Digital Commons Network^™

Direct Minimization Of Hartree-Fock-Roothaan Energy Functionals Using Derivative-Free Optimization Algorithms: A Case Study On The Use Of Noninteger Slater-Type Orbitals, Ali̇ Bağci

Turkish Journal of Physics

This study presents an evaluation of derivative-free optimization algorithms for the direct minimization of Hartree−Fock−Roothaan energy functionals involving nonlinear orbital parameters and noninteger-order quantum numbers. The analysis focuses on atomic calculations employing noninteger Slater-type orbitals. Analytic derivatives of the energy functional are not readily available for these orbitals. Four methods are investigated under identical numerical conditions: Powell’s conjugate−direction method, the Nelder−Mead simplex algorithm, coordinate-based pattern search, and a model-based algorithm utilizing radial basis functions for surrogate-model construction. Performance analysis is first carried out using the Powell singular function, a well-established test case exhibiting challenging properties, including Hessian singularity at the …

Multi-Frequency Associative Memory For Continual Graph Learning Through Nested Optimization, Shuvam Kundu

Master’s Dissertations

Graph Neural Networks struggle to learn new tasks without forgetting old ones a problem known as catastrophic forgetting. In graph domains, this is compounded by structural shift, where newly added edges corrupt the learned representations of historical nodes even when model weights remain unchanged. We present CAM-Titans, a continual graph learning framework built around a two-buffer associative memory to address both parametric and structural forgetting. Our architecture operates across three timescales of adaptation: a slow base memory updated via ordinary gradient descent, an intermediate task buffer re-encoded after every task using the delta-rule, and a transient in-context state for rapid …

Antioxidant Potential Of A Non-Heme Iron Complex: Mitigating H2O2-Induced Cellular Damage, Magy A. Mekhail, David M. Freire, Cameron Bowers, Grant Elam, Nora Del Bosque, Hannah K. Pyle, Sarah K. Dunn, Spencer Lanyon, Timothy J. Hubin, Giridhar Akkaraju, Kayla N. Green

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Iron complexes with antioxidant activity have garnered significant interest for both general and medical applications, yet few studies have yielded functional nonheme iron-based mimics for H₂O₂ mitigation in aqueous environments. Here, we investigate water-soluble nonheme iron complexes derived from 12-membered pyridinophanes (^CF₃PyN₃, PyN₃, ^NMe₂PyN₃, and Py₂N₂) to evaluate the impact of ligand scaffolds on H₂O₂ decomposition activity both in vitro and in a cellular model. Speciation and kinetic analyses reveal that both electronic and geometric modulation of the macrocyclic …

A System For The Prediction Of Election Results Using Vader And Hybridized Machine Learning Model, Abraham E. Evwiekpaefe, Khadijah Kabir, Georgina N. Obunadike

Tanzania Journal of Science

Integrating different classifiers along with sentiment lexicons like Vader, can enhance the performance of sentiment analysis systems. However, such a hybrid model remains underexplored, particularly in the context of regional elections in developing countries like Nigeria. The aim of this research is to develop a hybrid model that combines three machine learning classifiers and Vader lexicon to possibly achieve a higher accuracy. A case study of the 2023 governorship election in Kogi, Bayelsa and Imo State, Nigeria was examined. Twitter API library was utilized to extracted public and personal tweets using hashtags and keywords related to the target data from …

Extraction Of High-Quality Cashew Nutshell Liquid Using Carbon Dioxide-Expanded Hexane, Frank N. Jacob, Neema Msuya, Joseph Y.N Philip, Kando Khalifa Janga

Tanzania Journal of Science

Cashew nutshell liquid (CNSL) is a by–product from cashew processing industries containing four naturally occurring phenolic compounds. This study investigated an extraction approach using CO2–expanded hexane. The central composite design (CCD) was employed in experimental design to investigate the effects and interaction of CO 2 mole fractions and extraction temperature on the CNSL yield and quality (Colour) from Steamed CNSL. The dissolution power of the CO2–expanded hexane was assessed by determining the solubility of CNSL during the initial stages of extraction at different extraction conditions. Findings indicated that higher CO2 mole fractions reduced CNSL solubility, while higher temperatures enhanced it. …

A Switch-Point-Aware Contrastive Approach To Sentiment Analysis Of Hinglish Code-Mixed Text, Prasant Kumar Sahoo

