Digital Commons Network^™

3d Printed Fixed Wing Aircraft Competition, Sidney E. Long, Mitchell Heise, Jack Bride, Daniel Salinas

Mechanical Engineering

Cal State LA and Arlington University, Texas are hosting the same 3D printed, fixed wing aircraft competition for 2025. Cal Poly requires a competitive plane that can adhere to each rule and be piloted remotely to achieve the longest time in the air. The plane must utilize solely 3D printing technology for the wings, body, and all other structures. The only off-the-shelf components can be the motor and electronics, as well as mechanical devices such as hinges.

Degradation Characterization Of Nopal-Based Biopolymer Made From Opuntia Sp. Juice, Beeswax, Animal Protein, And Polyvinyl Alcohol, Logan Williams, Mary Elizabeth Holland, Spencer Williams

Materials Engineering

Since the introduction of polymers in the 1960s, there has been an exponential increase in use. Driven by rapidly growing demand, the volume of polymers in the production, application, and end-of-life stages has surged. The widespread use of these materials has led to escalating environmental pollution, which disrupts ecosystems, and contributes to global ecological degradation. While advancements in recycling technologies and infrastructure have shown promise, they have not maintained pace with polymer production and disposal. This imbalance warrants research into sustainable alternatives. Environmentally benign polymers derived from renewable sources and exhibiting minimal ecological impact at the end of their life …

Chemical Recycling Of Pet Plastic Waste, Charlie Parker, Benjamin Puga, Jake Verschoor

Materials Engineering

The growing accumulation of plastic waste, specifically polyethylene terephthalate (PET), has driven the need for more efficient and scalable chemical recycling methods. This study investigated the methanolysis of PET using zinc oxide (ZnO) nanoparticles as a catalyst and tetrabutylammonium chloride (NBu₄Cl) as an ionic liquid, aiming to reduce methanol consumption while achieving high PET conversion efficiency. ZnO nanoparticles were synthesized via wet chemistry and characterized using Dynamic Light Scattering (DLS), which showed an average particle size of 13.5 nm with a polydispersity index of 0.1556, indicating a moderately-high monodisperse distribution of particles sufficient for reactions. The main conversion product, dimethyl …

Performance Evaluation Of Aminated Multi-Walled Carbon Nanotubes Incorporated With Green Synthesized Iron Nanoparticles For Toxic Dyes Sequestration From Textile Wastewater, Titus Chinedu Egbosiuba, Cynthia Chukwuemeka, Jonah Chukwudi Umeuzuegbu, Nwanneka Chibuzo Mmonwuba, Ugochukwu Ewuzie, Monday Uchenna Okoronkwo, Valentine Chikaodili Anadebe, Saheed Mustapha, Ambali Saka Abdulkareem, Jimoh Oladejo Tijani, Ashish Patel, Virendra Kumar Yadav

Chemical and Biochemical Engineering Faculty Research & Creative Works

This study evaluates the performance of aminated multi-walled carbon nanotubes (AM-MWCNTs) integrated with zerovalent iron nanoparticles (ZVI) synthesized using cashew leaf (Anacardium occidentale) extract (AM-MWCNTs@ZVI) for the removal of Congo Red (CR) and Methylene Blue (MB) dyes from textile industrial wastewater. The nanocomposite was characterized using FTIR, XRD, BET, HRSEM, and HRTEM analyses, confirming its functional groups, crystalline structure, and enhanced surface area of 1050.4 m²/g. The ecological risk degree of the textile pollutants was assessed to determine the percentage concentrations of crystal violet, Congo red, methyl orange, methylene blue and rhodamine B. Batch adsorption experiments identified optimal …

Effect Of Manufacturing And Machining Process On Recycled Composite Connecting Rods Under Tension And Compression, Walter W. Oppelt

