Digital Commons Network^™

Building Trustworthy Information Systems: A Unified Framework For Comparative Risk Detection, Parisa Momeni

USF Tampa Graduate Theses and Dissertations

Risk detection in large scale information systems increasingly depends on heterogeneous data generatedby both centralized and distributed ecosystems. While centralized systems provide curated and validated reports, distributed environments produce large-scale and real-time observational evidence. Existing computational approaches analyze these ecosystems in isolation, limiting systematic comparison of risk repre-sentations across heterogeneous sources.

This dissertation presents a unified computational framework for comparative risk detection across centralized and distributed information systems. The framework provides a domain independent methodology for transforming heterogeneous risk reporting data into comparable multidimensional representations. To enable interpretable comparison of heterogeneous risk distributions, this work introduces the Geometric Overlap Score …

A Mathematical Model Of The Interactions Between A Collagen Lattice, Fibroblasts, And Fixed Surfaces With Varying Topographies, Mary Jenkins

Theses and Dissertations

Collagen is an important structural protein in the body, which plays a role in wound healing, particularly the contraction process. Collagen lattices have been studied for nearly 50 years to provide insight into wound contraction. In some cases, collagen interacts with surfaces that have fixed shapes, such as medical implants. Our model focuses on the interactions of a collagen lattice with such a fixed surface. We mathematically model a collagen lattice as a network of nodes connected by springs. We also model fixed surfaces that have various topographies. Our model includes fibroblast cells that connect to both surfaces and remodel …

An Analysis Of Heat Spread Through Smoldering Pine Needles, Timothy Keith

Theses and Dissertations

The goal of this thesis is to calculate the average speed of flame spread through smoldering pine needles. We present two different models for doing this: the first is a very large system of ODEs meant to represent the spread of flame through individual needles, the second is a macroscopic model based on the porous medium PDE. Simulations are run for each of these models and compared to each other as well as to existing models and experimental results.

Designing For Fitness And Resilience In Human Artificial Intelligence Systems, Thomas R. Gill

USF Tampa Graduate Theses and Dissertations

Over the last decade, new artificial intelligence models, frameworks, and applications have emerged that have radically changed the socio-technical landscape. These new technologies represent both great opportunities and great potential risks. Due to the recency of their emergence, there is little known about the longevity and long-term repercussions of artifacts powered by new artificial intelligence technology. In this dissertation, I evaluate A.I. and A.I.-based artifacts through the lens of the fitness-utility model, a tool developed by Gill and Hevner (2013) for the evaluation of an artifact's ability to survive and reproduce over long time horizons. In so doing, I also …

Learning Trajectories Of Online Batch Selection Methods, Luke Green

Theses and Dissertations

Modern deep neural networks achieve strong performance on large-scale datasets, but often require substantial training time. Online batch selection methods seek to reduce this cost by updating models on informative subsets of each batch rather than on all available examples. Recently introduced methods leverage teacher models and report substantial speedups, particularly in noisy-label settings. However, comparisons are often based on the number of epochs required to reach a target test accuracy, a coarse metric that is sensitive to implementation details and may obscure important differences in learning dynamics. In this thesis, we implement several online batch selection methods in a …

Advancing Data Usability, Activity Modeling, And Stability Optimization In Computational Enzyme Design, Spencer Gardiner

Theses and Dissertations

A grand challenge of computational biology is to computationally design, in a single pass, a protein sequence that catalyzes an arbitrary chemical reaction at a high rate under specified conditions [1]. This work details advances in three essential areas on the path to that goal: data quality, activity prediction and modeling, and stability optimization. The structure and implementation of the Allotrope Simple Model (a FAIR data format for many scientific instruments) was examined in [2], setting the stage for training deep learning models on high-quality experimental datasets from diverse sources. In [3], the limits of physics-based and deep learning tools …

Beyond Single Images: A Comprehensive Benchmark For Album-Level Vision-Language Understanding, Shawn Huang

