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Kilocycle Range Dislocation Damping In Dilute Magnesium Alloy Single Crystals, Robert Ray Nothdurft

Doctoral Dissertations

"The kilocycle range dislocation damping and Young's modulus of single crystals of magnesium and single crystals of magnesium containing small additions of lithium, zinc, or aluminum have been studied as a function of strain amplitude, temperature, and time during annealing and following a high strain amplitude vibration. The data are compared to the Granato-Lücke theory of dislocation damping, the Granato-Hikata-Lücke theory for the recovery of damping following plastic deformation, and the Yamafuji-Bauer theory for the recovery of damping following a high strain amplitude vibration. Reasonable qualitative agreement is obtained between the Granato-Lücke theory and the observed dependence of the damping …

Basic Iron (Iii) Alkanoate Complexes, Young Hee Kim

Masters Theses

"Much information appears in the literature concerning the preparation, properties and structure of the basic iron (III) acetates...This study was initiated to prepare a number of the basic trinuclear iron (III) alkanoate complexes and to investigate the possibility of a common structure for all of these as suggested by the work of Orgel. The structural investigation was done on the basis of stoichiometric relationships, infrared spectra and magnetic moments"--Abstract, pages ii-iii.

Noble Gases In The Earth And Its Atmosphere, Robert Anthony Canalas

Masters Theses

"Abundance of noble gases extracted from Fig Tree Shale exhibit a marked deviation from the gas content of eclogitic rocks purported to be mantle material. The abundances of the heavy noble gases in shale were found to exceed the highest known meteoritic values. The abundances of the lighter noble gases were found to be comparable to the abundances of these gases in typical chondrites.

Temperature gradient analyses show that excess heavy gases are released at low temperatures. This is interpreted to indicate a preferential adsorption of the heavy noble gases on fine-grained sediments when these gases were being released from …

A Subsurface Geologic Study Of Petroleum Possibilities In The Pennsylvanian Rocks Of Concho County, Texas, Gregory Paul Kraus

Masters Theses

"During early Pennsylvanian time the area now occupied by Concho County was a portion of the Texas peninsula, a broad, low arch with a karst topography developing on its exposed Ellenburger surface. A mid-Pennsylvanian marine transgression inundated the arch and it became an area of clear, shallow water deposition favorable to limestone development. Local sedimentation during Strawn time was largely controlled by its position relative to the Llano uplift and surrounding basins. A variety of subsurface maps were constructed for this study essentially utilizing electric log data. The results indicate that limestones of the Strawn platform facies rapidly change in …

Effect Of Environmental Hydrogen Pressure On The Hydrogen Yield From X‐Irradiated Polyethylenes, Otto H. Hill, R. Pat Lightfoot

Physics Faculty Research & Creative Works

An experimental assembly incorporating a capacitance‐type, differential pressure transducer, which provides resolutions of 3 x 10−4 torr at pressures extending to 30 torr, has been employed to monitor the effect of hydrogen environmental pressure on the hydrogen yield from x‐irradiated polyethylene's. Contrary to the observations of previous investigators, the hydrogen yield is found to be independent of hydrogen environmental pressures extending over the critical range up to at least 30 torr. It is demonstrated that neglecting the temperature and density gradients inherent in closed‐volume irradiation assemblies employing cryogenic traps to separate liberated gases into condensable and non condensable fractions may …

Handlos And Baron Model: Short Contact Times, J. Patel, Robert M. Wellek

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

The Mechanism Of The Electrooxidation Of Acetylene On Gold, James W. Johnson, J. L. Reed, William Joseph James

Chemical and Biochemical Engineering Faculty Research & Creative Works

Acetylene has been oxidized anodically in aqueous solutions at 80 °C on gold electrodes. It was found that the partial oxidation to CO₂ was accompanied by a polymer formation. Effects of potential, acetylene partial pressure, pH, and temperature on the rate (current) were measured. A discontinuity in the Tafel curves was noted that indicated a change in the reaction mechanism with potential. The discontinuity was also pH dependent. A mechanism involving the discharge of H₂O and/or OH− has been proposed that is consistent with the experimental results. © 1967, The Electrochemical Society, Inc. All rights reserved.

