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Electrochemical Investigations Of The Mechanisms Of Reduction Of Benzaldehyde Compounds In Sulfolane, Neal Russell Armstrong

Chemistry and Chemical Biology ETDs

The mechanisms of the reduction of benzaldehyde and several sub­stituted benzaldehydes in the dipolar, aprotic solvent sulfolane, have been investigated. A combination of cyclic voltammetry, transmission spectroelectrochemistry and ring-disk voltammetry was used in this study. Cyclic voltammetric studies indicated that the one-electron benz­aldehyde reduction was followed by a dimerization of the radical anion intermediate to the pinacol. The reduction peak potentials of the benzaldehydes were cathodically shifted in sulfolane compared to values obtained in aqueos media. This indicates an increase in the benzaldehyde reduction energy in the aprotic solvent. The rate of the following chemical reaction was also slower than …

Water Current, Volume 6, No. 10, October 1974

Water Current Newsletter

From the Desk of the Director
Thanks Don for a Job Well Done
Deadline for Research Proposals
NWRRI Hosts Research in Action Conference
Learn About Nebraska's Water Quality
NWRRI Advisory Committee Meets
Director Lectures at Maine
Hydrologist Position Available
Forestry Chairman Sought
Wise Water Use Advocated
MRBC Director Sees Adequate Water for Planned Development
MRBC Committee on Energy and Environment
Energy Research and Development Adminstration Established
EPA Reports on Future Wastewater Treatment Plant Needs
New Criteria for EPA Grants
"Second America" Needs Discussed by USGS
Research Review: Disposal of Cattle Feedlot Runoff on Agricultural Land

Metabolic Capabilities Of Sulfur Oxidizing Bacteria And Their Role In Water Pollution, M. I. H. Aleem

KWRRI Research Reports

This report describes investigations into the physiology of microorganisms that are commonly involved in the oxidation of inorganic sulfur compounds. The metabolic activities of these bacteria play a potent role in several fields of economic importance such as strip mining operations, water pollution, corrosion, metallurgy, petroleum technology and soil fertility processes.

The oxidation of inorganic sulfur compounds was studied in the chemolithotrophs Thiobacillus denitrificans, Thiobacillus A₂, Thiobacillus neapolitanus, and a photolithotroph Rhodopseudomonas palustris. Cell suspensions from all of the thiobacilli catalyzed completely the oxidation of sulfide, thiosulfate, and sulfite to sulfate. The oxidation of thiosulfate in R. palustris …

Concerns Of Postnatal Mothers About Sexuality, Sheela A. Gideon

Loma Linda University Electronic Theses, Dissertations & Projects

An exploratory study was designed to find out what questions mothers had about postnatal sexuality. A questionnaire was prepared by the nurse researcher to find out answers to the following questions.

1. What specific questions do mothers have about sexual relations following delivery?
2. Do mothers feel free to initiate discussion about resumption of intercourse following delivery?
3. Do mothers like their husbands to be included in the discussion?
4. When do mothers prefer to receive information regarding sexual relationships following delivery?

The questionnaire was mailed to fifty primipara mothers between three and four weeks after delivery. Mothers with pronounced anemia, heart and lung …

Prenatal Instruction Of Breast Feeding Mothers, Anita Berry

Loma Linda University Electronic Theses, Dissertations & Projects

This experimental study tested the effect of prenatal instruction on the success of a group of mothers who desired to breast feed their infants. It was hypothesized that mothers receiving information on how to nurse their infants, how to prevent complications and how to cope with common problems of breast feeding would have a higher success rate than those not so instructed.

Criteria for success was that the mothers would have an adequate supply of milk to meet the nutritional demands of their infant without supplementation, would have fewer and less severe complications, and would express a higher degree of …

A Non-Procedural High-Level Language For Automated Design Of Application Systems, J. F. Nunamaker

Department of Computer Science Technical Reports

No abstract provided.

16th Annual Rocky Mountain Spectroscopy Conference

Rocky Mountain Conference on Magnetic Resonance

Final program and abstracts from the 16th annual meeting of the Rocky Mountain Spectroscopy Conference, sponsored by the Rocky Mountain Section of the Society for Applied Spectroscopy. Held in Denver, Colorado, August 5-6, 1974.

A Position Paper Of Environmental Education For Nelson County, Geneva B. Hunt

Masters Theses & Specialist Projects

The results of a survey, concerning environmental education taken of the educators of the Nelson County School System, indicated a need for environmental education workshops and classes.

The status of environmental education in the nation and in Kentucky were studied and compared. A research was done of the status of environmental education in Nelson County, and implications were drawn for implementing environmental education in the Nelson County School System.

