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Crystal Structure Of New Polar Rare Earth Borates Na2.62Ln2.12(Bo3)3 (Ln = Pr, Nd, Sm) Containing Isolated Bo3 Groups, Alevtina A. Maksimova, Mark D. Smith, Hans Conrad Zur Loye

Faculty Publications

Three new rare earth borates, Na2.62Ln2.12(BO3)3 (Ln = Pr, Nd, Sm), were synthesized via a high-temperature solution reaction using a BaCO3–H3BO3–NaF flux and structurally characterized by single-crystal X-ray diffraction analysis. The compounds crystallize in the orthorhombic space group Amm2 with lattice parameters a = 5.0985(10) Å, b = 11.180(2) Å, c = 7.1483(14) Å, and a unit cell volume of 407.48(14) ų (Z = 2) for Na2.62Pr2.12(BO3)3, a = 5.0983(10) Å, b = 11.181(2) Å, c = 7.1491(14) Å, and a unit cell volume of 407.51(14) ų (Z = 2) for Na2.62Nd2.12(BO3)3, and a = 5.08630(10) Å, b …

Single Crystal Growth Of The Orthoborate Nabalu(Bo3)2 And Optical Investigation Of Eu3+ And Tb3+ Doped Nabalu(Bo3)2, Alevtina A. Maksimova, Mark D. Smith, Lakshani W. Masachchi, Hans Conrad Zur Loye

Faculty Publications

Sodium barium lutetium borate NaBaLu(BO₃)₂ crystals were synthesized using a high-temperature solution method. The crystal structure of this layered orthoborate is described and corresponds to that of an extensive orthoborates family, NaBaR(BO₃)₂ (R = Sc, Y, Yb, Tb – Lu). NaBaLu(BO₃)₂ was doped by Eu³⁺ and Tb³⁺ to explore its performance as a host material and to investigate the luminescent properties of the Eu³⁺ and Tb³⁺ doped materials. The emission spectra of the NaBaLu(BO₃)₂:Ln (Ln = Eu, Tb) crystals are presented. The most …

Thermal Conversion Of Cotton Gin Byproducts Into Liquid Fuels And High-Value Chemicals, Emmanuel Asare

Mechanical Engineering Theses

In this study, we performed fast pyrolysis, catalytic fast pyrolysis (CFP), and catalytic hydropyrolysis (CHP) of cotton gin byproducts (CGB) to investigate their conversion into hydrocarbon-rich liquid fuels and high-value aromatic chemicals. Five CGB fractions (CC1, CC2, SM, TM, and FCGB) were collected from different stages of cotton ginning operation and characterized by proximate, ultimate, and higher heating value (HHV) analysis. The feedstocks contained 41.5 44.8 wt.% carbon, 54.2–58.5 wt.% volatile matter, 6.0–15 wt.% ash, and higher heating values of 15.2–16.8 MJ kg⁻¹. All pyrolysis experiments were performed using a Pyroprobe 5200 coupled with GC-MS/FID, while catalyst loading, hydrogen pressure, …

Temperature And Salinity Effects On The Physiology Of Bullfrog Tadpoles (Lithobates Catesbeianus) From A Suburban Temperate Wetland, Angela Brown

Theses, Dissertations and Culminating Projects

One of the most robust amphibians is the American Bullfrog, Lithobates catesbeianus, which is a widespread species that is invasive worldwide, and is broadly tolerant of a range of environmental conditions. Despite this tolerance, survival and performance of adult L. catesbeianus can be negatively affected by increasing temperatures and salinity resulting from anthropogenic impacts, such as climate change and road salts. This study focuses on the effects of acute salinity exposure (mimicking road salt influx into a pond) on L. catesbeianus tadpoles at different larval stages. Increased salinity was predicted to negatively affect two physiological performance measures. Critical maximum temperature …

Evaluating The Responses Of Organic Corn Systems To Interseeded Cover Crops, Seeding Rate, And Tillage, Luvina B. Madrid

All Dissertations

Cover crop interseeding offers a potential strategy to increase plant diversity and make better use of above- and belowground resource niches within organic corn production systems. Interseeded cover crops can support agroecosystem sustainability through aboveground biomass production as well as belowground processes mediated by roots, including soil structural improvement, nutrient cycling, biological activity, and carbon storage. However, the success of interseeding depends on selecting cover crop species and management practices that provide these benefits without competing with the crop for water, nutrients, and light. Research studies were conducted to evaluate the effects of interseeded cover crop species, seeding rate, and …

