Digital Commons Network^™

Analysis Of Heat Transfer In A Two-Layer Circular Cylinder:Constant Flux On Outer Surface And Zero Flux On Inner Surface, Mary Elena Franklin

Mathematics & Statistics ETDs

The one-dimensional time-dependent equation of heat conduction is solved analytically for an infinite two-layer circular cylinder whose core may be either hollow or solid. On the outer surface of the cylinder, which has no heat loss due to convection, a constant heat flux from an external source of heating is applied uniformly. The layers are in perfect thermal contact, and there is no heat loss at their interface. At the smaller radius of the inner layer is a perfect insulator so that the heat flux on the inner surface of the two-layer cylinder is zero. The temperature is uniform initially …

Adaptive Nonlinear Prediction And Convergence Rates., Dirk Andrew Dahlgren

Mathematics & Statistics ETDs

Let x1,…,xm be radom variables with an arbitrary (initial) distribution functions F. For i>=m, define

Xi+1=f(theta,x1,…,x1-m+1)+oZi

Where theta is an unknown parameter in Euclidean r space and {Zi}inf m is a sequence of independent, identically distributed random variables with E[Zi]=0 and E[Z 2 i]=1. This type of process will be termed a generalized autoregressive process in the sequel.

The Ias Bulletin, V3n4, September 1969, Iowa Academy Of Science

IAS Bulletin

In this issue:

--- Officers, Directors, and Section Chairmen, 1969-1970
--- New Members Since May First
--- Membership by Section Interest
--- Board Meeting Scheduled
--- Geology Monograph "Water Resources of Iowa" to e Available Soon
--- Grant Received from NSF for Junior Academy Work
--- Academies of Science and Science Education
--- Activities of NSRA of Interest to Academy Members
--- Member Wants Critical Analysis of his Trisection
--- All High School Science Teachers in Iowa now on Information Mailing List
--- Several Vacancies Left by the Departure of One Active Member
--- Local Arrangements Named for April 1970 …

Effective Rates Of Evaporation And Chemical Properties Of The Precipitates., John Lincoln Rasho

Earth and Planetary Sciences ETDs

An experiment was designed to simulate the evaporation of sea water in the laboratory. The experiment was conducted isothermally at 35 1. Chlorinity, salinity, and density of the solution were determined at different stages of evaporation. Also the trace element contents of Sr, Rb, K, and Li of the precipitates were determined to study the possible changes, and the significance of these changes, in the concentration of these trace elements in solution at different stages of evaporation.

The results of this experiment and the work of previous investigators indicate that the rate of crystallization from sea water, at any given …

A Combinational Analysis Of Finite Minimal Uniform Covers, Gustavus J. Simmons

Mathematics & Statistics ETDs

No abstract provided.

Nmr Determination Of The Conduction-Electron Hyperfine Interaction In Crystalline Cdo, David C. Look

Physics Faculty Publications

Measurements of the Cd¹¹³ nuclear-spin-lattice relaxation time T₁ and Hall effect in crystalline CdO, a degenerate semiconductor, have yielded the contact hyperfine strength of the conduction electrons at the nuclei. The product T₁T=168 sec °K, independent of temperature T and frequency ν for T=1.4,4.2, and 77-350 °K, and for ν=2-10 MHz. Taking the carrier concentration N=2.6×10¹⁹ cm^-3 independent of temperature to within 3% at 4.2, 77, and 300°K, and using an effective electron mass m_e^*=0.2m_e, we calculate an averaged electron probability density at the nucleus, 〈|φ_F(0)|^{2 …}

Data Retrieval In Mass Spectrometry By An Optical Coincidence System, Cynthia Helmintoller O'Donohue

Master's Theses

The object of this work was to develop an information storage and retrieval system for use in mass spectroscopy. The information to be stored was the compound's name, the mass spectrum, and distinctive physical and chemical properties. It was desirable that the system be one that could be used in the mass spectral laboratory. At the time this project was initiated, no system for mass spectroscopy had been developed with the characteristics of simplicity, rapid retrieval, and practicality of use in the laboratory without elaborate and space consuming equipment. Thus, a system was needed to aid the laboratory personnel in …

