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Thin Layer Chromatography Of Platinum And Palladium-Ammine Complexes, Edgar Roberto Montezuma

University of the Pacific Theses and Dissertations

Recent work in this laboratory has centered around Platinum metals and their coordination compounds. Specifically, Thin-Layer Chromatography of Platinum metal ions has been reported in one of the recent dissertations (1). The purpose of the present work was to carry out a systematic study of Thin-Layer Chromatography on the following complexes: Tetrammine Platinum (II) Chloride [Pt (NH₃)₄]Cl₂ Tetraammine Palladium (II) Chloride. [Pd (NH₃)₄]Cl₂ Hexammine Platinum (IV) Chloride. [Pt (NH₃)₆]Cl₄ Hexammine Palladium (IV) Chloride [Pd (NH₃)₆]Cl₄

After the complexes had been …

A Kinetic Investigation Of The Reaction Of Ethylenedinitrilotetraacetic Acid (Edta) And Cerium (Iv) In Acid Solution, Sahmia K. Al-Hashimi

Masters Theses

"The reaction between Ce(IV) salt solutions and EDTA solution was followed titrimetrically and spectrophotometrically and found to occur in stages. Four equivalents of Ce(IV) are reduced per mole of EDTA almost instantaneously at room temperature or even lower. With increasing temperature and reaction time an ultimate of about 14 equivalents of Ce(IV) is consumer per mole of EDTA. Formaldehyde, carbon dioxide, and other unidentified compounds are the products of oxidation of EDTA with Ce(IV). The kinetics of the reaction in aqueous sulfuric acid (0.09 - 2.95 M̲) was studied over the temperature range 11.7-40⁰ by a spectrophotometric technique. In the …

The Downhole Suspension And Testing Of An Electrodynamic Shear Wave Exciter, Robert Franklin Kehrman

Masters Theses

"The work in this research project was aimed at designing a Downhole Electromagnetic Shear Wave Generator capable of delivering a wide frequency band, random, continuous signal. This Exciter was built using a compressed-air driven piston assembly for downhole application. The device was tested in the laboratory in a concrete test facility. It proved to be capable of transmitting a continuous, measurable stress into the concrete in a 100 to 5,000 hertz frequency band"--Abstract, page ii.

Procedure And Structure For An Instructional Laboratory Which Supplements Research, R. S. Adams Jr.

Journal of the Minnesota Academy of Science

This paper describes the organization of a laboratory course in Soil Chemical Analysis. Students select and pursue small research problems to gain experience in the soil analyses that are discussed in lecture and required in the laboratory. Involvement of the class in an actual research problem proved challenging to both the instructor and the class. The data obtained often supplemented current departmental research. Individual projects were found to be easier to supervise than team problems. This paper reports results of a team project examining parameters of a pot experiment. Shape of the pot, methods of watering, methods of fertilizing, and …

Current Density-Anodic Potential Curves Of Single Crystal Gaas At Low Currents In Koh, Martin E. Straumanis, J. P. Krumme, William Joseph James

Materials Science and Engineering Faculty Research & Creative Works

Single p-type, GaAs crystals of high purity, Zn doped, were used to determine whether or not the inverse octahedral {111} faces show potential differences and various rates of anodic dissolution. The Ga{111}, As{111}, {110}, and {100} faces, were polished, etched, and etch-polished with concentrated H₂SO₄ + H₂O₂, and immersed in IN KOH. The Ga{111} faces were found to be the most noble with respect to rest and anodic dissolution potentials. The potential difference between the inverse {111} faces was as large as 0.14v for the rest and 0.123v for the dissolution potentials. The …

Ground Water Flow Systems Of Central Nevada, G. William Fiero Jr

UNLV Theses, Dissertations, Professional Papers, and Capstones

The U.S. Atomic Energy Commission has been evaluating a large area of central Nevada in order to define a supplemental test site for the underground testing of high-yield nuclear devices. Safety considerations involving the radiocontamination of the ground water in the vicinity of the test site necessitated that research be conducted to determine the direction and rate of flow of the ground water. This investigation defines the ground water flow systems in eighteen valleys comprising 12,000 square miles of central Nevada.

