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Thermochemical Hydrogen-Deuterium Isotope Effects, Wayne C. Duer

Doctoral Dissertations

"The heats of solution at 25.0 ± 0. 1°C for each member of hydrogen-deuterium isotopic pairs (chloroform/chloroform-d, acetone/acetone-d₆, methanol/methanol-d₁, ethanol/ethanol-d₁, and water/heavy water) have been determined as a function of molality in a variety of solvents. The heats for most of the systems could be described as a linear function of average molality with an average deviation in fit of less than one per cent. Using these linear equations, heats of solution at infinite dilution were obtained by extrapolation to zero molality. The heats of solution at infinite dilution of the hydrogen containing compounds were subtracted from those of the …

Extension Of Some Theorems Of Complex Functional Analysis To Linear Spaces Over The Quaternions And Cayley Numbers, James E. Jamison

Doctoral Dissertations

"In this work certain aspects of Functional Analysis are considered in the setting of linear spaces over the division rings of the real Quaternions and the real Cayley algebra. The basic structure of Banach spaces over these division rings and the rings of bounded operators on these spaces is developed. Examples of finite and infinite dimensional spaces over these division rings are given. Questions concerning linear functionals, the Hahn-Banach Theorem and Reflexivity are considered. The Stone-Weierstrass Theorem is proven for functions with values in a real Cayley Dickson algebra of dimension n. The concepts of inner product spaces and Hilbert …

An Experimental And Theoretical Study Of The Nucleation Of Water Vapor On Ions In Helium And Argon, Daniel R. White

Doctoral Dissertations

"The nucleation of water vapor on ions in atmospheres of helium and argon was studied using an expansion type cloud chamber. Separation of the positive and negative ions was achieved so that the nucleation could be studied as a function of both the sign of the ionic charge and the supersaturation. A semiphenominological theory was developed as an extension of the classical theory to include the effects of the ionic charge on the nucleation process. The theoretical model of the prenucleation embryo was assumed to possess an oriented dipole surface layer with the direction of orientation dependent on the sign …

Upper Cretaceous And Lower Cenozoic Foraminifera Of Three Oil Wells In Northwestern Iraq, Farouk Sunallah Al-Omari

Doctoral Dissertations

"Seventy-five samples of well cuttings and cores from the Iraq Petroleum Company Butmah Well No. 9, Ain Zalah Well No. 16 and Ain Zalah Well No. 17, in northwestern Iraq at approximately 36° 37' north latitude and 42° 41' east longitude, have been examined in detail. The lithologic descriptive term "marl" is replaced by calcareous shale or argillaceous limestone, and the term "globigerinal limestone" is not considered applicable. The foraminiferal fauna from the upper part of the Shiranish Formation prove to be of Maestrichtian age. The Mesozoic-Cenozoic boundary is recognized on the basis of "smaller foraminiferal" faunal assemblages; it is …

A Coordinate Oriented Algorithm For The Traveling Salesman Problem, Joseph Sidney Greene

Doctoral Dissertations

"The traveling salesman problem may be stated as follows: "A salesman is required to visit each of n given cities once and only once, starting from any city and returning to the original place of departure. What route should be chosen in order to minimize the total distance traveled?" A new algorithm is developed which gives a good approximation to the solution for a large number of cities using reasonable computer time and which will converge to the exact solution if allowed to continue. This algorithm is a branch and bound technique which utilizes the distance between cities in its …

A Quasi-Lattice Model Of Simple Liquids, Jesse Herbert Collins

Doctoral Dissertations

"A cellular model of simple liquids is proposed which eliminates the objectionable feature of long range order found in other cell models. The volume is divided into N identical spherically symmetric cells, each occupied by one molecule. The cell-center density distribution relative to an average given cell center forms a series of Gaussian peaks whose width is proportional to the square root of the distance from the given cell center. The number of cell centers and average radial distance represented by each of the peaks correspond to a face-centered cubic lattice. The molecular pair distribution function is determined for several …