Theses and Dissertations

Automatic album organization has been studied extensively over the past decades due to significant progress in digital photography. Recent Vision-Language Models (VLMs) have shown strong performance on multi-image understanding, making them natural candidates for automating album organization workflows. While VLMs’ abilities in multi-image understanding have been widely studied, their performance on album organization remains underexplored. To bridge this gap, we introduce AlbumBench, the first comprehensive benchmark for automatic album organization. Specifically, we (1) define album organization tasks as photo selection for album-specific user objectives, photo rating according to how well user intents are fulfilled, and album-specific photo grouping given a …

Re: Conditional Approval Letter For The Butte Priority Soils Operable Unit (Bpsou) Clark Tailings Consolidated Waste Management Area (Ctcwma) Site Investigation Quality Assurance Project Plan (Qapp) (Dated June 1, 2026), Emma Rott

Silver Bow Creek/Butte Area Superfund Site

No abstract provided.

Artificial Intelligence Empowered Biological Research: Paradigm Shifts, Application Scenarios, And Strategic Layout, Xinguang Zhu, Yiming Bao, Zhenong Jin, Xin Li, Sijia Wang, Yueming Wang, Yungui Yang, Cao Xu, Yan Xiong, Bin Han

Bulletin of Chinese Academy of Sciences (Chinese Version)

Life related processes are characterized by high dimensionality and multi-scale properties. Understanding mechanisms underpinning life processes helps promote national healthcare, agricultural development, sustainable ecological civilization, and national security. Current life science research is confronted with an enormous challenge of dimensionality stemming from data explosion and data fragmentation, for which the recent rapid advancement of artificial intelligence (AI) provides novel solutions. AI will catalyze a paradigm shift in life science research from the current experiment based empirical induction to a new closed-loop knowledge acquisition including large scale data collection, model building, model prediction, experimental validation, and iterative of these procedures. Life …

American Sign Language Recognition And Analysis Using Deep Learning, Saurabh Kumar Soni

Master’s Dissertations

In this work I build a system that recognizes isolated American Sign Language (ASL) words, and I use it to ask one fairly direct question: when training data is scarce, is it better to look at the video pixels or at the geometry of the signer’s body? To find out, I train two very different models on exactly the same clips. The first is appearance-based. Every frame is run through standard preprocessing and a ResNet50 backbone pre-trained on ImageNet, which turns it into a 2048-dimensional feature vector, and a Bidirectional LSTM then reads that sequence over time. The second model …

An Empirical Study Of Rlvr Fine-Tuning For Mathematical Problem Solving In Llms, Rashmi Konnur

Master’s Dissertations

Large language models have shown immense improvement in coding and math performances thanks to reinforcement learning boosted algorithms. However, its true impact on broadening the reasoning and analytical capacities of an LLM is still contended. In this dissertation, we outline the foundations of Large Language Models, and delve into Reinforcement Learning with Verifiable Rewards (RLVR). We discuss various strategies to efficiently manipulate memory during a fine tuning update. We finally perform RLVR fine-tuning techniques on different models with varied use cases and compare their performances, which corroborate the efficiency of RLVR.

Knowledge, Attitude, And Practice Regarding Vitamin D Among Adults In Western Libya: Assessment And Socio-Demographic Influences, Abdounasser Albasher Omar, Kawther Adaila, Mofida M. Alfaid, Abdurrahman M Sweidan, Ruqayah Kasheem, Samia Emhemmed Abadi, Abdulnabi Ali Abushita, Hafsa A. Alemam

Al-Bahir

Vitamin D deficiency is a widespread public health concern, necessitating a clear understanding of knowledge, attitudes, and practices (KAP) among populations. Therefore, this study was conducted to assess Libyan citizens' knowledge, attitude, and practice (KAP) regarding vitamin D in the western region of Libya. This study was carried out between June and September of 2021. A questionnaire was distributed across the study area and the complete responses were 314, with 62.7% were females and 37.3% were males.  The scores were calculated as percentages and statistically tested. Additionally, the impact of some socio-demographic factors (age, gender, education level, job, and salary) …

