Digital Commons Network^™

Approaches To The Synthesis Of Dentin Bonding Agents Containing Vinyl And Carbamate Functional Groups, Steven W. Amato

Theses

The synthesis of four new monomers containing vinyl and carbamate functional groups was attempted. The desired products were N-m-methacryloxyphenyl-O-phenyl carbamate, N-p-methacryloxy-O-phenyl carbamate, m-N-phenylcarbamato-2-methacryloxyethoxy benzoate, and p-N-phenylcarbamato-2-methacryloxyethoxy benzoate. The carbamate functional group was derived by the Lewis Acid catalyzed reaction of meta-aminophenol, para-aminophenol, meta-aminobenzoic acid, and para-aminobenzoic acid with diphenyl carbonate. The vinyl function was derived, in the case of the aminophenols, by reaction with methacrylyl chloride, and in the case of the aminobenzoic acids, with 2-hydroxyethyl methacrylate.

Partial products only were prepared, these being the two carbamate functional phenols, the two carbamate functional benzoic acids, the two methacryloxy functional derivatives …

Reactions Of Atomic Hydrogen With Dichloromethane In A Flow System, Shun-Hsien Huang

Theses

The reaction kinetics of atomic hydrogen with dichloromethane were studied in a tubular flow reactor with 2.6 cm I.D. Pyrex tube at pressure of 2.1 to 2.7 torr absolute and room temperature . Hydrogen atoms were generated by a microwave discharge plasma. Atomic hydrogen concentration were measured by chemiluminescence titration with nitrogen dioxide. The concentrations of hydrogen atom ranged from 2.0 * 10¹⁴ to 5.0 * 10¹⁵ atoms per cm³. Chlorocarbon reagent and products were monitored by online gas chromatography (FID).

Major products observed were hydrogen chloride and methane. The conversion of dichloromethane increases first to …

Reaction Of Hydrogen With Methylene Chloride And Carbon Tetrachloride At High Temperature, Hun Tsao

Theses

The reactions of methylene chloride and carbon tetrachloride in hydrogen in the temperature range 500 - 1000° C were studied using tubular flow reactors of three diameters. (ID: 0.40, 1.05, 1.60 cm). Residence time range was from 0.3 to 3.5 seconds. Temperature profiles of the reactors was kept within +/- 5° C of central 85% for the 18 inch long reactor, at a total pressure of 1 atmosphere. No chlorinated hydrocarbon products were observed at or above 950° C. The major products in this temperature range were CH4, C2H₂, C2H₄, C2H₆ and HCl.

The pseudo …

Degradation Of Aniline And Nitrobenzene In A Photoreactor, Michael Joseph Sowa

Theses

Degradation of aniline and nitrobenzene in aqueuous solutions was studied. Five reaction processes were utilized, including ultraviolet light, ozone, O₂/UV, O₃/O₂/UV, and H₂O₂/UV. A 30 liter semi-batch gas sparged reactor was used for the development of reaction rate and mass transfer parameters in these systems. The results were used to model a continuous stirred tank reactor (CSTR) for the O₃/O₂/UV case. Reasonable agreement was obtained for steady state exit concentrations between the experimental data and those predicted from the model.

A Theoretical Investigation Of The Possibility Of Coexistence Of Three Microbial Populations Competing Purely And Simply In Configurations Of Three Interconnected Chemostats, Shiuan-Wu Chang

Theses

It is known from the literature that out of any number of microbial populations competing purely and simply in an environment which is homogeneous and has time invariant inputs (e.g. in an ideal chemostat) only one population can survive in a steady state under any conditions. However it has been proven possible for two competitors to coexist in two interconnected chemostats, which indicates that spatial heterogeneities may lead to coexistence of pure and simple competitors. The present study investigates whether the spatial heterogeneities created by three interconnected bioreactors may lead to a mixed culture (i.e. coexistence) of three pure and …

Size Distribution Of Sediment As Affected By Surface Residue And Slope Length, John E. Gilley, S. C. Finkner, G. E. Varvel

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Runoff samples for determination of size distribution of sediment were collected under simulated rainfall conditions at selected downslope distances on plots covered with sorghum and soybean residue at rates ranging from 0.00 to 6.73 t/ha . The effects of surface residue and slope length on size distribution of sediment were evaluated. Substantial movement of sediment in the form of aggregates was found for each of the residue treatments. Significant differences in size distribution of sediment occurred between residue treatments. For a given residue rate, differences in sediment size distribution were found between sorghum and soybean residue. Size distribution of sediment …

A Chronicle Of The Kentucky Transportation Research Program, Robert C. Deen, Ronald D. Hughes

Kentucky Transportation Center Research Report

The basis for the Kentucky Transportation Research Program (KTRP) was established more than 45 years ago and some of the current staff members have over 35 years experience in transportation research. Over the years, principal investigators have developed expertise in major areas of transportation and have made significant contributions in highway safety, pavement design and performance, embankment analyses, fatigue detection in bridges, noise abatement, traffic control and operations, voidless concrete, pavement texture and skid resistance, structural design and analyses of culverts, traffic forecasting, and numerous other areas.