A Study Of Far Infrared Grid Filters, Harold Victor Romero

Doctoral Dissertations

"The diffraction theory for the transmission of electromagnetic fields through a grid in a dielectric is derived and experimentally checked in the visible wavelength region. In the far infrared, an approximate mathematical representation is found to describe the grids in dielectrics. The empirical equations in the far infrared are combined with the electrical circuit-transmission line analog for inductive grids. Detailed structure of the transmittance versus wave number curves are presented. Then the theory of multielement grid filters is derived and compared with experiment. The properties of the filters can be predicted from a knowledge of the characteristics of the individual …

A Heuristic Algorithm For Determining A Constructive Suboptimal Solution To The Combinatorial Problem Of Facility Allocation, Harry Kerry Edwards

Doctoral Dissertations

"The major problem in plant layout is to determine the most economical relative location of facilities. There are two distinct types of suboptimal solutions to this combinatorial problem: construction and improvement. The writer has developed Modular Allocation Technique (MAT) which is the first useful construction suboptimal technique. The MAT general algorithm, a theorem relating the MAT solution to the optimal solution and an example problem are given. A computer program has been written that will apply MAT to the allocation problem for a maximum of 40 facilities. Results are given to demonstrate how MAT solutions may be used as initial …

Completeness And Related Topics In A Quasi-Uniform Space, John Warnock Carlson

Doctoral Dissertations

"Completions and a strong completion of a quasi-uniform space are constructed and examined. It is shown that the trivial completion of a T₀ space is T₀ . Examples are given to show that a T₁ space need not have a T₁ strong completion and a T₂ space need not have a T₂ completion. The nontrivial completion constructed is shown to be T₁ if the space is T₁ and the quasi-uniform structure is the Pervin structure. It is shown that a space can be uniformizable and admit a strongly complete quasi-uniform structure and not admit a complete uniform structure. Several counter-examples …

Discrimination Of Signal And Noise Events On Seismic Recordings By Linear Threshold Estimation Theory, David Nuse Peacock

Doctoral Dissertations

"The object of this study is the investigation of a linear threshold element technique for identifying surface multiples on a single seismic trace. Traces of seismic events were generated which contained primaries, surface multiples, and various levels of Gaussian random noise. Since it was necessary to separate the events as much as possible, the traces were subjected to pulse-compression deconvolution processing prior to LTE analysis. Mean frequency, peak frequency, amplitude spectrum variance, periodicity, and polarity were employed as pattern parameters. A set of weights was found that would maximize the moment of inertia of the S line distribution of the …

Heuristic Algorithms For The Generalized Vehicle Dispatch Problem, Leland Ray Miller

Doctoral Dissertations

"A heuristic algorithm, called the sweep algorithm, is developed for the vehicle dispatch problem with distance and load constraints for each vehicle. A mathematical development and a step procedure for the sweep algorithm is given. Also given are eight problems and their solutions derived by the sweep algorithm. The solutions for this algorithm are compared with solutions from other vehicle dispatch algorithms, and the sweep algorithm is found to give better results for almost every problem. Various modifications are also presented for the sweep algorithm. A mathematical formulation is given for the vehicle dispatch problem with arbitrary cost functions at …

Theory Of Droplet Growth In Clouds. I. The Transient Stage Of The Boundary-Coupled Simultaneous Heat And Mass Transport In Cloud Formation, John C. Carstens, Joseph T. Zung

Physics Faculty Research & Creative Works

Two solutions to the system of equations describing the simultaneous heat and mass transport involved in the condensational growth of a droplet in a supersaturated atmosphere are presented. The first, valid for very short times, describes the transient stage of such growth; the second, valid for longer times, presupposes the establishment of a steady-state condition. The two are shown to be complementary for the cases examined. The equations examined satisfy the usual boundary conditions imposed on a drop in a concentric sphere as required by the cellular model for cloud formation. Hence our results can be immediately extended to the …

Evaluation Of The Social Impact Of Reservoir Construction On The Residential Plans Of Displaced Persons In Kentucky And Ohio, Richard L. Ludtke, Rabel J. Burdge

KWRRI Research Reports

The states of Kentucky and Ohio have numerous reservoir projects at various stages of planning and construction. Each of the projects produces substantial social impact for the residents of the area and particularly for those persons affected by a loss of property and homes. This impact is not uniform in that people respond differently to displacement and the methods of adjusting relocation are known to differ among people.

