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An Experimental Investigation Of Highly Undercooled Magnesium Silicate Chondrule-Like Spherules, Harry Nicholas Planner

Earth and Planetary Sciences ETDs

A series of experiments, involving molten magnesium silicate spherules that were subjected to high initial cooling rates and allowed to nucleate at high temperatures (985-1350°C), were performed so as to compare their thermal histories to the resulting internal features. Such comparisons could be used to decipher the thermal history of chondrules and the conditions surrounding their formation based on their mineralogy, crystal morphology, and overall texture. Various features of the spherules were correlated with the initial high cooling rate process, nucleation temperature, and the maximum temperature attained during the recalescance to demonstrate the restrictions resulting from or their sensitivities to …

Syntheses And Characterizations Of Vanadyl (Iv) Complexes With Dihydroxydicarboxylate Ligands, Sharon K. Hahs

Chemistry and Chemical Biology ETDs

Binuclear complexes of the vanadyl(IV) tartrates have already been shown to exist both in the solid state and in solution. These complexes consist of two vanadyl(IV) ions bridged by two tartrato(4-) ligands, either of the same--DD (or LL)-- or opposite--DL--enantiomeric configuration. (The meso isomer of tartaric acid will not form binuclear complexes with vanadyl(IV).) The DL complex is more stable than the DD complex due to a greater degree of staggering between the vicinal hydrogen atoms on each tartrate chain. Investigations of vanadyl(IV) complexes with substituted tartaric acid ligands--specifically, (±)-dimethyltartaric acid and (±)-threomethyltartaric acid--have been undertaken to determine whether this …

Pi-Meson Absorption On The Deuteron, Bruce Goplen

Physics & Astronomy ETDs

The nonradiative absorption of positive pi-mesons by deuterons is studied within the framework of Lagrangian formalism and the impulse approximation. The pi-nucleon absorption interaction is taken to be pseudovector; however, the reaction is believed to be dominated by pi­nucleon scattering. Thus, the main thrust of the investigation is directed at three different approaches to the scattering interaction. First, the Hamiltonian formalism of Koltun and Reitan is extended to include energetic pions. An off-shell form is chosen for p-wave scattering which at low energy reduces to the field-theoretical result of Klein. In the second approach, the S-matrix formalism of Lazard, Ballot …

A Theoretical Study Of The Predissociation Of The O2 B 3Ʃu- Electronic State, Richard Allan Harris

Physics & Astronomy ETDs

It has been known for many decades that the B 3Ʃ_u^- state of the oxygen molecule, the upper state of the Schumann-Runge electronic band system, is predissociated. The predissociation has been attributed to the 3Π_u state, arising from the ground state, separated atom, manifold of molecular states, by previous investigators with the crossing point of the potential energy curves ranging from somewhere on the inner limb to somewhere on the outer limb of the bound excited B 3Ʃ_u^- state. This research has been undertaken to quantitatively describe the observed predissociation. A model with adjustable parameters …

On The Benefactive Feature In Transitivity, Dale Ellen Gaucas

Electrical Engineering and Computer Science - Technical Reports

An elaboration on the transitivity system network introduced by M. A. K. Halliday is developed. This extension consists of a separate feature system network for the participant role of “beneficiary”. The formulation of the proposed grammar rules to conjoin this network and Halliday's is facilitated by building up the transitivity network to describe "systemically” and uniquely each type of benefactive and range clause presented by Halliday. Systemic descriptions of these clauses are given as examples throughout the discussion.

Multiple Uses Of Utah Irrigation Canals: Cache County As A Case Study, James J. Kennedy, Komain Unhanand

Reports

Irrigation use is an obvious benefit of Utah canals that has been recognized for over 100 years. This study attempts to illustrate other, less obvious, uses. the major use examined was recreational, but canals are presently functioning as storm drainage systems and have potential for diverting flood crests in many river systems.