The Transportation Research Building houses several fully equipped laboratories. Special effort was made …

The Relationship Between Linguistic And Image Based Learning Approaches For Complex Problem Solving: A Case For Computer Generated Animation In Instructional Presentation Of Complex Technical Processes, Stanley T. Bissinger

Graduate Research Papers

The purpose of this study is to provide a rationale for development of new approaches to educating students about complex technical processes. This study may also prove helpful for determining what type of technical content is better suited for computer animated presentation.

An Investigation Of The Uses Of Scanning Electron Microscopy In The Analysis Of The Substructure Morphology Of Semiconducting Devices, Michael E. Courbat

Graduate Research Papers

The purpose of this study is to determine the technical requirements of SEM failure analysis in regard to its' inclusion in the Energy and Power curriculum of the Department of Industrial Technology, University of Northern Iowa.

Surabaya Indonesia: Options In Solid Waste Management, Samuel A. Vigil

Civil and Environmental Engineering

The Government of Indonesia requested assistance from the United States Trade and Development Program (TDP) regarding improvements to the solid waste management system of the City of Surabaya. TDP retained the author to prepare a Preliminary Feasibility Study which will enable TDP to make an informed decision on the desirability of funding further engineering work leading to solid waste projects.

Wetlands Protection: The 404 Program, Patrick A. Parenteau

Water as a Public Resource: Emerging Rights and Obligations (Summer Conference, June 1-3)

13 pages.

Includes unsigned annotations by David Getches.

The Clean Water Act, Water Quality, And Water Use, Bruce D. Ray

Water as a Public Resource: Emerging Rights and Obligations (Summer Conference, June 1-3)

56 pages.

Includes unsigned annotations by David Getches.

Nurturing Public Values In The Water Resource—The Montana Way, Matthew W. Williams

Water as a Public Resource: Emerging Rights and Obligations (Summer Conference, June 1-3)

21 pages.

Contains references.

Federal Regulatory Rights In Water, Lawrence J. Macdonnell

Water as a Public Resource: Emerging Rights and Obligations (Summer Conference, June 1-3)

29 pages.

Contains 1 page of references.

Agenda: Water As A Public Resource: Emerging Rights And Obligations, University Of Colorado Boulder. Natural Resources Law Center

Water as a Public Resource: Emerging Rights and Obligations (Summer Conference, June 1-3)

Conference organizers and/or faculty included University of Colorado School of Law professors Lawrence J. MacDonnell, David H. Getches, and Charles F. Wilkinson.

This conference focused on the legal rights associated with a broad range of public uses and interests in water including recreation, fish and wildlife protection, and water quality. Evolving legal areas such as the public trust doctrine, instream flow laws, federal reserved rights, and wetlands protection were discussed.

Water as a Public Resource: Emerging Rights and Obligations considered the extension of the public trust doctrine to areas previously not covered by this concept, as well as developments in …

Analysis Of Nitrated Polycyclic Hydrocarbons, Pah-Quinones And Related Compounds In Ambient Air, Yalan Wang

Theses

Studies were conducted to characterized airborne particulate extractable organic matter (EOM) with respect to chemical composition and biological activity. It has been well established that the nitrated polycyclic hydrocarbons (nitroPAH) are environmental contaminants. To identify nitro-PAH in ambient air sample, a technique was developed involving introduction of a reducer column into an reversephase high performance liquid chromatography (HPLC) system. Strong fluorescence signals were achieved from nitro-PAH and detected together with u.v. signals for the qualitative and quantitative analysis of nitro-PAH. 2-Nitrotriptycene was synthesized according to published procedures and used as an internal standard. By use of the above technique, 9nitroanthracene, …

Process Hazard Review For Drug Development, Rudolph R. Schwarz

Theses

The development of drugs has become increasingly complex, requiring the use of a wide variety of pharmaceutical actives and isolated intermediates, a majority of which are not always completely characterized with respect to their hazard potential. This can present a source of potential exposure to those who handle these substances during initial drug development, manufacturing of the drug active and ultimately the finished pharamaceutical product. It is, therefore, essential that safety and health information be documented and communicated during the entire drug development process.