The Anodic Dissolution Of Cadmium, James W. Johnson, E. Deng, S. C. Lai, William Joseph James

Chemical and Biochemical Engineering Faculty Research & Creative Works

The anodic dissolution of cadmium has been studied in aqueous solutions containing Cl−, Br−, I−, Ac−, SO₄=, and NO3− ions. The normal valence (+2) was found in all solutions with the exception of NO₃−. The apparent valence (calculated) of cadmium ions in nitrate solutions varied from 1.2 to 2.0 and was found to be a function of NO₃− concentration, current density, and temperature. An anodic dissolution mechanism has been proposed involving local corrosion and disintegration of the anode which is consistent with the experimental results. © 1967, The Electrochemical Society, Inc. All rights reserved.

The Role Of The Doctor Of Engineering Degree In Graduate Education, Wouter Bosch, Robert E. Carlile

Chemistry Faculty Research & Creative Works

No abstract provided.

Anodic Dissolution Of Zinc In Potassium Nitrate, Martin E. Straumanis, J. L. Reed, William Joseph James

Materials Science and Engineering Faculty Research & Creative Works

The apparent valence of pure zinc dissolving anodically in 3% KNO₃ was determined as a function of current density, temperature, and ultrasonic agitation. The apparent valence of zinc dissolving anodically at 24°C diminishes from 2.01 ± 0.01 at low current densities to 1.86 at about 50 ma and remains fairly constant up to about 80 ma cm−2. This valence is affected to some extent by the preparation, e.g., polishing of the electrode, but is independent of its structure (mono- or polycrystal). Ultrasonic vibrations do not influence the apparent valence at high current densities. In all cases a black film …

A Psychrophilic Yeast From Mammoth Cave, Kentucky, David Brashear, Ralph F. Wiseman, Thomas C. Barr Jr.

International Journal of Speleology

Samples collected in Mammoth Cave, Kentucky, revealed the presence of a psychrophilic yeast, tentatively identified as a strain of Candida albicans. The yeast is saprophytic on dead animal tissues and exhibits a pale yellow colour when growing in the cave. In vitro, the yeast grows poorly at 37°C. and well at 130 and 200, but loses its pigmentation. It is non-pathogenic in rabbits but appears to show low-grade parasitism in frogs.

A Calorimetric Study Of The Effects Of Surface Energy In A Type Ii Superconductor, Robert Rex Rice

Doctoral Dissertations

"A calorimetric study of the effects of the interphase surface free energy has been conducted on ellipsoidal samples of first and second kind superconductors. The measurements were performed using a specially designed magnetization calorimeter by two different techniques. The measurements were made on lead, tin, lead-4at%thallium, and tin-6at% indium. The results confirm the existence and experted sign of the surface energy in a well annealed lead-4at%thallium sample, and indicate that the interphase surface energy in lead and tin is too small to be directly detected by this method. The measured latent heats of transition of lead and tin agree well …

An X-Ray Study Of The Lead Titanate-Bismuth Chromate System, Tsen-Tsou Shih

Masters Theses

"The lead titanate-bismuth chromate system was studied employing x-ray diffraction techniques at both room and high temperatures. Samples were prepared by sintering stoichiometric mixtures of the corresponding oxides followed by air quenching. Bismuth chromate was prepared by resintering and air quenching for four times. The results of the analyses show the structure of BiCrO₃ to be tetragonal with 8 molecules per unit cell. Solid solutions exist over the range 100 to 35 mole percent PbTiO₃ of the binary system, although small amounts of other phases are present in some regions. X-ray data at room temperature indicate the tetragonal perovskite structure …

The Effect Of Charged Interfaces On The Ionic Distribution In Solution, Myron Elliot Feinstein

Dissertations, Theses, and Capstone Projects

No abstract provided.

