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Computational Design Of Nanoporous Materials For The Adsorption Of Per- And Polyfluoroalkyl Substances, Daniel D. Mottern Dec 2025

Computational Design Of Nanoporous Materials For The Adsorption Of Per- And Polyfluoroalkyl Substances, Daniel D. Mottern

Dissertations

Per- and polyfluoroalkyl substances (PFAS) are a large family of chemicals that have seen wide usage due to their fluorinated carbon backbone. The presence of strong C-F bonds in the backbone lends PFAS molecules high thermal and chemical stability, as well as strong hydrophobicity and lipophobicity. This combination of properties has led to heavy use of PFAS as surfactants, non-stick coatings, and aqueous foam forming films and flame retardants. However, these properties bring their own consequences. The high chemical and thermal stability of PFAS renders them persistent, with the C-F bonds resisting naturally occurring forms of degradation. Existing forms of …


Empowering Youth In A Changing Climate: Design, Implementation, And Evaluation Of A Salt Marsh Summer Science Program, Dan Levesque Dec 2025

Empowering Youth In A Changing Climate: Design, Implementation, And Evaluation Of A Salt Marsh Summer Science Program, Dan Levesque

Graduate Masters Theses

Climate change presents not only environmental challenges but also emotional challenges for today’s youth. This thesis documents the design, implementation, and evaluation of a field-based summer science program aimed at empowering adolescents with coastal salt marsh ecology while addressing climate change emotions and science identity development. The program, based in a Massachusetts salt marsh, was adapted from existing public environmental curricula and guided by place- and experience-based learning principles. Over Spring and Summer 2025, 13 students (ages 13-18) participated in extra-curricular field trips, hands-on research activities, and reflective discussions about the environment and the emotions it brings forth. Pre- and …


Patterns Of Llm Weaponization: A Comparative Analysis Of Exploitation Incidents Across Commercial Ai Systems, George Antoniou Dec 2025

Patterns Of Llm Weaponization: A Comparative Analysis Of Exploitation Incidents Across Commercial Ai Systems, George Antoniou

Faculty and Staff Publications & Presentations

This comparative study examines patterns of Large Language Model (LLM) weaponization through systematic analysis of four major exploitation incidents spanning from 2023-2025. While existing research focuses on isolated incidents or theoretical vulnerabilities, this study provides one of the first comprehensive comparative frameworks analyzing exploitation patterns across state-sponsored cyber-espionage (Anthropic Claude incident), academic security research (GPT- 4 autonomous privilege escalation), social engineering platforms (SpearBot phishing framework), and underground criminal commoditization (WormGPT/FraudGPT ecosystem). Through comparative analysis across eight dimensions: Adversary sophistication, target selection, exploitation techniques, autonomy levels, detection evasion, attribution challenges, defensive gaps, and capability democratization, this research identifies critical cross-case patterns …


From Enhancement To Substitution: A Strategic Provocation On Simulation-Based Sport, Grant B. Morgan, Andreas Stamatis Dec 2025

From Enhancement To Substitution: A Strategic Provocation On Simulation-Based Sport, Grant B. Morgan, Andreas Stamatis

Journal of Applied Sport Management

Advances in artificial intelligence, large-scale machine learning, and simulation technologies are rapidly transforming how sport is played, analyzed, and consumed. To date, most scholarly and industry discussions frame these technologies as tools that enhance embodied sport by improving performance, officiating, media production, and fan engagement. This paper extends that conversation by posing a more provocative strategic question: under what conditions might simulation move from enhancement to substitution? Focusing explicitly on sport as a business and entertainment enterprise, we argue that many of sport’s core sources of cultural and economic value—uncertainty of outcome, narrative continuity, legitimacy, and collective meaning—are structurally …


Role-Playing Game Studies: A Transmedia Approach Por José Pablo Zagal, Y Sebastian Deterding, (Editores). (2018). [Reseña], Cristo Leon, Edgar Meritano Dec 2025

Role-Playing Game Studies: A Transmedia Approach Por José Pablo Zagal, Y Sebastian Deterding, (Editores). (2018). [Reseña], Cristo Leon, Edgar Meritano

