flowerday, Ryan Thalman, Matthew C. Asplund, Samuel A. Badstubner, Adam K. Cook, Philip Lundrigan, Jaron C. Hansen

ScholarsArchive Data

Data collected by the BBCEAS and BBCEAS-FP instruments described in the paper "Open Path Spectroscopic Detection of the Hydroxyl Radical: A Comparison Between Broadband Cavity-Enhanced Absorption Spectroscopy (BBCEAS) and BBCEAS coupled with a Fabry-Pérot Interferometer (BBCEAS-FP)"

3d Printed Microfluidic Platforms For Elisa-Based Diagnostics: Advancing Toward Point Of Care, Brandi Marie Binkley

Graduate Theses, Dissertations, and Problem Reports (ETD)

Protein biomarker detection is a critical analytical method for quantifying proteins in biological samples. It is relevant not only in medical diagnostics and research but also numerous other fields such as environmental monitoring, pharmacology, food safety, and biotechnology. Sensitive detection at picogram-per-milliliter (pg/mL) levels is essential for diagnosing diseases, monitoring progression, and tailoring treatments, especially for low-abundance biomarkers like troponin, interleukin 6, carcinoembryonic antigen (CEA), activin A, and vascular endothelial growth factor (VEGF). Immunoassays, particularly enzyme-linked immunosorbent assays (ELISAs), are the gold standard for protein biomarker detection due to their high specificity and sensitivity. The development of point-of-care (POC) diagnostic …

Community-Wide Impacts Assessment Of Silver Carp (Hypophthalmichthys Molitrix) In The Ohio River, Luka Marques

Graduate Theses, Dissertations, and Problem Reports (ETD)

Invasive species can cause measurable impacts on the properties of recipient ecosystems, with effects that often vary spatially and temporally. One of the most complex and pressing invasion cases in the United States involves invasive carp. Invasive carp have quickly expanded throughout the Mississippi River Basin, with ecological impacts that may vary across space and time. Silver Carp has the potential to provoke community-wide impacts on native fish abundances and food webs of native fish communities. My study area ranged from the confluence of the Mississippi River and the Ohio River to R.C. Byrd Lock and Dam. The Ohio River …

Expanding The Vibrating Sharp-Edge Spray Ionization Toolkit For Oligonucleotide Characterization, Sultan Mahmud

Graduate Theses, Dissertations, and Problem Reports (ETD)

A gentle or soft Ionization process is a critical component in native mass spectrometry (MS) to lift the biomolecules from the bulk solution into the gas phase environment of the mass spectrometer preserving their shape, topology and non-covalent interactions. Electrospray ionization (ESI) facilitates structural preservation of proteins, nucleic acids and their complexes and as a result it has been extensively used in native MS. However, in negative ion mode, ESI is somewhat limited in sensitivity due to corona discharge effect resulting from the requirement of a high amount of voltage. This often disrupts the ESI process and may not preserve …