Recreational use of canals falls into two categories. There is passive use such as its landscape values, affects on creating shade and bird-wildlife habitat, etc., that is difficult to quantify but no less important than active canal use such as tubing, hiking, bank-play, bicycling, etc. We selected several …

Models For Estimating Psychiatric Bed Needs, Patricia A. Brenneman

Loma Linda University Electronic Theses, Dissertations & Projects

Inland Counties Comprehensive Health Planning Council wished to estimate the psychiatric bed needs by type (such as state hospitals, board and care homes, etc.) in San Bernardino County from the distributions of patient arrivals and of lengths of stay. A statistical description of the system during 1973 was considered the first step toward estimating future bed needs. A computer simulation model using IBM's programming language General Purpose Simulation System (GPSS) was developed and was found to be unsatisfactory.

Theorems were then developed for a statistical model, seeking to predict future bed needs. The most convenient of these theorems states that …

Unusual Lavas From Molokai, Hawaii: Alkalic Olivine Basalts Transitional To Hawaiites And Strontium-Rich Mugearites, Paul Frank Hlava

Earth and Planetary Sciences ETDs

ABSTRACT

Systematic data has recently been published on the compositions of major mineral phases in rocks of the tholeiitic, alkalic, and nephelinic suites from the island of Maui, Hawaii. The present study was initiated to provide similar data from the rocks of Molokai, Hawaii, from which the nature of interisland variations could be established. During the study, it became obvious that many of the rocks were unusual and so this study also provides information on the bulk rock, trace element, and mineral compositions of alkalic olivine basalts transitional to hawaiites and Sr-rich mugearites.

From a total of 14 basalts collected …

Geology Of The Northern Part Of The Sierra Cuchillo, Socorro And Sierra Counties, New Mexico, Florian Maldonado

Earth and Planetary Sciences ETDs

The northern Sierra Cuchillo, Socorro and Sierra Counties, New Mexico is approximately 32 miles northwest of Truth or Consequences, New Mexico. The Sierra Cuchillo is a narrow fault-block range in the Basin-Range province and is a structurally high element west of the Rio Grande trough. It is bordered on the west by the Winston graben and the Black Range and on the east by Monticello graben and the San Mateo Mountains.

Permian rocks consist of the Yeso and San Andres Formation, with an aggregate thickness of 2100 ft (640 m). Upper Cretaceous rocks, 40 ft (10 m) thick, consist of …

Public Access To The Beaches Of Connecticut, Don W. Oswalt

Marine Affairs Theses and Major Papers

Elements of the public of Connecticut are engaged in direct conflict against private and municipal property rights over the issue of increased public access to beaches of the state. In Connecticut, as well as the nation, definite solutions to the problem are slow to materialize. The public's right to the whole beach is being clarified by only a few states, while public access under common law remains a clouded issue nationwide. The research study I am proposing would examine in detail the legal issues involved, the state and federal legislative actions, geographical considerations, etc. I feel that the resulting collation …

The Development Of An Arsenic(V) Selective Electrode, Sandra Gee Kang

Dissertations and Theses

The object of this research was to develop an arsenic(V) selective electrode. The electrode is based on a solid state membrane prepared by pressing a precipitate of silver arsenate-silver sulfide into a pellet. After the electrode was made, experiments were designed to check for three general characteristics of the electrodes: dependence of potential on pH for constant arsenic(V) concentration; dependence of potential on arsenic(V) concentrations at constant pH and extent of interference due to phosphate and arsenic(III) ions. From these measurements, it was found that Ag₂HAs0₄ was formed originally in the membranes containing a small fraction of …

Erratum: On Improved Wkb (Uniform Asymptotic) Quantum Conditions, Dunham Corrections, The Langer Modification, And Rkr Potentials, Russell T. Pack

Faculty Publications

In Eqs. (28) and (29) p should be changed to t.