Comparison Of Lower-Extremity Coordination Patterns During Countermovement Jumps Between Dancers And Nondancers, Danielle Joseph

Honors Theses

Jumping is a skill essential to several different sports, including dance. For athletes in jump-dominant sports, jump strategies can vary with differences in task demands while jump performances are similar. The countermovement jump (CMJ) has been utilized to analyze jumps because of their reliable indications of power and neuromuscular function. Methods of describing jump strategies using CMJ, such as force plate metrics, vector coding analysis, and coordination phases, have been used to describe the jumps of athletes in jump dominant sports such as basketball and volleyball. However, less jump strategy research has been done on dancers, especially to describe the …

Evaluating Pfas And Marine Microbial Interactions In Estuarine Sediments With Varying Urbanization And Assessments Of Microbial Responses To Pfos, Zachary J. Padgett

All Theses

Per- and polyfluoroalkyl substances (PFAS) are a diverse class of synthetic chemicals that have become globally distributed due to their extensive use in industrial and consumer products and their extraordinary resistance to environmental degradation. Their persistence and documented toxicity have made them a growing concern in coastal environments, particularly in estuaries where urban runoff, wastewater, and industrial discharges concentrate these compounds. Estuaries are unique in that tidal mixing and interactions with fine-grained sediments and organic matter promote PFAS retention, while the microbial communities living directly within estuarine sediments are positioned where PFAS preferentially accumulate, creating conditions for prolonged exposure and …

Understanding The Potential Sources Of Bacteria And Turbidity Pollution In The Edisto Island Watershed, Brynne Sumner

All Theses

Anthropogenic pollution introduces contaminants, such as pathogenic bacteria and turbidity, into coastal watersheds. These contaminants are the major contributors to water quality impairments in the three sub-watersheds encompassing Edisto Island and the Town of Edisto Beach (hereafter referred to as the Edisto Island Watershed), located within the ACE Basin, South Carolina, USA. With 18 locations impaired for fecal bacteria and 19 for turbidity on the 2024 South Carolina 303(d) list of impaired waters, the Edisto Island Watershed offers valuable insights into the water quality challenges rural coastal communities face.

This study aimed to identify the sources of fecal bacteria and …

Odyssey To The Extraordinary: Living Our Land Grant Mission And Beyond, Jeffrey P. Gold, Katherine S. Ankerson, Tiffany Heng-Moss

Institute of Agriculture and Natural Resources: Institute Publications

Presents a strategy intended to guide future directions for the University of Nebraska-Lincoln's (UNL) Institute of Agriculture and Natural Resources (IANR) including issues related to governance, funding, organizational structure, and strategic alignment within UNL and the University of Nebraska system.

From Genes To Streams: Mitochondrial Approaches To Population Monitoring Of The Santa Ana Sucker Catostomus Santaanae, Mariana Antonio

Electronic Theses, Projects, and Dissertations

This study was developed to use aquatic environmental DNA (eDNA) as a tool to detect the presence of the Santa Ana sucker (Catostomus santaanae), a federally threatened fish species, across the Santa Ana River in Southern California. Environmental DNA is any genetic material that an organism sheds into the environment. We can get an idea of what aquatic species are present when sampling water at a given site. We sequenced the complete mitochondrial genome (mitogenome) of the Santa Ana sucker and designed custom DNA primers to improve eDNA detection accuracy. These primers were selected based on high genetic …

The Effect Of Sustainable 3d Store Design On Consumer Online Shopping Behavior, Sophie G. Roussel

Apparel Merchandising and Product Development Undergraduate Honors Theses

Sustainability has become a significant factor in shaping consumer shopping habits. Companies are implementing 3D store designs to provide a more immersive and interactive experience. Further study is needed to investigate whether a sustainable, green-focused 3D storefront shifts consumers’ satisfaction with online shopping and their intention to buy products from a sustainable store. This study seeks to fill the research gap by examining how sustainable 3D store design influences consumer shopping behavior. Specifically, three distinct 3D store mockups were developed using Visual Retailing (VR) technology. The same number of visually appealing features, products, and store layouts was used to make …

All-Cause And Cause-Specific Mortality In Gambling Disorder: Evidence From A Nation-Wide Matched And Sibling Cohort Study In Taiwan, Yang-Chieh Brian Chen, Chih-Wei Hsu, Liang-Jen Wang, Mu-Hong Chen, Yao-Hsu Yang, Chih-Sung Liang, Edward Chia-Cheng Lai

Children’s Nutrition Research Center Staff Publications

Background and aims: Gambling disorder (GD) has been linked to suicidal ideation and suicide deaths; however, evidence on all-cause and cause-specific mortality-particularly in Asian populations-remains limited. Using a retrospective cohort study based on nationwide matched and sibling cohort, we investigated all-cause and cause-specific mortality risk in patients with GD.