The need for application of process hazard review techniques to the development of new drug materials …

Separation Of Chromium From Waste Sludges By An Electric Membrane Process, Freeman Nai-Tchun Ho

Theses

The process is characterized by using metallic membrane as a filter which is charged by a separate DC-power supply and it may become experimentally very effective in increasing the separation potency and migration flux. The technique of integrating migration with electromembrane was evaluated for the removal of chromium. The transport was found to be adequately described by an equation in which the rate is proportional to the chromium concentration. The rate of dichromate ions transported across the membranes and the gel water content of membrane increased when the ratio of electromembrane potential and cell system potential was increased. The back …

Characterization Of Pulse Duplicator Model For Testing Of Heart Valves, Pankesh Nilkamal Kadam

Theses

The design and development of a pulse duplicator system for testing of prosthetic valves is described. The performance characteristics were evaluated by computing the input impedance of the system from the measured pressure and flow signals for different simulation configurations. The study has been further extended to determine the feasibility of evaluating the cardiovascular status of a patient after major open heart procedure or in state of shock.

Built on hydrodynamic principles, the model allows for a wide range of heart rates, flow rates and mean pressures to be simulated. The artificial circulatory system used as a load to the …

Finite Element Stress Analysis Of The Femoral Hip Stem Prosthesis - Bone Interface, Mark C. Buechel

Theses

A three-dimensional finite element model is used to examine the stresses of the femoral hip stem prosthesis and surrounding bone, specifically at the interface between the stem and the bone. Using General Electric's GEOMOD modelling program, 3-dimensional models of the hip stem prosthesis, and both the cortical and cancellous bone, are generated. Due to the complexity of the individual models, General Electric's SUPERTAB modelling program is required to merge the three separate models into one complete model. The model is then broken down into finite elements for analysis. The model assumes isotropic properties to cortical bone and cancellous bone. Several …

Groundwater Contamination Studies At A Sanitary Landfill In New Jersey, Yau-Chorng Chien

Theses

Edgeboro Landfill, a site used for the disposal of municipal and industrial refuse, is one of the largest landfills in New Jersey. The landfill has been in operation since 1954, serving the solid waste disposal needs of local townships and a major portion of Middlessex and the surrounding counties. The landfill was not equipped with a liner and a leachate collection system at the time of start up. The leachate collection line around the landfill, on-site leachate treatment by three stabilization ponds and subsurface cut-off wall were provided to minimize the discharge of leachate into adjacent waters in 1979. Groundwater …

The Effect Of Platelet Activating Factor On Leukocyte Adhesion To The Post Capillary Walls And Developing Dose Response Relationships, Michael Francis Fitzpatrick

Theses

Blood circulation at the microcirculatory level plays an important role in the inflammatory process. Adhesion and emigration of white blood cells are among the major microcirculatory responses to inflammation. It has been recently suggested that platelet activating factor (PAF) may be a significant mediator in the local inflammatory response. This research was undertaken to characterize and quantitate the effects of PAF on the adhesion of white cells to the wall of postcapillary venules of 7-80um diameter.

The hamster cheek pouch microcirculation was used as a model for microcirculatory dynamics and was prepared for both bright field and fluorescent intravital microscopy. …

Optimization Of The Design Of The Harrington Distraction Rod And Hooks, Margaret Ann Pisani

Theses

The Harrington Distraction Rod is presently attached to the spines of patients who suffer from scoliosis and vertebral fractures. The rod's purpose is to apply a distractive force to the scoliotic curve in an attempt to reduce its severity. In fractures this rod is implanted to reduce the fracture and increase the stability of the spinal column. Harrington distraction rods are also inserted in order to give mechanical support to the spinal column.

Presently the Harrington Distraction Rod, manufactured by Zimmer, is one—quarter inch in diameter and made of 316L cold—worked stainless steel. The proximal end of the rod consists …

Kinetic Study Of Degradation Of Refractory Organic Chemicals : 2, 4-Dichlorophenol, 2, 4-D And Pyridine; Using Ozone/Hydrogen Peroxide/Uv Radiation, Milind K. Pradhan

Theses

In this study Ozone/Hydrogen Peroxide/UV radiation is used to destroy refractory organic chemicals in aqueous solutions. 2,4-dichlorophenol, 2,4-D and Pyridine are the three chemicals used. Hydrogen Peroxide in combination with UV light proved to be most effective in destroying the parent chemical completely. Ozone and UV system was the next most effective system. UV alone was the least effective.