Molecular Model For Ice Clusters In A Supersaturated Vapor, Barbara N. Hale, P. L. M. Plummer

Physics Faculty Research & Creative Works

A molecular model previously applied to prenucleation water clusters is used to examine ice I_h, embryos. The canonical partition function is evaluated for clusters having from 6 to 64 water molecules. The intermolecular vibrational free energies are extrapolated to clusters containing up to 120 molecules and free energies of formation, nucleation rates, and critical supersaturation ratios are calculated and compared with experiment. For the clusters studied, the ice I_h structure appears to be much less stable at all temperatures than the more spherical clathratelike cluster.

Electrochemical Investigations Of The Mechanisms Of Reduction Of Benzaldehyde Compounds In Sulfolane, Neal Russell Armstrong

Chemistry and Chemical Biology ETDs

The mechanisms of the reduction of benzaldehyde and several sub­stituted benzaldehydes in the dipolar, aprotic solvent sulfolane, have been investigated. A combination of cyclic voltammetry, transmission spectroelectrochemistry and ring-disk voltammetry was used in this study. Cyclic voltammetric studies indicated that the one-electron benz­aldehyde reduction was followed by a dimerization of the radical anion intermediate to the pinacol. The reduction peak potentials of the benzaldehydes were cathodically shifted in sulfolane compared to values obtained in aqueos media. This indicates an increase in the benzaldehyde reduction energy in the aprotic solvent. The rate of the following chemical reaction was also slower than …

Matrix Fields Over The Integers Modulo M, Robert M. Mcconnel, Jacob T. B. Beard Jr.

Mathematics Technical Papers - Archive

Let Zm denote the ring of integers modulo m and let [see pdf for notation] denote the complete ring of all [see pdf for notation] matrices over Zm under the usual matrix addition and multiplication. The primary purposes of this paper are to characterize and count all subfields of the ring [see pdf for notation] . Related results are given on field extensions in [see pdf for notation] of subfields of [see pdf for notation] . Partial results on subfields of [see pdf for notation] when R is an arbitrary finite commutative ring with identity are also given. Having basic …

The Purification And Characterization Of Methylmalonyl Coa Mutase From Bovine Brain, Damon Martin

Theses and Dissertations

Methylmalonyl CoA mutase has been purified over 2300-fold from bovine brain using fractional precipitation, ion exchange resins, and gel filtration procedures. The crude extract had an equal mixture of mutase in the halo- and apoenzyme form. After the final purification step the ratio had changed to 86% holo-enzyme and 14% apoenzyme. The mutase enzyme had a pH optimum of 7. 0 in Tris-HCI buffer. The Km values for L-methylmalonyl CoA and succinyl CoA were 7.7 x 10^-4 M and 1.8 x 10^-4 M respectively. The equiIibrium constant in the direction of succinyl CoA formation was 19. Inhibition with N-ethylmalei-mide was …

Characterization Of Zinc-Containing Metalloproteins By Resonance Raman Spectroscopy, Robert Edward Derry

Dissertations and Theses

Cobalt-substituted carboxypeptidase and carbonic anhydrase were chosen as candidates for resonance Raman spectroscopy because they possess visible absorption due to the Co(II)-protein complex. However, no evidence for resonance-enhanced peaks due to the cobalt-containing chromophore was found with laser excitation near the visible absorption bands (514.5 nm) or closer to the ultraviolet absorption bands (457.9nm).

Arsanilazocarboxypeptidase and model azotyrosine compounds were selected for a Raman spectroscopic investigation because they have intense absorption bands in the visible region. All of these substances yielded similar resonance Raman spectra. Although there was no evidence for specific zinc-ligand vibrations, shifts in vibrational frequencies of the …

Statistical Modelling Of Computer Systems: A Review, Amrit L. Goel, Anand M. Joglekar

Electrical Engineering and Computer Science - Technical Reports

This paper briefly reviews the data dependent statistical methods useful for computer systems modelling. The techniques are classified according to their applicability toward comparison, tuning and design of computer systems. A review of publications dealing with statistical modeling of computer systems is presented and a comprehensive bibliography is included to provide a useful source of reference toward the present and potential applications of statistical methods for computer system modelling.