Design, setting and participants: A retrospective cohort study was conducted using 2000-2022 data from Taiwan's National Health Insurance Research Database. A cohort of 961 individuals diagnosed with GD was identified. An age- and sex-matched control cohort (n = 3,844) and an unaffected sibling cohort (n = 675) were constructed. Cumulative survival …

Genetic Regulation Of Uterine Organogenesis, Diana A. Machado

Dissertations and Theses (Open Access)

In eutherian and marsupial mammals, the site of embryo implantation and gestation is the uterus. The precursor tissue of the uterus, oviducts, cervix, and upper vagina is the Müllerian duct epithelium and its adjacent mesenchyme. Morphological uterine variation between species is established during embryogenesis by species-specific differences in Müllerian duct fusion at the midline, growth, and differentiation. For example, laboratory mice have a bipartite uterus with two uterine horns and a single cervix, whereas humans have a simplex uterus with a single chamber and single cervix. In humans, variations in the fusion process can alter typical uterine morphology, correlating with …

Paleolimnology And Diatom Taxonomy From Lake Tanganyika, Sristika Adhikari

All-Inclusive List of Electronic Theses and Dissertations

Lake Tanganyika is one of the world's largest freshwater ecosystems, supporting rich aquatic biodiversity and providing several ecosystem services to surrounding communities. Environmental changes such as rising lake surface temperatures, pollution, and land-use alterations threaten the lake’s sustainability. This research examines spatial and temporal variations in nutrient dynamics and primary productivity of Lake Tanganyika using diatom assemblages from multiple locations. Our findings indicate reduced nutrient levels and longer stratification periods in the lake’s central basin during most of the Common Era, as indicated by a remarkable increase in the relative abundance of long, needle-shaped planktonic Nitzschia species. In the southern …

Evaluating The Motivations Of Participants In Online Equine Extension Courses, Sarah Vos

Department of Animal Science: Dissertations, Theses, and Student Research

Traditional program evaluations emphasize participant demographics, knowledge gain, behavior change, and program impact. However, evaluating participant motivation can provide addition insight into why participants enroll in extension programs and help explain participant engagement and persistence throughout a program. The purpose of this study was to evaluate participant motivation in two online equine extension courses and examine potential relationships between motivation, demographics, and course delivery method, and describe participant engagement in Virtual Horse Judging Camp (VHJC). This cross-sectional study utilized convenience sampling of participants in two online equine extension courses, Horse Adult Leader Training and Educational Resource (HALTER) and VHJC. The …

Fibrous Protein Biomaterials: Characterization Of Solitary Bee Silk And Cocoons, And Development Of Recombinant Hagfish And Bee Silk Materials, Oran Wasserman

All Graduate Theses and Dissertations, Fall 2023 to Present

This dissertation explores two complementary aspects of fibrous protein biomaterials: the characterization of understudied naturally occurring solitary bee silk and cocoons; and recombinant expression and biomaterial formation of recombinant hagfish intermediate filaments (rHIF) and a single Osmia lignaria Say (Hymenoptera: Megachilidae) silk protein. Some solitary bee species, which make up about 75% of all bee species, spin silk to construct protective cocoons during development. Despite the importance of silk and cocoons to the solitary bees' life history, their properties remain largely unexplored. This dissertation presents a novel method for isolating and testing individual silk fibers without interfering with the development …

The Influence Of Habitat And Individual Specialization On Mountain Lion (Puma Concolor) Hunting Strategy In A Multi-Prey System, Hannah B. Klugman

All Graduate Theses and Dissertations, Fall 2023 to Present

There is a growing recognition that animal species considered generalists (having a broad and varied diet), are actually specialists, a collection of individuals with different preferences and strategies known as specializations. The diet of a specialist depends on the variety and quantity of available food options, and their own ability to take what they need. Mountain lions (Puma concolor) are known for their ability and tendency to hunt large prey, such as elk (Cervus canadensis) and mule deer (Odocoileus hemionus), but despite the fact they overlap with other potential large prey, like feral horses …

Drought And Diet Breadth: Does Insect Specialization Influence Herbivory When Plants Are Under Stress?, Jakob Palmer