Estimations Of The Effective Electrolytic Surface Area Of Rough And Porous Silver Electrodes ; Ii. Potentiostatic Oxidation Of Silver In Alkaline Electrolyte, James Glenn Bearss

Theses and Dissertations

This dissertation is written in two sections. The first section deals with the development of methods for the estimation of the effective electrolytic surface area of rough and porous silver electrodes in alkaline electrolyte. Data are presented comparing the results of three different methods of surface area estimation. Model pore electrodes were also prepared and oxidized to study the reactions in a pore. Data for constant current oxidations of these electrodes is given. The second section deals with the potentiostatic oxidations of silver in alkaline electrolyte. Data are presented on the total charge acceptance versus applied potential for a potential …

A Kinetic Study Of The Oxidation Of The 2, 3, And 4 Pyridine Aldehydes By Cobalt (Iii) Perchlorate In Aqueous Solution., Ronald Barry Giuntoli

All Master's Theses

Cobalt(III) perchlorate has been shown to be a powerful oxidizing agent and kinetic investigations of the mechanism of oxidation of many organic compounds including organic acids have been performed.

On The Theory Of Quaternions, Earle David Smith

All Master's Theses

Ordered triplets serve to describe space geometrically just as ordered pairs serve to describe the plane. A multiplication can be defined on pairs consistent with the complex numbers. However, as this paper will show, one cannot define a multiplication on triplets which is consistent with the complex numbers.

The Effects Of Herbicides On Three Soil Inhabiting Blue Green Algal Species, Lee C. Darlington

All Master's Theses

The object of this study was to examine the effects of varying concentrations of 2, 4-D, Dalapon, and Tordon on the growth of several nitrogen-fixing blue-green algal species obtained from soil samples and grown under culture conditions in the laboratory.

A Thermodynamic Approach To The Study Of Phase Equilibria In The Sodium-Potassium Alloy System I. The Phase Diagram For Nak At Atmospheric Pressure ; Ii. High Pressure Phase Studies, Donald Ray Anderson

Theses and Dissertations

Ultra-pure reagents, platinum resistance thermometry and modern inert atmosphere glove box facilities have made possible a detailed examination of the NaK system at atmospheric pressure. A thermoanalytical study of solid-liquid phase equilibria in the NaK alloy system was conducted in the tetrahedral press to 55 kbars to investigate possible intermediate compound formation and shifting of the invariant points at various pressures. An expected shift in the eutectic composition to lower potassium content with an increase in the halt temperature on increasing pressure was confirmed. A merging of the meritectic and eutectic points at 343 ±2°K and 37 ±3 kbars occurred …

Thermodynamics Of Proton Dissociation And Metal Ion Complexation In Aqueous Solution. I, Cation Binding With Cyclic Polyethers: Significance In Ion Transport Processes. Ii, Proton Dissociation From Adenosine, Several Monosaccharides And Related Compounds. Iii, Proton Dissociation From Several Pyrimidines And Their Nucleosides At 10, 25 And 40°, Joseph Howard Ryttling

Theses and Dissertations

The log K, ΔH° and ΔS° values for the interaction of several metal ions with the two isomers of the cyclic polyether, 2,5,8,15,-18,21 hexaoxatricyclo[20.4.0.0^9,14]hexacosane are reported. The stability order found for alkali metal ion interaction with either isomer is identical to the order of ion permeability through reconstituted biological membranes for structurally related antibiotics. The size of the metal ion is critical in determining the extent of interaction. A calorimetric titration study of proton ionization from several monosaccharides and derivatives, pyrimidine bases and their nucleosides, adenosine and its derivatives, and cycloheptaamylose is described. The heats of reaction obtained in this …

A Study Of Folic Acid Dependent Reactions In Bovine Brain, Dillard Spencer Broderick

Theses and Dissertations

The enzymatic interconversion of serine to glycine and N5, N10-methylene tetrahydrofolate to N5 -methyl tetrahydrofolate have been studied in a cell-free system derived from bovine brain. A partial purification of serine transhydroxymethylase and N5, N10 -methylene tetrahydrofolate reductase has been achieved by ammonium sulfate fractionation, protamine sulfate fraction, and by various column chromatography procedures. The two enzymes studied catalyze sequentially the reductive transfer of the hydroxymethyl group of serine to the N5 position of tetrahydrofolate forming N5 -methyl tetrahydrofolate. The products of these reactions were assayed by the incorporation of C14 from a one-carbon precursor i.e., L-beta-(C14)-serine, or N5 -methyl …