This research was initiated to develop and test a model for explaining migration under such conditions. The model includes a consideration of people's potential for transferring existing statuses to new residences, the …

Note On "Approximate Free Energies For Heisenberg Ferromagnets", J. H. Hemmann, Harry A. Brown

Physics Faculty Research & Creative Works

No abstract provided.

Measurements Of Excited-State Population Ratios Of Atomic Hydrogen Produced By Charge-Exchange Neutralization Of Energetic Proton Beams, Robert H. Mcfarland, Archer H. Futch

Physics Faculty Research & Creative Works

Excited-state population ratios for atomic hydrogen have been measured for energetic hydrogen ions neutralized by charge exchange with a number of different metallic vapors and permanent gases. Electric field ionization techniques were used to determine excitation ratios. Detection of the energetic ions and neutrals was accomplished using partially depleted surface-barrier detectors. Counting, using phase-detection techniques in which an add-subtract scaler was phased to the signal, provided an improved signal-to-noise ratio. Two methods were used to provide desired targets. Metallic vapor and permanent-gas thin targets of the order of 10-5 mTorr cm were produced as chopped neutral beams, using conventional crossed-beam …

Ground-State Wave Function Of Shallow Donors In Uniaxially Stressed Silicon: Piezohyperfine Constants Determined By Electron-Nuclear Double Resonance, Edward B. (Boyd) Hale, Theodore G. Castner

Physics Faculty Research & Creative Works

Stress-induced changes in the ENDOR spectra of a shallow donor electron interacting with various Si29 nuclei neighboring the donor have been experimentally and theoretically investigated. For each of the three measured donors - As, P, and Sb - the compressional, uniaxial stress was applied along the [001] axis and its magnitude corresponded to strains up to 10-3. To describe the observed linear and quadratic shifts and splitting's of the lines in an ENDOR shell, we have defined a set of piezo hyperfine constants. One piezo hyperfine constant was measured for each axis-class shell; three independent piezo hyperfine constants were measured …

(02) The Papers Of Robert H. Goddard, Volume I: [1927 And 1933: Material For An Autobiography], Robert H. Goddard, Esther C. Goddard, G. Edward Pendray

The Papers of Robert H. Goddard

Meticulously curated and edited by Esther C. Goddard and G. Edward Pendray, The Papers of Robert H. Goddard is a 1700-page 3 volume set published in 1970. The set presents a careful and exhaustive chronological presentation of Robert Goddard’s life through diary snippets, notebook entries, correspondence, publications, speeches, patent outlines, school papers, press, reports and more.

This section contains material for an autobiography written by Robert Goddard in 1927 with interpolations in 1933.

Disclaimer: The images in these scans have been rendered somewhat distorted after the fact. We apologize for this error. Thankfully, most of the photographs used in these …

(04) The Papers Of Robert H. Goddard, Volume I: 1898-1924 [1898-1914: Speculation And Preparation], Robert H. Goddard, Esther C. Goddard, G. Edward Pendray

The Papers of Robert H. Goddard

Meticulously curated and edited by Esther C. Goddard and G. Edward Pendray, The Papers of Robert H. Goddard is a 1700-page 3 volume set published in 1970. The set presents a careful and exhaustive chronological presentation of Robert Goddard’s life through diary snippets, correspondence, publications, speeches, patent outlines, school papers, press, reports and more.

This section covers Robert Goddard's life from age sixteen through thirty-two. It contains diary entries, correspondence, school themes, entries from his green notebooks (used for calculations), a graduation oration, published articles,

This section contains the following articles:
"The Use of the Gyroscope in the Balancing and …

(03) The Papers Of Robert H. Goddard, Volume I: 1898-1924 [1921: Autobiographical Statement], Robert H. Goddard, Esther C. Goddard, G. Edward Pendray

The Papers of Robert H. Goddard

Meticulously curated and edited by Esther C. Goddard and G. Edward Pendray, The Papers of Robert H. Goddard is a 1700-page 3 volume set published in 1970. The set presents a careful and exhaustive chronological presentation of Robert Goddard’s life through diary snippets, notebook entries, correspondence, publications, speeches, patent outlines, school papers, press, reports and more.

