Digital Commons Network^™

Inside Unlv, Diane Russell, Shane Bevell, Carol C. Harter, Lori Bachand, Cate Weeks, Mamie Peers

Inside UNLV

No abstract provided.

Secondary N-Nitrosocarbamate Anions: Structure And Alkylation Reactions. A Dft Study, Vladimir Benin

Chemistry Faculty Publications

The current article reports theoretical studies (DFT: B3LYP/6-31+G(d)) on the structure and alkylation reactions of the anions of some secondary N-nitrosocarbamates, a class of ambident nucleophiles whose chemistry has been little explored. Several anions (1–4), with an increasing size of the carbamate alkyl (aryl) group were investigated, in an attempt to establish the influence of the size of that group on the thermal stability and regioselectivity of alkylation of the title anions. The conclusion is that thermal stability and the mode of reaction are affected significantly only in the presence of very large and branched carbamate groups. The thermal …

Coastal Aquaculture And Conservation Can Work Together, Tim Dempster, Pablo Sanchez-Jerez, Fernando Tuya, Damian Fernandez-Jover, Just Bayle-Sempere, Arturo Boyra, Ricardo Haroun

Research outputs pre 2011

Current fishing practices are regarded as unsustainable (Pauly et al. 2002), yet our appetite for seafood grows. To meet the growing gap, there are increasing calls for mankind to tame the oceans through aquaculture (Marra 2005). Close to the coast, rapid expansion of marine aquaculture is underway throughout the world. Sea cages enclose 2.5 million tons of fish, while 12 million tons of mussels, oysters and clams hang from floating ropes or grow on racks or trays (FAO 2004). Aquaculture structures are now ubiquitous to many coastlines. As the expansion continues, how can we best manage the interaction between natural …

Biosorption Of Priority Pollutants Of Petroleum Refinery Wastewater, Deen Adnan Sheikha

Theses

Heavy metals and organic materials pollution in the aquatic system have become a serious threat today. Zinc, phenol and naphthalene are common environmental contaminants. The fate and transport of these chemicals must be sufficiently understood to predict detrimental environmental impacts and to develop technically and economically appropriate remedial action to minimize environmental degradation. In this study, microbial biomass has emerged as an option for developing economic wastewater treatment. Dead algal biomass may passively sequester metals and organic materials by the process of biosorption from dilute solutions, where biomass functions as an ion exchanger by virtue of various reactive groups available …

Chemistry & Biochemistry Newsletter, Department Of Chemistry & Biochemistry, South Dakota State University

Chemistry & Biochemistry Newsletter: 2002-2015

Inside:

Page 2-4 Campus Mass Spectrometry Facility

Page 4 Alumni News

Page 5 Alum Featured; Scholarships and Awards

Page 6 Two New Departmental Scholarships; Recent Faculty Publications; Funding

Page 7 2006 Chemistry and Biochemistry Graduates

Iowa Academy Of Science: The New Bulletin, V02n2, Spring 2006, Iowa Academy Of Science

New Bulletin

Inside This Issue:

--Message from the Executive Director

--Iowa’s Young Scientists Shine at American Junior Academy of Science Conference

--Iowa Academy of Science Election 2006

--Saylorville Visitor Center

--IAS Donors

--Iowa Science Teachers Section Fall Conference

Decision Modeling: Why Farmers Do Or Do Not Convert To Organic Farming, Ryan Locke

Independent Study Project (ISP) Collection

This study examines why farmers in Northern New South Wales, Australia do or do not convert to organic farming from conventional farming practices. Organic agriculture provides a production alternative that may be environmentally and nutritionally beneficial. Because the structural settings of economy and society influence decision-making on an individual basis at the farm level, discussions of policy must consider why farmers do, or do not, convert to organic farming. Ultimately, the successfulness of a policy depends on the effectiveness of motivating individual action. A hierarchical decision tree was created using ethnographic decision tree modeling. Elimination criteria, motivational criteria, and constraints …

Impacts Of Salt Production On Pemba, Lauren Wolchok

Independent Study Project (ISP) Collection

The economic, social, and environmental impacts of salt production were studied on the eastern coast of Pemba Island. Solar salt production is associated with the clear cutting of mangrove forests, which are significant as soil stabilizers, animal habitats, and as an economic resource. An environmental assessment of this industry is necessary to determine whether the socio-economic gains from salt production justify the environmental costs. Interviews with owners, employees, and day laborers from 20 salt farms were conducted to assess the general sustainability of the industry. The average annual owner income was determined to be approximately 570 000 Tsh, while employees …

Inside Unlv, Diane Russell, Shane Bevell, Carol C. Harter, Cate Weeks, Mamie Peers, Regina Vaccari

Inside UNLV

No abstract provided.