The definition of the systems was made following a compilation of existing hydrologic and geologic data for the area. …

Infrared Related Solid State Studies, Donald George Rathbun

Masters Theses

"Infrared reflectivity measurements have been made on single crystal CdS. Classical dispersion analysis has been used in an analysis of the data to obtain the index of refraction, the extinction index, and the dispersion parameters. These are compared with previously published results. The procedure used in this analysis has been outlined for future reference. Also, the shallow donor impurity theory has been used to numerically calculate the d_±1 levels for Si and Ge. The theory is extended for the case of the impurity in the bulk semiconductor and the d₀, d_±2 and, for high n, the s, p₀, …

Analysis Of A Focus Log Electrode In A Non Homogeneous Medium, John Julian Zenor

Doctoral Dissertations

"The mathematical model presented for the focused logging system is applicable to any resistance logging tool of the electrode type. Horizontal or cylindrical resistance interfaces may be included in any combinations. The tool and its environment are compartmentalized, and the integral form of the condition for continuity of current is applied to each compartment. Acceleration methods are applied to the iterative solution of the resulting large-scale system of linear equations. Two specific models are presented, one for the study of the effects of invasion and the other for the study of the effects of bed thickness on the apparent resistivity …

Solutions To Axisymmetric Seepage From Ponds Through Homogeneous And Nonhomogeneous Porous Media, Roland W. Jeppson

Reports

No abstract provided.

Air Pollution Control And Abatement Proceedings Of A Symposium, Allen D. Kartchner

Reports

No abstract provided.

Mechanical Effects Of Acoustic Transients On Tobacco Mosaic Virus, Philip Edward Hamrick

Theses and Dissertations

The mechanical breakage of tobacco mosaic virus (TMV) due to the action of acoustic transients has been investigated. The acoustic transients were produced by transient heating of a Prussian blue dye solution (attenuation coefficient of 1000 per cm) when a ruby laser light (20 x 10⁶ watts) was incident on the dye surface. A quartz piezoelectric transducer was used to determine the amplitude and form of the acoustic wave. The production of acoustic waves by transient heating is discussed, and the theoretical form of the acoustic wave determined for various boundary and initial conditions are compared to the experimentally …

Endogenous Metabolism Of Polyporus Sulfureus. : Utilization Of Exogenous Carbohydrates And Fatty Acids, Shu-Mei Wang

Masters Theses

"A strain of Polyporus sulfureus from the collection at the University of Missouri at Rolla was used in this investigation. Organisms of this genus have been reported to produce eburicoic acid in good yield and this was confirmed for the organism used in this study by the isolation and identification of eburicoic acid from the mycelium. Growth studies of this organism showed that 4% malt extract is a better medium than synthetic media containing asparagine, nitrate or nitrate plus 0.5% yeast extract as nitrogen sources. An examination of the pH of the culture medium led to the conclusion that regardless …

A Study Of Succinic Dehydrogenase, Indole Acetic Acid Oxidase, Nitrate Reductase And Cytochrome C Reductase In Hygrophorus Conicus, Jagdish M. Mehta

Doctoral Dissertations

"The activity of the enzyme succinic dehydrogenase (succinate : phenazine methosulfate oxidoreductase, EC 1.3.99.1) of Hygrophorus conicus, a member of a class of fungi known as basidiomycetes, was found to be stimulated by nitrate. Two substances were tested as electron acceptors in the measurement of succinic dehydrogenase activity. Of the two substances tried, phenazine methosulfate and brilliant cresyl blue, the former was found to be the best. Nicotinamide adenine dinucleotide (NAD⁺) was a necessary cofactor for the enzyme and could be readily dissociated from the enzyme. The enzyme has the properties of a high molecular weight nucleo- or lipoprotein.