This section is a brief Autobiographical Statement written by Robert Goddard in 1921. It was presumed to have been written for the Inventors Bulletin, but it is now known whether the statement was ever published.

Disclaimer: The images in these scans have been rendered …

(08) The Papers Of Robert H. Goddard, Volume Ii: 1925-1937 [1925-1930: Liquid-Propellant Rockets Fly], Robert H. Goddard, Esther C. Goddard, G. Edward Pendray

The Papers of Robert H. Goddard

Meticulously curated and edited by Esther C. Goddard and G. Edward Pendray, The Papers of Robert H. Goddard is a 1700-page 3 volume set published in 1970. The set presents a careful and exhaustive chronological presentation of Robert Goddard’s life through diary snippets, notebook entries, correspondence, publications, speeches, patent outlines, school papers, press, reports and more.

This section covers Robert Goddard's life from 1925 through the middle of 1930. During this time, Goddard achieved his greatest success on March 16, 1926, with the first ever flight of a liquid-propellant rocket. This period also saw a 1929 flight that attracted a …

(01) The Papers Of Robert H. Goddard, Volume 1: 1898-1924 [Forward, Introduction], Esther C. Goddard, G. Edward Pendray

The Papers of Robert H. Goddard

Meticulously curated and edited by Esther C. Goddard and G. Edward Pendray, The Papers of Robert H. Goddard is a 1700-page 3 volume set published in 1970. The set presents a careful and exhaustive chronological presentation of Robert Goddard’s life through diary snippets, notebook entries, correspondence, publications, speeches, patent outlines, school papers, press, reports and more.

This section contains a forward by G. Edward Pendray and an introduction by Esther C. Goddard.

Disclaimer: The images in these scans have been rendered somewhat distorted after the fact. We apologize for this error. Thankfully, most of the photographs used in these papers …

An Elementary Mathematics Curriculum Study To Determine If Achievement And Attitude Can Be Influenced By A Textbook Adoption, Elsie M. Railey

All Master's Theses

There is on the market a wide range of contemporary mathematics textbooks available. Textbooks approach mathematics differently and there is a variation in terms of the amount of time allocated to a topic, the development of elementary concepts and laws of arithmetic, and the amount of drill and repetition. The sequential development of the texts follows closely, but the scope and content differ significantly. Specifically, it is the purpose of this study to determine if there is a significant difference between series, as opposed to those in another mathematics series, in the variables of attitude and achievement. The two textbooks …

Realistic Impulsive P Wave Source In An Infinite Elastic Medium, Joseph Hugo Hemmann

Doctoral Dissertations

"The generally assumed instantaneous impulsive pressure sources for an elastic P wave in an infinite medium lead to basic contradictions, a step function source yielding infinite displacements as the shear modulus goes to zero, and the total energy radiated by a delta function (or any derivative of the delta function) source being infinite. By noting that the character of the solution in the elastic region must match the acoustic case near the source, a realistic impulsive pressure source is postulated which has a finite time history. The elastic field produced by this source is then obtained in closed form. A …

The Reaction Of N-Sulfinylamines With Diazoalkanes, Harry R. Musser

Doctoral Dissertations

"The photochemical decomposition of diphenyldiazomethane in the presence on N-sulfinylamines leads to ketimines. By-products include tetraphenylethylene, benzophenone, thiobenzophenone, and benzophenone azine. This reaction is the first example of carbene addition to a non-carbon containing multiple bond system. Evidence indicates that the carbene adds to the N=S bond of the N-sulfinylamine to give the corresponding thiaziridine-S-oxide which spontaneously decomposes to give ketimine and SO. In the dark N-sulfinylaniline catalyzes the decomposition of diazoalkanes to carbenes. This decomposition presumably takes place through a thiatriazole-1-oxide intermediate. The carbene then reacts either with N-sulfinylaniline to form ketimine, after loss of SO, or with diazoalkane …