Master's Theses

Carbon fiber reinforced polymer (CFRP) is an engineering material renowned for its high-strength and low-density material properties. Such properties make CFRPs especially useful for applications across many industries, including aerospace, automotive, marine, sporting goods, oil and gas, and more. However, with such favorable material properties comes the cost of high energy usage required to produce raw carbon fiber. Recycled carbon fiber (rCF) has emerged as a promising alternative, offering a significant reduction in energy usage. This research explores the viability of applying recycled CFRPs to internal combustion engines to both reduce energy costs during manufacturing and while in use. Mechanical …

Myceli-Yum: Elucidating Structure-Property Relationships For Polymer Degradation By Mycelial Digestion, Jordan Scott Ford

Master's Theses

Since the industrial entrance of polymer plastic materials, plastic has become ubiquitous in both everyday use and waste. Due to inefficiencies and knowledge gaps, current recycling methods are not able to account for the high scale of plastic waste, resulting in the bulk of this waste being landfilled, mishandled, and deposited in the environment. Mycelium, the microorganism responsible for fruiting mushroom bodies and mold growth, holds potential to reduce plastic waste and can potentially be utilized as a method of industrial recycling. Following a drug-design approach, the active site of mycelial enzymes responsible for natural biopolymer degradation have been assessed …

Design Principles For Robotic-Controlled 3d Printing Of Soft Tissue-Mimicking Materials, Karina Mealey

Master's Theses

Geometrically and physically accurate 3D models are emerging as essential tools for surgeons in pre-operative planning and training, but current methods of producing these models are not sufficient. Existing solutions have downsides such as high costs, long and tedious production times, high complexity resulting in a lack of scalability, or an inability to meet material requirements for accurately simulating human tissue.

The objective of this work is to develop principles for a low-cost, easy-to-use 3D printing system capable of prototyping with soft tissue-mimicking materials. To pursue this goal, a MyCobot280 robot arm was used as the mechanism to explore the …

Thermal Modeling Techniques For Additively Manufactured Porous Metals, Lucas D. Rambo

Master's Theses

Advances in additive manufacturing have enabled the creation of metallic components with tailored porosity, offering design flexibility for thermal, structural, and fluid transport applications. This thesis investigates the effective thermal conductivity (ETC) of porous Inconel 625 (IN625) and Inconel-ceramic composites (IN625-RAM2) fabricated by Laser Powder Bed Fusion (LPBF) using Elementum 3D’s PermiAM technology. Experimental measurements of thermal conductivity using the laser flash method are compared to numerical models built from micro-computed tomography data. Simulations were performed using both finite element (FE) and finite volume (FV) methods to evaluate thermal transport in real microstructures. The study investigates the effects of micro- …

Multimodal Self-Folding Of Shape Memory Polymer Using Laser Induced Graphene, Liam Harrison Drew

Master's Theses

Shape memory polymers (SMPs) can undergo programmed shape transformations when heated above their glass transition temperature (T_g), enabling actuation through stimuli such as infrared (IR) radiation and Joule heating. These materials are promising for deployable systems and soft robotics due to their lightweight structure and elimination of traditional mechanical components. While IR-based actuation is simple and low-cost, it lacks precision in uncontrolled environments. Joule heating offers improved control but is often limited by conductive ink properties such as thickness, stiffness, or poor adhesion. This work introduces a novel method for multimodal SMP actuation using laser-induced graphene (LIG) transferred …

Comparative Study Of Experimental And Fea Strain Data For Cnt-Coated Fiberglass Sensors, Extensometers, And Metal Foil Strain Gauges, Omar Dwidar

Master's Theses

Material testing is essential across industries such as aerospace, automotive, and construction, playing a critical role in verifying material selection, diagnosing failures, and understanding the development of flaws in structures. These insights are key to designing successful, reliable systems. Conventional metal foil strain gauges are low cost and reliable but provide limited sensitivity with a typical gauge factor around 2. Extensometers provide highly sensitive strain measurements with the disadvantage of a bulky form factor. With advanced materials such as carbon nanotubes, it is possible to manufacture a sensor with the sensitivity closer to that of an extensometer with the small …

Thermomechanical And Thermal Characterization Of Pressureless Sintered Tib2, Simone Taraborelli, Simone Failla, Diletta Sciti, Steven M. Smith, Jeremy Watts, William G. Fahrenholtz, Greg E. Hilmas