Investigation Of Air Emissions With A Local Composites Industry, Chris White

ETDs from 2020-2029

Workers at an office space raised complaints about a sweet-smelling odor directly outside their building. After an initial assessment of the surrounding businesses and their processes, it was determined that the workers were most likely exposed to styrene emissions from a nearby composites company. This investigation utilizes multiple weeks of direct readings with a photoionization device and active environmental sampling with a charcoal tube and pump to confirm the styrene exposure hypothesis. Weather trends were also recorded to determine correlation between weather and exposure to the sweet-smelling chemical. The direct readings found an exposure maximum of less than 2 ppm …

Production, Purification, And Crystallization Of The Recombinant Her2 Tyrosine Kinase Domain (Her2-Tkd), Edanur Topalan, Hali̇li̇brahi̇m Çi̇ftçi̇, Hasan Demi̇rci̇

Turkish Journal of Chemistry

The human epidermal growth factor receptor 2 tyrosine kinase domain (HER2-TKD) is an important therapeutic target in oncology. In this study, we developed a practical and cost-effective approach for producing soluble recombinant HER2-TKD in Escherichia coli as a basis for structure-based drug discovery. The gene encoding HER2-TKD was cloned into a pET28a(+) expression vector and expressed in E. coli. Since the protein was initially obtained as inclusion bodies, solubilization with 1.5% sarcosyl was applied to recover it in soluble form. The purified protein was obtained through size-exclusion chromatography, followed by tag removal using reverse affinity purification. Crystallization trials were performed …

Quantum Engineered Mxene–Graphene–Plasmonic Nanocomposites For Next-Generation Transparent And Flexible Space Photovoltaics, Arash Vaghef-Koodehi

Turkish Journal of Chemistry

This study presents a quantum‑engineered, tricomponent heterostructure comprising Ti3C2T MXene quantum dots (2–5 nm), single‑layer graphene, and plasmonic gold nanoparticles (15 ± 3 nm) uniformly embedded within electrospun polyacrylonitrile nanofibers. This integrated architecture demonstrates a remarkable combination of optical transparency (89.3 ± 1.1%) and power conversion efficiency (19.7 ± 0.4%) under AM0 solar illumination, representing 340% enhancement over state‑of‑the‑art transparent photovoltaic devices. A multiscale computational framework, bridging density functional theory and device‑level drift-diffusion modeling, identifies optimal interlayer spacing (3.4 ± 0.1 Å) as the key to achieving 89.3% charge‑transfer efficiency. Concurrently, localized surface plasmon resonances at 532 nm generate electromagnetic …

Efficient Heterogeneous Photo-Fenton Degradation Of Azo Dyes Using The Nanocomposite Mgfe2o4/Mos2, Zahra Zeinali, Leila Ershadi Afshar, Naz Chaibakhsh, Farnaz Isapour

Turkish Journal of Chemistry

In the present work, a facile hydrothermal route was employed to synthesize the nanocomposite MgFe2O4/MoS2, which acted as a heterogeneous photo-Fenton catalyst for the degradation of a synthetic diazo dye, Acid Blue 113 (AB113). The nanocatalyst produced underwent analysis using multiple characterization techniques. The parameters influencing the oxidative reaction were statistically modeled and optimized using response surface methodology. Optimal degradation efficiency for AB113 (94.92%) was attained at pH 8.79 using 10 mg of MgFe2O4/MoS2 nanocatalyst, 1.6 mL of H2O2, and a reaction duration of 27 min. The synergistic effect resulting from the formation of electron-hole pairs renders the combined photocatalysis …

Electrochemical Biosensing Of Alpha-Fetoprotein Based On Carboxylated Multi-Walled Nanotube-Polyazur A (In Des)-Gold Nanoparticles, Merve Yilmaz Çilçar, Meli̇ke Bi̇lgi̇ Kamaç