Modified Method Of Linear Associative Retrieval, James Donald Byrd

Masters Theses

"It is becoming increasingly important for those in decision making positions to have the most current and accurate data possible as related to their particular needs. Although there are several well known retrieval techniques available an intensified effort is being made at many installations to provide a retrieval system that will supply the demands of their own needs. One well known approach to the solution of information retrieval is linear associative retrieval. The solution that has been proposed requires several computer runs on some requests and therefore is very time consuming. The author has implemented a method to eliminate unnecessary …

St. Louis Limestone, Stratigraphy And Petrography, Near Its Type Locality, Abd El-Aziz El-Hady A. Borahay

Masters Theses

"The St. Louis Limestone of the Upper Meramecian Series, Mississippian System, is typically lithographic, light-to light-olive gray in color, dense, and fractures conchoidally. It is brecciated, especially in the lower part, and contains some chert nodules. Oolites are present close to the top of the formation. The Salem-St. Louis contact is placed at the base of the lowest breccia zone and the top of Salem is characterized by crystalline quartz and abundance of chert nodules. The appearance of typical Ste. Genevieve oolites with sand-size quartz grains indicates the St. Louis-Ste. Genevieve contact. The St. Louis Limestone is characterized by dominance …

Evaluation And Application Of Dye Tracers In Karst Terrain For Determining Aquifer Characteristics, Milton Frank Bradley

Masters Theses

"As ground water becomes increasingly important as a source of water in the United States, reliable information on the hydrological characteristics of carbonate aquifers must be obtained in order to develop them intelligently. Various tracers have been used in the past to determine if two or more points are connected hydrologically. Today there exists a number of excellent dye tracers and tracer methods have been developed in unconsolidated and clastic aquifers for determining hydrological characteristics. This paper reviews the various dye tracers and methods which might be applied in a carbonate karst terrain using wells as injection and sampling points. …

Petrology And Diagenesis Of The Cyclic Maquoketa Formation (Upper Ordovician) Pike County, Missouri, Edwin Carl Kettenbrink Jr.

Masters Theses

"The Maquoketa Formation (Upper Ordovician-Cincinnatian Series) has been extensively studied for over one hundred years, but a petrographic study of its cyclic lithologies has been neglected. The following six distinct Maquoketa lithologies have been recognized in this study in Pike County, Missouri: 1) phosphatic biosparite, 2) phosphorite, 3) micrite-microsparite, 4) dolomitic shale, 5) dolomitic marlstone, and 6) dolomitic quartz siltstone. Three cycle types are present in the Maquoketa. They are expressed as thin beds (1-20 inches) of alternating micrite-shale, micrite-marlstone, and shale-siltstone. Contacts between different lithologies are sharp, indicating a primary sedimentological origin for the cycles. Precisely what mechanism was …

Radiative Lifetime Of The A¹Π State And The Transition Moment Variation Of The Fourth Positive Band System Of Carbon Monoxide, Joseph George Chervenak

Doctoral Dissertations

"The lifetime of the A¹π state of carbon monoxide has been measured using a pulsed invertron excitation source and delayed coincidence measurement technique on the fourth positive system. Eighteen bands, originating from the upper states v' = 0 to 5, were examined at pressures between 500 and 50 microns, with no pressure dependence noted. The data were corrected for photon "pile up" and least-squares fitted to the sum of two exponentials. The transition moment was found to vary and was expanded about the r-centroid of the v' = 0 to v" = 0 transition. Oscillator strengths are calculated and compared …

A Fundamental Investigation Of The Gas Phase Polymerization Of Styrene And Vinyl Type Monomers In A Low Power Inductively Coupled 4 Mhz Rf Plasma, L. F. Thompson

Doctoral Dissertations

"A study has been made on the plasma polymerization of styrene and vinyl type monomers in a cold, low power, inductively-coupled RF plasma. All vinyl type monomers yielded an insoluble, crosslinked film which was slightly colored. A kinetic study is reported for styrene. The effects of power level, bleed rate of monomer, pressure and reactor geometry on the rate of polymer formation are reported. A mechanism is postulated for plasma polymerization. It was found that the initiation step was the rate controlling step and that the reaction followed a cationic polymerization scheme. Both crosslinking and discoloration of the polymers occur …