Digital Commons Network^™

Characterization Of Poly(Methyl Methacrylate) From Radiation‐Induced Polymerization In The Presence Of A Kaolin Clay Substrate, J. J. Beeson, Kenneth G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

Two types of polymer are formed in the radiation‐initiated polymerization of methyl methacrylate (MMA)–kaolin clay complexes. Homopolymer can be extracted from the complex by the use of organic solvents. Inserted polymer must be removed by dissolution of the polymer–clay complex with hydrofluoric acid. The polymers formed show no differences in structure (as determined by infrared analysis), had high molecular weights (1–5 x 106), and had similar molecular weight distributions (as determined by GPC). The molecular weights of the homopolymer increased as temperature increased (25°–75°C), and dose rate decreased (24.9–7.35 rads/sec). The isotacticity of the polymers when compared to irradiated bulk …

Study Of Cold-Formed Steel Structural Members Made Of Thick Sheets And Plates, William M. Mckinney, Victor A. S. Liu

CCFSS Library (1939 - present)

INTRODUCTION In steel design, the Specification for the Design of Cold-Formed Steel Structural Members l issued by the American Iron and Steel Institute has long been used for structural members cold-formed to shape from steel sheet or strip used for load-carrying purposes in buildings and other thin walled steel structures. Even though no thickness limitation was included in previous editions of the Specification, 2,3, the thickness of material used in the cold-formed steel construction was often limited to about 1/4 inch because the maximum thickness of steels used under all ASTM Specifications listed in Section 1.2 of the AISI Specification …

Column Research Council Proceedings, Fritz Engineering Foundation

CCFSS Library (1939 - present)

These Proceedings are a record of the Annual Meeting containing the abstracts of the reports presented and the transcription of our panel discussion.

Saturated Enthalpies For Mixtures Of Propane And Propene, David B. Manley, George W. Swift

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

The Plasma Polymerization Of Vinyl Monomers. Ii. A Detailed Study Of The Plasma Polymerization Of Styrene, L. F. Thompson, Kenneth G. Mayhan

Chemical and Biochemical Engineering Faculty Research & Creative Works

A study has been made on the plasma polymerization of styrene monomer in a cold, low‐power, inductively coupled RF plasma. Styrene monomer yielded an insoluble, crosslinked film which was slightly colored. A kinetic study is reported for styrene. The effects of power level, bleed rate of monomer, pressure, and reactor geometry on the rate of polymer formation are reported. A mechanism is postulated for plasma polymerization. It was found that the initiation step was the rate controlling step and that the reaction followed a cationic polymerization scheme. Both crosslinking and discoloration of the polymers occur at the time of polymerization …

Assumptions In Forrester's Urban Dynamics Model And Their Implications, Daniel L. Babcock

Engineering Management and Systems Engineering Faculty Research & Creative Works

Forrester's Urban Dynamics model is examined in terms of 1) his assumptions about complex dynamic systems, 2) the a priori bias revealed using a "normalized" model, 3) equilibrium changes when the model is modified to fit urban data, and 4) policy predictions of such a modified model. Copyright © 1972 by The Institute of Electrical and Electronics Engineers, Inc.

The Morphology Of Cellular Precipitation In Aluminum Rich Aluminum-Silver Alloys, Santiago Ibarra Jr.

Doctoral Dissertations

"The morphology of cellular precipitation in Al-29.8wt%Ag alloy has been investigated in bulk specimens by transmission electron microscopy and in solution treated specimens by means of hot stage microscopy. Both cellular and general precipitation were observed to occur simultaneously in quench-aged and isothermally aged alloys. By studying the early stages of precipitation in the hot stage, the mechanism for the growth of cells in Al-Ag alloys was developed. According to this mechanism, the grain boundary allotriomorphs begin to form, the boundary then interacts with the allotriomorphs by bowing, and then either trailing precipitation forms on the allotriomorphs or new lamellae …