Master’s Dissertations

With the increasing use of social media in non-English-speaking regions, especially in India, people often use Romanized Hindi and English together in their online communication. In a single sentence, they frequently mix Romanized Hindi and English, creating code-mixed text. However, most multilingual transformer models are pre-trained primarily on monolingual data. As a result, NLP systems face challenges when processing code-mixed text, as a single word may be fragmented into meaningless subword pieces, making it difficult for the model to capture its semantic meaning accurately. In this dissertation, we propose a parameter efficient neural architecture consisting of three main components to …

Tuning Ion Mobility And Molecular Confinement In High-Performance Polymer Electrolytes For Energy Storage, Ezzeldien Yousef Muhammed Yousef

Theses and Dissertations

This research addresses the critical energy density limitations of aqueous supercapacitors, which are traditionally constrained by the narrow electrochemical stability window (ESW) of water 1.23 V. By employing two distinct molecular engineering strategies, this study developed high-performance electrolyte systems that significantly extend voltage stability and thermal resilience.

The first system, CsBr@PAM/HA, utilizes a polyacrylamide and hyaluronic acid hydrogel matrix. This system exploits the chaotropic nature of Cs⁺ ions to disrupt the aqueous hydrogen-bonding network, enhancing ionic conductivity to 104 mS cm^-1. Through systematic salt screening, CsBr was identified as the optimal electrolyte, enabling a stable 2.0 V …

Towards Sustainable Marine Education: Assessing High School Students’ Understanding Of Conservation Concepts, Cheng-Chieh Chang, Tsuyoshi Sasaki, Ya-Yin Liao, Ling-Ya Hung, Liang-Ting Tsai

Journal of Marine Science and Technology–Taiwan

This study assesses the concepts of marine resource conservation and sustainability among Taiwanese high school students by developing a Chinese version of the Marine Resources Conservation and Sustainability Scale. Grounded in the cognitive, socio-emotional, and behavioral learning objectives outlined in UNESCO’s Education for Sustainable Development Goals (ESDGs), the scale targets students aged 16 to 18 to examine gender differences in marine knowledge and conservation concepts. The scale comprises 31 items across four dimensions: the first section evaluates marine knowledge, while the remaining dimensions utilize a four-point Likert scale to assess cognitive, socio-emotional, and behavioral learning objectives, respectively. The results indicate …

Face-To-Face Versus Distance Education In Competence-Based Maritime Education And Training, Clara Borén, Marcella Castells-Sanabra, Manel Grifoll

Journal of Marine Science and Technology–Taiwan

The COVID-19 pandemic created significant challenges for higher education, with universities being shut down and face-to-face teaching and assessment shifting to an online format. This presented an opportunity to focus on the continuity of learning through distance education, especially in the maritime context, due to the on-board training requirements, and even though five years have passed, this shift has reshaped the education landscape, proving that remote learning has come to stay.

At the Barcelona School of Nautical Studies, we have developed a weather routing software in the framework of distance education and teaching innovation. We conducted a teaching trial alternatively …

Automatic Glossing In Under-Resourced Languages: Case Studies In Bribri And Cook Islands Māori, Carter D. Anderson

Linguistics Undergraduate Senior Theses

Interlinear glossing is a major task in Indigenous language documentation. In this paper, I explore how effectively two Large Language Models, ByT5 and Gemini 2.5 Flash, can produce interlinear glossed text. I also examine how prompting an LLM with different types of information (dictionary entries, other training samples, and translations) can augment model performance. I apply these models to two under-resourced Indigenous languages: Bribri, which is morphologically complex from Costa Rica, and Cook Islands Māori, which has a simpler morphology and is from the Cook Islands in the Pacific Ocean. ByT5 exhibits much better performance when glossing Cook Islands Māori …

Custom Sbc Gps Tracking And Geocaching Carputer Software Development And Implementation, Joshua A. Davis

University Honors Theses

This thesis argues that hardware-integrated capstone projects develop software engineering skills that traditional coursework cannot replicate. A team of eight developers built a GPS tracking system on a Raspberry Pi 4 over two academic terms, integrating real-time position streaming, the APRS amateur radio protocol for network-independent location sharing, and PostGIS spatial queries for "new road" detection. The system implements SmartBeaconing for adaptive GPS data reduction, achieving approximately 80% storage savings while preserving route fidelity. The project exposed challenges absent from classroom assignments: hardware debugging without stack traces, cross-layer integration failures, and coordination overhead when deploying to unfamiliar architecture; demonstrating that …

Effects Of Fine Sediment On The Productivity Of Stream Ecosystems In The Pacific Northwest, Veena I. Davis

