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Detection Of Endocrine-Disrupting Chemicals In Personal Care Products Using A Polyhedral Oligomeric Silsesquioxane-Based Hybrid Material, Aarthi K Apr 2024

Detection Of Endocrine-Disrupting Chemicals In Personal Care Products Using A Polyhedral Oligomeric Silsesquioxane-Based Hybrid Material, Aarthi K

Theses and Dissertations

Personal care products (cosmetics) are a diverse group of goods, that includes all the essential routines including the personal hygiene products used in our day-to-day life. It contains a variety of ingredients in its formulation, including preservatives, flavor, UV filters, and other additives. Few of the chemicals utilized are found to impair human health and have serious environmental impacts. The major chemicals include parabens, triclosan, oxybenzone, phthalates, heavy metals, fragrances, etc, Though the Scientific Committee on Consumer Safety (SCCS) has set the usage limits for the chemicals used, exposure to these chemicals from multiple products may exceed the exposure limit. …


Eco-Efficient Coatings For Healthy Indoors: Ozone Deposition Velocities, Primary And Secondary Emissions, Alessandra Ranesi, Paulina Faria, M. Rosario Veiga, Elliott T. Gall Apr 2024

Eco-Efficient Coatings For Healthy Indoors: Ozone Deposition Velocities, Primary And Secondary Emissions, Alessandra Ranesi, Paulina Faria, M. Rosario Veiga, Elliott T. Gall

Mechanical and Materials Engineering Faculty Publications and Presentations

Volatile organic compounds (VOCs) and ozone (O3) are harmful pollutants present in indoor air. Indoor concentrations of VOCs are typically higher than outdoors, due to the presence of indoor sources like building materials and ozone-surface reactions. The study aims to identify and quantify the ozone reactivity and primary and secondary emissions of different indoor coatings. The coatings selected for the study were three gypsum-based plastering mortar, with and without the addition of a bio-waste from Acacia dealbata (raw bark, BA, and bark heated at 250°C, BA250), two clay plasters (one with sand and the other with seashells as additional aggregate), …


Development Of Novel Radiotherapy Treatment Monitoring And Quantitative Cherenkov Surface Dosimetry For Diverse Populations, Savannah M. Decker Apr 2024

Development Of Novel Radiotherapy Treatment Monitoring And Quantitative Cherenkov Surface Dosimetry For Diverse Populations, Savannah M. Decker

Dartmouth College Ph.D Dissertations

In the U.S. alone, nearly 2 million people will be diagnosed with cancer annually, and over half of them will receive radiation therapy throughout the course of their care. While widely regarded as safe, radiation therapy presents unique challenges that other procedures, such as surgery, lack. Namely, the invisible nature of the radiation itself makes it impossible to directly visualize treatment. Many immobilization and localization techniques exist to minimize the chance of incorrect radiation dose delivery, yet incidents still occur. Within the last decade, Cherenkov imaging has emerged as a new radiation therapy delivery verification technique. Cherenkov imaging is unique …


Excellence Summit 2024, Office Of Research And Sponsored Projects Operations Apr 2024

Excellence Summit 2024, Office Of Research And Sponsored Projects Operations

Excellence Summit (Research Week) Archived Proceedings

In it's 17th year, the University of the Incarnate Word, welcome all to read and review the proceedings of the annual research week. The 2024 Excellence Summit highlighted academic excellence across all schools featuring topics from nutrition studies to soil amendments, artificial intelligence, medical case studies, and music composition studies. The rich mixture of humanities, health sciences, physical sciences, education, and business can be found in this booklet. We thank all that contributed to these works and hope the community enjoys learning from today's and tomorrow's leaders in research, inquiry, and scholarship.