Journal of Roleplaying Studies and STEAM

"Role-Playing Game Studies: A Transmedia Approach," editado por José P. Zagal y Sebastian Deterding (2018b), es una recopilación exhaustiva del estado actual de la investigación sobre los juegos de rol a través de diversas disciplinas, culturas y medios. El libro traza la historia de los juegos de rol desde sus precursores en los juegos de guerra (wargames) hasta los juegos de mesa (Tabletop), el juego de rol en vivo (live-action role-play), y los juegos de rol contemporáneos de computadora y en línea. Cada capítulo ofrece perspectivas y hallazgos de disciplinas clave como …


Journal Of Roleplaying Studies And Steam (Jrpssteam) Vol. 4 [2025], Número 2 (Issue 2), Cristo Leon, Romano Ponce-Díaz Phd, Ivan Avila Gonzalez Phd, James Lipuma Dr., Bruce G. Bukiet, Ricardo Victoria-Uribe, Nazario Robles-Bastida, Chris Birmingham, Ximena Diaz Santillan, Edgar Francisco Vázquez Martínez He, Jorge Prieto Terrones, Juan Carlos C. González Vidal S, Edgar Meritano, Laura Magela Garcés Ramírez Dec 2025

Journal Of Roleplaying Studies And Steam (Jrpssteam) Vol. 4 [2025], Número 2 (Issue 2), Cristo Leon, Romano Ponce-Díaz Phd, Ivan Avila Gonzalez Phd, James Lipuma Dr., Bruce G. Bukiet, Ricardo Victoria-Uribe, Nazario Robles-Bastida, Chris Birmingham, Ximena Diaz Santillan, Edgar Francisco Vázquez Martínez He, Jorge Prieto Terrones, Juan Carlos C. González Vidal S, Edgar Meritano, Laura Magela Garcés Ramírez

Journal of Roleplaying Studies and STEAM

En una sesión de juego por medio del registro lingüístico se organiza la escena, se orienta la manera de nombrar las tareas, se distribuyen los roles actanciales, se establecen la expectativas; por lo tanto, se establece una puesta en escena. De tal forma, las prácticas lúdicas y ficcionales se configuran a partir de nuestra mirada del mundo e irremediablemente también reconfiguran esa misma mirada. El ser y el estar en un espacio es la especificidad mediática fundamental de los juegos de rol; dicho de otra manera, en los sistemas de juego de rol dentro de sus universos narrativos, en su …


Electrochemical Characterization And Modulation Of Biological Processes, Yue-Qi Li, Wei-Hua Huang, De-Chen Jiang, Bao-Hong Liu, Bin Su, Yang Tian, Jing-Juan Xu, Ping Yu, Feng Zhao, Huang-Xian Ju, Jing-Hong Li Dec 2025

Electrochemical Characterization And Modulation Of Biological Processes, Yue-Qi Li, Wei-Hua Huang, De-Chen Jiang, Bao-Hong Liu, Bin Su, Yang Tian, Jing-Juan Xu, Ping Yu, Feng Zhao, Huang-Xian Ju, Jing-Hong Li

Journal of Electrochemistry

Electrochemical processes lie at the core of biological function, governing energy transduction, metabolic flux, and molecular signaling. Recent advances in electrochemical science now allow these processes to be probed and controlled with unprecedented spatial, temporal, and chemical resolution. In this review, we present an integrated framework that progresses from fundamental mechanisms to analytical technologies and functional modulation. We begin by outlining electron transfer pathways in mitochondrial respiration, microbial extracellular electron transfer, and DNA- and protein-based charge conduction, followed by the principles of photon-electron conversion in photosynthesis and the central role of redox equilibrium in coordinating cellular responses. We then highlight …


Review Of Video Steganography By Using Deep Learning Methods: Datasets, Techniques, And Evaluations, Noor Fahem Sahib, Soukaena Hassan Hashem, Ekhlas Falih Naser Dec 2025

Review Of Video Steganography By Using Deep Learning Methods: Datasets, Techniques, And Evaluations, Noor Fahem Sahib, Soukaena Hassan Hashem, Ekhlas Falih Naser

Journal of Soft Computing and Computer Applications

The growing prevalence of cyber threats, including fraud and attacks, has intensified the demand for secure methods of safeguarding confidential information exchanged between users. As telecommunications increasingly rely on multimedia data, video steganography has become a prominent technique to address these concerns. By embedding sensitive data within video files, this approach enhances protection against unauthorized access and common internet-based attacks, offering a robust layer of security in an era of escalating digital risks. With the introduction of Deep Learning (DL) steganography methods recently, video steganography can be defined as a rapidly developing subject within information security. This study provides a …