The …

A Study Of Solvent Effects On The Reaction Between P-Nitrobenzyl Chloride And Hydroxide Ion In Aqueous Dioxane Homogeneous Media, Ken K. Ho

Masters Theses

"The kinetics and activation parameters of the reaction between p̲, p̲' - dinitrostilbene quantitatively, have been studied in five aqueous dioxane solvent systems at five different temperatures between 20⁰ and 40⁰C. At any one temperature the second-order rate constants are minimum in the 30% dioxane solvent mixture, reach a maximum in the 50% dioxane systems, and fall off slightly in the 60% and 70% dioxane systems. The Arrhenius activation energies are highest in the 30% dioxane and lowest in the 70% dioxane systems. The free energies of activation change in the same direction but the magnitude of change is much …

Beiträge Zur Kenntnis Der Cavernicolen Antroleucosomiden (Diplopoda, Ascospermophora), Ionel Tabacaru

International Journal of Speleology

The family of the Antroleucosomidae is known from the Mediterranean region. In this paper the author describes the new genus Dacosoma with the species D. motasi of caves of the southern Carpathians together with two new species of Bulgarosoma, B. Ocellatum n. sp. of the caves of Mount Banat and B. meridionalis of the cave on Rhodope mountains. A new and complete description is also given for Antroleucosoma banaticum Verh. 1899 and B. bureschi Verh. 1926 based on the study of material coming from the type localities.

Test 964: Allis-Chalmers 180 (Diesel), Nebraska Tractor Test Lab

Nebraska Tractor Tests

EXPLANATION OF TEST REPORT GENERAL CONDITIONS East tractor is a production model equipped for common usage. Power consuming accessories can be disconnected only when it is convenient for the operator to do so in practice. Additional weight can be added as ballast if the manufacturer regularly supplies it for sale. The static tire loads and the inflation pressures muse conform to recommendations in the Tire Standards published by the Society of Automotive Engineers. PREPARATION FOR PERFORMANCE RUNS The engine crank case is drained and refilled with a measured amount of new oil conforming to specifications in the operator’s manual. The …

A Survey Of The Breakfast And Snack Habits Of Adventist And Non-Adventist Adolescents, Consuelo A. Bustista

Loma Linda University Electronic Theses, Dissertations & Projects

A study was undertaken to survey by questionnaire and interview methods the breakfast and snack habits of Adventist and non-Adventist adolescents. The purposes of the study were: (I) to find out if there is any difference in the practices of Adventist and non-Adventist teenagers, and (2) to determine their attitudes toward snacking and omission of breakfast.

Results of the questionnaire were coded, punched onto IBM cards, and fed into computing machines for item and statistical analysis. Chi-square test analyses were done on denominational classification against some questions of interest to show any significant differences between Adventist and non-Adventist students' responses. …

9th Annual Meeting Rocky Mountain Spectroscopy Conference

Rocky Mountain Conference on Magnetic Resonance

Program and abstracts from the 9th annual meeting of the Rocky Mountain Spectroscopy Conference, sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, August 7-8, 1967.

A Spectral Study Of The 4-Arylamino-1,2-Naphthoquinone System, Lloyd Myles Phipps

Masters Theses

No abstract provided.

The Synthesis, Characterization And Reactions Of 1,2-Dihydro-2-Thiono, 3,1-Benzoxazin-4-One And Its Isomer The 3,1-Benzothiazine-2 (1h), 4-Dione, Joan Louise Davis

Chemistry Honors Papers

This 52 page thesis investigates the reactions of thioisatoic anhydride with sodium hydroxide, ammonia, a series of diprotic amines and methyl iodide.