Probabilistic Models For Construction Estimating And Bidding, James E. Spooner

Doctoral Dissertations

"Two probabilistic models are offered as a means for quantitatively determining contingency in a lump-sum bid. The first model is based on the isolated project and requires subjective evaluation of probabilities associated with the individual elements of the estimate. Contingency is defined as a function of the standard deviation of project field costs. Procedures are developed to obtain the variance of the total field cost from three-value estimates of the primary quantities. The second model considers the business as a stochastic process with an initial risk reserve and a positive risk loading, and contingency in this model is a function …

Methods And Applications Of Systems Identification, Allen Glenn Behring

Doctoral Dissertations

"A "Schmidt filter" is proposed to compute an optimal orthonormal basis for a set of "noisy" filter input functions. Procedures for determining the transfer function and inverse transfer function of the filter are given. The Schmidt filter is applied to the problem of determining mathematical models of discrete, stationary, linear, dynamic systems for the case where measurements may be corrupted by noise of unknown statistics. The identification problem is reconsidered for the case where noise and signal moments are specified. Procedures are given which insure unbiased, adaptive estimates of system order and parameters for this case. These theoretical propositions are …

Preliminary Studies With A Variable Transfer Composite Polymer Membrane., Samuel Walter Dortch

Masters Theses

"A preliminary study was done to determine the feasibility of using a compressed fibrous teflon (PTFE) silicone polymer membrane in extracorporeal oxygenation devices. A series of composite membranes were fabricated, using different concentrations of a dimethyl silicone polymer dissolved in petroleum ether, to give membranes having variable oxygen transfer properties. A gas-gas system was chosen to obtain the necessary transfer data. Data were obtained by transferring pure oxygen through the membranes into a mixture of 47 mole percent oxygen and 53 mole percent carbon dioxide. All analyses were obtained by chromatographic techniques. The results of these experiments show that membranes …

Analysis And Measurement Of A Zener Diode Voltage-Reference, Armond C. Maxeiner

Masters Theses

"Output voltage sensitivity equations are derived for a zener voltage-reference circuit. The circuit consists of a DC-DC converter, a voltage-resistor current generator, and a zener diode. The performance of the voltage-reference is calculated using the sensitivity equations and compared to measurement data taken from a laboratory model of the circuit. The results are in reasonable agreement.

It was concluded that with careful selection of components, two of three major sources of error can be predicted and controlled; these are changes due to input voltage and changes due to temperature. The third, changes due to time, requires calibration against a voltage …

A Sensitive Temperature Measuring System, Larry Dean Morris

Masters Theses

"A sensitive temperature measuring system, providing an analog output proportional to sensor temperature, has been designed for use in the wall temperature control system of a cloud simulation chamber. A platinum resistance element is the sensor, and a precision wirewound resistor is the reference in a bridge circuit which uses four low cost operational amplifiers arranged to provide two precision 1000 Hz current sources. Problems with an initial bridge amplifier design were corrected in the final design by the use of a low Q bandpass amplifier for the bridge signal followed by a phase detector and an output low pass …

On The Complex Index Of Refraction For Liquids, Juan Guillermo Ochoa Sierra

Masters Theses

"Methods for determining the optical constants, the real and the imaginary part of the complex index of refraction, for weakly and strongly absorbing liquids are reviewed and evaluated. Both reflection and transmission methods were considered and preliminary steps are taken for determining the optical constants for both water and oil in the visible region (0.45 - 0.65 microns) of the spectrum. A low resolution spectrometer was used and the transmission measurements through fuel oil, number 1 through 6, and crude oil were performed. The imaginary part of the complex index of refraction was deduced from the above measurements and appears …

An Investigation Of Stage I Fatigue Crack Growth In Fcc, Bcc, And Hcp Metals, Marion Anthony Russo

Masters Theses

"The objectives of this investigation were to 1) determine if Stage I mode or fatigue crack growth could be extended beyond the 45 degree maximum shear plane in metals having a face-centered, body-centered and hexagonal close pack crystal structure; 2) identify the crystallographic planes or crack propagation in Stage I growth in each crystal structure; 3) characterize the fracture surface topography or Stage I growth in each crystal structure. The test material used for this investigation consisted of alpha brass (70% Cu, 30% Zn), Armco iron and commercially pure titanium which are representative of FCC, BCC, and HCP crystal structures …