Spatial Correspondence Of Cortical Activity Measured With Whole Head Fnirs And Fmri Toward Clinical Use Within Subject, Anthony Zinos, Julie C. Wagner, Scott A. Beardsley, Wei-Liang Chen, Lisa Conant, Marsha Malloy, Joseph Heffernan, Brendan Quirk, Robert W. Prost, Mohit Maheshwari, Jeffrey Sugar, Harry T. Whelan Apr 2024

Spatial Correspondence Of Cortical Activity Measured With Whole Head Fnirs And Fmri Toward Clinical Use Within Subject, Anthony Zinos, Julie C. Wagner, Scott A. Beardsley, Wei-Liang Chen, Lisa Conant, Marsha Malloy, Joseph Heffernan, Brendan Quirk, Robert W. Prost, Mohit Maheshwari, Jeffrey Sugar, Harry T. Whelan

Biomedical Engineering Faculty Research and Publications

Functional near infrared spectroscopy (fNIRS) and functional magnetic resonance imaging (fMRI) both measure the hemodynamic response, and so both imaging modalities are expected to have a strong correspondence in regions of cortex adjacent to the scalp. To assess whether fNIRS can be used clinically in a manner similar to fMRI, 22 healthy adult participants underwent same-day fMRI and whole-head fNIRS testing while they performed separate motor (finger tapping) and visual (flashing checkerboard) tasks. Analyses were conducted within and across subjects for each imaging approach, and regions of significant task-related activity were compared on the cortical surface. The spatial correspondence between …


Electrodeposition Of Gadolinium Metal Thin Films For Neutron Phase Contrast Imaging, Mary Louise Gucik Apr 2024

Electrodeposition Of Gadolinium Metal Thin Films For Neutron Phase Contrast Imaging, Mary Louise Gucik

Chemical and Biological Engineering ETDs

A rare earth metal, gadolinium has unique magnetic properties and the largest neutron absorption cross section making it highly sought after in emerging technology. However, unlike most metals, it is difficult to work with and lacks a damascene process. When incorporated into alloys, gadolinium’s properties are muted and the film thickness must increase to account for the low concentration. Gadolinium metal films have been deposited successfully through sputter coating, but these films have density deficiencies and are limited to line-of-sight substrates. In this work, the deposition of gadolinium metal thin films was investigated for use on complex geometries via electrophoretic …


Application Of High-Deflection Strain Gauges To Characterize Spinal-Motion Phenotypes Among Patients With Clbp, Spencer Alan Baker Apr 2024

Application Of High-Deflection Strain Gauges To Characterize Spinal-Motion Phenotypes Among Patients With Clbp, Spencer Alan Baker

Theses and Dissertations

Chronic low back pain (CLBP) is a nonspecific and persistent ailment that entails many physiological, psychological, social, and economic consequences for individuals and societies. Although there is a plethora of treatments available to treat CLBP, each treatment has varying efficacy for different patients, and it is currently unknown how to best link patients to their ideal treatment. However, it is known that biopsychosocial influences associated with CLBP affect the way that we move. It has been hypothesized that identifying phenotypes of spinal motion could facilitate an objective and repeatable method of determining the optimal treatment for each patient. The objective …


Research On 3d Printing Resin Exposure Properties And Its Application On Centrifugal Microfluidic Platform Based On Fluorescence Detection, Zheng Qiao Apr 2024

Research On 3d Printing Resin Exposure Properties And Its Application On Centrifugal Microfluidic Platform Based On Fluorescence Detection, Zheng Qiao

LSU Doctoral Dissertations

This dissertation encapsulates significant advancements in the field of SLA 3D printing and centrifugal microfluidics. Central to the research is the development of a novel mathematical model for predicting trapped resin thickness in SLA 3D printing, a groundbreaking contribution that addresses a critical aspect of printing intricate structures. This model, the first to establish a mathematical relationship for resin thickness, is rooted in a comprehensive study of the resin curing process. The research leverages the concept of 'critical dosage' for resin curing, leading to a more refined and theoretically grounded approach for calculating curing thickness. Experimentation further validates the model, …


Testing Resilience Of Microalgae Biofilms When Exposed To Hydrothermal Liquefaction Aqueous Phase, Davis Haag Apr 2024

Testing Resilience Of Microalgae Biofilms When Exposed To Hydrothermal Liquefaction Aqueous Phase, Davis Haag

Student Research Symposium

Hydrothermal liquefaction (HTL) is a process that transforms wet biomass into a mixture of aqueous phase (AP), biochar solids, biocrude oil, and biogas.