Materials Science and Engineering Faculty Research & Creative Works

The impact of high-energy milling using WC[sbnd]Co media on the pressureless sintering and properties of TiB₂ was studied. After 30 mins of milling, samples sintered at 2200 °C achieved a high relative density (>98 %) and a fine mean grain size (<2 >µm). In the microstructure WxBy phases, often containing Co, were observed at triple points, due to contamination from the milling media. Moreover, core-rim structures with multiple rims were detected: the cores consisted of pure TiB₂ grains, the rims were (TixWy)B2 solid solutions. The core-rim formation was significantly more pronounced compared to a reference sample of …

Ni-Mn-In Heusler Alloy Ribbon For Magnetocaloric Application, Bao Nguyen

Masters Theses

A traditional cooling system, which applies compression technology within the working fluid, has had a lot of negative impacts on the environment and has low efficiency. They have almost reached the thermodynamic efficiency; there is little room for further improvement. Therefore, solid-state cooling systems, especially those that use the magnetocaloric effect (MCE), have drawnmuch interest as an alternative solution for the vapor-compression system. The Heusler alloy, especially Ni-Mn-In in this research, can be an excellent candidate for this application due to its unique properties, such as the shape memory effect and giant MCE. Their giant MCE results from a first-order …

Student-Led Video Podcasting In A Chemical Behavior Of Materials Course, Erick Salvador Vasquez

Chemical and Materials Engineering Faculty Publications

Video podcasts, or vodcasts, are a form of podcasting that combines video and audio to deliver various types of educational content effectively. To our knowledge, very few studies have focused on student-produced podcasting for learning technical engineering concepts. This study explores using student-created technical videos in a course on the chemical behavior of materials through three separate assignments. The first assignment centered on sustainability aspects. Students, divided into groups of three, were tasked to review two influential journal articles on plastic waste input into the ocean and metal recycling. Each group had to prepare and deliver a technical script about …

Energy Conversion Materials: Computational Design Of Electrocatalysts Toward Sustainable Energy Applications, Courtney M. Brea

Dissertations, Theses, and Capstone Projects

As the global-scale need for sustainable energy technologies emerges due to anthropogenic climate change, electrocatalysis plays a crucial role in facilitating many sustainable processes. Several heterogenous cathode materials can perform different electrochemical activities using water, oxygen, hydrogen, carbon dioxide to deliver renewable electricity and value-added chemicals. By using the density functional theory method, it is possible to explore the structural and electronic properties that govern a catalysts’ activity and selectivity. In this thesis, we start by exploring 48 reconstructed transition metal dichalcogenides edges (MX₂, M = Mo, W; X = S, Se, Te) for carbon dioxide reduction reaction …

Colloidal Quantum Dots: A Path Toward Making Mid-Wave Infrared Sensing A Ubiquitous Technology, Mohammad Mostafa Al Mahfuz

Dissertations

Reducing the size, weight, power consumption, and cost (SWaP-C) of infrared detectors could make infrared sensing more widely accessible. In the critical mid-wavelength infrared (MWIR) spectral range of 3-5 gm, commercially available detectors are limited by the high costs associated with epitaxial growth and hybridization, as well as the need for cryogenic cooling. These factors restrict their use to defense and space applications.

Colloidal quantum dots present a promising material for overcoming these challenges, with wafer-scale monolithic integration and Auger suppression being the key material capabilities to minimize the sensor's SWaP-C. Infrared sensors based on colloidal quantum dots have been …

Interaction Of Liquid Phase Diisopropyl Methyl Phosphonate (Dimp) With Material Surrogates For Components Of Soil And Combustion Products Of Metal Fuels, Khushi Sunil Patel