Hate Speech Detection Using Optimized Feature Representation Via Spiral-Grey Wolf Optimizer-Based Machine Learning Approaches, Noor S. Farhan, Matheel E. Abdulmunim, Hasanen S. Abdullah Dec 2025

Hate Speech Detection Using Optimized Feature Representation Via Spiral-Grey Wolf Optimizer-Based Machine Learning Approaches, Noor S. Farhan, Matheel E. Abdulmunim, Hasanen S. Abdullah

Journal of Soft Computing and Computer Applications

Hate speech detection is crucial as social media diversifies. This research present a lightweight, scalable system using traditional machine learning methods along with a new approach called Spiral-Grey Wolf Optimizer (S-GWO).

S-GWO effectively selects key features that consider both meaning and content from the Term Frequency Inverse Document Frequency (TF-IDF) space, leading to high-quality representation without excessive computing power.

The propoused system was tested on Arabic and another English datasets using six machine learning methods: SVM, RF, LR, KNN, NB, and SGD. It achieved 92% accuracy and F1 score on the Arabic dataset, while reaching 100% accuracy on the English …


(R2164) The Nature Of The Big Bang Singularity In Inhomogeneous Szekeres Cosmological Frameworks, Ahmed M. Al-Haysah, Abdul-Majeed Al-Izeri Dec 2025

(R2164) The Nature Of The Big Bang Singularity In Inhomogeneous Szekeres Cosmological Frameworks, Ahmed M. Al-Haysah, Abdul-Majeed Al-Izeri

Applications and Applied Mathematics: An International Journal (AAM)

Without killing vector fields, the Szekeres metric is an explicit example of an anisotropic and inhomogeneous solution to the Einstein equations. The inhomogeneous Szekeres cosmological models (ISCM) within the Big Bang singularity (BBS) are obtained. This indicates that the Szekeres solution represents a more general class of exact solutions. It is known to exhibit axial symmetry. We investigate a Big Bang theory of the cosmos, which unexpectedly predicts that the universe started at the so-called BBS a finite length of time ago. A growing number of astrophysical researchers are using inhomogeneous extensions of the Friedmann-Lemaitre-Robertson-Walker (FLRW) solution and, by extension, …


Novel Spectrophotometric Method For The Determination Of Paclitaxel Through Complex Formation With Osmium, Basima A.A.Saleem, Salim A. Mohammed, Amer Th. Al-Taee Dec 2025

Novel Spectrophotometric Method For The Determination Of Paclitaxel Through Complex Formation With Osmium, Basima A.A.Saleem, Salim A. Mohammed, Amer Th. Al-Taee

Turkish Journal of Chemistry

Paclitaxel (Pac) is an important anticancer bioactive compound, and the availability of an accurate and robust analytical method for its quantification is of utmost importance. In this investigation, a novel, direct, and reliable spectrophotometric method has been proposed for the estimation of Pac via a complex formation reaction with osmium (Os). The method was based on the reaction of Pac with Os tetroxide, which produced a yellowish-brown complex. The resulting complex is soluble in water and displays a maximum absorption peak at 482 nm. The reaction conditions, including reactant concentration, pH, temperature, and reaction time, were optimized to obtain the …


Synthesis, Characterization, Antimicrobial, Antioxidant, And Antiinflammatory Evaluation And Molecular Docking Studies Of N-((2-Hydroxy-3-(2-(Substitutedbenzylidene)Hydrazine-1-Carbonyl)Naphthalen-1-Yl)(3-Nitrophenyl/3,4-Dimethoxyphenyl)Methyl)Acetamide Derivatives, Shikha Kamboj, Alka Yadav, Samridhi Thakral, Rekha Tanwar, Sunil Kumar, Vikramjeet Singh Dec 2025

Synthesis, Characterization, Antimicrobial, Antioxidant, And Antiinflammatory Evaluation And Molecular Docking Studies Of N-((2-Hydroxy-3-(2-(Substitutedbenzylidene)Hydrazine-1-Carbonyl)Naphthalen-1-Yl)(3-Nitrophenyl/3,4-Dimethoxyphenyl)Methyl)Acetamide Derivatives, Shikha Kamboj, Alka Yadav, Samridhi Thakral, Rekha Tanwar, Sunil Kumar, Vikramjeet Singh