Turkish Journal of Chemistry

AFP, a cancer biomarker, is monitored during fetal development and in the serum of pregnant women. Sensitive and rapid monitoring of AFP is crucial for effective management. In this study, screen-printed carbon electrodes (SPCEs) modified with multi-walled carbon nanotubes (MWCNT-COOH), polyAzur A (PAA), which was prepared in a deep eutectic solution (DES), and gold nanoparticles (AuNP) were fabricated. AFP biosensors were developed for practical, sensitive, low-cost, and rapid detection of AFP. Optimizations of nanostructures (MWCNT-COOH, AuNP) and polymers (PAADES) were performed. The MWCNT-COOH, PAADES, and AuNP-modified SPCEs were characterized by FE-SEM-EDX, FTIR, and XRD techniques. The amounts of 6-MOH, APTES, …

[H]-Mediated Enhancement Of The Fenton Reaction Over A Pd/Uio-66(Zr)-F4 Catalyst, Juanhong Li, Suqin Wang, Xin Liu, Feng Liu

Turkish Journal of Chemistry

A [H]-accelerated catalytic Fenton system was developed using Pd/UiO-66(Zr)-F4 as the catalyst. This system enabled the regeneration of Fe²⁺ and facilitated the continuous generation of both ·OH and 1O2 through [H]-mediated electron transfer at ambient temperature and pressure. Under the conditions of 0.2 g L−1 catalyst (Pd loading 0.516 wt%), 25 μM Fe2+, 60 mL min−1 H2 flow (as the [H] source), 20 mM H2O2, and pH 3, approximately 89% of carbamazepine (initial concentration 20 mg L−1) was degraded within 3 h using trace iron. However, the catalytic activity of Pd/UiO-66(Zr)-F4 gradually declined from 89% to 53% over six reaction …

Alcohol-Based Microextraction Of Rhodamine 6g From Soft Drink, Food, And Cosmetic Samples, Mustafa Soylak, Esra Yamaner, Özgür Özalp

Turkish Journal of Chemistry

By using alcohol-based solvent extraction without tetrahydrofuran, a liquid–liquid microextraction technique was developed for the separation–enrichment of trace levels of Rhodamine 6G from complex matrices, including soft drinks, food, cosmetics, hygiene products, and natural waters. Numerous experimental parameters were tuned, including pH, alcohol volume, ultrasonication time, and sample and eluent volume. The enrichment factor (EF), limit of detection (LOD), and limit of quantification (LOQ) were used to assess the analytical performance of the suggested approach. The LOD and LOQ were 6.92 ng mL−1 and 23 ng mL−1, respectively, and the EF was 14. Through the use of the standard addition …

Synthesis Of Two Hofmann-Type-Like Clathrates, Characterizations, And Investigation Of Their Structures, Spectroscopic And Theoretical Properties, Zari̇fe Si̇bel Şahi̇n, Zeki̇ Kartal

Turkish Journal of Chemistry

This study concerns two Hofmann-type-like clathrates using 4-aminopyridine (4AP) as ligands and the transition metal atoms copper (Cu) and zinc (Zn). These clathrates have the structural features of heteronuclear tetracyanonickelate(II) and contain H2O and 4AP molecules as guest molecules, respectively. These two clathrates were characterized by infrared spectroscopy (IR), elemental analysis, and single crystal X-ray diffraction (SC-XRD) techniques. Based on elemental and spectral data, the structural formulae describing these clathrates were found to be [Cu(II)(4AP)4Ni(μ-CN)2(CN)2]·H2O (1) and [Zn(II)(4AP)4Ni(μ-CN)2(CN)2]·(4AP) (2). In addition, the values of some optical, electronic, and thermochemical properties of the two obtained clathrates calculated with the Gaussian 03 …

Physically Mixed Graphene Aerogel:Carbon Black (Ga:Cb)-Supported Pt Or Hydrothermally Synthesized Ga-Pt/Cb Hybrid Electrocatalysts For Pem Fuel Cells, Emi̇ne Teke Öner, Meli̇s Irmak Aydin, Merve Ni̇da Dursunoğlu, Ayşe Bayrakçeken