Theses

Combustion products of three different Al-based materials, Al-CaCO₃, Al-SiO₂, and Al-Fe₂O₃ , have been produced to understand their interaction with liquid diisopropyl methyl phosphonate (DIMP), a surrogate for chemical weapon agents. The purpose of this is to see which materials were more effective at DIMP adsorption and decomposition at different temperatures. Prepared materials were characterized using electron microscopy, x-ray powder diffraction, and nitrogen adsorption. Prepared powders were submerged in DIMP and heated in a thermal analyzer, tracking the mass changes as a function of temperature. Surfaces of the recovered materials were studied using …

Fire Fossils: Biomineral Infrastructures In Untangling Climates, Tanmayee More

Masters Theses

Diatoms drift, sediments sink, wildfires generate their own weather. Lightning strikes can blast sand into glass, and microscopic organisms do the same in the cold recesses of the ocean. What alchemies and metabolisms catalyze space, time, and energy? What are the thermodynamics of infrastructure in Climate Change?

Places, materials, and beings are afterimages. Through alchemical experiments, and multi-scalar imaging, I develop simulations of wildfires, and their profound, reverberating effects. In this thesis, a glass-meets-landscape experimental process enters these obscured conditions and renders new material relations for the built environment.

Designing Between Worlds, Levon Kostandyan

Masters Theses

This thesis reimagines design as a means of cultural continuity—an act of memory, resistance, and transformation. Rooted in the diasporic Armenian experience, it explores how identity is carried not only through storytelling, but through materials, rituals, and objects that evolve across time and place. Through the transformation of pomegranate skin from waste into a meaningful design material, the project navigates the space between symbolism and substance, honoring both the fruit’s ancestral weight and its potential as a living material language.


The work moves between personal narrative, historical research, and material experimentation, engaging with themes of displacement, hybridity, and embedded knowledge. …

Building Ecologies: Maintaining Land, Working With Wood, Taylor Jais

Masters Theses

This thesis critiques contemporary architecture and building practices for their fundamentally unsustainable and place-less assemblies that rely on extracting finite resources that generate significant emissions while simultaneously neglecting to consider the needs and existence of humans and non-human species with in the built environment. Through experimental material research that diverts “wood” waste streams and integrates land and multispecies care, this work demonstrates how maintenance-based approaches to construction can transform built assemblies into ecological systems. By deconstructing wood to its cellular components and recombining these elements in novel ways, this research reveals possibilities for collaborative, materials-driven, place-based building practices. This thesis …

Strongly Confined Bi2se3 Quantum Dots Via Pulsed Laser Ablation In Liquids, Gregory Guisbiers, Rajendra Subedi, Burningham Burningham, Francisco Francisco Ruiz-Zepeda, Qiaohui Zhou, Xin Lu

Faculty Scholarship

Bismuth selenide (Bi2Se3) is a binary compound displaying a strong spin−orbit coupling, resulting in a narrow bulk bandgap material with a gapless metallic surface. By shrinking the size of Bi2Se3 within the strong confinement regime, its optoelectronic properties changed drastically. To achieve this goal, strongly confined Bi2Se3 quantum dots (QDs) were produced by pulsed laser ablation in liquids (PLAL). The laser used for the synthesis was a nanosecond Nd/YAG laser emitting at 1064 nm and pulsing at ∼13 mJ/pulse. The irradiation of the bulk target was performed at 1 kHz in acetone and lasted 5 min. Finally, the Bi2Se3 QDs …

Preparation And Modification Of Mxene Composites For Application In Electrochemical Energy Storage, Zhang-Hai You, Ding-Ze Lu, Kiran Kumar Kondamareddy, Wen-Ju Gu, Peng-Fei Cheng, Jing-Xuan Yang, Rui Zheng, Hong-Mei Wang

Journal of Electrochemistry

With the acceleration of advanced industrialization and urbanization, the environment is deteriorating rapidly, and non-renewable energy resources are depleted. The gradual advent of potential clean energy storage technologies is particularly urgent. Electrochemical energy storage technologies have been widely used in multiple fields, especially supercapacitors and rechargeable batteries, as vital elements of storing renewable energy. In recent years, two-dimensional material MXene has shown great potential in energy and multiple application fields thanks to its excellent electrical properties, large specific surface area, and tunability. Based on the layered materials of MXene, researchers have successfully achieved the dual functions of energy storage and …