Turkish Journal of Chemistry

Hydrazone chemistry has become important and plays a key role in the development of organic compounds. Hydrazones can be useful pharmacophores for creating novel derivatives, owing to their broad range of activities. In this study, a series of N-((2-hydroxy-3-(2-(substitutedbenzylidene)hydrazine-1-carbonyl)naphthalen-1-yl)(3-nitro-phenyl/3,4-dimethoxyphenyl)methyl)acetamide derivatives were prepared, characterized by FTIR, 1H-NMR, 13C-NMR, and mass spectroscopy, and evaluated for their antimicrobial, antiinflammatory, and antioxidant activities along with in silico studies. The substituted derivatives were synthesized by the reaction of acetonitrile, chlorosulphonic acid, and substituted benzaldehyde with the hydrazones. The antimicrobial evaluation showed that compound 3i had more antimicrobial potential than the other tested molecules. Compound 3j …


Enhancing Analytical Performance Of Tyrosinase-Based Sensors With Nanoparticles For Detection Of Isoproterenol, Aysel Oktay, Sevi̇nç Kurbanoğlu, Gülsüm Gündoğdu, Cem Bülent Üstündağ, Frieder W. Scheller, Aysu Yarman Dec 2025

Enhancing Analytical Performance Of Tyrosinase-Based Sensors With Nanoparticles For Detection Of Isoproterenol, Aysel Oktay, Sevi̇nç Kurbanoğlu, Gülsüm Gündoğdu, Cem Bülent Üstündağ, Frieder W. Scheller, Aysu Yarman

Turkish Journal of Chemistry

In this work, electrochemical biosensors utilizing tyrosinase (Tyr) for the detection of the nonselective beta-adrenergic agonist isoproterenol (ISO) are presented. Three different configurations for immobilizing Tyr on a graphite electrode (GE) are compared: (1) GE modified with poly(diallyldimethylammonium chloride) (PDADMAC), PDADMAC/Tyr/GE; (2) PDADMAC combined with iridium nanoparticles (IrNPs) in a stepwise preparation, resulting in PDADMAC/IrNPs/Tyr/GE; and (3) a composite of PDADMAC and IrNPs mixed with Tyr at a 1:1 (v:v), forming PDADMAC/(IrNPs-Tyr)/GE. Surface morphology was characterized using scanning electron microscopy (SEM). Cyclic voltammetry (CV) and amperometry were applied to characterize the biosensor’s performance. Within the linear range of 5 μM …


Synthesis Of Biogenic Silver Nanoparticles From Apricot Kernel Extracts For The Colorimetric Determination Of Gold, Ayça Gi̇rgi̇n, Hi̇lal Akbiyik, Buse Tuğba Zaman, Omid Nejati, Ayça Bal Öztürk, Gülten Çeti̇n, Sezgi̇n Bakirdere Dec 2025

Synthesis Of Biogenic Silver Nanoparticles From Apricot Kernel Extracts For The Colorimetric Determination Of Gold, Ayça Gi̇rgi̇n, Hi̇lal Akbiyik, Buse Tuğba Zaman, Omid Nejati, Ayça Bal Öztürk, Gülten Çeti̇n, Sezgi̇n Bakirdere

Turkish Journal of Chemistry

Gold is abundant in nature, however, precise and reliable analytical methods for its detection are required stemming from its increasing prevalence in environmental, biological, and industrial systems, as well as the growing interest in understanding its function in living organisms and its effects on human health. This study investigates the use of biogenically synthesized silver nanoparticles (AgNPs) for the preconcentration and determination of gold ions prior to determination by UV-Vis spectrophotometry. AgNPs were synthesized by reducing silver nitrate through the use of an apricot kernel extract as both reducer and stabilizer agent. The colloidal yellowish AgNPs interacted with gold ions, …


Efficient Recovery Of Y3+ From Aqueous Media Using Mdlm Technique:Transport Behavior And Kinetic Modeling, Volkan Demi̇rel, Ramazan Donat, Hacer Şensöz Dec 2025

Efficient Recovery Of Y3+ From Aqueous Media Using Mdlm Technique:Transport Behavior And Kinetic Modeling, Volkan Demi̇rel, Ramazan Donat, Hacer Şensöz