A tentative program for implementing environmental education in the Nelson Country schools was given, and a bibliography of resources and materials to be used in said program was included.

Analysis Of Unsteady Flow Toward Artesian Wells By Three-Dimensional Finite Elements, Yang H. Huang, Shen-Jyh Wu

KWRRI Research Reports

A three-dimensional finite element computer program was developed for analyzing unsteady flow toward artesian wells. The program is designed especially for determining the drawdown around an artesian well penetrating fully or partially a nonhomogeneous and anisotropic aquifer of irregular shape and cross section. It can also be used as a general program for aquifer simulation and evaluation. A major advantage of the program lies in the minimum amount of input data required. By assuming the top and bottom boundaries of the aquifer as two arbitrary planes, the aquifer will be divided into six- or eight-node elements, and their nodal coordinates …

Water Current, Volume 6, No. 8, August 1974

Water Current Newsletter

Guest Editorial: Mandatory versus Voluntary, Dayle Williamson, Executive Secretary, Nebraska Natural Resources Commission
Deadlines for Research Projects
NWRRI Hosts Research in Action Conference
DEC Director Named
Nebraska Receives Discharge Elimination Report
Sewage Treatment Plant in Lincoln
Nebraska Drought
South Dakota Seeks Additional Missouri River Benefits
Main-Stem Water Marketing
OWRR Reorganized
ERTS Begins Third Year in Orbit
Sirotherm - An Australian Development for Purifying Water
Purpose, Policy and Objectives
Research Review: Alternatives in Area Management of Groundwater

Noise Pollution A Study In Kalamazoo, Michigan, William Thomas Williams

Masters Theses

No abstract provided.

Synthetic Analogs Of The Active Sites Of Iron-Sulfur Proteins. Viii. Some Electronic Properties Of [Fe4S4(Sr)4]3; Analogs Of Reduced Bacterial Ferredoxins, R. B. Frankel, T. Herskovitz, B. A. Averill, R. H. Holm, P. J. Krusic, W. D. Phillips

Physics

One-electron reduction of the synthetic tetramers [Fe₄S₄(SR)₄]^2- (R = CH₂Ph, Ph), by chemical and electrochemical methods affords the corresponding trianions. The collective results from optical, electron paramagnetic resonance, and Mössbauer spectroscopy, when compared to available data for reduced 4-Fe and 8-Fe ferredoxin proteins and super-reduced Chromatium high-potential protein, reveal that [Fe₄S₄(SR)₄]^3- are electronic analogs of the [Fe₄S₄(S-Cys)₄] active sites of these proteins.

The Monadnock Volume 48, June 1974, Clark University Geographical Society

The Monadnock (Clark Geographical Society)

Volume 48 of The Monadnock. The Monadnock was the alumni magazine of the Clark University Geographical Society (1927-1985) (2014-present).

Vibration Damping Characteristics Of Typical Harpsichord Strings, Jack Lee Simmons

Dissertations and Theses

Present-day builders of harpsichords disagree as to the use of iron or carbon-steel wire in their attempt to duplicate the tonal qualities of the early 16th century instruments. The variations in tone produced by vibrating iron and steel wires may be due, at least in part, to differences in their decay characteristics. A wire was set into vibration by placing a section in a magnetic field and passing a variable-frequency alternating current through it. A condition of resonance was established by appropriately selecting frequencies, lengths, and tensions that would simultaneously satisfy the relationship: fr = n/2L(T/p)1/2. Then measurements of decay …

The Energy Future: An Unanswered Question, Jeffrey A. Carver

Marine Affairs Theses and Major Papers

The purpose of the following paper is to examine broadly some of the implications of the energy shortage, in terms of the following: the new kinds of technology being developed to tap alternative energy sources; the relationship between the energy shortage and the soon-to-be-felt shortages of other resources; possible effects of the energy shortage upon efforts to protect the environment; and social implications of the inevitable limitation to economic and population growth, at least on this planet. The paper is presented in two parts. The first will be a brief discussion of the major elements of the problem and a …

Alternate Energy Removal Modes For Nuclear Power Reactors, Robert L. Carter

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

Attention is focussed upon the unique qualities of high energy fission particles, and upon the fundamental limits to the direct removal of their kinetic energy by electrostatic means and by cyclotron resonance deceleration. Efficiencies of secondary and tertiary product ionization and excitation produced by fission particles are examined. The potential for delivery of power through various non-thermal modes is discussed, and the significant unknowns relating thereto are identified.