Three-Dimensional Melamine Carbon Sponge/Nai As Cathode Materials For Sodium-Ion Batteries, Qian-Ying Huang, Yue Liu, Zi-Xin Lin, Shu-Yi Zheng, Ting-Ting Mei, Yu-Ting Tang, Ying-He Zhang, Jun Liu

Journal of Electrochemistry

The sodium-iodine (Na-I) battery exhibits significant potential as an alternative energy storage device to the lithium-ion battery. However, its development is hindered by inadequate electrical and thermal stability, as well as the dissolution and shuttling of polyiodide. In this study, we report a preparation method for melamine carbon sponge (MC) via carbonizing a commercially available kitchen sponge. It was revealed that the as-prepared MC, composed of unique self-growing carbon nanotubes, could provide both physical and chemical adsorption capabilities for intermediate polyiodides to improve the electrochemical performance of NaI. Consequently, the NaI/MC electrode effectively minimized polyiodide dissolution and reduced the electrochemical …

Understanding The Morphology And Mass Transport Resistance Of Mesoporous Carbon-Supported Pemfc Based On Modeling Analysis, Hao Deng, Jia Liu, Zhong-Jun Hou

Journal of Electrochemistry

Mesoporous carbon supports mitigate Pt sulfonic poisoning through nanopore-confined Pt deposition, yet their morphological impacts on oxygen transport remain unclear. This study integrates carbon support morphology simulation with an enhanced agglomerate model to establish a mathematical framework elucidating pore evolution, Pt utilization, and oxygen transport in catalyst layers. Results demonstrate dominant local mass transport resistance governed by three factors: (1) active site density dictating oxygen flux; (2) ionomer film thickness defining shortest transport path; (3) ionomer-to-Pt surface area ratio modulating practical pathway length. At low ionomer-to-carbon (I/C) ratios, limited active sites elevate resistance (Factor 1 dominant). Higher I/C ratios improve …

Optimization Of Renewable Energy Systems: Comparative Analysis Of Advanced Algorithms And Photovoltaic-Electrolyzer Performance For Cost Reduction And Efficiency Enhancement, Mohamed-Amine Babay, Mustapha Adar, Ahmed Chebak, Mustapha Mabroukia

Journal of Electrochemistry

The increasing demand for cost-effective and efficient renewable energy solutions presents significant optimization challenges in hybrid energy systems. This paper addresses these challenges by conducting a comparative analysis of three advanced optimization algorithms—Lévy Flight Optimization (LFO), Archimedean Optimization (AO), and Quantum Gorilla Optimization (QGO)—to minimize the Total Net Present Cost (TNPC) and Levelized Cost of Energy (LCOE) in hybrid renewable energy systems. The study integrates critical cost parameters such as Capital Expenditure (CAPEX), Operational Expenditure (OPEX), replacement costs, and salvage values into an advanced optimization framework. Three system configurations are evaluated: Wind Turbines and Fuel Cells (WT/FC), Photovoltaic Systems and …

Theoretical Insights Into The Atomic And Electronic Structures Of Polyperyleneimide: On The Origin Of Photocatalytic Oxygen Evolution Activity, Yi-Qing Wang, Zhi Lin, Ming-Tao Li, Shao-Hua Shen

Journal of Electrochemistry

Polymeric perylene diimide (PDI) has been evidenced as a good candidate for photocatalytic water oxidation, yet the origin of the photocatalytic oxygen evolution activity remains unclear and needs further exploration. Herein, with crystal and atomic structures of the self-assembled PDI revealed from the X-ray diffraction pattern, the electronic structure is theoretically illustrated by the first-principles density functional theory calculations, suggesting the suitable band structure and the direct electronic transition for efficient photocatalytic oxygen evolution over PDI. It is confirmed that the carbonyl O atoms on the conjugation structure serve as the active sites for oxygen evolution reaction by the crystal …

Using Predictive Analytics To Reduce Small Business Cost Estimation Error, Diana Solt