The HTL process is not economically viable on a large scale partially because the HTL-AP is a toxic waste product with no current use.

The HTL-AQ contains high amounts of nitrogen (N) and phosphorus (P), but also environmental toxins such as phenolic compounds. The N and P could potentially be used to grow algae if it can survive the toxins.

Rotating algal biofilm reactors (RABRs) provide a method to grow algae biomass as a biofilm on plastic …


Effects Of Process Design And Light Quality On Biomass Growth And Nutrient Uptake In Rotating Algal Biofilm Reactors, Emily Hanson, Hayden Harrison, Colby Hamson, Shanelle Sorensen Apr 2024

Effects Of Process Design And Light Quality On Biomass Growth And Nutrient Uptake In Rotating Algal Biofilm Reactors, Emily Hanson, Hayden Harrison, Colby Hamson, Shanelle Sorensen

Student Research Symposium

Goal: Produce algae, to be used as bioproducts, from wastewater containing high concentrations of nitrogen and phosphorous. Determine if a single-stage or a two-stage reactor has a higher algae biomass yield.

Approach: Use single-stage and two-stage reactors to conduct experiments in triplicate to determine the reactor design that leads to the highest biomass yield and nutrient uptake.


The Application Of Poly-Ε-Caprolactone Nanoparticles For Endotoxin Removal, Mikaela Ritchie Apr 2024

The Application Of Poly-Ε-Caprolactone Nanoparticles For Endotoxin Removal, Mikaela Ritchie

Undergraduate Research Conference at Missouri S&T

Lipopolysaccharides (LPS), also known as endotoxins, are toxins released from the cell walls of gram-negative bacteria upon their death. Ingestion of LPS by humans or animals can initiate inflammatory immune responses, resulting in blood vessels dilation, organ dysfunction and potential death. These toxins contaminate a variety of manufacturing processes from the pharmaceutical industry to animal feed production, posing a risk to humans and animals alike. This study details the production of PCL nanoparticle capable of removing LPS from water and a preliminary analysis of the removal efficiency. The outcomes of this research hold significant implications for industries reliant on bacterial …


Biosensors For Antibacterial Medical Applications, Ryan Fagan, Shelby Wallen Apr 2024

Biosensors For Antibacterial Medical Applications, Ryan Fagan, Shelby Wallen

Undergraduate Research Conference at Missouri S&T

Healthcare associated infections are significant concern in medicine and as antibiotics are becoming less effective, we need new alternative methods to treat them. We are testing various materials that can be used to prevent infections in healthcare settings and in wound treatments. These materials include bioactive glass and modified hydrogel materials. From these studies we've learned these are effective in killing bacteria and preventing infections. The goal of this project is to determine the mechanism at which these materials kill bacteria. Our approach is to construct biosensor strains that can indicate bacterial stress response to antimicrobial agents. We have used …


Phytoremediation Of Nonpoint Source Pollution, Tylor Cheatham Apr 2024

Phytoremediation Of Nonpoint Source Pollution, Tylor Cheatham

Undergraduate Research Conference at Missouri S&T

Stormwater can bring high concentrations of nutrients into urban ponds resulting in eutrophic conditions and subsequent algal blooms. These 91 blooms can lead to hypoxic water that will ultimately cause fish deaths and loss of recreation. Often, the majority of urban stormwater flows into local ponds through an inlet, which provides a target area for nutrient removal methods. One method being explored by researchers is the use of floating treatment wetlands (FTWs). FTWs are floating mats with plants anchored to them, allowing the roots to be suspended in the water column for nutrient removal. Our previous research focused on optimizing …