Turkish Journal of Chemistry

This study investigates the extraction behavior of Y³⁺ ions using a Multi-Dropped Liquid Membrane (MDLM) system that employs di(2-ethylhexyl) phosphoric acid (D₂EHPA) as the carrier ligand. The focus is on the system’s ability to transport ions between aqueous phases selectively. The extracted complex was analyzed spectrophotometrically via ultraviolet–visible (UV–Vis) measurements after complexation with 0.05% Arsenazo III. The aim of this study was to determine the influence of the optimum D₂EHPA carrier concentration, together with the pH and temperature conditions of the donor and acceptor phases, on the system’s extraction performance. Accordingly, a series of extraction experiments was performed at different …


Bioorganometallic Tagging Of N-Acetylhistamine With An Fe(Co)₃ Unit: Synthesis, X-Ray Structure, And Protonation Behavior, Salah Merniz, Louiza Himed, Rofia Djerri, Belkis Akachat Dec 2025

Bioorganometallic Tagging Of N-Acetylhistamine With An Fe(Co)₃ Unit: Synthesis, X-Ray Structure, And Protonation Behavior, Salah Merniz, Louiza Himed, Rofia Djerri, Belkis Akachat

Turkish Journal of Chemistry

This study highlights the potential of organometallic carbonyl complexes as selective markers for biomolecules, enabling sensitive infrared (IR) detection. The regio- and stereoselective coupling of N-acetylhistamine, a histidine analogue, with the precursor complex 1 [Fe(CO)₃(1,4-η⁵-N-pyridiniocyclohexa-1,3-diene)] BF₄ affords the labeled complex 3 [Fe(CO)₃(1,4-η⁵-N-acetylhistaminocyclohexa-1,3-diene)]. X-ray diffraction (XRD) confirms the exo stereochemistry and reveals a rigid, well-defined architecture. IR and 1H nuclear magnetic resonance spectroscopic studies combined with IR-monitored acid–base titration demonstrate the complex’s stability in aqueous media between pH 5 and 8, alongside a modest increase in basicity relative to the free ligand. These findings establish the Fe(CO)₃ moiety as a robust …


A Method For Advance Detection Of Underground Concealed Water Hazards In Coal Mines Based On Borehole Transient Electromagnetic Method And Vector Synthesis, Fan Tao, Hao Yue, Li Ping, Zhao Rui, Liu Zaibin, Ma Liang, Li Peng, Yan Junsheng Dec 2025

A Method For Advance Detection Of Underground Concealed Water Hazards In Coal Mines Based On Borehole Transient Electromagnetic Method And Vector Synthesis, Fan Tao, Hao Yue, Li Ping, Zhao Rui, Liu Zaibin, Ma Liang, Li Peng, Yan Junsheng

Coal Geology & Exploration

Background The advance detection of underground concealed water hazards in coal mines is crucial to ensuring the safe and efficient roadway tunneling. The borehole transient electromagnetic (TEM) method allows for long-distance advance detection. However, due to the limitation of the spatial structure of boreholes, currently available techniques can only effectively identify low-resistivity anomalies (e.g., water-bearing structures) in the radial direction, leaving blind areas in the primary tunneling direction (i.e., the axial direction of boreholes). Objective and Method To address this challenge, this study proposed a method for the advance detection of concealed water hazards in the axial direction of boreholes …


Investigating Surface-Borehole Transient Electromagnetic Responses From Veined Orebodies Considering Induced Polarization Effects, Li Jianhui, Wang Yao, Wang Wenchuang, Xie Shaojian, Zhu Siwei Dec 2025

Investigating Surface-Borehole Transient Electromagnetic Responses From Veined Orebodies Considering Induced Polarization Effects, Li Jianhui, Wang Yao, Wang Wenchuang, Xie Shaojian, Zhu Siwei

Coal Geology & Exploration

Objective The observational data derived using the surface-borehole transient electromagnetic (TEM) method tend to feature complex curve morphologies, a problem posing significant challenges to data processing and interpretation. This study aims to ascertain the mechanisms behind the generation of such complex responses using forward modeling.Methods Using the vector finite element-based spectral method and the Cole-Cole model, this study developed a 3D forward modeling technique incorporating the induced polarization (IP) effect. By constructing a typical theoretical model of low-resistivity veined orebodies, it systematically analyzed the electromotive force (EMF) responses excited by transmitter loops at different orientations. Results and Conclusions The …


Performance And Migration Path Tracing Of Magnetic Grouts For Fractured Rock Masses, Shang Hongbo, Wang Hao, Wang Xiaodong, Qiao Wei, Wang Tiantian, Sun Junqing, Sun Jie Dec 2025

