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Experimental Flow Visualization For Corrugated Airfoils At Low Reynolds Number Including Development Of A Pitch And Plunge Fixture, Jeremy Ryan Sparks Jan 2011

Experimental Flow Visualization For Corrugated Airfoils At Low Reynolds Number Including Development Of A Pitch And Plunge Fixture, Jeremy Ryan Sparks

University of Kentucky Master's Theses

Micro Air Vehicles (MAV’s) have small size and extreme maneuverability which makes them ideal for surveillance. Propulsion mechanisms include propellers, rotors, and flapping airfoils. Flapping motions, along with biologically-inspired wing profiles, are of interest due to their use of natural physics. Corrugated airfoil structures appears to have poor aerodynamic performance at higher Reynolds numbers, but serve well at Re<10,000. Understanding flow structures around corrugated profiles and comparing them to a standard airfoil will aid in understanding how these corrugated profiles perform well and have been adopted by some of nature’s most acrobatic flyers. Motivation for this investigation is to compare static flow visualizations of corrugated profiles to a standard National Advisory Committee for Aeronautics (NACA) airfoil from low to high angles of attack and further observe flow structure development of a pitching and plunging flat plate at a Re<10,000 and a Strouhal number relevant to natural fliers. The static visualization was conducted at Re=1,000 with a NACA 0012 airfoil and two corrugated models. The Pitch and Plunge Fixture (PPF) developed was constructed by simplifying flapping wings as a two degree of freedom motion in plunge (translation) and pitch (rotation). Results obtained from the PPF were compared with a numerical simulation.


Perch Landing Maneuvers And Control For A Rotating-Wing Mav, Jonathan Louis Lubbers Jan 2011

Perch Landing Maneuvers And Control For A Rotating-Wing Mav, Jonathan Louis Lubbers

University of Kentucky Master's Theses

This thesis addresses flight control of the perch landing maneuver for micro-aerial vehicles. A longitudinal flight model is constructed for a pigeon-sized aircraft. In addition to a standard elevator control surface, wing-rotation also considered as a non-standard actuator for increasing low-speed aerodynamic braking. Optimal state and control trajectories for the perch landing maneuver are computed using commercial software. A neighboring optimal control law is then developed and implemented in a set of flight simulations. Simulations are run with both a quasisteady and an unsteady aerodynamic model. The effectiveness of wing rotation and of the neighboring optimal control law is discussed, …


Solution Phase And Membrane Immobilized Iron-Based Free Radical Reactions: Fundamentals And Applications For Water Treatment, Scott Romak Lewis Jan 2011

Solution Phase And Membrane Immobilized Iron-Based Free Radical Reactions: Fundamentals And Applications For Water Treatment, Scott Romak Lewis

University of Kentucky Doctoral Dissertations

Membrane-based separation processes have been used extensively for drinking water purification, wastewater treatment, and numerous other applications. Reactive membranes synthesized through functionalization of the membrane pores offer enhanced reactivity due to increased surface area at the polymer-solution interface and low diffusion limitations. Oxidative techniques utilizing free radicals have proven effective for both the destruction of toxic organics and non-environmental applications. Most previous work focuses on reactions in the homogeneous phase; however, the immobilization of reactants in membrane pores offers several advantages. The use of polyanions immobilized in a membrane or chelates in solution prevents ferric hydroxide precipitation at near-neutral pH, …


Femtosecond Laser Micromachining Of Microstructures For Sensing And Detection, Yukun Han Jan 2011

Femtosecond Laser Micromachining Of Microstructures For Sensing And Detection, Yukun Han

Doctoral Dissertations

"This thesis focuses on the fabrication and analysis of miniature functional devices that can be used for different sensing and detection applications. As the first step, the surface characteristics and morphology of the micro/nano structures on substrates (fused silica and silicon) fabricated in water and in air by femtosecond laser were investigated. Based on this study, three micro devices have been designed and fabricated by femtosecond laser, and they were analyzed for optical and chemical sensing and detections. The three micro devices are: 1) an optical Fabry-Perot interferometer in optical fiber (made from fused silica) with smooth cavity surfaces. The …


Spatio-Temporal Variations In Soil Moisture And Physicochemical Properties Of A Typical Semiarid Sand-Meadow-Desert Landscape As Influenced By Land Use, L. Duan, T. Liu, X. Wang, G. Wang, L. Ma, Y. Luo Jan 2011

Spatio-Temporal Variations In Soil Moisture And Physicochemical Properties Of A Typical Semiarid Sand-Meadow-Desert Landscape As Influenced By Land Use, L. Duan, T. Liu, X. Wang, G. Wang, L. Ma, Y. Luo