Water Quality Profiles In Two Rolla Ponds: Implications For Nutrient Management, Tylor Cheatham Apr 2024

Water Quality Profiles In Two Rolla Ponds: Implications For Nutrient Management, Tylor Cheatham

Undergraduate Research Conference at Missouri S&T

Eutrophication of aquatic ecosystems is a growing global issue due to anthropogenic inputs. One of the main issues associated with eutrophication is fish death. Eutrophic waters can lead to algal blooms, resulting in hypoxic conditions where there is not enough oxygen to support the oxygen-breathing organisms like fish. This can happen in lakes or where rivers meet the ocean. These hypoxic conditions are a concern for lake managers and people who make a living fishing in waters that are now experiencing fish death. One method to target the oxygen levels in lakes is adding aerators. Because of how dynamic ecosystems …


Identify And Quantify The Adverse Effects Of Plastics In Water-Soil-Plant System, Junjie Tang Apr 2024

Identify And Quantify The Adverse Effects Of Plastics In Water-Soil-Plant System, Junjie Tang

Student Research Symposium

Plastic pollution has become impossible to ignore.

- Within that roughly 20-year span, we have generated 2.5bn tonnes of plastic waste and each year we produce about 380 million tonnes. More.

- Plastic waste:

(1) beaches

(2) landfills

(3) fruits and vegetables

(4) human organ


Floating Treatment Wetlands For Zinc Phytoremediation, Grace Duong Apr 2024

Floating Treatment Wetlands For Zinc Phytoremediation, Grace Duong

Undergraduate Research Conference at Missouri S&T

Stormwater pollution from urban and mining areas can pose challenges to downstream waters because of zinc contamination. Floating treatment wetlands (FTWs) have demonstrated the ability to mitigate nutrient and metal contamination. To investigate the effectiveness of native Missouri plants in FTWs, fourteen 10-liter mesocosms were constructed, dosed with nutrients, and placed in a greenhouse. Four mesocosms acted as controls, five contained pickerelweed, and five contained palm sedge. After one week of acclimation, mesocosms were dosed with ZnCl2 in concentrations of 0, 5, and 10 mg/L of zinc. Objectives of this study include characterizing zinc immobilization and assessing both pickerelweed and …


Wake Characteristics Of In-Phase And Out-Phase Array Of Oscillation Airfoils, Yi-Cheng Chen Apr 2024

Wake Characteristics Of In-Phase And Out-Phase Array Of Oscillation Airfoils, Yi-Cheng Chen

Student Research Symposium

In order to solve the hydrodynamics of a school of fish using the open-source SEM solver Nek5000, an oscillating mesh is required to simulate fish oscillations and at the same time simplify the process of mesh partitioning and satisfy the limitation of nek5000 that the mesh must be quadrilateral.


Quantifying And Characterizing The Behavior Of Dissolved And Suspended Icp-Oes Detectible Elements In Utah Lake, Rachel Ann Valek Apr 2024

Quantifying And Characterizing The Behavior Of Dissolved And Suspended Icp-Oes Detectible Elements In Utah Lake, Rachel Ann Valek

Theses and Dissertations

For Utah Lake in Utah, USA, we analyzed a uniquely comprehensive and longitudinal water quality dataset that extended over two summer sampling seasons. We measured 61 parameters using Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES), YSI ProDSS water sondes, and laboratory procedures to quantify and characterize dissolved and suspended behavior of trace elements in Utah Lake. We analyzed the data using principal component analysis (PCA) and multidimensional scaling (MDS) to understand the lake geochemistry and inform Utah Lake management decisions regarding nutrients and algal blooms. We found that 1) sediments rich in phosphorus (P) act as a source for bioavailable …