Experimental Studies Of Supporting Wire Disturbances In The Near Viscous Wakes Of Slender Supersonic Bodies, Kenneth Anthony Mirly

Masters Theses

"Wires have often been used as a means of mechanically supporting a model so that its wake will be relatively free of support interference. Such support systems have many advantages over stings and are less costly than magnetic suspension systems. Investigations into the disturbances caused by these supporting wires have been carried out with the use of a two-dimensional flat plate and a wire supported slender cone. The tests were conducted in the University of Missouri-Rolla axisymmetric, supersonic wind tunnel at Mach 3.15, and at a Reynolds number of 2.14 X 10⁶ per inch. Schlieren photography, pitot and static pressure …

A Study And Design Of A Cardiac Interbeat Interval Timer System, Richard William Mooney

Masters Theses

"This thesis reports the design of a system which can measure and record the cardiac interbeat times of human subjects in a continuous beat to beat manner, using the bioelectrical signal associated with the heart as an input. The design is in response to the needs of clinical researchers.

The means of obtaining the bioelectrical signal and previous designs of electrocardiographic equipment, especially electrocardiotachometers, are reviewed. A design is proposed which consists of a preamplifier to amplify the bioelectrical signal, a 60 Hz rejection filter, and a beat detector which uses a differentiation technique to obtain a reliable single output …

A Study Of Fmfb Demodulator Operation In The Presence Of Radio Frequency Interference And Gaussian Noise, Terry D. Wormington

Masters Theses

"A digital computer model of an FMFB demodulator has been used to study the effects of radio frequency interference on the detection of a sinusoidally modulated carrier. The effectiveness of selecting the feedback factor to suppress the interference for three values of modulation index is investigated. Also, the required IF bandwidth for the minimization of the mean-square error of the loop output between a signal corrupted by interference and the same signal without interference was investigated. More work is required before the effects of Gaussian noise plus interference on loop operation can be ascertained"--Abstract, page ii.

Reconstruction Of Finite Duration Signals, John A. Stuller

Electrical and Computer Engineering Faculty Research & Creative Works

The Problem of Reconstructing a Finite-Duration Finite- Energy Signal that Has Been Band Limited and Sampled is Considered. an Interpolation Formula is Derived that, in Principle, Permits Perfect Signal Reconstruction in the Noiseless Case Provided Only that the Sampling Frequency Exceeds the Cutoff Frequency of the Band-Limiting Filter. the Degradation Introduced by Measurement Noise on the Samples is Evaluated. © 1972, IEEE. All Rights Reserved.

Continuous Interfacial Polycondensation Of Nylon 6-6, Chandrakant A. Patel

Theses

Nylon 6-6 has been prepared by continuous interfacial polycondensation from hexamethylene diamine and adipyl chloride in a stirred system. The effect of monomer concentration and stirring on the intrinsic viscosity of polyamide 6-6 solution in formic acid (90%) was determined.

As stirring rate and monomer ratio increased, the intrinsic viscosity and polymer yield went through a maximum. Diffusion coefficient (D_AB) for hexamethylene diamine was calculated and from that J_D and mass transfer coefficient /D_AB were calculated. A relation between Reynolds number and J_D factor was established by correlation curve.

Thermal Expansion Of Tungsten At Low Temperatures, Jayant S. Shah, Martin E. Straumanis

Materials Science and Engineering Faculty Research & Creative Works

Lattice parameters, thermal expansion coefficients, and Grüneisen parameters of tungsten are determined by an x-ray method in the temperature range of 180-40 K without the use of liquid gases. Lattice parameters are expressed as a function of temperature. Thermal-expansion coefficients decrease with temperature and show no anomaly in contrast to a hypothesis proposed by Featherston and Neighbours. Grüneisen parameters γ are decreasing with temperature in accordance with the theoretical predictions. © 1971 The American Institute of Physics.

Current Mechanical Fastener Specifications And Test Procedure, John Fraczek

American Iron and Steel Institute (AISI) Specifications, Standards, Manuals and Research Reports (1946 - present)

No abstract provided.