Synthesis Of Aspernigrin A, Erica Joerger

Undergraduate Theses and Capstone Projects

Aspernigrin A is a compound correlated with inhibiting the growth of cancer cells in the colon. A five-step synthesis was designed for aspernigrin A, projected to yield four intermediates and the final product. The intermediates were analyzed by high field 1HNMR and FT-IR spectroscopy before proceeding to the next step. A model pyridone ring system was successfully prepared from a commercially available pyrone precursor in two steps. These results provide a proof of concept that the synthetic scheme should successfully yield the natural product.

Semiparametric Analysis For Correlated Recurrent And Terminal Events, Yining Ye, Jack Kalbfleisch, Doug E. Schaubel

The University of Michigan Department of Biostatistics Working Paper Series

In clinical and observational studies, recurrent event data (e.g. hospitalization) with a terminal event (e.g. death) are often encountered. In many instances, the terminal event is strongly correlated with the recurrent event process. In this article, we propose a semiparametric method to jointly model the recurrent and terminal event processes. The dependence is modeled by a shared gamma frailty that is included in both the recurrent event rate and terminal event hazard function. Marginal models are used to estimate the regression effects on the terminal and recurrent event processes and a Poisson model is used to estimate the dispersion of …

Adjusting For Covariate Effects On Classification Accuracy Using The Covariate-Adjusted Roc Curve, Holly Janes, Margaret S. Pepe

UW Biostatistics Working Paper Series

Recent scientific and technological innovations have produced an abundance of potential markers which are being investigated for their use in disease screen- ing and diagnosis. In evaluating these markers, it is often necessary to account for covariates which are associated with the marker of interest. These covariates may include subject characteristics, expertise of the test operator, test proce- dures, or aspects of specimen handling. In this paper, we propose the AROC, a covariate-adjusted measure of the classification accuracy. The AROC is the common covariate-specific ROC curve, when the covariate does not affect dis- crimination, and a weighted average of covariate-specific …

Investigation Of Copper Contamination And Corrosion Scale Mineralogy In Aging Drink Water Distributions Systems, Nadja F. Turek

Theses and Dissertations

Research has shown higher levels of copper appear in drinking water conveyed through relatively new copper piping systems; older piping systems typically deliver lower copper levels in their drinking water. This research contributes field data from a real drinking water distribution system, providing a better understanding of this phenomenon, as it relates to treatment considerations and compliance with the Lead and Copper Rule. Copper pipes and copper levels were sampled from drinking water taps of 16 buildings with pipes ranging in age from less than 1 to 48 years. Water samples from each building were collected before and following a …

Development Of A New Deer Repellent For The Protection Of Forest Resources, Bruce A. Kimball, Dale L. Nolte

United States Department of Agriculture Wildlife Services: Staff Publications

We have identified hydrolyzed casein as a promising repellent for minimizing damage to forest resources inflicted by browsing ungulates. Eight and twelve percent hydrolyzed casein formulations prepared in water with a latex-based agricultural sticker significantly reduced browse damage by captive black-tailed deer (Odocoileus hemionus columbianus) to western redcedar (Thuja plicata) saplings. These repellent formulations can be prepared by the user at significant cost savings versus commercial products.

Is This Safe To Eat?

United States Department of Agriculture Wildlife Services: Staff Publications

The harvest and consumption of wildlife is as old as humankind and often has sustained human exploration into unsettled areas. Wildlife still remain a primary foodbase for many native peoples throughout the world. From shellfish to bear, humans today continue to hunt, fish, and otherwise harvest wildlife for recreation, social and cultural needs, dietary supplementation, subsistence, and other purposes that result in the consumption of game meat (Fig. 5.1).

Over time, experience has taught people what food is safe to eat and how it should be prepared. This is especially true for those who subsist upon wildlife. Fortunately, the meat …

Session 1c: Superfund, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

• The University of Kentucky Superfund Basic Research Program: Overview and Examples of Research Projects, Bernhard Hennig, Leonidas Bachas, and Lindell Ormsbee, UK
• Reductive Dechlorination of Toxic Organics by Bimetallic Nanoparticles in Polyacrylic Acid (PAA) Functionalized MF Membranes, Jian Xu and Dibakar Bhattacharyya, Dept Chemical and Materials Engineering, UK
• Chlorinated Organic Compounds Destruction by Modified Fenton Reaction Involving Immobilized Iron-Chelate, YongChao Li, Leonidas Bachas, and Dibakar Bhattacharyya, Dept Chemical and Materials Engineering, UK
• An Outreach Program Translates Basic Research for Superfund Communities to Improve Health through Nutrition, Lisa Gaetke and Sandra Bastin, Dept Nutrition and Food Science, …

Proceedings Of 2006 Kentucky Water Resources Annual Symposium, Kentucky Water Resources Research Institute, University Of Kentucky

Kentucky Water Resources Annual Symposium

This symposium was funded in part by the U.S. Environmental Protection Agency, with Clean Water Act, Section 319(h) grant money through the Kentucky Division of Water and the Kentucky Waterways Alliance, #C9994861-00.