The Catalytic Hydrogenation Of Benzodiazines.|Ni.|Pphthlazine.|Nii.|Pquinazoline, Danny Lee Elder

Theses and Dissertations

Quinazoline and phthalazine were hydrogenated at low pressure and temperature (60 psi, room temperature) and high pressure and temperature (2000 psi, 100°C, 150°C} in neutral and acidic solvents over 5% Pd/C, 5% Ru/C, 5% Rh/Al2O3 , 5% Rh/C, and 5% Pt/C. Chromatographic methods for determining the qualitative and quantitative composition of hydrogenation mixtures were developed. The compositions of quinazoline and phthalazine-hydrogenation mixtures were determined. Eight phthalazine-hydrogenation products were detected and isolated: (1) 1,2-dihydrophthalazine, (2) 1,2,3,4-tetrahydrophthalazine, (3) a,a'-diamino-o-xylene, (4) o-methylbenzylamine, (5) 1,3-dihydroisoindole, (6) o-xylene, (7 and 8) cis- and trans- 1,2-dimethylcyclohexane. These products were identified by isolating them from reaction mixtures …

Solid-Liquid Phase Equilibria Of The Sodium-Rubidium And Sodium-Potassium-Rubidium Alloy Systems, Chen-Chao Hsu

Theses and Dissertations

Thermal methods were used, to determine with high precision, the solid-liquid phase equilibria diagrams for the sodium-rubidium and sodium-potassium-rubidium systems. In the sodium-rubidium system, the results differ greatly from those of earlier works, especially near the eutectic composition where differences in freezing points as large as 25°K occur. A detailed search was made for possible intermetallic compounds (especially Na2Rb). Neither slow temperature cycling in the temperature range where compound formation could occur nor extended periods of annealing just above the eutectic temperature produced any evidence for compound formation in the sodium-rubidium system. A 2:1 (sodium to rubidium) sample was subjected …

Mechanism Of Water Transport Through Reverse Osmotic Membranes, Cheryl Kay Murphy

Theses and Dissertations

Cellulose acetate membranes show a higher permeability to water than to salt and are being used for desalination of salt water by reverse osmosis. Use of highly acetylated cellulose membranes give a higher salt rejection but also decrease flow rate of the water. The addition of very-short-chain substances or alkyl groups larger than one carbon atom to the cellulose membrane also decreases water flux. A proposed mechanism of transport through the membrane is that the water molecule is passed along the chain by hydrogen bonding with the acetyl groups, The NMR shows a change in the chemical shift of water …

Fission Barriers And Transition-State Spectra For 232th, 234th, 238u, 240u, 242pu, And 244pu From 9t, Pf0 Reactions., James D. Cramer

Physics & Astronomy ETDs

Joliot and Curie’s discovery of artificially induced radio-activity in several nuclei by a-particle bombardment encouraged Fermi and his collaborators in 1934 to attempt similar experiments using neutron bombardment of various target elements/ Using natural uranium as a target material they discovered at least four radioactive products, assumed to be elements in the transuranium region. These experiments were repeated in 1937 by Meitner, Hahn and Strassman in Germany where they found that some of these radioactive elements produced by neutron bombardment of uranium had barium-like chemistry, and were assumed to be isotopes of radium. Further investigation proved that these products could …

Stratigraphic Analysis Of The Upper Permian And Lower Triassic Strata In Southern Utah, Charles Dennis Irwin Jr.

Earth and Planetary Sciences ETDs

Permian sedimentation in southwestern Utah was influenced by three principal depositional areas. These areas were the Oquirrh basin in north-central Utah, the Cordilleran geosyncline in eastern Nevada, and the Quemado-Cuchillo basin on the northern shelf of the Sonoran geosyncline in east-central Arizona and west-central New Mexico. Throughout Permian time, marine sediments and their well-developed beach and continental eolian sandstone equivalents were deposited within these basins and upon their surrounding shelves. Each of the three basins appear to have exerted their influence upon sedimentation during a discrete period of geologic time. Thus while one basin was sedimentationally active the other two …

Generalized Threshold Decoding Of Convolutional Codes, Luther D. Rudolph

Electrical Engineering and Computer Science - Technical Reports

It is shown that any rate l/b systematic convolutional code over GF(p) can be decoded up to its minimum distance with respect to the decoding constraint length by a one-step threshold decoder. It is further shown that this decoding method can be generalized in a natural way to allow “decoding” of a received sequence in its unquantized analog form.