Ferroelectric Properties Of Pbzro₃-Bifeo₃ Solid Solutions, Robert Gerson, Pen-Chu Chou, William Joseph James

Physics Faculty Research & Creative Works

Solid solutions of BiFeO and PbZrO₃ were investigated for crystallographic and dielectric properties. A new pseudocubic perovskite phase was found, which has been tentatively indexed as orthorhombic with the same unit cell as PbZrO₃ but with dielectric properties characteristic of a ferroelectric substance. The Curie point in this series of solid solutions has a minimum of about 155°C at a composition of about (PbZrO₃)_0.80 (BiFeO₃)_0.20, which at room temperature lies on the boundary between the orthorhombic antiferroelectric and the pseudocubic ferroelectric phases. This composition has a relative dielectric constant of 800 …

Quartzite Karst In Southeastern Venezuela, William B. White, Gene L. Jefferson, Jon F. Haman

International Journal of Speleology

Minor weathering forms on the Roraima Quartzite in the Carrao River Basin of Southeastern Venezuela have the appearance of the karren that form on limestone surfaces in karst terrains. Climatological and chemical evidence indicates that these forms were generated by a solutional mechanism and that this area thus exhibits a minor karst topography on quartzite.

Répartition Géographique Et Validité De L'Espéce Troglobie Asellus Lusitanicus Frade (Crustacé Asellote), Guy Magniez

International Journal of Speleology

The troglobitic Asellid Asellus lusitanicus Frade (1938) is now known from three caves of the Serra de Aire (Central Portugal). It seems to be a good eyeless species of the “coxalis” group.

Les Mycetophilidae (Diptères) Cavernicoles De La Collection Biospeologica (IvE-ViiiE Séries Des «Grottes Visitées»), Anca Burghele-Balacesco

International Journal of Speleology

Study of the Mycetophilidae of the Biospeologica collection (Series IV to VIII of “Grottes visitées” was the objective of the present study. Thirty species have been identified, including Exechia peyerimhoffi n. sp. and Rhymosia pseudocretensis n. sp. The cave fauna contains several rare species - Exechia pollicata Edw., E. unguiculata Lundst., and Rhymosia cretensis Lundst. The ovipositors of Exechia coremura Edw. and E. landrocki Lundst. are figured for the first time.

Sur La Faculté D'Absorption De Substances Colorées Par La Cuticule De Caecosphaeroma Burgundum Dollfus, Crustacé Isopode Des Eaux Souterraines, François Graf, Claude Marvillet

International Journal of Speleology

The discovery, in certain subterranean waters, of “pigmented,” brown or black Caecosphaeroma burgundum, led to the systematic study of the action of pigmented substances on these crustaceans. The results of these experiments demonstrate that the colorations thus obtained or observed in nature are due to the agglutination of coloured substances on the surface of the carapace and, in certain cases, to an impregnation of the cuticle itself.

Deux Nouveaux Halacariens D'Israël - Limnohalacarus Capernaumi N. Sp. Et Lohmannela Heptapegoni N. Sp., Anelya Petrova

International Journal of Speleology

Two new species of Halacarinae of a thermal slightly brackish spring near the Tiberiade lake in Israel are reported. Limnohalacaras capernaumi n. sp. has certain characteristics typical of other species of the Genus, but is clearly distinguished by proper elements. Lohmannell heptapegoni n. sp. resembles Lohmannella stammeri Viets, of which it is distinguished by the structure of the dorsal plates, the palp and the morphology of the genital apparatus.

Neobisium (Roncobisium) Allodentatum N. Sg., N. Sp. De Pseudoscorpion Neobisiidae (Arachnides) Habitant Une Caverne Du Département De Saône-Et-Loire, France, Max Vachon

International Journal of Speleology

Neobisium (Roncobisium) allodentatum, a species inhabiting a cave in Saone-et-Loire, France, belongs to a new subgenus of Neobisium of which the essential characters are the possession of accessory teeth on the chelae (fig. 14) and a relative position of trichobothria eb and esb (fig. 8) recalling that of the species of Roncus. A determination key fixes the position of this new subgenus with respect to the four other known subgenera of Neobisium.

Underground Solution Canyons In The Central Kentucky Karst, U.S.A., Richard A. Watson

International Journal of Speleology

Solution canyons are underground voids 1 to 15 + meters wide, 3 to 45 + meters high, and 30 to 300 + meters long. Floors are stepped, ceilings level. Size increases downstream. Their course is sinuous, with some angularity. They occur parallel to and directly under or slightly offset from the thalwegs of re-entrant valleys tributary to major karst valleys. A section across a re-entrant and underlying solution canyon shows a rough hour-glass shape. Solution canyons are related genetically to solutional vertical shafts, forming where removal of the impermeable sandstone caprock permits the vertical descent of water through jointed limestone. …

Die Lampen-Moosflora Der Beatushöhle Und Deren Vergleich Mit Anderen Europäisehen Höhlen, R. Bernasconi

International Journal of Speleology

The Bryological flora on the lamps of the St- Beatus Höhle is analysed. A statistic comparison of lampenflora from other 18 European caves shows the composition and the type of this flora is related to the humidity and to the difference in substratum. Ten species can be referred to as typical flora of show caves.