Planning for this conference was conducted as part of the state water resources research annual program with the support and collaboration of the Department of Interior, U.S. Geological Survey and the University of Kentucky Research Foundation, under Grant Agreement No. 01HQGR0133.

The views and conclusions contained in this document are those of the abstract authors and should not be interpreted as necessarily representing the official policies, either expressed …

Evaluating The Predictiveness Of A Continuous Marker, Ying Huang, Margaret S. Pepe, Ziding Feng

UW Biostatistics Working Paper Series

Consider a continuous marker for predicting a binary outcome. For example, serum concentration of prostate specific antigen (PSA) may be used to calculate the risk of finding prostate cancer in a biopsy. In this paper we argue that the predictive capacity of a marker has to do with the population distribution of risk given the marker and suggest a graphical tool, the predictiveness curve, that displays this distribution. The display provides a common meaningful scale for comparing markers that may not be comparable on their original scales. Some existing measures of predictiveness are shown to be summary indices derived from …

Refuge Update – March/April 2006, Volume 3, Number 2

RefugeUpdate (USFWS-NWRS)

Table of Contents:
Energy Company Fine Benefits Ottawa Refuge, page 3
Hide and Seek…but Mostly Hide page 4
Focus on …Pollinators, page 10
Great Storytellers, page 18

Hydrodynamic Mediation Of Density-Dependent Growth And Adult-Juvenile Interactions Of A Spionid Polychaete, Brent T. Hentschel, Amy A. Larson

Environmental Science and Management Faculty Publications and Presentations

Abstract We performed an experiment to test the effects of adult density on the growth rates of juvenile Polydora cornuta. Our experiment was performed in three identical counter-rotating annular flumes, each set to one of three different flow speeds for a period of 3 d (U 5mm = 3, 6, or 12 cm s^-1 , where U_5mm = velocity measured 5 mm above bottom). We implanted replicate vials containing a premeasured juvenile P. cornuta and either 0, 2, or 5 adults into a 2-cm layer of sediment in the flume. The relative growth rates of the juveniles …

Analysis Of Bacterial Population And Distribution In The Developing Strata Of A Constructed Wetland Used For Chlorinated Ethene Bioremediation, Milton J. Clausen Jr.

Theses and Dissertations

Chlorinated hydrocarbons and their degradation products are among of the most common organic groundwater contaminates in the United States. These compounds attack the central nervous system in animals and can affect the photosynthesis of plants. These compounds are also resistant to degradation in the environment and, because of this, pose a risk to any ecosystem in which they are present. This study identified the dominant microbial species in a constructed treatment wetland at Wright-Patterson AFB, Dayton, Ohio using 16S rRNA gene sequence analysis. Samples were taken from three different depths and during each of the four seasons. These samples were …

Total Plasma Protein And Renesting By Greater Sage-Grouse, Michael A. Gregg, Mike R. Dunbar, John A. Crawford, Michael D. Pope

United States Department of Agriculture Wildlife Services: Staff Publications

Greater sage-grouse (Centrocercus urophasianus) population declines have been attributed to reduced productivity. Although renesting by sage-grouse may contribute significantly to annual productivity during some years, little information is available on this aspect of sage-grouse reproductive ecology. We investigated the relationship between total plasma protein, age of hen, time of first nest initiation, and time of first nest loss on occurrence of renesting. We captured, assigned age, extracted blood, and radiomarked prelaying, female sage-grouse on 4 study areas during 1999–2004. We monitored radiomarked females from mid-April through June to identify period of nest initiation (early, mid, or late), nest …

Forage Testing Program, Michael Judge

Kentucky Alfalfa and Stored Forage Conference

Livestock farmers who need hay can find it right here in Kentucky. Listings of farms with hay for sale can be found on the Hay and Forage Program page of the Kentucky Department of Agriculture’s Web site, www.kyagr.com.