Performance And Migration Path Tracing Of Magnetic Grouts For Fractured Rock Masses, Shang Hongbo, Wang Hao, Wang Xiaodong, Qiao Wei, Wang Tiantian, Sun Junqing, Sun Jie

Coal Geology & Exploration

Objective For coal mining areas in the middle reaches of the Yellow River basin, sealing mining-induced fractures via grouting serves as an effective approach to preventing water inrushes from coal seam roofs while also protecting groundwater resources. However, accurately identifying the migration paths of grouts remains a bottleneck for the further application of grouting modification technology to fractured rock masses. Methods This study investigated a coal mine threatened by both water inrushes from the coal seam roof and a short supply of water resources within the Jurassic coalfield in the middle reaches of the Yellow River basin, focusing on the …


Application Of Long-Distance Tunneling And Detection For Advance Detection In Excavation Using Shield Tunneling Machines, Chen Chao, Li Ping, Li Wei, Wei Rong Dec 2025

Application Of Long-Distance Tunneling And Detection For Advance Detection In Excavation Using Shield Tunneling Machines, Chen Chao, Li Ping, Li Wei, Wei Rong

Coal Geology & Exploration

Objective and Method During the rapid excavation process using shield tunneling machines in coal mines, the advance detection of concealed geological anomalies encounters challenges of limited space and insufficient accuracy. To overcome these issues, this study investigated highly-located drainage roadway 3211 in the Tiandi Wangpo Coal Mine in Jincheng City, Shanxi Province using the long-distance tunneling and detection technology, the core of which is long directional boreholes combined with comprehensive borehole geophysical prospecting. This roadway is located in the roof of the No.3 coal seam, and it is necessary to conduct shield construction in the stable sandstone layer located from …


A Method For Interpretating Acoustic Reflection Imaging Logging Data Of Fractured-Vuggy Reservoirs Based On Their Theoretical Response Characteristics, Huang Ruokun, Jiang Kai, Wu Xingneng, Ma Kunyu, Su Yuanda, Wang Bing, Chen Xu Dec 2025

A Method For Interpretating Acoustic Reflection Imaging Logging Data Of Fractured-Vuggy Reservoirs Based On Their Theoretical Response Characteristics, Huang Ruokun, Jiang Kai, Wu Xingneng, Ma Kunyu, Su Yuanda, Wang Bing, Chen Xu

Coal Geology & Exploration

Objective During the exploration and development of fractured-vuggy carbonate reservoirs, acoustic reflection imaging logging technology enables the detection of fractured-vuggy bodies around wells. However, this technology suffers from unclear response characteristics and a strong multiplicity of solutions. Focusing on the Tarim Oilfield, this study aims to establish a tailored interpretation method by integrating geological and geophysical characteristics. The purpose is to enhance the identification accuracy and reliability of fractured-vuggy bodies in these reservoirs. Methods Based on the distribution characteristics of fractured-vuggy carbonate reservoirs in the Tarim Oilfield, this study established the numerical simulation models of three typical fractured-vuggy bodies: inter-breccia …


Co2-Water Displacement Characteristics Of Saturated Sandstones With Different Pore Structures, Liu Ting, Li Jinglin, Li Yi, Dan Wendong, Diao Yujie, Ma Xin Dec 2025

Co2-Water Displacement Characteristics Of Saturated Sandstones With Different Pore Structures, Liu Ting, Li Jinglin, Li Yi, Dan Wendong, Diao Yujie, Ma Xin

Coal Geology & Exploration

Objective The pore structures of clastics play a crucial role in assessing the potential of saline aquifers for geologic CO2 sequestration. Current studies on pore structures during CO2 sequestration focus primarily on artificial cores. However, compared to artificial cores, natural cores feature more complex pore size distributions and stronger heterogeneity. Methods This study examined a natural core from deep reservoirs in the Ordos Basin and two artificial cores with different porosities through CO2-water displacement experiments under water-saturated conditions. Using a nuclear magnetic resonance (NMR) analysis and imaging system for multiphase fluid displacement, this study analyzed the …


Multi-Field Coupling-Based Numerical Simulations Of Co2 Storage In Saline Aquifers: A Case Study Of The Dingji Coal Mine, Huainan Mining Area, Li Dianshang, Zheng Sijian, Liao Qingfa, Miao Wei, Tian Yuchen, Zhang Helong, Liu Yanzhi, Liu Shiqi Dec 2025