Journal of Applied Packaging Research

Small and medium packaging companies generally employ the use of custom-developed quoting programs to bid goods and services. Custom bid programs (e.g. Excel) are used to capture the company-specific costs of production. The inputs of variable costs, such as machine rate and scrap rate, are critical to get correct; however, companies often rely on educated guesses and industry expertise to quote packaging products to end-users. Due to the guesswork involved there can be a financial difference between the quoted costs and actual costs. This variance is often the cause of significant lost dollars. Price, if not determined correctly, could negatively …

The Influence Of Extrusion Geometry And Ratio On Extrudate Mechanical Properties For A 6005a Alloy Containing Either Sc And Zr Or Cr And Mn Dispersoid Formers, Eli A. Harma, Paul Sanders, Thomas Wood, Timothy Langan

Michigan Tech Publications

There is a demand for a 6005A series extrusion alloy with improved strength that maintains good extrudability. Replacing Mn and Cr dispersoid formers with Sc and Zr is expected to increase the room temperature mechanical properties while not affecting extrudability. Al3X dispersoids with a Sc core surrounded by a Zr shell are stable at higher temperatures and enhance recrystallization resistance and precipitation strengthening. However, there is little information on how the Sc and Zr additions affect the properties of an extrudate as a function of extrusion geometry and ratio. A 6005A series alloy with Cr and Mn additions is compared …

Reliability Of Cazro3 And Mgo Capacitors At High Temperatures, Alan Devoe, Hung Trinh, Fatih Dogan

Materials Science and Engineering Faculty Research & Creative Works

Calcium zirconate and magnesium oxide have both been found to have useful dielectric properties at high temperatures. Multilayer ceramic capacitors (MLCCs) were made with these dielectrics and platinum electrodes. The relationship between the lifespan (mean-time to failure) and applied voltage was determined using Weibull statistics. CaZrO₃ capacitors were tested between 550◦C and600◦C while MgO capacitors were tested between 600◦C and 650◦C. The temperature coefficient Ea and the voltage coefficient n of the Prokopowicz Vaskas equation were determined under various test conditions. Activation energiesforcalciumzirconateandmagnesiumoxidewere3.25eVand3.48eV, respectively. Resistance degradation of CaZrO₃ and MgO capacitors, tested at 600◦Cand250V, were compared.

Development Of Non-Precious Iron-Cobalt Alloy Catalyst For Electrocatalytic Reaction, Harsh Panchal

Electronic Theses & Dissertations

The development of a FeCo alloy catalyst with tunable Fe/Co ratios is examined to improve electrocatalytic performance in reactions like the oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and oxygen reduction reaction (ORR). Many energy conversion devices, such as fuel cells, metal-air batteries, and water-splitting systems, depend on these interactions to function. These technologies have huge potential to meet the increasing need for hydrogen production and renewable energy sources worldwide, which are critical to attaining a sustainable energy future. When compared with noble metal-based catalysts, the FeCo alloy catalyst shows much higher catalytic activity, according to previous studies. Hydrothermal …

Production Of Sustainable Liquid Fuel From Waste Polymeric Materials Via Thermal Pyrolysis, Md. Sabbir Ahmed, Selim Reja, Sk Md Ali Zaker Shawon, Farhana Nazmin, Abdullah Mohammad Sarjish, Yousuf Ali, M. Azizur R. Khan, M. Jasim Uddin, Md. Wasikur Rahman

Mechanical Engineering Faculty Publications

The widespread use of polymeric materials has become an environmental threat as they are durable and nonbiodegradable in nature, which is directly responsible for severe ecological consequences. Thermal pyrolysis offers a sustainable and efficient approach to converting these polymeric waste materials into liquid fuel, which is also referred to as pyrolysis oil (PO). In this study, a novel method was developed for producing oil from a composite of waste polymers that include vehicle tires, tubes, and medical waste. A fixed-bed stainless steel reactor is used to thermally breakdown the waste polymeric feedstock (300–750°C) in an inert environment. The PO was …