Civil & Environmental Engineering Faculty Publications

A good understanding of the interrelations between land cover alteration and changes in hydrologic conditions (e.g., soil moisture) as well as soil physicochemical properties (e.g., fine soil particles and nutrients) is crucial for maintaining the fragile hydrologic and environmental conditions of semiarid land, such as the Horqin Sandy Land in China, but is lacking in existing literature. The objectives of this study were to examine: (1) spatio-temporal variations of soil moisture and physicochemical properties in semiarid land; and (2) how those variations are influenced by land cover alteration. Using the data collected in a 9.71 km2 well-instrumented area of the …


Analysis Of The Performance Of Peanut Fame In A Single Cylinder Idi Engine And Investigations Of Neat Methyl Ester Influence On Fuel Quality, Jeffery Lewis Jan 2011

Analysis Of The Performance Of Peanut Fame In A Single Cylinder Idi Engine And Investigations Of Neat Methyl Ester Influence On Fuel Quality, Jeffery Lewis

College of Graduate Studies: Theses & Dissertations

Author's abstract: To meet evolving standards set forth by the U.S. EPA and U.S. Energy Policy it is necessary to consider a variety of feedstock for biofuels synthesis and to understand the role individual fatty acids contribute to the overall performance. It is the belief of the authors that excess peanut production would provide an excellent source for high quality biodiesel feedstock, and the complete property and combustion analysis of the fatty acid components will provide insight for future biofuel developments. The preliminary investigations of the project focused on the combustion performance and thermal efficiency of peanut FAME and its …


Evaluation Of The Physicochemical Properties And Stability Of Solid Lipid Nanoparticles Designed For The Delivery Of Dexamethasone To Tumors, Melissa Howard Jan 2011

Evaluation Of The Physicochemical Properties And Stability Of Solid Lipid Nanoparticles Designed For The Delivery Of Dexamethasone To Tumors, Melissa Howard

University of Kentucky Doctoral Dissertations

Pre-clinical and clinical trials suggest that pre-treatment with dexamethasone (Dex) may facilitate enhanced uptake of subsequently administered chemotherapeutic agents. To reduce the side effects associated with systemic administration of Dex, solid lipid nanoparticles (SLNs) containing dexamethasone palmitate (Dex-P) were prepared as a means of achieving tumor-targeted drug delivery. These studies were aimed at evaluating the physicochemical properties and both the physiological and storage stability of the SLNs.

SLNs were prepared using nanotemplate engineering technology. Stearyl alcohol (SA) was used as the lipid phase with Brij® 78 and Polysorbate 60 as surfactants and PEG6000 monostearate as a long-chain PEGylating agent. …


Three Dimensional Modeling And Animation Of Facial Expressions, Alice J. Lin Jan 2011

Three Dimensional Modeling And Animation Of Facial Expressions, Alice J. Lin

University of Kentucky Doctoral Dissertations

Facial expression and animation are important aspects of the 3D environment featuring human characters. These animations are frequently used in many kinds of applications and there have been many efforts to increase the realism. Three aspects are still stimulating active research: the detailed subtle facial expressions, the process of rigging a face, and the transfer of an expression from one person to another. This dissertation focuses on the above three aspects.

A system for freely designing and creating detailed, dynamic, and animated facial expressions is developed. The presented pattern functions produce detailed and animated facial expressions. The system produces realistic …


Hybrid Inorganic/Organic Nanostructured Tandem Solar Cells: Simulation And Fabrication Methods, Patrick Michael Boland Jr. Jan 2011

Hybrid Inorganic/Organic Nanostructured Tandem Solar Cells: Simulation And Fabrication Methods, Patrick Michael Boland Jr.

Electrical & Computer Engineering Theses & Dissertations

Organic solar cell technologies continue to be an extremely active area of scientific research. With their promise of providing low-cost, easily-processable, multi-application photovoltaics, these devices could very possibly be the most viable and practical form of renewable energy among many being explored. However, significant technological obstacles remain that must be overcome if this technology is to successfully realize the goal of providing abundant energy while simultaneously reducing dependence on fossil fuel-based sources. Compared with inorganic solar photovoltaics, power conversion efficiencies in organics are still too low to compete economically.