Multi-Field Coupling-Based Numerical Simulations Of Co2 Storage In Saline Aquifers: A Case Study Of The Dingji Coal Mine, Huainan Mining Area, Li Dianshang, Zheng Sijian, Liao Qingfa, Miao Wei, Tian Yuchen, Zhang Helong, Liu Yanzhi, Liu Shiqi

Coal Geology & Exploration

Background Saline aquifers are characterized by extensive distribution, abundant reserves, and substantial potential for CO2 storage, establishing them as the most promising geological media for carbon capture, utilization, and storage (CCUS). CO2 storage in saline aquifers plays a crucial role in mitigating the greenhouse effect and achieving the goals of peak carbon dioxide emissions and carbon neutrality. Thoroughly investigating CO2 storage in deep saline aquifers within the Huainan mining area helps alleviate the regional pressure of carbon emission reduction while also providing important support for expanding the technical pathways of CCUS and promoting its engineering applications. Methods …


Environmental Risk Assessment Of Co2 Storage Combined With The Overlying Coal Mining, Gu Leiyu, Li Wenhui, Huang Wei, Zhou Quanchao, Zhu Yalong, Li Xiaying, Liu Guizhen, Li Qi Dec 2025

Environmental Risk Assessment Of Co2 Storage Combined With The Overlying Coal Mining, Gu Leiyu, Li Wenhui, Huang Wei, Zhou Quanchao, Zhu Yalong, Li Xiaying, Liu Guizhen, Li Qi

Coal Geology & Exploration

Objective Carbon capture, utilization, and storage (CCUS) technology serves as a key method for carbon neutrality. However, large-scale engineering applications of CCUS are still confronted with serious challenges of environmental risks. Therefore, systematic environmental risk assessment plays an essential role in ensuring the environmental safety and social acceptability of CO2 geological storage projects. Methods Targeting the CO2 geological storage project combined with overlying coal mining in Zhengning County, Gansu Province, this study performed the environmental risk assessment of CO2 leakage based on the requirements of the Technical Guideline on Environmental Risk Assessment for Carbon Dioxide Capture, Utilization, …


Physical Simulation Experiments On 4d Visualization Of Dynamic Methane Diffusion And Adsorption In Low-Porosity And Low-Permeability Coals, Liu Tong, Jiao Baizhuo, Lin Baiquan, Sang Shuxun, Yang Wei, Liu Shiqi, Liu Ting, Li He, Yang Mingxing Dec 2025

Physical Simulation Experiments On 4d Visualization Of Dynamic Methane Diffusion And Adsorption In Low-Porosity And Low-Permeability Coals, Liu Tong, Jiao Baizhuo, Lin Baiquan, Sang Shuxun, Yang Wei, Liu Shiqi, Liu Ting, Li He, Yang Mingxing

Coal Geology & Exploration

Objective and Method The diffusivity of methane (CH4) in coal seams significantly influences the surface extraction of coalbed methane (CBM) and underground gas drainage. However, the visualized characterization of the diffusion and migration processes of CH4 in coals remains challenging. To address this issue, this study systematically demonstrated the similarity between krypton (Kr) and CH4 in their adsorption and diffusion behavior in coals. Utilizing Kr—a gas with high X-ray attenuation—as a tracer substitute for CH4, this study achieved the transparent observation of the dynamic gas migration process in low-porosity, low-permeability, and heterogeneous coals using …


Water Quality Characteristics And Reutilization Of Goaf Water From Shallow Coal Seams Within The Datong Mining Area, Shanxi Province, China, Li Jun, Gui Herong, Ding Pengfei, Chen Yongqing, Wan Heyong, Li Weiqi, Huang Dawei, Peng Weihua, Hu Yang, Guo Yan Dec 2025

Water Quality Characteristics And Reutilization Of Goaf Water From Shallow Coal Seams Within The Datong Mining Area, Shanxi Province, China, Li Jun, Gui Herong, Ding Pengfei, Chen Yongqing, Wan Heyong, Li Weiqi, Huang Dawei, Peng Weihua, Hu Yang, Guo Yan