All Graduate Theses and Dissertations, Fall 2023 to Present

Climate change will alter precipitation worldwide, causing more frequent and severe drought events worldwide. Drought affects many ecological processes, including plant-herbivore interactions, which are critical to biodiversity and ecosystem health. A variety of plant characteristics can influence herbivory – such as how hairy, nutritious, or toxic a leaf is – and drought has been shown to alter many of these traits. Unique characteristics of herbivore species are also important: herbivores can either feed on a variety of plants (generalists) or a group of closely related plants (specialists). Specialists can cope with traits of the plants they eat, while generalists are …

History-Dependent Gain Control In The Paraventricular Thalamus: Neural Substrates Of Stress-Enhanced Fear Learning, Michael Martino

MUSC Theses and Dissertations

Post-traumatic stress disorder (PTSD) is characterized by hyperarousal and heightened reactivity that generalize beyond the original traumatic event, yet the neural mechanisms by which prior stress experience biases future fear learning remain poorly understood. Stress-enhanced fear learning (SEFL) is a well-validated rodent model of this phenomenon, in which a severe stressor produces persistent sensitization of subsequent fear acquisition. This dissertation used a 30-day SEFL paradigm to identify the brain-wide functional signature of stress sensitization and to identify candidate neural substrates.

Whole-brain cFos mapping during acute fear acquisition revealed a predominant pattern of suppressed neural activity in sensitized animals, with limbic …

Effects Of Beverage Color During Mouth Rinsing On Measures Of Muscular Endurance, Muscular Strength, And Exercise Perceptions During Isometric Handgrip Testing, Sydney Andrews

Exercise Science Theses & Dissertations

Previous research has shown that color can influence psychological responses, physiological responses, and exercise performance. These effects have been previously attributed to learned associations or expectations which may influence exercise-related outcomes. This study aimed to investigate whether beverage color influences muscular performance during intermittent isometric handgrip exercise. This randomized, single-blind, deceptive crossover study consisted of 34 physically active adults (21.9±3.1 years) who completed a handgrip endurance test under three conditions: red beverage rinse, clear beverage rinse, and no-rinse. Participants were informed that the study would examine the effects of mouth rinsing two commercially available carbohydrate containing sport drinks on muscular …

Long-Term Spatiotemporal Change In Coral Reef Fish Populations And Communities In The Philippines, John Christopher Whalen

Biological Sciences Theses & Dissertations

The Visayas Region of the Philippines is a global epicenter of marine fish biodiversity. Hypotheses attribute this peak of species richness within the Coral Triangle to processes that occur at geological time scales. However, changes in biodiversity may occur on ecological time scales, allowing for the assessment of the potential impact of anthropogenic activities. Recent declines in genetic, species, and ecosystem diversity have been observed in the tropics, including the Philippines. Within the Philippines the Visayas Region is considered the epicenter of species adversity due to anthropogenic stressors such as habitat degradation, overfishing, and harvesting individuals for the aquarium trade. …

Computational And Ai Tools For Understanding Telomere-Associated Cancer Mechanisms, Eleni Adam

Computer Science Theses & Dissertations

Telomeres are the protective caps of the human chromosomes and are critical for genome stability. Dysfunctional telomeres caused by their erosion with age and cell proliferation as well as by defects in their maintenance is a major early event leading to genome changes and cancer. Subtelomeres possess the critical role of regulating adjacent telomeres. Due to their complex repeat structure and high variance from one person to another, these areas have not been analyzed in detail. We present a set of computational and machine learning tools to aid in the understanding of subtelomere structure and its rearrangements in cancer.

Initially, …

Divergent Belowground Strategies Of Savanna Grasses Under Varying Fire Regimes, Abigail C. Schmidt

All Graduate Theses and Dissertations, Fall 2023 to Present

Savannas are unique ecosystems, where trees and grasses live together across the landscape, not quite forming full forests or open grasslands. The ability for trees and grass to coexist is largely the result of widespread disturbances, such as fire. Fire in savannas is largely thought of in how it maintains plants above ground, however, fire also plays a key role in ecosystem and plant processes belowground. First, fire can change how soil nutrients, namely phosphorus, are cycled. Phosphorus is a key nutrient that plants need to function, and plants acquire phosphorus through their roots. Frequent fire can enhance phosphorus availability, …

Agronomic And Economic Evaluation Of Alternative Forage Crops Under Irrigation Technologies And Deficit Irrigation, Shikha Sharma

All Graduate Theses and Dissertations, Fall 2023 to Present

Water is becoming more limited in the western United States, including Utah, so farmers need forage crops that can produce well while using less irrigation water. This study examined how different forage crops respond to reduced irrigation and different irrigation application methods, and whether some crops can provide better economic returns under limited water conditions.