A Polynomial Dual Of Partitions, Jacob T. B. Beard, Ann D. Dorris

Mathematics Technical Papers - Archive

Let [see pdf for notation] be a non-negative integral polynomial. The polynomial P(x) is m-graphical, and a multi-graph G a realization of P(x), provided there exists a multi-graph G containing exactly P(1) points where [see pdf for notation] of these points have degree i for [see pdf for notation]. For multi-graphs G,H having polynomials P(x), Q(x) and number-theoretic partitions (degree sequences) [see pdf for notation], the usual product P(x)Q(x) is shown to be the polynomial of the Cartesian product [see pdf for notation], thus inducing a natural product [see pdf for notation] which extends that of juxtaposing integral multiple copies …

On The Method Of Vector Lyapunov Functions, V. Lakshmikantham

Mathematics Technical Papers - Archive

The method of vector Lyapunov functions consists of employing several Lyapunov-like functions and the theory of vectorial differential inequalities. This general comparison technic leads to a more flexible mechanism to study the qualitative properties of nonlinear differential systems. This method is also effective in discussing interconnected dynamical systems where a construction of a single Lyapunov function is difficult. However, an unpleasant fact in this approach is the requirement of quasimonotone property of the comparison system. An idea to get around this will be indicated which might be useful in applications. Also, an extension of this technic to abstract cones will …

Concerns Of Postnatal Mothers About Sexuality, Sheela A. Gideon

Loma Linda University Electronic Theses, Dissertations & Projects

An exploratory study was designed to find out what questions mothers had about postnatal sexuality. A questionnaire was prepared by the nurse researcher to find out answers to the following questions.

1. What specific questions do mothers have about sexual relations following delivery?
2. Do mothers feel free to initiate discussion about resumption of intercourse following delivery?
3. Do mothers like their husbands to be included in the discussion?
4. When do mothers prefer to receive information regarding sexual relationships following delivery?

The questionnaire was mailed to fifty primipara mothers between three and four weeks after delivery. Mothers with pronounced anemia, heart and lung …

Prenatal Instruction Of Breast Feeding Mothers, Anita Berry

Loma Linda University Electronic Theses, Dissertations & Projects

This experimental study tested the effect of prenatal instruction on the success of a group of mothers who desired to breast feed their infants. It was hypothesized that mothers receiving information on how to nurse their infants, how to prevent complications and how to cope with common problems of breast feeding would have a higher success rate than those not so instructed.

Criteria for success was that the mothers would have an adequate supply of milk to meet the nutritional demands of their infant without supplementation, would have fewer and less severe complications, and would express a higher degree of …

A Non-Procedural High-Level Language For Automated Design Of Application Systems, J. F. Nunamaker

Department of Computer Science Technical Reports

No abstract provided.

Restrictions On The Potential And Cross Section For Collisions Between Rigid Rotors, Louis Biolsi Jr.

Chemistry Faculty Research & Creative Works

A restricted distorted-wave treatment of the total cross section when two rigid diatomic molecules with orbital and nuclear spin angular momenta collide is examined. There are certain restrictions on the intermolecular potential and on the possible combinations of the various quantum numbers. These restictions are examined for the lowest order nonspherical elastic and the lowest order inelastic contributions to the total cross section. The effects of degeneracy averaging and of collisions between indistinguishable molecules are also briefly examined.

Exploration Of The Incidence Of Identified Emotional Disorders In Selected General Hospitals Of Nebraska, Arlene M. Van Horn

Loma Linda University Electronic Theses, Dissertations & Projects

A descriptive-comparative survey using content analysis of medical records has been done to determine the frequency with which emotional disorders are identified by medical personnel in the population hospitalized in small general hospitals in north-central Nebraska.

A systematic, random sample of medical records was taken from two hospitals arbitrarily included in the study on the basis of bed capacity and distance from mental health facilities.