Turkish Journal of Chemistry

Graphene aerogels (GAs), having the superior properties of graphene and aerogel structures, are promising support materials for Pt nanoparticles to be used as electrocatalysts for PEM fuel cells. In this study, two routes were followed to synthesize GA-based electrocatalysts. In the first route, after GA synthesis it was physically mixed with carbon black (CB) by changing the mass ratios from 0% to 100% with 25% increments and then decorated with Pt nanoparticles via microwave irradiation, resulting in Pt/GA:CB electrocatalysts. In the second route, firstly, Pt/CB electrocatalyst was synthesized and then GA was hydrothermally added to the Pt/CB by changing the …

A Nonenzymatic Electrochemical Glucose Sensor Depending On A Ninps/Co3o4/Functionalized Graphene Oxide-Modified Working Electrode, Sümeyra Pekmez, Muhammet Güler

Turkish Journal of Chemistry

In the present research, the aim was to develop a novel electrochemical enzyme-free glucose sensor dependent upon a nickel nanoparticles (NiNPs)/cobalt (II, III) oxide (Co3O4)/carboxylated graphene oxide (GO-COOH)-modified glassy carbon (GC) electrode. The electrocatalytic performance of the electrode was tested using various electrochemical methods such as amperometry and cyclic voltammetry (CV). The NiNPs@Co3O4/GO-COOH/GC electrode showed noticeably superior electrocatalytic behavior for glucose oxidation in 0.1 M NaOH media, ascribed to the good synergistic impact between NiNPs, Co3O4, and GO-COOH. The amperometric response of the NiNPs@Co3O4/GO-COOH/GC electrode to glucose exhibited two linear determination ranges at +0.55 V potential. The first one was …

Amending Planting Media With Typha-Derived Biochar For Sustainable Horticulture, Elissa Touma

USF Tampa Graduate Theses and Dissertations

Constructed wetlands are widely used to improve water quality by removing excess nutrients from wastewater and stormwater. Nutrients are stored within wetland vegetation, particularly in fast-growing plants such as Typha. Harvesting vegetation provides an opportunity to permanently remove these nutrients while generating biomass suitable for beneficial reuse. Converting harvested biomass into value-added products such as compost and biochar can support nutrient recovery and sustainable biomass management. In addition, increasing concerns regarding the environmental impacts of peat extraction have created interest in renewable alternatives for horticultural growing media. Therefore, the objective of this study was to evaluate the potential of harvested …

Data-Driven Electrochemistry Reveals The Impact Of Hydrophobicity On Aptamer Cross-Reactivity, Emily Carroll, Michael A. Pence, Elizabeth Winterholler, Taylor D. Sparks, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

Electrochemical aptamer-based (E-AB) biosensors offer a promising platform for reagentless detection of molecular targets, yet aptamer recognition can be limited by cross-reactivity, particularly for hydrophobic analytes such as steroid hormones. To investigate how cross-reactivity influences E-AB sensor performance, we use automation and machine learning to screen a library of possible interferent molecules against a steroid-binding aptamer, with progesterone serving as a physiologically relevant test case. Here, we develop a label-free E-AB sensor for progesterone detection using a methylene blue-modified aptamer anchored with a hexanethiol linker. We then used an automated electrochemistry platform to perform reproducible and high-throughput characterization of our …

Student Worksheets Based On The Local Wisdom Of Besilek Serawai For Sixth-Grade Elementary Science Learning, Mice Agustin, Tomi Hidayat, Irwandi Irwandi

Jurnal Pendidikan Sains

This study aims to develop a Student Worksheet (Lembar Kerja Peserta Didik [LKPD]) based on the local wisdom of Besilek Serawai for sixth-grade elementary science education and to evaluate its validity. The study employed the ADDIE development model, consisting of five stages: Analyze, Design, Develop, Implement, and Evaluate. The developed LKPD integrates Besilek Serawai, a traditional martial art of the Seluma community, with the concept of the human locomotor system in science instruction. The worksheet was validated by two subject-matter experts and two media experts. Material validation yielded an average score of 4.26, equivalent to a validity percentage of 85.2%, …

You Mean What? Commognitive Conflict In Resolving Contextual Logarithm Problems, Endrayana Putut Laksminto Emanuel, Fatkul Anam, Radhitya Duta Pradana, Anik Kirana, Sikky El Walida