Coal Geology & Exploration

Objective The Datong mining area in Shanxi Province of China faces serious threats from goaf water hazards, while the goaf water drainage is constrained by environmental protection policies. Therefore, the reutilization of goaf water serves as an effective approach to eliminating mine water hazards, protecting water environments, and mitigating water scarcity in the mining area. Methods This study investigated goaf water from shallow coal seams in the Datong mining area. Based on water quality assessment theories and a range of hydrogeochemical indices, including saturation index (SI), chloro-alkaline index (CAI), and sodium adsorption ratio (SAR), this study conducted a joint determination …


Advances In Research And Future Prospects Of Borehole Geophysical Prospecting Technology For Coal Mines, Li Ping, Wei Rong, Fan Tao, Zhao Rui, Jiang Bici, Tian Xiaochao, Wang Bingchun Dec 2025

Advances In Research And Future Prospects Of Borehole Geophysical Prospecting Technology For Coal Mines, Li Ping, Wei Rong, Fan Tao, Zhao Rui, Jiang Bici, Tian Xiaochao, Wang Bingchun

Coal Geology & Exploration

Background Borehole geophysical prospecting technology for coal mines integrates the advantages of both drilling and geophysical prospecting. Accordingly, multiple critical advances have been achieved in its applications to the technologies and equipment for intelligent coal mining in recent years, enabling long-distance, relatively high-precision geological exploration. This technology plays an increasingly important role in a range of fields, including deep mineral resource exploration and the reconnaissance surveys of hidden disaster-causing factors, providing robust support for safe and efficient coal mining. Advances This study systematically reviews the development history of borehole geophysical prospecting technology, elaborating advances in research on the methodology, theories, …


Mathematical Modeling Of Awareness-Driven Interventions For Gender-Based Violence Control In A Closed Population, Furaha M. Chuma, Edward K. Ngailo, Zubeda S. Mussa Dec 2025

Mathematical Modeling Of Awareness-Driven Interventions For Gender-Based Violence Control In A Closed Population, Furaha M. Chuma, Edward K. Ngailo, Zubeda S. Mussa

Tanzania Journal of Science

Gender-based violence (GBV) remains a critical global health issue with profound social, economic, and psychological implications. Despite concerted efforts to address this challenge, traditional intervention approaches often fall short of effectively mitigating its prevalence. In recent years, there has been growing recognition of the potential impact of awareness-based interventions in addressing various social and health crises. This paper introduces a modeling framework to explore the efficacy of awareness-based interventions in influencing the dynamics of the GBV epidemic within a closed population. A detailed sensitivity analysis, utilizing a normalized sensitivity index method, reveals that the violence transfer rate between perpetrators and …


Fast Dispersion-Curve Inversion Using Automatic Differentiation Gradient-Based Calculation, Theodosius Marwan Irnaka, Eddy Hartantyo Dec 2025

Fast Dispersion-Curve Inversion Using Automatic Differentiation Gradient-Based Calculation, Theodosius Marwan Irnaka, Eddy Hartantyo

Makara Journal of Science

Surface wave inversion is a crucial technique in geophysics for subsurface imaging. However, traditional methods can be computationally intensive, especially for complex models. This study introduces automatic differentiation (AD) as an efficient alternative to finite difference (FD) methods for gradient calculation in surface wave inversion. We compare AD and FD methods using three synthetic examples of varying complexity. Our results demonstrate that AD is significantly faster, with speed improvements of 3 to 12 times over FD, depending on model complexity. Moreover, AD requires up to 3 times less memory than FD. In terms of accuracy, AD provides gradient calculations that …


Design And Modeling Of A Thin Water Falling-Film For Convection-Cloud Chambers, Grant T. Schlaff, Jesse Anderson, Brandon Kieranen, Constantine M. Megaridis, Raymond Shaw Dec 2025

Design And Modeling Of A Thin Water Falling-Film For Convection-Cloud Chambers, Grant T. Schlaff, Jesse Anderson, Brandon Kieranen, Constantine M. Megaridis, Raymond Shaw

Michigan Tech Publications

Convection–cloud chambers offer a controlled environment to study aerosol-cloud interactions. Ensuring sustained supersaturation in these chambers requires a reliable and efficient water sourcing mechanism. Maintaining saturated boundary conditions on side-walls is important in chambers with large vertical dimensions (up to 10m) aimed at achieving collisional growth of cloud droplets. This study introduces the design, modeling, and measurement of a falling-film system capable of maintaining a stable, continuously replenished water film for continuous evaporation. A distributor is tested, ensuring uniform water coverage over a panel with a range of surface treatments. These surface treatments with micron to 100micron-scale roughness allow for …