Much research has been accomplished over the past three decades in …


A Microfluidic Device For Impedance Spectroscopy, Ahmet Can Sabuncu Jan 2011

A Microfluidic Device For Impedance Spectroscopy, Ahmet Can Sabuncu

Mechanical & Aerospace Engineering Theses & Dissertations

Recently, microfluidics has become a versatile tool to investigate cellular biology and to build novel biomedical devices. Dielectric spectroscopy, on the other hand, allows non-invasive probing of biological cells. Information on the cell membrane, cytoplasm, and nucleus can be obtained by dielectric spectroscopy provided that appropriate tools are used in specific frequency ranges. This dissertation includes fabrication, characterization, and testing of a simple microfluidic device to measure cell dielectric properties. The dielectric measurements are performed on human T-cell leukemia (Jurkat), mouse melanoma (B16), mouse hepatoma (Hepa), and human costal chondrocyte cells. Dielectric measurements consist of measuring the complex impedance of …


Assessing System Architectures: The Canonical Decomposition Fuzzy Comparative Methodology, Jason Paul Dauby Jan 2011

Assessing System Architectures: The Canonical Decomposition Fuzzy Comparative Methodology, Jason Paul Dauby

Doctoral Dissertations

"The impacts of decisions made during the selection of the system architecture propagate throughout the entire system lifecycle. The challenge for system architects is to perform a realistic assessment of an inherently ambiguous system concept. Subject matter expert interpretations, intuition, and heuristics are performed quickly and guide system development in the right overall direction, but these methods are subjective and unrepeatable. Traditional analytical assessments dismiss complexity in a system by assuming severability between system components and are intolerant of ambiguity. To be defensible, a suitable methodology must be repeatable, analytically rigorous, and yet tolerant of ambiguity. The hypothesis for this …


Selective Laser Sintering Of 13-93 Bioactive Glass, Krishna C. R. Kolan Jan 2011

Selective Laser Sintering Of 13-93 Bioactive Glass, Krishna C. R. Kolan

Masters Theses

"Bioactive glasses are promising materials for bone scaffolds due to their ability to assist in tissue regeneration. When implanted in vivo, bioactive glasses can convert to hydroxyapatite, the main mineral constituent of human bone and form a strong bond with the surrounding tissues, thus providing an advantage over polymer scaffold materials. Bone scaffold fabrication using additive manufacturing techniques like selective laser sintering (SLS) provide control over pore interconnectivity during the fabrication of scaffold, which helps in mimicking human trabecular bone. 13-93 glass, a third-generation bioactive material designed to accelerate the body's natural ability to heal itself, was used in …


Bi-Harmonic Atomic Force Microscopy, Santosh R. Kodandarama Jan 2011

Bi-Harmonic Atomic Force Microscopy, Santosh R. Kodandarama

Masters Theses

"In tapping mode atomic force microscopy, surface features are measured indirectly via the amplitude of the tapping cantilever. A change in surface profile is detectable only if it results in an amplitude change that is significant enough to be measured by the optics. Previous works have focused on improving sensitivity through the system's Q-factor, either by changing physical cantilever properties or using feedback control, but those approaches undesirably slow down the dynamic response. In this work we take a novel approach to sensitivity amplification by reshaping the tapping trajectory. By shaping the trajectory so that the probe spends a greater …


Ozone Uptake Rates And Secondary Product Emissions Of Green Building Materials, Seth Paul Lamble Jan 2011

Ozone Uptake Rates And Secondary Product Emissions Of Green Building Materials, Seth Paul Lamble

Masters Theses

"Building materials considered "green" were tested for their ability to remove ozone and their potential to generate undesirable byproducts such as aldehydes. Three types of ceiling tile were tested, along with seven flooring materials and eight wall materials. These materials were selected based on "green" criteria. For several this means they were recycled or produced from renewable resources. Others were designed to be low emitting, or due to their composition were likely to be low emitting. Ozone deposition velocities ranged from 0.25 m h-1 for a type of resilient linoleum type flooring to 8.23 m h-1 for a clay based …


Design And Control Of A Multi-Axis Micro-Electro-Mechanical System Array For Coordinated Micro-Manipulation, Patrick Jesse White Jan 2011

Design And Control Of A Multi-Axis Micro-Electro-Mechanical System Array For Coordinated Micro-Manipulation, Patrick Jesse White

Masters Theses

"Micro-electro-mechanical system design and implementation is a field that has received much attention over the past few decades. These robotic systems with features on the micro-scale have an unparalleled opportunity to change the way scientists interact with and understand micro and nano-scale phenomenon. Their capabilities allow experimentation that cannot be achieved with standard macro-scale equipment. Potential applications range from observing biological processes in living cells, to smart materials that automatically detect microcracks. So far, however, only a few truly successful applications have been realized. One of the most elusive goals in MEMS design is creating a system capable of coordinated …


The Feasibility Of Using Bifidobacteria Bifidum (Atcc 700541) For The Production Of Prebiotic Oligosaccharides, Candice Marie Luehrs Jan 2011

The Feasibility Of Using Bifidobacteria Bifidum (Atcc 700541) For The Production Of Prebiotic Oligosaccharides, Candice Marie Luehrs