Investigating Which Muscles Are Most Responsible For Tremor Through Both Experimental Data And Simulation, Daniel Benjamin Free Apr 2024

Investigating Which Muscles Are Most Responsible For Tremor Through Both Experimental Data And Simulation, Daniel Benjamin Free

Theses and Dissertations

Tremor affects millions of people and many patients desire alternative treatment options to medication or neural surgery. Peripheral suppression techniques are gaining greater use, but are currently applied in a trial-and-error method. To optimize these techniques, the muscles most responsible for an individual patient's tremor need to be identified. In this dissertation, I explored two parallel paths that both could aid in identifying muscles responsible for tremor. The first method utilizies measured data and a technique (coherence) that quantifies the frequency dependent correlation between two signals. Using coherence to identify muscles contributing to tremor requires at least two parts: an …


Meso-Scale Seabed Quantification With Geoacoustic Inversion, Tim Sonnemann, Jan Dettmer, Charles W. Holland, Stan E. Dosso Apr 2024

Meso-Scale Seabed Quantification With Geoacoustic Inversion, Tim Sonnemann, Jan Dettmer, Charles W. Holland, Stan E. Dosso

Electrical and Computer Engineering Faculty Publications and Presentations

Abstract Knowledge of sub-seabed geoacoustic properties, for example depth dependent sound speed and porosity, is of importance for a variety of applications. Here, we present a semi-automated geoacoustic inversion method for autonomous underwater vehicle data that objectively adapts model inference to seabed structure. Through parallelized trans-dimensional Bayesian inference, we infer seabed properties along a 12 km survey track on the scale of about 10 cm and 50 m in the vertical and horizontal, respectively. The inferred seabed properties include sound speed, attenuation, density, and porosity as a function of depth from acoustic reflection coefficient data. Parameter uncertainties are quantified, and …


Investigating The Role Of Fluid Shear Stress During Metastasis On Enhanced Breast Cancer Extravasation, Alejandra M. Ham Apr 2024

Investigating The Role Of Fluid Shear Stress During Metastasis On Enhanced Breast Cancer Extravasation, Alejandra M. Ham

LSU Master's Theses

In 2022, ~288,000 American women were diagnosed with metastatic breast cancer which was the leading cause of patient mortality with ~43,000 American women succumbing to the disease. Women can be diagnosed with four different molecular subtypes of breast cancer: luminal A, luminal B, human epithelial growth receptor type 2 enriched (HER2+), and triple-negative breast cancer (TNBC). TNBC accounts for ~12% of all breast cancers, yet it has the worst outcomes. TNBC is highly invasive, with ~46% of TNBC patients developing metastatic disease. A further understanding of metastatic TNBC is needed to provide a greater understanding of how to treat this …


Formulation, Characterization, And In Vivo Immunogenicity Evaluation Of Heat-Stabilized Dissolvable Polymeric Microneedles, Aidan Lane Leyba Apr 2024

Formulation, Characterization, And In Vivo Immunogenicity Evaluation Of Heat-Stabilized Dissolvable Polymeric Microneedles, Aidan Lane Leyba

Biomedical Engineering ETDs

Since its introduction, vaccination has improved health outcomes tremendously. However, modern vaccination efforts are still difficult to implement, particularly in developing countries with warm climates. This includes complex and expensive cold-chain management of vaccines to maintain stability, a lack of medical personnel to administer parental vaccines, and needle phobia. As an alternative, dissolvable microneedles have recently been studied for their simple and painless application. In this thesis, I present a novel manufacturing process for polymer-based dissolvable microneedles, loaded with virus-like particles vaccines conjugated to TRIO or Sialokinin peptides to target malaria and arboviruses, respectively. We have performed multiple characterization studies …


Profiling Of Voltage-Gated Sodium Channel Subtype Expression And Resulting Susceptibility To Targeted Osmotic Lysis In Cancer, Spencer Gerard Lemoine Apr 2024