An Overview Of Natural Gas Supply And Availability, D. E. Gibbs

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

Natural gas presently supplies almost one-third of the total U.S. energy supply--and like oil, has had its proven reserves reduced by ever-increasing production. The potential gas reserves of the United States are sufficient to maintain our present demand for a considerable period of time, if these reserves can be found. The exploration necessary has to be financed by increased gas cost. Additional technology will be necessary to increase the amounts of gas that can be produced from our present and future supplies. Several methods of obtaining the capital necessary to perform the additional drilling and areas of technical improvement are …

An Advanced Supervisory Indication, Control & Data Acquisition System, George W. Fox

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

Electric Utility systems in the United States double in growth every ten years. This growth necessitates the construction of substations in new areas and expansion of substations in existing areas.

Troubles quite often cannot be quickly and accurately diagnosed until a sufficient number of calls have been received from customers to establish a pattern.

This paper will describe an advanced supervisory system utilizing latest state-of-the-art electronic equipment interfaced with digital computers to provide the trouble dispatcher with a rapid update as to the status of his system at all times. He will also be able to remotely control his system …

Abstracts Of Papers Scheduled For Presentation At The 86th Session Of The Iowa Academy Of Science, April 19-20, 1974, Iowa Academy Of Science

Iowa Academy of Science Documents

Presentation abstracts from the annual meeting of the Iowa Academy of Science

The Tanker And Ocean Oil Pollution, Raymond Coombs

Marine Affairs Theses and Major Papers

It is now clear that the capacity of the oceans to accept some of the by-products of civilization is limited. The oceans can no longer be the world's sink, it we are to maintain the ecological viability of the biosphere. The dangers of the present situation are compounded by the difficulties in defining "marine pollution." Today's concern with pollution and its effects upon our way of life requires that the impact of ships on the marine environment be considered in order to minimize the risk that waterborne cargoes, particularly petroleum products, present to the ecology.

The Dilemma Of Deep Ocean Mining, Paul W. Dillingham Jr.

Marine Affairs Theses and Major Papers

Mineral substances and materials derived from them, whether in the form of fuels, construction materials, metals for farbication, tools, chemicals, or fertilizers, are the foundation of our technological civilization. The modern industrial civilization depends upon the continued availability of mineral raw materials. The problem is not one of actual scarcity ; the raw materials are there in the ground and in the sea in great supply. The question and the uncertainty is economic; How will these resources be recovered and by whom? This proposition becomes the central force in order to adjust to the new resources climate.

Macrocyclic Polyether Sulfide Syntheses, The Preparation Of Thia-Crown-3, 4, 6, And 7 Compounds, Yau-Kwong Joseph Hui

Theses and Dissertations

Macrocyclic polyether sulfides have been prepared by reacting an oligoethylene glycol dichloride with a dithiol or sodium sulfide in ethanol. The following new compounds were prepared: 1-thia-(9-crown-3), 1,4-dithia-(9-crown-3), 1,4-dithia-(12-crown-4), 1,4,7-trithia-(12-crown-4), 1-thia-(18-crown-6), I,4-dithia-(18-crown-6), 1,7-dithia-(18-crown-6), 1,4,7-trithia-(18-crown-6), 1,7-dithia-(21-crown-7), 1,4,7-trithia-(21-crown-7). Four other previously reported macrocyclic polyether sulfides were also prepared. The symmetry of the nmr spectra of these compounds give added evidence for the proposed ring structures. The following subjects were presented and discussed: studies of cyclization by-products, dependence of cyclization yield on the size of the rings, high dilution principle and its application, medium-sized rings, effect of hetero-atoms on cyclization and melting point …

Ua11/1/5 Hilltoppers In The News, Wku University Relations, Skip Church

WKU Administration Documents

Hilltoppers in the News radio program regarding the student fair and science fair.

Rabies Vector Control In Alberta, J.B. Gurba

Vertebrate Pest Conference Proceedings: 6th (1974)

Following the last serious outbreak of rabies in 1952-57, the province of Alberta remained virtually free of the disease for 13 years. In 1970 a sudden increase occurred with 16 cases in various species. The Alberta Central Rabies Control Committee was reactivated to cope with the situation. Pre-immunization of high risk personnel and domestic pets was initiated along with supportive research to monitor infection rates in various species. Vector control programs were established to stop the spread of rabies by known wildlife vectors, particularly skunks (Mephitis mephitis) which had brought rabies across the great plains to the Alberta-Saskatchewan …

Oxidation Reactions Of Unsaturated Hydrocarbons For Fuel Cells, James W. Johnson, William Joseph James, A. K. Agrawal

UMR-MEC Conference on Energy / UMR-DNR Conference on Energy

The anodic oxidation of unsaturated hydrocarbons has been the subject of numerous studies, primarily on Pt and Au electrodes at low temperatures, < 100°C. The complete oxidation to CO₂ is usually the predominant reaction with both H₂O and OH^- having been proposed as the oxygen source. Usually a single study consists of a comprehensive investigation of a single compound on a single electrode or a somewhat limited study of several compounds on a single electrode. A diversity of proposed mechanisms has resulted and is illustrated by the following summary.