University Honors Theses

Salmon are important to the culture, ecosystem and economy of the Pacific Northwest. However, populations have declined significantly since European colonization. Salmon require specific conditions for each life stage and are highly sensitive to environmental stressors. Excess fine sediment is a leading form of pollution as it degrades salmon spawning habitat and the benthos upon which their main food source, stream insects, live. To evaluate the effect of sediment pollution on food availability for salmon smolt, we conducted an experiment  estimating the amount of stream insect biomass and calories lost due to sediment pollution. We counted insects on substrate samples …

Digital Bodily Autonomy: Consent Issues, Labor Displacement, And Legal Understandings Of Ai Generated Deepfake Pornography, Mariah Barrett

Undergraduate Theses, Capstones, and Recitals

In the United States, nonconsensual pornographic deepfakes are becoming an increasingly prevalent problem as AI deepfake creation software improves and becomes widely available. Despite this, patchwork legislation across the country is inconsistent and conflicting regarding this issue. In this paper, I explore the background of pornography and obscenity laws and demonstrate how these frameworks are not properly constructed to apply to the digital sphere. Then, I address major themes within deepfake literature such as consent issues, bodily autonomy, labor displacement, and verifiable identity as a commodity through the case study of OnlyFans. I explore current and proposed legislation within the …

Phase-Resolved Measurement And Arbitrary Mode Conversion Of Structured Light, Somayeh Ghazanfarpour

Electronic Theses and Dissertations

This dissertation presents a single-shot phase and amplitude retrieval technique based on spatial light modulator (SLM)-based digital holography. The proposed method enables accurate reconstruction of complex optical fields from a single interferogram, reducing sensitivity to environmental fluctuations and improving experimental stability compared to conventional multi-shot approaches. In addition, a programmable arbitrary mode converter is developed using SLM-based wavefront shaping. By introducing controlled astigmatism and engineering the differential Gouy phase between orthogonal components, the system enables flexible transformation between structured light modes, including Hermite–Gaussian and Laguerre–Gaussian beams. Numerical results demonstrate reliable phase recovery and efficient mode conversion, validating the performance of …

Design Principle For Staple-Mediated Stabilization Of Peptides And Proteins, Samantha C. Hatfield

Theses and Dissertations

Macrocyclization, or stapling, has emerged as a powerful strategy to enhance the stability and function of peptides and proteins by constraining their conformational ensembles. Stapling can improve thermodynamic stability, increase resistance to proteolytic degradation, and enhance biomolecular recognition, making it particularly valuable for the development of peptide-based therapeutics. Despite these advantages, staple design remains largely empirical, relying on iterative screening of linker chemistries, lengths, and attachment sites. This trial-and-error approach limits scalability and hinders the rational design of stabilized peptide systems. In this work, we address this challenge by integrating large-scale experimental datasets with molecular dynamic simulations to develop predictive …

Medical Image Integrity Protection Through U-Net Based Roi Segmentation And Hybrid Integer Wavelet–Quadtree Embedding, Muna M. Jawad, Rasha F. Nadhim, Noor A. Yousif, Ashwaq T. Hashim

Journal of Intelligent Informatics, Networking, and Cybersecurity

For decades, secure techniques in medical images have focused on securing the sensitive information through limiting direct access to the images themselves. Nonetheless, these methods tend to cause distortion on the images that can affect the diagnostic value and cause loss of crucial information. There arises the fundamental problem of secure embedding of medical data in such a way that does not affect the diagnostic integrity of the image. To overcome this limitation, a secure yet hidden data-hiding mechanism is introduced that is exploited U-Net-based deep learning for accurate Region of Interest (ROI) segmentation. Therefore U-Net architecture is used for …

Desert Dichotomies: Climatic Imaginaries Of The Arid+[Ant]Arctic, Amanda Aman

Mavs Open Press Open Educational Resources

Desert Dichotomies is a research-based architecture design studio that examines the impacts of climate change across arid and polar desert environments, revealing unexpected parallels between landscapes often understood as environmental opposites. Focusing on Antarctica, Arctic Alaska and the Sonoran Desert, the project investigates how climate change, resource extraction and human systems of control are transforming ecological processes, water systems and cultural landscapes. While arid deserts face increasing drought and water scarcity, polar deserts are experiencing accelerated warming, ice loss, permafrost thaw and flooding. Despite these contrasting conditions, both regions exhibit similar consequences, including declining water quality, biodiversity loss, infrastructural vulnerability …

Beyond Emergency: Charting Pathways To Sustainable Development In Fragile And Conflict-Affected Settings: A Case Study Of Yemen, Sharif Abdurabu Salem Farid Alsahbool