Jurnal Pendidikan Sains

Students’ approaches to solving contextual mathematics problems involving logarithms vary significantly due to differences in their prior mathematical understanding. These differences may trigger commognitive conflict during the interpretation and reasoning processes when students attempt to construct mathematical meaning from contextual situations. This qualitative study aimed to explore how commognitive conflict emerges as a mechanism of mathematical interpretation in students’ discourse while solving logarithmic contextual problems. Twenty students participated in the study and were grouped based on their performance. One student was selected as the main research subject for an in-depth analysis. The findings reveal that commognitive conflict appeared in two …

The Effect Of Project-Based Learning Model On Entrepreneurship (Pjbl-E) With A Deep Learning Approach On Students' Problem-Solving And Cognitive Skills, Ricce Oktasari, Irwandi Irwandi, Siti Darwa Suryani

Jurnal Pendidikan Sains

This study aims to examine the effect of the Entrepreneurship-based Project Based Learning (PjBL-E) model integrated with a pedagogical Deep Learning approach on students’ problem-solving skills and cognitive learning outcomes in biology learning. The novelty of this study lies in the integration of entrepreneurship values and pedagogical deep learning principles into Project Based Learning to create contextual and meaningful learning experiences. Entrepreneurship integration encourages students to develop innovative products, identify real-world problems, and apply biological concepts in practical and socio-economic contexts. Meanwhile, the pedagogical Deep Learning approach promotes reflective thinking, conceptual understanding, critical analysis, and the ability to connect theory …

Morphodynamic Evolution Of Midnight Pass, West-Central Florida, Sydney C. Scott

USF Tampa Graduate Theses and Dissertations

This study takes advantage of a rare opportunity provided by the reopening of Midnight Pass due to two consecutive hurricanes in 2024, to examine the morphologic evolution of a newly reopened inlet and subsequent beach-inlet interactions. Historical aerial photos since the 1940s were collected and analyzed to understand the last closure of Midnight Pass, and to gain knowledge on the future of the newly reopened inlet. Time-series topography and bathymetry survey of the beach-inlet system were conducted bimonthly to quarterly for the first year and a half after the reopening, with the goals of quantifying the morphologic changes and understanding …

Adaptive Intervention Strategies In Co-Evolving Multiplex Networks: A Reinforcement Learning Approach To Real-Time Misinformation Containment, Anjali Ashokrao Bhadre Dr., Harshvardhan Prabhakar Ghongade Dr.

Northeast Journal of Complex Systems (NEJCS)

The growing transmission of misinformation via social media creates serious challenges to public health, democracy and social cohesion. To date, methods used to contain misinformation rely upon static representations of networks and set rules for interventions. In contrast, this study presents the first Multiplex Adaptive Reinforcement Intervention Network (MARIN), a framework for real-time adaptive intervention in the context of dynamic misinformation transmission using co-evolving multiplex networks and deep reinforcement learning. Unlike past studies that have assumed static network structures, MARIN has the ability to allow for dynamic changes in network topology as a result of both misinformation transmission and intervention …

Tinyvgg-Based Real-Time Degradation Classification For Adverse Driving Scenes Using A Newly Collected Iraqi Driving Dataset, Yousif N. Abbas, Matheel E. Abdulmunim, Nada H. Ali, Ismail A. Mageed

Journal of Soft Computing and Computer Applications

Environmental conditions such as low-light at night, fog scattering, glare artifacts, rain streaks, and rain smear distortions are significant issues of camera-based perception in Autonomous Vehicles (AVs). These degradations alter the statistics of the scene, mask structure, introduce non-uniform noise, and adversely affect downstream vision processes, including detection and tracking. To overcome this shortcoming, this paper presents a lightweight TinyVGG-based degradation classification system that runs in real time. The network extracts discriminative spatial features with hierarchical convolutional encoding and projects them to a lower-dimensional semantic representation with fully connected layers and a multi-class predictor based on SoftMax. In addition, a …