Reduced Nicotinamide Adenine Dinucleotide Dehydrogenase, Piericidin Sensitivity, And Site 1 Phosphorylation In Different Growth Phases Of Candida Utilis, S. Grossman, John G. Cobley, T. P. Singer, H. Beinert

Chemistry Faculty Publications

Reports in the literature indicate that during the exponential phase of growth of Candida utilis NADH oxidation is insensitive to rotenone, that rotenone sensitivity is acquired during the transition to the late stationary phase and is again lost on catabolite repression. The acquisition and loss of rotenone sensitivity appears to be accompanied by similar changes in Site 1 phosphorylation but does not appear to be reflected in the rate of oxidation of NADH (by mitochondria) or of NAD-linked substrates (by mitochondria or whole cells). In the present paper evidence is presented that these fluctuations in sensitivity to inhibitors of NADH …

Ua35/11 Student Honors Research Bulletin, Vol. Ii, Wku Honors Program

WKU Administration Documents

Articles written by honors program students. They were originally research projects, class papers or essays written for academic credit, but in each case the student has done further work editing and improving his or her manuscript for this publication. The articles represent a broad range of interests and disciplines, and they indicate a healthy attempt on the part of at least some students to dig for deeper knowledge and understanding than is usually associated with undergraduate study.

• Greene, Bruce. The Traditional Fiddle Music of South-Central Kentucky
• Moody, Marlin. Some Effects of the Herbicide Glyphosate on Johnson Grass Rhizomes
• Jones, Larry. …

Blood And Tissue Identification Of Selected Birds And Mammals, Part 1, David W. Oates, Craig W. Brown, Debra L. Weigel

Other Publications in Wildlife Management

Identification of blood and tissue samples for law enforcement purposes was initiated in 1968 by Carl Wolfe, Senior Biologist, Research Division, Nebraska Game and Parks Commission. At that time and up to the present, a great deal of assistance, time and advice has been received from Carl R. Jolliff, Director of the Clinical Laboratory of Lincoln; Dr. Connell L. Marsh, Professor of Biochemistry, University of Nebraska, and Dr. Leonard W. Staudinger, Chairman of Biology Department, Nebraska Wesleyan University. Grateful appreciation is extended to Dr. Stan Cassel DVM and all Game Commission personnel of Nebraska and South Dakota who aided in …

A Study Of Oxomolybdenum Chelate Compounds Of Oxidation States (V) And (Iv) When Prepared By Photochemical Reduction Of Oxomolybdenum (Vi) Complexes In Ethanol Under Inert Atmosphere And By Chemical Reduction, Richard Donald Dendinger

Electronic Theses and Dissertations

A photolysis system was designed for meticulous exclusion of oxygen and moisture. Photolyzed ethanol solutions of dioxobis(acetylacetonato)­-molybdenum(VI), Mo0₂ (acac)₂, were studied via preparation of derivatives with several uninegative bidentate ligands (chelH, cysteine was designated cystH₂) and pyridine (py). Infrared spectroscopy was a useful tool in identifying these compounds. An oxomolybdenum(IV) compound, MoO(dtc)₂ was isolated from the red photolyzed solution when dtc was the N,N-diethyldithiocarbamate ion. Tropolone, 8-hydroxyquinoline, N,N-diethyldithiocarbamate, and cysteine formed products formulated as the dioxo bridged molybdenum(V) compounds, Mo₂0₄(che1)₂. Acetylacetone, tropolone, 8-Hydroxyquinoline and N,N-diethyldithiocarbamate, formed derivatives formulated …

Fresnel Drag In Uniformly Moving Media, William F. Parks, J. T. Dowell

Physics Faculty Research & Creative Works

A general first-order formula is derived for the Fresnel-drag effect in a uniformly moving medium with a plane surface. The two classical equations due to Lorentz and Laub are shown to be special cases corresponding to different experimental arrangements. The recent experiment of Bilger and Zavodny on Fresnel drag in a ring laser is discussed. © 1974 The American Physical Society.