The Influence Of Thermo-Gradients Upon Water Movement And Retention In Unsaturated Soils, Jose V. Salazar

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Temperature differences of about 5, 10, and 15 V, were applied to uniformly packed and insulated horizontal column of Millville silt loam soil using mean temperatures near 13, 14, 15, 16, 17, 18, 19, 20 and 23.5 C. The temperature distribution along the soil column was determined using copper constantan thermocouples. Soil samples were taken to determine volumetric moisture content, and soil water potential, using the vapor pressure psychometer technique. The thermodynamic flow equation of Taylor and Cary, (1964) was used to calculate the hydro-thermal transfer coefficient (ß) as given by:

-ß = d(μ_w)_T / dlnT

where …

The Influence Of Irrigating With Saline Water On The Energy Status Of Water In Soil And Plant, Rolando H. Braun

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

1. Changes in the energy status of water that occurred in Milville silt loam and in bean (Phaseolus vulgaris L.) plants growing on it , during two consecutive 6-day periods while being irrigated with saline solutions, were studied.
2. Total soil water potential (Ψ soil) (measured with thermocouple psychrometers), matric-potential (Ψ_m) (measured with tensiometers) were considered. In leaf samples, the total water potential (leaf) and the osmotic potential (Ψ_π)--after freezing-- were determined with thermocouple psychrometers; by difference, the pressure potential (Ψ_p) was obtained.
3. There is no evidence of close relationship between changes taking place in …

The Seventy-Ninth Session Of The Iowa Academy Of Science And The Thirty-Fifth Convention Of The Iowa Junior Academy Of Science, April 21, 22, 1967, Iowa Academy Of Science

Iowa Academy of Science Documents

No abstract provided.

Development Of A Method For Measuring Magneto-Optical Rotatory Dispersion, Donald K. Loving

Masters Theses

No abstract provided.

Earthworms: Their Intensive Propagation And Use In Biological Soil Building - Part V, Thomas Barrett

Green Revolution

Reprint of section of book Earthworms by Thomas Barrett.

A Stratigraphic And Sedimentologic Analysis Of The Tongue River And Sentinel Butte Formations (Paleocene), Western North Dakota, Chester F. Royse Jr.

Theses and Dissertations

The Tongue River-Sentirel Butte contact has been regarded by many workers as a vague color boundary of minor extent within a relatively homogeneous sequence of Paleocene strata. Consequently, the Sentinel Butte has come to be regarded as a subordinate unit of the ”Tongue River Formation. As defined in report, the contact is a distinctive horizon between two discrete lithogenetic units. It characterized by three criteria: a horizon (HT Butte bad) &t the top of the Tongue River sequence; a. basal sandy unit in the Sentinel Butte sequence, and a marked change in color between buff yellow Tongue River sediments below …

An Investigation Of The Reaction Of Benzhydryl Chloride With Potassium T-Butoxide In Dmso, Lawson Gibson Wideman

Masters Theses

"The ultimate aim of this study was to elucidate the mechanism of formation of tetraphenylethylene from benzhydryl chloride and potassium t-butoxide in dimethyl sulfoxide. The development of a suitable technique for following the reaction rate and of an analytical method to determine the extent of the reaction became an important object in this project"--Introduction, page 2.

Analysis Of Trace Elements In River And Spring Waters, Faridoon Andeshire Namdarian

Masters Theses

"Methods for the analysis of trace elements in natural fresh waters were investigated.

Preconcentration of the water samples by reducing the volume and by using cation adsorption resins was studied. It was concluded that cation absorption was the more promising procedure.

The methods used for analysis were absorption spectrophotometry, neutron activation analysis, and atomic absorption spectrophotometry. Atomic absorption spectrophotometry was considered the most suitable method for the analysis of trace elements in waters.

Calcium, copper, lead, zinc, and cadmium were determined in a number of Missouri springs and stream water samples"--Abstract, page ii.

Finite Difference Solutions To Free-Surface Flow Through Nonhomogeneous Porous Media, Roland W. Jeppson

Reports

No abstract provided.

Application Of An Electronic Analog Computer To The Problems Of River Basin Hydrology, J. Paul Riley, Duane G. Chadwick

Reports

As demands upon available water supplies increase, there is an accompanying increase in the need to assess the downstream consequences resulting from chances at specific locations within a hydrologic system. This problem was approached by electronic analog simulation of the hydrologic system. The complexity of a hydrologic model depends to a large extent upon the magnitude of the time and spatial increments utilized in the model. The increment size selected depends upon the types of problems to be solved. Three models are described, and in each succeeding model the definition in terms of time and/or space is improved. While the …