Theses and Dissertations

For nearly a decade, Yemen's eastern governorates of Hadramawt, Shabwah, and Al‑Mahrah have been relatively stable, yet the international aid system has kept delivering short‑term humanitarian relief like food baskets and water trucking instead of shifting to sustainable development that could rebuild people's lives, create jobs, fix infrastructure, and strengthen local government. This thesis investigates why this transition has taken so long. Based on 21 interviews with government officials, international NGO staff, and local NGO managers in these three governorates, the study develops a new way of understanding the problem. It introduces three ideas: the 'emergency mentality', which is a …

Re: Approval Letter For The Butte Priority Soils Operable Unit (Bpsou) Revised Draft Final Unreclaimed Sites: New And Mahoney (Ur-23) Construction Completion Report (Ccr), Molly Roby

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Re: Approval Letter For The Butte Priority Soils Operable Unit (Bpsou) Unreclaimed Sites: Ur-03 Construction Completion Report (Ccr), Molly Roby

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Structural Characteristics Limiting Digestion Of Forage Fiber, D E. Akin

IGC Proceedings (1977-2023)

Cell walls of forage were studied for structural and chemical factors that limit digestion by rumen microorganisms. Tech­niques used to investigate digestion were histochemistry, electron microscopy, and anaerobic culturing of rumen populations on specific substrates. Certain tissues, such as the xylem cells, totally resisted degradation by rumen microorganisms; these tissues stained positive for lignin with acid phloroglucinol (Weisner test). Other supportive tissues, such as the sclerenchyma in blades, stained positive for lignin with chlorine-sulfite (and also the Maule test) and were also generally resistant to microbial digestion. Microscopic studies revealed that certain living tissues (i.e., those having cytoplasm and organelles …

Employing Ac And Dc Electrolysis To Modulate Electroenzymatic Pathways For Efficient And Stereoselective H-D Exchange, Wassim El Housseini, Rokas Gerulskis, Nibedita Behera, Huaijun Guan, Rohit G. Jadhav, Zachary A. Nguyen, Egor Baiarashov, Michael A. Pence, Vamshi Krishna Kamaja, Trevor Larkin, Long Luo, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

Stereoselective hydrogen isotope exchange (HIE) at chiral centers is an increasingly important strategy for preparing labeled molecules, yet its practical implementation depends on reliable control of nicotinamide cofactor regeneration. Here we introduce a redox-programmable electroenzymatic platform for stereoselective HIE based on electrode-controlled manipulation of the nicotinamide cofactor state. A wired ferredoxin–NADP⁺ reductase (FNR) electrode enables reversible electrochemical interconversion of NADP⁺ and its deuterated reduced form (NADPD) directly from D2O. Coupling this cofactor cycling with enantioselective alcohol dehydrogenases (ADHs) establishes a reversible alcohol–ketone redox manifold that drives efficient and stereoselective H-D exchange at chiral alcohols. Stereochemical outcomes are programmed …

Unraveling The Nanoscopic Characteristics Of The Heterogeneous Deep Eutectic Solvent Formed By Lauric Acid And N-Methylacetamide: An Experimental And Computational Approach, Laura X. Sepulveda

LSU Doctoral Dissertations

Deep eutectic solvents (DESs) are attractive systems for extraction and separation of compounds. One example of this is the DES formed by the combination of lauric acid (LA) and N-methylacetamide (NMA), system that has been shown to efficiently separate oil/water mixtures through gel formation between LA and oil molecules. Structural characterization of this system using small-angle X-ray scattering (SAXS) and vibrational spectroscopy revealed the existence of nanometer-scale LA domains embedded in a continuous polar NMA phase, where LA and NMA interact through hydrogen bonding. These LA domains are responsible for the separation efficiency of linear organic molecules. However, this DES …

Context-Sensitive Control-Flow Analysis For Non-Standard Language Semantics, Tim Whiting

Theses and Dissertations

Control-Flow Analysis (CFA) is a static technique for understanding the execution of higher-order programs without running the code. CFA aids in identifying bugs, assisting program comprehension, and exposing optimization opportunities. Constructing a CFA typically begins with an idealized evaluator--such as an abstract machine or interpreter--and proceeds by approximating components of evaluation to ensure that: (a) the analysis is sound (representing all possible behaviors), and (b) the analysis is guaranteed to terminate (finitely representable). These constraints necessitate a loss of precision, providing an approximation of the values that flow to program locations rather than exact execution traces. This imprecision causes the …

Ai In Education And Information: Tool, Threat, Or Teammate? How Academia Is Shaping The Future Of Intelligent Work, Essraa Nawar

Library Presentations, Posters, and Audiovisual Materials

Artificial intelligence is rapidly changing the future of intelligent work across education, healthcare, leadership, communication, workplace culture, and health information management. Yet while AI adoption continues accelerating, institutions and professionals are still trying to understand what this transformation actually means for people, learning, careers, ethics, trust, governance, and human judgment. This interactive and forward-thinking panel brings together voices from higher education and healthcare information management to explore how AI is reshaping classrooms, workplaces, healthcare systems, professional identity, and future workforce expectations across generations.