Kinetic study of the Hydrogen Peroxide and UV system was done using a Chemkin program. The results predicted by the Chemkin program matched closely with the experimental results. More work is currently being done using the Chemkin program to study other …

Sorption Characteristics And Their Effects On Geotechnical Properties Of Illite, Gnanmoorthy Selvakumar

Theses

An experimental investigation of the sorption characteristics of phenol, chlorophenol and chlorobenzene on to illite and of the effect of sorption on the geotechnical properties of illite was performed. Various adsorption isotherms have been considered for the equilibrium adsorption study data. It was found that the Freundlich adsorption isotherm closely fits the experimental results. In addition, the results of desorption study indicated that the sorption process for these systems is not completely reversible.

The index properties of illite were found to be influenced by the sorption of contaminants, i.e., the Atterberg limits of illite increased in accordance with increases in …

Theoretical Studies Of A Norbornane Mimic Of Acyl-Alpha-Chymotrypsin, Pin-Nan Chen

Theses

Molecular mechanics calculations were used to investigate the structural flexibility of the norbornane mimic which is a model of an acyl-alpha-chymotrypsin intermediate. The Amber molecular mechanics force field was used to perform the conformational analysis.

Comparison of the optimized conformations of different energy has shown the relative structural rigidity of this molecule. Structural superposition of the minimized mimic to the native conformation of chymotrypsin shows that the mimic has a very similar spatial arrangement of its functional groups compared to the catalytic triad of the real enzyme.

Molecular electrostatic potential maps calculated in planes parallel to the average plane containing …

The Degradation Of Trace Pollutants In Wastewater, Christine M. Cheng

Theses

The effect of different treatments on the degradation of chlorinated organic pollutants in wastewater has been studied. The model compound investigated was para-chlorophenol. The different treatments used were ozone, UV irradiation, ultrasound, air flow and pure oxygen.

It is concluded that ozone has the greatest effect, ozone-UV irradiation follows closely behind, and UV irradiation has much less of an effect in degrading the p-chlorophenol.

P-chlorophenol was found to have an immeasureably slow degradation rate when treated with air even at an elevated temperature of 55°C.

The oxygen, at room temperature, showed a degradation of p-chlorophenol which, although small, was much …

A Study Of The Dynamics Of Microbial Competition For A Single Resource In A Chemostat Between Reversible Attachment To Solid Surfaces, Pericles Theofilos Lagonikos

Theses

It is known that two microbial populations competing for a single non-renewable resource in a homogeneous environment with time-invariant inputs cannot coexist in a steady state. The case where two microbial populations exhibiting reversible attachment to the walls of a chemostat compete for a single resource is studied theoretically. Because of the cell's attachment to the walls, the environment is no longer homogeneous. The present study considers the case where the attached cells form no more than a monolayer. The Baltzis-Fredrickson model is used to represent the attachment to the walls. In one system the attachment of cells of the …

The Study Of The Response Of Nucleus Ambiguus Neurons To Blood Pressure Changes, Adrienne Zoe

Theses

The purpose of the project is to aid the study of the response of nucleus ambiguus neurons to changes in blood pressure. The sampling runs indicate that there is a correlation between blood pressure and neuron activity for some of the neurons monitored. Some neurons react to blood pressure increases by Increased neural firing rate while others react by decreased neural firing rate. Some neurons do not respond to blood pressure manipulation comprising the non-vagal neurons. A system was developed for the DIN PC to collect electrocardiogram, blood pressure, and neuron activity from a dog, and to perform non-real time …

Steady-State Operation Of Bench-Scale Activated Sludge Process Using Phenol And 2-Chlorophenol As Substrates, Jeffrey Richard Caputi

Theses

Experiments were conducted to determine whether a continuous process similar to the common activated sludge process could be operated at a relative steady state with phenol and 2-chlorophenol as the sole carbon sources. After a number of unsuccessful trials, process conditions were developed which allowed for operation at a relative steady state with respect to the concentration of microorganisms in the reactor and the concentration of phenol and 2-chlorophenol in the effluent.

Phenol and 2-chlorophenol were removed at better than 99 percent efficiency on a continuous basis. The mixed liquor grown under the conditions of the experiment was highly filamentous …