The Oxidative Decarboxylation Of Polyaminocarboxylic Acids - I. A Study Of The Reaction Of Ethylenedinitrilotetraacetic Acid (Edta) With Cerium (Iv) In Acid Solution, Samir B. Hanna, S. Al-Hashimi, William H. Webb, William R. Carroll

Chemistry Faculty Research & Creative Works

The reaction between Ce(IV) and EDTA was followed titrimetrically and spectrophotometrically and was found to occur in stages. Four equivalents of Ce(IV) are reduced per mole of EDTA almost instantaneously at room temperature. With increasing temperature and reaction time an ultimate of about 14 equivalents of Ce (IV) is consumed per mole of EDTA. Carbon dioxide, formaldehyde, and other yet unidentified compounds are the products of oxidation of EDTA. The kinetics of the reaction in aqueous sulfuric acid was studied over the temperature range 11.7°-40°C by a spectrophotometric technique. The effects of the acidity of the medium and of added …

Cyclization Studies Involving The Synthesis Of 5-Substituted-1-Naphthol, Clark Keelock Chow

Dissertations and Theses

The γ-o-substituted-phenylparaconic acids were prepared by a method patterned after that of Fuson. These paraconic acids were prepared in good yield. A re-investigation of the Perkin and Fittig methods of preparing γ-phenylisocrotonic acid was carried out without success.

The synthesis of γ-o-halophenylisocrotonic acids by thermal, and catalyzed decarboxylation of γ-o-halophenylparaconic acid, have been carried out in good yield. An effective catalyst, optimum temperature and reaction period of decarboxylation of the γ-o-halophenylparaconic acids have been determined. Infrared absorptions have characterized the γ-o-halophenylisocrotonic acids formed to be in the stable trans form. …

Syntheses Via Modifications Of The Knorr-Paal Procedure :|Ba. Derivatives Of 2,6-Dioxa-10-Azatricyclo[5.2.1.0[Superscript 4,10]]Decane ; B. Highly Sterically Crowded 1,2,5-Trialkylpyrroles And Pyrrolidines, Weldron Severin Burnham

Theses and Dissertations

Earlier work in these laboratories on the heterotricyclic system 2,6-dioxa-10-azatricyclo[5.2.1.04,10]-decane, formed from 1,4-diketones and 2-amino-1,3-propanediols by a product-water-azeotroping procedure, was extended with the synthesis of analogous compounds, e.g., the 1,4,7-triethyl-, 1,7-dimethyl-4-isopropyl-1,7-diethyl-4-isopropyl-, 1,7-dimethyl-3- and 4-phenyl- compounds. The 1,7-dimethyl heterotricycle, the kinetically-controlled product, was accompanied by the thermodynamically-controlled product, 2-(2,5-dimethyl-1-pyrryl)-1,3-propanediol. The 1,7-diethyl heterotricycle was also accompanied by the isomeric pyrrole as were the 1,7-dimethyl-3- and 4-phenyl compounds. A scheme postulating a common intermediate is presented. The interesting analogous compounds, 1,7-dimethyl-2-oxa-6-thia-10-azatricyclo[5.2.1.04,10]decane, 1,4,7-trimethyl-2,6-dioxa-11-azatricyclo[5.3.1.04,11]undecane and 11-hydroxymethyl- and 11-methyl-9,13-dioxa-14- azatetracyclo[6.5.1.02,7 011,14]tetradeca-2,4,6-triene were also prepared. The syntheses in good yields of a considerable number of moderately to …

Geology Of Part Of The Creston Range, Mora County, New Mexico, Tim T. Schowalter

Earth and Planetary Sciences ETDs

The low hills and hogback ridges of the Creston Range form the southeastern edge of the Sangre de Cristo Mountains.