Rather than focusing only on technology itself, the conversation will examine the broader cultural and organizational shift …

Data Science In The Utah Draft K-12 Standards Of Mathematics, Kate Webster Green

Theses and Dissertations

In today's data-driven world, the field of data science is becoming increasingly important. Research has shown that more job listings in Utah require applicants to have data science skills than ever before. Due to this growing demand, there is a push to begin data science instruction in grades K-12; however, what data science instruction is in grades K-12 is not yet clearly defined. Previous research has identified the skills and processes that make up data science in grades K-12, and several states and research groups have begun developing and implementing data science standards and learning progressions. This study analyzes the …

Predicting Cybermindfulness With The Cyber-Health Belief Model, James Robinson, Yan Tian, Thomas Skill

Journal of Cybersecurity Education, Research and Practice

This study describes the development of a Cyber-Health Belief Model (CHBM). The health belief model (HBM) is a message strategy that is widely and successfully used in public health research [1] and has been extended into phish training. Most phish training programs assume  end users are victimized because they have insufficient information to defend themselves. While near-term training effectiveness has shown to be effective, evidence for sustained behavioral change is thin [4]-[7].  This problem indicates that the traditional approaches need to be reconsidered and that new models are needed.  Recent research suggests attentional deficits, cyber-fatigue and fatalism and a sense …

Cyber-Ready Libraries, Building Digital Fortresses For Tomorrow, Adeyinka B. Tella, Oluchi Precious Ogbonna Dr, Adebola Aderemi Olatoye Mrs

Journal of Cybersecurity Education, Research and Practice

Background and Purpose: Libraries are evolving into highly networked information ecosystems in this age of fast digital transformation, which increases their susceptibility to cybersecurity risks. The study "Cyber-Ready Libraries: Building Digital Fortresses for Tomorrow" looks into how prepared libraries are to face cyber threats and considers methods for creating information systems that are safe, robust, and ready for the future. To safeguard digital assets and user data, the study aims to assess existing cybersecurity practices in library settings and offer a roadmap for combining technological, human, and governance solutions.

Design/Method: The existing literature, case studies, and policy frameworks pertaining …

Structure And Spectroscopy Of Free Base, Copper, And Zinc Tetrapentylporphyrin, Christopher J. Ziegler, Nneka Damola Ajayi, Victor N. Nemkyin, G Richard Geier Iii

University Research

Synthetic porphyrins have been crucial as models for heme units and other biological porphyrins, as well as components of advanced materials and catalysts. Much of the work on synthetic porphyrins has focused on the meso-substituted 5,10,15,20-tetraphenylporphyrin (TPP) or the pyrrole-substituted 2,3,7,8,12,13,17,18-octaethylporphyrin (OEP). In this report, we present a comprehensive spectroscopic, electrochemical, and computational study of free-base, zinc(II), and copper(II) 5,10,15,20-tetrapentylporphyrin (TPeP). TPeP can be prepared via a two-step, one-flask reaction of pyrrole and hexanal mediated by Montmorillonite K10, followed by oxidation with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) in yields of around 40%. Similar to TPP, the TPeP systems have the highest occupied molecular …

A Comprehensive Review Of Optimization Techniques For Healthcare Using Cancer Datasets, Dina Tbaishat, Mohammad Tubishat, Sharif Naser Makhadmeh, Mohammed Azmi Al-Betar

All Works

This study presents a systematic review of metaheuristic optimization techniques applied to healthcare problems using cancer datasets. A structured search of recently published peer-reviewed literature was carried out, focusing on five major application areas: feature selection, classification, image segmentation, hyperparameter tuning, and early detection. For each eligible study, the optimization strategy, dataset characteristics, data modality, learning model, validation protocol, and reported outcomes are provided. The reviewed works were organized into a taxonomy of original, modified, and hybridized algorithms, and a descriptive analysis was performed to assess algorithm prevalence and dataset utilization. The findings highlight that feature selection remains the most …