Profiling Of Voltage-Gated Sodium Channel Subtype Expression And Resulting Susceptibility To Targeted Osmotic Lysis In Cancer, Spencer Gerard Lemoine

LSU Doctoral Dissertations

Cancer is a disease characterized by a wide array of dysregulated cellular function, activity, and growth. At times, specific dysregulations associated with cancer can be exploited as avenues of potential treatment. The sodium handling mechanisms and their associated proteins in cancer have received closer attention recently closely as such a potential mechanism to exploit for treating advanced cancer. Some novel treatments aim to inhibit the expression or activity of these sodium handling proteins in an attempt to prevent the cancer from advancing or becoming more aggressive; however, such approaches have had limited success. Targeted osmotic lysis (TOL) is a new …


Localized Collocation Meshless Method For Modeling Transdermal Pharmacokinetics In Multiphase Skin Structures, Eduardo Divo Apr 2024

Localized Collocation Meshless Method For Modeling Transdermal Pharmacokinetics In Multiphase Skin Structures, Eduardo Divo

Math Department Colloquium Series

The human skin has a complicated structure with many multi-scale, biophysical effects impacting the propagation of skin-injected substances, such as partitioning, metabolic reactions, adsorption and elimination. An extended version of Fick’s second law governing the process of the compound diffusion in various skin layer is employed in the current work by considering the conservation of mass of the substance and the metabolic reaction of the substance in viable skin. Additionally, a model assuming linear coupling between the substance concentrations that are bound and unbound with blood was developed. Using such a model, a set of coupled partial differential equations are …


Electrochemical Phosphorus Recovery From The Anaerobically Digested Sludge: Mechanism, Performance, Application, And Solids Disposal, Zixuan Wang Apr 2024

Electrochemical Phosphorus Recovery From The Anaerobically Digested Sludge: Mechanism, Performance, Application, And Solids Disposal, Zixuan Wang

McKelvey School of Engineering Graduate Student Theses & Dissertations

Phosphorus (P) is life’s bottleneck element and an essential nutrient for food production. However, phosphate rock is a non-renewable resource and its geological distribution is highly uneven, making P recovery a crucial step for a circular economy. Approximately 55% of mined phosphorus ends up in centralized wastewater treatment plants (WWTPs), where up to 90% is captured in the sludge. This sludge, treated in anaerobic digesters to produce anaerobically digested sludge (ADS), emerges as a viable secondary source for phosphorus recovery. Recovering phosphorus from ADS typically involves leaching and separation. Leaching mobilizes phosphates from sludge solid phase into a liquid phase, …


Implementing A Solar Photovoltaic Station In Watering Systems Utilizing Complex Software, Akbarxon Sarvar O'G'Li Uroqov, Faxriddin Jaylovovich Nosirov, G'Olibjon Pardayevich Arzikulov, Zarina Amriddin Qizi Sayfutdinova Apr 2024

Implementing A Solar Photovoltaic Station In Watering Systems Utilizing Complex Software, Akbarxon Sarvar O'G'Li Uroqov, Faxriddin Jaylovovich Nosirov, G'Olibjon Pardayevich Arzikulov, Zarina Amriddin Qizi Sayfutdinova

Technical science and innovation

This article explores the benefits of transitioning from traditional agricultural irrigation systems to more cost-effective alternatives powered by renewable energy sources. By integrating solar photovoltaic technology into irrigation processes, significant reductions in resource wastage, estimated at 45-50%, are achievable through the implementation of drip irrigation techniques. This results in enhanced agricultural productivity. Moreover, the utilization of solar panels in green zones mitigates surface temperature increases, contributing to a 2-5% boost in electricity production. Currently, irrigation facilities primarily rely on the main energy grid. However, transitioning to renewable energy sources decreases reliance on non-renewable fuels, reduces greenhouse gas emissions, and fosters …