Rocks ranging from Precambrian to Quaternary are exposed in the Creston Range. The Precambrian rocks consist of generally foliated, medium-grade metamorphics intruded by concordant, simple pegmatites. These rocks have been subjected to at least two episodes of deformation of Precambrian age. Approximately 9,000 feet of sedimentary rocks of Devonian (?)-Mississippian to Permian age that were deposited in an intracratonic basin to shelf environment are present. Tertiary-Quaternary rocks are represented by outliers of a basalt flow from the Ocate colcanic field …

High Pressure, High Temperature Syntheses Of Selected Lanthanide-Tellurium Compounds, John Francis Cannon

Theses and Dissertations

High pressure, high temperature technics were employed to successfully synthesize HoTe1.7, ErTe1.7, TmTe1.7, LuTe1.7, YTe1.7, and LuTe3. The pressure-temperature regions in which synthesis of each compound is successful were determined. Pressures to 100 kbars concurrently with temperatures to 1200 °C were used in an attempt to prepare ScTe1.7 and ScTe3, but these efforts met with failure. X-ray studies of these new compounds confirmed that they are extensions of the LTe2-X (0≤x

Glycosidic Enzymes Of The Tropaeolum Majus, Donald Richard Snowden

All Master's Theses

The purpose of this study is to investigate the hydrolytic enzymes of Tropaeolum majus. This particular plant is the only example of the Tropaeolum genus found in the northern hemisphere. It is the well-known Indian cress or common garden nasturtium.

The Effect Of Selected Nurse-Patient Contacts On The Attendance Of Non-Private Patients At Preparation For Childbirth Classes, Judith A. Hart

Loma Linda University Electronic Theses, Dissertations & Projects

The purpose of this study was to determine whether selected nurse-patient contacts effected the attendance of non-private patients at Preparation for Childbirth classes. During the data collection period only six of the eight patients who met the criteria for this study were available. Each of the six patients was reached by at least one of the three types of nurse-patient contacts-- a letter of invitation to the Preparation for Childbirth classes, weekly contacts with the patients at the classes and three home visits to each patient. Tools used to collect data for this study were a personal information questionnaire, home …

A Historical Study Of The Nursing Care Of The Newborn Infant In The Hospital Nursery, Synnove Wasli

Loma Linda University Electronic Theses, Dissertations & Projects

This was a historical study of past ideas, beliefs, and practices in the nursing care of the normal newborn infant in the hospital nursery. The study covered the years 1930 to 1965 and was divided into four cross sections, namely, 1930 to 1935, 1940 to 1945, 1950 to 1955, and 1960 to 1965.

The primary sources used in this study consisted of one hundred infant medical records which were made available by a 382-bed, private, general hospital located in a Los Angeles suburb. One procedure manual used in this hospital during the years 1944-1955 qualified as a primary source. Personal …

The Effect Of Removing The Crevicular Epithelium Upon Canine Tooth Replantation, Leon A. Leonard

Loma Linda University Electronic Theses, Dissertations & Projects

The nature of epithelium and the remarkable facility with which it aggressively covers granulation tissue, suggests that removal of the sulcular epithelium surrounding the extraction wound of a tooth to be replanted could promote reattachment of the periodontal tissues at a more nearly ideal coronal level. To investigate this hypothesis twenty mature teeth in five mongrel dogs were experimentally replanted. One half of them were replanted in alveoli around which the crevicular epithelium had been removed, the remaining teeth without creviculoectomy acting as controls. Animals were euthanized at one, two, three, five, and sixteen weeks. After clinical evaluation of the …

Late Cenozoic Geomorphic History Of Lee Canyon, Spring Mountains, Nevada, John Henry Gucwa

UNLV Theses, Dissertations, Professional Papers, and Capstones

Located in the west central portion of Clark County, Nevada, the Spring Mountain Range borders the western edge of the Las Vegas Valley. Within the mountain range, a fault block, there are several canyons whose geomorphic history is closely related to the geomorphic history of the major alluvial fans which flank the mountains. Lee Canyon, which is the study area is one of these canyons. In Lee Canyon is preserved a complex canyon fill which has been subjected to several periods of down-cutting and valley-widening. The details of the canyon's geomorphic history recorded by filling and fill removal has not …