Further Investigations Into Bacterial And Algal Populations Of Caves In South Wales, M. Ann Mason-Williams

International Journal of Speleology

Some physical data collected over a period of a year in seven locations of the Ogof Ffynnon Ddu cave system in South Wales are reported, including humidity, air and water temperature, pH of the water, as well as the organic oxygen demand of the water. It is shown that seasonal variations in the physical constant in this particular cave system are not well marked. Algae and bacteria were isolated from the soil samples and from calcareous deposits. A total of 30 algal species, of which 13 belong to the Cyanophyta, 22 to the Chlorophyta, and 7 to the …

A New Species Of Gomphonema (Bacillariophyta) From Mammoth Cave, Kentucky, Sam L. Van Landingham

International Journal of Speleology

In some materials collected from Mammoth Cave, Kentucky, a diatom was found which could not be identified with any known species. A taxonomic description of Gomphonema hotchkissii nov. spec. is given.

Analyse Du Comportement Alimentaire Du Poisson Cavernicole Aveugle Anoptichthys Gen. Et D'Hybrides F1 (Astyanax X Anoptichthys) Et F2, Georges Thines, Monique Soffie, Erik Vandenbussche

International Journal of Speleology

The feeding behaviour of the blind cave fish Anoptichthys is characterised by two phases, an initial short chemioreceptic one and second one in which the fish explores the bottom systematically for a longer period. The whole process last approximately 30 seconds, both in adults as in youngsters.

Mise En Evidence De Substances Fluorescentes Dans Les Organes Jaunes De Caccosphaeroma Burgundum Dollfus, Crustacé Isopode Des Eaux Souterraines, H. Descimon, C. Marvillet

International Journal of Speleology

Chromatographic analysis of the yellow organs of the fresh-water Isopod Crustacean Caecosphaeroma burgundum Dollfus revealed, through observation of the chromatograms in ultraviolet light, the occurrence of both absorbing and fluorescent substances. Among the latter, only isoxanthopterin has been identified. The yellow pigment, which probably has a pteridine nucleus, could not be identified as a known compound and will be the object of later investigations.

Algal Growth Experiments In The Baradla Cave At Aggtelek (Biospeleologica Hungarica Xxi), Erzsebet Kol

International Journal of Speleology

The author kept 108 algal strains (Cyanophyta 53, Chlorophyta 35, Chrysophyta 20), of axenic cultures from the Kol-Algotheca in the Botanical Division of the Hungarian National Sciences Museum in the Baradla Cave, at Aggletek (Hungary) in darkness for 204-420 days under different environmental conditions. The experiments have proven that several algal strains can tolerate well the complete absence of light. Furthermore, that some algal strains show intensive development even under such conditions. These axenic cultures kept in the cave in metal boxes on inorganic medium have shown that the energy source used by these green coloured algae is not …

Documents Pour Servir À La Connaissance De La Laune De Mammifères Des Grottes Du Banat (Roumanie), Alexandrina Negrea, Lazare Botosaneanu, Stefan Negrea

International Journal of Speleology

The authors assembled from about 70 caves a rich collection of osteological material and specimens of living or fossil mammals. A list of the caves is given with an enumeration of the identified species for each cave. Under each species the caves which supplied the material are listed. This is followed by an inventory of the osteological material and by observations on the living animals (especially bats). Fifty-three mammal species (fossil and living) were accurately determined (14 carnivores, 6 artiodactyls, 1 lagomorph, 10 rodents, 3 insectivores, and 19 bats).

Summary Of Results Obtained During A Preliminary Investigation Into The Bacterial And Botanical Flora Of Caves In South Wales, M. Ann Mason-Williams, Kathryn Benson-Evans

International Journal of Speleology

The results of an investigation into the bacterial and botanical flora of South Welsh caves are presented in tabular form. Bacterial counts and species isolated from the caves both from soil and water samples as well as from the air, also the macroscopic plants found in the photic zone are enumerated.