Globular Protein For Surface Modification Of Cellulosecontaining Materials, Nodira Saydaliyeva Apr 2024

Globular Protein For Surface Modification Of Cellulosecontaining Materials, Nodira Saydaliyeva

Technical science and innovation

The purpose of this work is the chemical modification of cotton fabrics with natural globular protein. Modification was carried out in the process of finishing cotton fabrics, after decoction and bleaching in a continuous mode. The effect of modification on the strength, protein content and functional groups of cotton fabric has been studied. According to the results obtained using the AUTOGRAPH AGS-N machine, it was found that the modification of cotton fabrics with a solution of globular protein increases the strength of the treated fabrics, depending on the concentration of the modifier and the temperature regime. Treatment with a highly …


Dying Of Natural Silk Deglued By Various Methods, Venera Djavdatovna Khamidova Apr 2024

Dying Of Natural Silk Deglued By Various Methods, Venera Djavdatovna Khamidova

Technical science and innovation

Products made of natural silk are indispensable for their hygienic properties and will always be in great demand. To obtain an even and intense coloration on a textile material, it is necessary to ensure its effective preparation with the most complete removal of hydrophobic contaminants (both natural and silicone oils applied during the weaving process, lubricants, etc.), which hinder the dyeing of the substrate and reduce the color characteristics of the obtained colors. Therefore, the issue of preparing natural silk for dyeing is relevant. In view of the sensitivity of the main fiber-forming component of natural silk - fibroin to …


Reliability Of Using Secondary And Tertiary Treated Wastewater In Concrete Mixing And Curing, Amany G. Micheal Prof., Haidy Abd El Salam Apr 2024

Reliability Of Using Secondary And Tertiary Treated Wastewater In Concrete Mixing And Curing, Amany G. Micheal Prof., Haidy Abd El Salam

Architectural Engineering

Water scarcity is a problem that faces many regions. In a developing and arid countries, the need for fresh water is exponentially increasing. One of the most water consuming industries is the construction industry, especially in concrete manufacturing. This research is an evaluation of the Reliability of recycled wastewater to be used in concrete manufacturing. Two different wastewater treatment regimens are implemented: secondary and tertiary treated wastewater. The treated wastewater, either secondary or tertiary, replaces potable water with percentages of 25%, 50%, and 100%. The mixture of the two types of water is used in concrete mixing and curing. Control …


Synthesis And Characterization Of Titanium Nitride–Carbon Composites And Their Use In Lithium-Ion Batteries, Helia M. Morales Ramirez, Horacio Vieyra, David A. Sanchez, Elizabeth M. Fletes, Michael Odlyzko, Timothy P. Lodge, Victoria Padilla-Gainza, Mataz Alcoutlabi, Jason Parsons Apr 2024

Synthesis And Characterization Of Titanium Nitride–Carbon Composites And Their Use In Lithium-Ion Batteries, Helia M. Morales Ramirez, Horacio Vieyra, David A. Sanchez, Elizabeth M. Fletes, Michael Odlyzko, Timothy P. Lodge, Victoria Padilla-Gainza, Mataz Alcoutlabi, Jason Parsons

Mechanical Engineering Faculty Publications

This work focuses on the synthesis of titanium nitride–carbon (TiN–carbon) composites by the thermal decomposition of a titanyl phthalocyanine (TiN(TD)) precursor into TiN. The synthesis of TiN was also performed using the sol-gel method (TiN(SG)) of an alkoxide/urea. The structure and morphology of the TiN–carbon and its precursors were characterized by XRD, FTIR, SEM, TEM, EDS, and XPS. The FTIR results confirmed the presence of the titanium phthalocyanine (TiOPC) complex, while the XRD data corroborated the decomposition of TiOPC into TiN. The resultant TiN exhibited a cubic structure with the FM3-M lattice, aligning with the crystal system of the synthesized …