Boundary Pressure Fluctuations Due To Macroturbulence In Hydraulic Jumps, F. R. Schiebe, C. E. Bowers

Symposia on Turbulence in Liquids

Data concerning the statistical properties of pressure fluctuations on the containment structure associated with the hydraulic jump have been studied at the St. Anthony Falls Hydraulic Laboratory. The incident Froude numbers were investigated through the practical range from 4 to 9. The mean square of the fluctuating pressure, the mean pressure, and the power spectrum were determined as a function of position under the jump. In addition, mean and rms turbulent velocity profiles and entrained air concentration profiles throughout the jump volume were determined.

The principal tests were performed in a channel 20 inches wide and 3 feet deep. Other …

A Critical Survey Of Turbulence In Bearings, E. A. Saibel, N. A. Macken

Symposia on Turbulence in Liquids

The subject of turbulence in bearings is critically surveyed. Both experimental and theoretical investigations are discussed. It is noted that beyond the laminar range, Taylor vortices develop. Some vortex structure exists even up to the highest Reynolds numbers. This suggests that the turbulence in bearings is much different from that which is found in other flows such as pipes or boundary layers. Unfortunately, the theoretical models have been based on mixing length or "law of the wall" information. A call is made for experimental information to formulate new theory applicable to bearings.

Recent Developments Of Electrochemical Wall Mass Transfer Probes And Their Application To Drag-Reducing Polymers, T. J. Hanratty, L. D. Eckelman, G. Fortuna

Symposia on Turbulence in Liquids

Electrochemical mass transfer probes are used to measure the velocity gradient at a wall. Recent advances in their application are reviewed. These include corrections for the time response of the probe, the simultaneous measurement at a number of locations of the two components of the fluctuating velocity gradient and a study of the influence of drag reducing polymers on turbulence. It is found that drag-reducing polymers cause an increase in the scale of flow oriented eddies in the viscous sublayer.

The Oxidation Of Carbon Monoxide By Magnesium Aluminate, James A. Whelan

Dissertations

In this research the catalytic oxidation of carbon monoxide was investigated on magnesium aluminate catalysts, MgO:xAl₂O₃, with five different compositions, x, ranging from 1.0 to 3.0. The reaction was run at temperatures ranging from 500 to 600 °C. with radioactive carbon monoxide as the tracer. An experimental technique has been devised for the analysis of unreacted CO which takes into account a correction for the solubility of CO in CO₂.

Four mathematical models were postulated to explain the mechanism of reaction. The models were examined against experimental data by means of non-linear least squares …

Air Pollution Control Training In Colleges And Universities In The United States, Harold M. Cota

Civil and Environmental Engineering

A nationwide survey of air pollution control training efforts in the United States at colleges and universities was carried out for the S-ll Education and Training Committee, Air Pollution Control Association. Information from 91 schools having four year or graduate programs and five community colleges was received. Questions include type of course work, backgrounds of participating faculty and students, and eventual placement. At the present time about 70% of those in training are graduate students. It was found that most students taking initial employment in air pollution control activities had the M.S. degree. Recommendations for updating this information are made.

Aggregate Shape And Skid Resistance, Jerry G. Rose

Kentucky Transportation Center Research Report

This report concerns further efforts toward the measurement and analysis of the relative influence of aggregate shape on pavement skid resistance. A simple test method for determining aggregate shape in a meaningful way with respect to skid resistance is included. Proposed specifications for skid-resistant, sand-asphalt surface and skid-resistant, Class I, Type A, Modified, bituminous concrete surface containing lightweight aggregate are introduced.

Crictical Shear Loading Of Curved Panels Of Corrugated Sheets With Restrained Edges, George Abdel-Sayed

CCFSS Proceedings of International Specialty Conference on Cold-Formed Steel Structures (1971 - 2018)

No abstract provided.

Nonlinear Buckling Of Thin-Walled Components, T. Y. Yang

CCFSS Proceedings of International Specialty Conference on Cold-Formed Steel Structures (1971 - 2018)

No abstract provided.

A Review Of The Effective Width Formula, N. C. Lind, M. K. Ravindra, J. Power

CCFSS Proceedings of International Specialty Conference on Cold-Formed Steel Structures (1971 - 2018)

No abstract provided.