Alfalfa Hay For Horses, Robert Coleman

Kentucky Alfalfa and Stored Forage Conference

When horse owners consider hay for their animals a number of criteria are generally considered. Of major importance is the hay must be free of mold and dust, it needs to contain nutrients needed by the horse and it must be palatable. If these criteria are met, the type of hay should not matter. However, that is not the case with many horse owners. When discussing hay, many owners first consider the type of hay. Can it be alfalfa or should it be a grass or how about a mix of grass and a legume. If a group of horse …

Interpreting Forage Quality Test Reports, Donna M. Amaral-Phillips

Kentucky Alfalfa and Stored Forage Conference

Forages are the foundation for building diets for beef and dairy cattle, horses, sheep and goats. The quality of these forages directly impacts forage intake, animal performance, and, ultimately, the profitability to their owners. As the quality of forages decline, consumption of that forage decreases and the amount of grain or byproducts which must be fed increases. The cost for a unit of performance increases and/or the animal can not perform (i.e. milk or gain) to the optimum level thus lowering profitability to the animal owner. These relationships are especially true with young and high performance ruminants, such as high …

Use Of Infrared Thermography To Detect Signs Of Rabies Infection In Raccoons (Procyon Lotor), Mike R. Dunbar, Kathleen A. Maccarthy B.S.

United States Department of Agriculture Wildlife Services: Staff Publications

Infrared thermography was evaluated as a technique to determine if raccoons (Procyon lotor) experimentally infected with rabies virus could be differentiated from non-infected raccoons. Following a 10-day adjustment period, raccoons (n = 6) were infected with a virulent rabies street strain raccoon variant by injection into the masseter muscle at a dose of 2 x 10⁴ tissue-culture infectious dose (TCID₅₀) in 0.2 ml (n = 4) or 10⁵ TCID₅₀ in 1 ml (n = 2). Five of the six raccoons developed prodromal signs of rabies 17 to 22 days post-inoculation …

Crop Updates 2006 - Farming Systems, Wayne Pluske, Bill Bowden, Craig Scanlan, Stephen Davies, Chris Gazey, Peter Tozer, Derk Bakker, Louise Barton, David Gatter, Renee Buck, Daniel Murphy, Christoph Hinz, Bill Porter, Meredith Fairbanks, Nicolyn Short, Ian Foster, James Fisher, Doug Abrecht, Mario D'Antuono, Tracey M. Gianatti, Paul Carmody, Frank D'Amden, Rick Llewellyn, Michael Burton, Caroline Peek, Nadine Eva, Chris Carter, Megan Abrahams, Andrew Blake, Paul Blackwell, Sylvian Pottier, Michael Robertson, Greg Lyle, Lisa Brennan, Tony J. Vyn, Simon Teakle, Peter Norris, Jeff Russell, James Fisher, Roy Murray-Prior, Deb Pritchard, Mike Collins, Greg Hamilton, Rob Hetherington, Andrew Van Burgel, Cliff Spann

Crop Updates

This session covers nineteen papers from different authors:

SOIL AND NUTRIENT MANAGEMENT

1. Inve$tigating fertili$er inve$tment, Wayne Pluske, Nutrient Management Systems

2. KASM, the potassium in Agricultural System Model,Bill Bowden and Craig Scanlan, DAWA Northam and UWA, School of Earth and Geographical Sciences

3. Long term productivity and economic benefits of subsurface acidity management from surface and subsurface liming, Stephen Davies, Chris Gazey and Peter Tozer, Department of Agriculture

4. Furrow and ridges to prevent waterlogging, Dr Derk Bakker, Department of Agriculture

5. Nitrous oxide emissions from a cropped soil in Western Australia, Louise Barton^{1 …}

Corn And Other Annuals, Jeff Mccutcheon

Kentucky Grazing Conference

There are many factors to consider when planting alternative crops. One of the most important factors is deciding if you need additional forage. In our area the basis of any grazing system should be perennial cool-season grasses and legumes. Have you done all that you can to improve that forage production through managed grazing and fertility management? If you have, then you may be ready to consider annual forages in your grazing system.

Mineral Supplements And Feed Additives--Can They Eliminate Fescue Toxicity?, John Thomas Johns

Kentucky Grazing Conference

Fescue is the predominate cool season grass in much of the United States due to its wide adaptation and hardiness. Many of these acres however, contain an endophytic fungus resulting in production of toxins with negative effects on grazing cattle. The two primary responses in beef cattle are an increase in core body temperature and a decrease in dry matter intake. As a result, decreases in reproductive rates, milk production, weaning weights and ADG are seen (Tables 1 and 2). Many approaches to pasture management have been advocated to overcome or minimize the problem such as incorporation of legumes, rotational …

Animal Behavior: Impacts On Grazing, Mark Kennedy

Kentucky Grazing Conference

I am not an expert on this subject and give all credit for my limited understanding of this subject to Dr. Fred Provenza, Utah State University; Katy Voth, Livestock for Landscapes, LLC; Jim Gerrish and others. I have tried to put into practice, both personally and with other producers, many of these principles to aid in improved grazing management. This presentation will address only 2 aspects of animal behavior; 1) How animal behavior impacts grazing distribution and forage utilization over the landscape, and 2) How animal behavior affects diet selection.