Each medical record that was reviewed has been placed in a category based on whether an emotional disorder was identified in it by the medical personnel, or whether it contained recorded behaviors that could indicate …

Alumina-Catalyzed Cope Rearrangement, Paul Jhy-Shing Wang

Dissertations and Theses

The alumina-catalyzed Cope rearrangements of meso- and dl-3,4-diphenylhexa-1,5-diene were examined in detail, following up a preliminary observation by H. Berg at Portland State University. Commercial column-chromatography grade alumina was employed, and was further activated before use by heating at 650-700° for four hours.

Using a ratio of 20 mg of dl-3,4-diphenylhex-l,5-diene to 1 g of alumina in heptane, the Cope rearrangement was complete within 15 minutes at room temperature to give exclusively trans,trans-1,6-diphenylhexa-1,5-diene. This was identified.by melting point, infrared spectroscopy and vapor phase chromatography.

The catalyzed rearrangement of meso-3,4-diphenylhexa-l,5-diene was run using the same diene …

The Effects Of Pentachlorophenol On The Electrical Conductivity Of Lipid Bilayer Membranes, William Harvey Perman

Dissertations and Theses

The effects of pentachlorophenol (PCP), a widely used pesticide, on the electrical characteristics of lipid bilayer membranes has been studied. When a small amount of PCP (even at a concentration of a few micromoles per liter) is present in the electrolytic solution surrounding the membrane, the electrical conductivity of the membrane significantly increases. The present work was concerned with detailed measurements of the changes in the conductivity caused by PCP under chemically controlled conditions. The experimental results were analyzed to determine the permanent species in the membrane, and an attempt was made to correlate the data with existing models of …

A Position Paper Of Environmental Education For Nelson County, Geneva B. Hunt

Masters Theses & Specialist Projects

The results of a survey, concerning environmental education taken of the educators of the Nelson County School System, indicated a need for environmental education workshops and classes.

The status of environmental education in the nation and in Kentucky were studied and compared. A research was done of the status of environmental education in Nelson County, and implications were drawn for implementing environmental education in the Nelson County School System.

A tentative program for implementing environmental education in the Nelson Country schools was given, and a bibliography of resources and materials to be used in said program was included.

Metabolism Of 3-Isopropyl-4h-2,1,3-Benzothiadiazin-4-(3h)-One-2,2-Dioxide (Bentazon) In Agitated And Non-Agitated Sediment, David Cortez Gutierrez

Theses and Dissertations

Bentazon, (3-isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-l-2,2-dioxide) a new experimental herbicide, was studied under the effects of sterile and non-sterile conditions, 12 hours light: 12 hours dark and totally dark conditions, and agitated and non-agitated conditions in aquatic sediment. The effects of the different levels of BOD/COD values on the decomposition of Bentazon were studied. Photoperiod, sterility, and BOD/COD levels appeared to have no influence in the breakdown of Bentazon. Agitation-time interaction appeared to be the only factor that influenced the more rapid degradation of Bentazon. Bentazon was the major 14C-residue found in the water; it was followed by an unknown. The third major metabolite …

The Attack Of Hard And Soft Nucleophiles On 6-Methylsulfonyl-, 6-Methylsulfinyl-, And 6-Methylthioaminopteridines, William David Johnston

Theses and Dissertations

In an attempt to prepare 6-anilino and 6-benzylaminopteridines, 2,4,7-triamino-6-methylsulfonyl and 2,4,7-triamino-6-methylsulfinylpteridines were prepared and reacted with a number of benzylamines and aniline. These hard nucleophiles gave amine exchange products with no displacement at the 6 position. Aliphatic amines gave exchange in the 2,4-and 7-positions. The exchange occurring in the 7-position must be occurring by an AE mechanism. This is the first such exchange reported in a ring other than a 1,3-azine. Aniline gave no exchange product except in an acid catalyzed reaction, and then gave exchange in only the 2 and 4-positions. Numerous reactions on related substrates, are reported. Soft …