Field studies were conducted at three Utah locations, Cedar City, Logan, and Vernal, from 2020 to 2024. The alternative forage crops included teff, sorghum-sudangrass (sudex), and forage rye. For economic comparison, conventional forage crops included alfalfa, corn, and three-way small grains. Four to five irrigation …

Understanding The Impact Of Environmental Change On Shorebird Abundance And Distribution Across The Intermountain West Over The Past 30 Years, Sharon Montecino

All Graduate Theses and Dissertations, Fall 2023 to Present

Shorebirds have declined worldwide over the past century, mainly due to wetland loss and degradation. Wetlands are sites that are temporarily or permanently flooded and provide critical habitat for shorebirds, especially in arid and semi-arid regions such as the Intermountain West. However, climate change and human water use threaten these wetlands, and how these threats may affect shorebirds in this region remains poorly understood. In the early 1990s, shorebird counts at over 160 wetlands across the Intermountain West provided a broad assessment of shorebird populations in the region. These counts remained the only large-scale surveys until 2022, when the Intermountain …

Integrating Space Use And Demography To Support Management Of An Endangered Alpine Ungulate, Danielle J. Berger

All Graduate Theses and Dissertations, Fall 2023 to Present

The places animals choose to live affect the food they find, the dangers they face, and the weather conditions they experience. These experiences influence whether individual animals survive and reproduce, which in turn affects the size and health of animal populations. Although scientists have long believed that animal movements play an important role in population trends, there has been limited real-world evidence showing this connection. Advances in GPS tracking technology now allow researchers to follow animals over long periods and better understand how movement influences survival. Using 20 years of GPS tracking data from the endangered Sierra Nevada bighorn sheep …

Carbon Cycling, Salinization, And Long-Term Water Quality Trends In Rocky Mountain Streams, Allyson J. Marrs

All Graduate Theses and Dissertations, Fall 2023 to Present

Humans have greatly affected streams and rivers worldwide through urbanization, agriculture, and water use. The purpose of my dissertation is to increase our understanding of various human impacts on rivers. In chapter two, I aim to determine whether there are differences in greenhouse gas (GHG) emissions between a natural river and manmade canals. I did this by measuring the emissions and dissolved concentrations of three of the most prevalent GHGs, carbon dioxide (CO₂), methane (CH₄), and nitrous oxide (N₂O). I found that most of the sites I studied were emitting CO₂ and CH …

Integrated Soil-Water Processes And Irrigation Management For Agricultural Water Optimization In Semi-Arid Regions, Tejinder Singh

All Graduate Theses and Dissertations, Fall 2023 to Present

Water is one of the most important resources for agriculture in the western United States. In semi-arid regions, farmers depend on irrigation to grow crops, but water supplies are becoming less reliable because of drought, declining snowpack, groundwater depletion, and increasing competition for limited water. Improving agricultural water use is therefore not simply about applying less water. It also requires understanding where water goes after it enters a field, how long it remains available to crops, and how farmers can use that information to make better irrigation decisions. This dissertation follows water through irrigated agricultural systems to better understand how …

Understanding Agricultural Irrigation Practices Along Utah's Wasatch Front Through Farmer-Reported Data, Garland Ledbetter

All Graduate Theses and Dissertations, Fall 2023 to Present

Water is a growing concern in Utah, especially along the Wasatch Front, where cities, farms, and communities all rely on the same limited water supply. Agriculture uses a large portion of the state’s water, so understanding how farms manage irrigation is important for statewide water planning. Utah currently uses a dataset called Water-Related Land Use (WRLU) to estimate agricultural water use across the state. This dataset provides useful information about irrigated land and crop types. However, it does not capture many of the day-to-day decisions farmers make when managing irrigation.

To better understand irrigation practices, this study surveyed 61 farmers …

Understanding And Predicting Precipitation Characteristics In The United States Through Machine Learning, Numerical Modeling And Measurements, Cody Luther Ratterman

All Graduate Theses and Dissertations, Fall 2023 to Present

Precipitation is one of the most important yet uncertain variables in the climate system. It varies dramatically in terms of timing, accumulation, rate, and phase, depending on location, season, circulation patterns, and atmospheric conditions. Precipitation forecasts, especially snowfall, are essential to supporting drought mitigation and water management in the Intermountain West. Because rainfall and snowfall lead to opposite effects on snowpack, accurately partitioning rain and snow is important to estimate snowpack levels, winter recreation, mountain ecosystems and runoff. The research findings in this dissertation have advanced the understanding and prediction of precipitation and snowpack in the U.S. by addressing the …