Masters Theses

"Galactooligosaccharides (GOS) are prebiotics that are being used to influence intestinal microbiota towards health promoting, beneficial bacteria like bifidobacteria. Natural sources of GOS are not found in suitable levels to achieve the desired health effects so economically viable commercial production methods are important. Enzymatic conversion of lactose to GOS through transgalactosylation is a preferred method since the starting material is inexpensive and readily available. Enzymes used in batch production are purified from fungal or bacterial sources or remain in whole cells cultured for GOS production. Purified or unbound enzymes are single use whereas enzymes retained within whole cells can potentially …


Effects Of A Nickel Reactor Liner And Other Reaction Variables During Supercritical Water Reformation Of Glycerin, Michael S. Stever Jan 2011

Effects Of A Nickel Reactor Liner And Other Reaction Variables During Supercritical Water Reformation Of Glycerin, Michael S. Stever

Masters Theses

"The non-catalytic reformation of glycerin using supercritical water was conducted in a 400-mL tubular reactor constructed of Haynesʼ Alloy 230. The evaluated parameters for this thesis include water-to-glycerin molar ratios ranging from 3 to 24 and reactor temperatures ranging from 500⁰C to 700⁰C. In addition, experiments were performed using the Haynes' Alloy 230 reactor both without a liner and with a Nickel 201 liner. Space time was maintained at approximately 100 seconds and the reactor pressure was kept constant at 24.1 MPa. The resultant effect on product gas composition and carbon gasification was determined. The product gases consisted of a …


Managing A Solar Sensor Array Project: Analyzing Insolation & Motivation, Beth A. Yount Jan 2011

Managing A Solar Sensor Array Project: Analyzing Insolation & Motivation, Beth A. Yount

Masters Theses

"The renewable power industry is rapidly growing today and is in need of much data to augment the advancement of the field. Photovoltaic technology, while making substantial improvement over the last 60 years, still has some significant hurdles to overcome. When shading, dust, or damaged cells reduce the power output of one panel, the traditional series-parallel configurations make it so every panel in series with that lower current panel, will also have its current lowered; this lowers the overall power output of the array significantly. Advancements in configurations and converters could change this phenomenon and dramatically increase a solar array's …


Production And Characterization Of Supported Palladium Nanoparticles On Multiwalled Carbon Nanotubes By Gamma Irradiation, Jessika Viviana Rojas Marin Jan 2011

Production And Characterization Of Supported Palladium Nanoparticles On Multiwalled Carbon Nanotubes By Gamma Irradiation, Jessika Viviana Rojas Marin

Masters Theses

"Carbon nanotubes are being studied for a variety of applications due to their outstanding mechanical, chemical, electrical, and optical properties that make them interesting in different areas. Nowadays, different methods to modify the structure of the nanotubes are being developed in order to expand the application fields of such materials. In this work, palladium nanoparticles were directly produced and supported on multi-walled carbon nanotubes (MWCNT) by gamma irradiation. A solution with a 2:1 water-isopropanol ratio was prepared and mixed with palladium chloride as precursor of palladium ions. Radiolysis of water produces certain species that reduce the ions down to a …


Quantifying The Carbon Footprint Of Lean Waste, Kristen Donovan Balinski Jan 2011

Quantifying The Carbon Footprint Of Lean Waste, Kristen Donovan Balinski

Masters Theses

"The objective of this paper is to provide a method of quantifying lean wastes in terms of carbon dioxide emissions by using value stream mapping. Lean manufacturing, a process based on waste identification and reduction, is a growing trend in industry and a proven method of lowering costs. The environmental impact of these wastes can be quantified by identifying the metrics associated with them, and using existing reports to convert those metrics into measurements of carbon dioxide. Growing environmental concerns are prompting federal government regulation of greenhouse gas or carbon dioxide emissions, as seen in the American Clean Energy and …


Characteristic Vertical Response Of A Footbridge Due To Crowd Loading, Colin C, Caprani, Joe Keogh, Paul Archbold, Paul Fanning Jan 2011

Characteristic Vertical Response Of A Footbridge Due To Crowd Loading, Colin C, Caprani, Joe Keogh, Paul Archbold, Paul Fanning

Conference papers

The characteristic vertical vibration of a flexible footbridge subject to crowd loading is examined in this paper. Typically, bridge vibrations produced from a crowd of pedestrians are estimated by using an enhancement factor applied to the effect caused by a single pedestrian. In this paper, a single pedestrian model, represented by a spring mass damper, which incorporates variables such as pedestrian mass and body stiffness, is used to calibrate a computationally efficient moving force model. This calibrated moving force model is further used in Monte Carlo simulations of non-homogenous crowds to estimate characteristic vertical vibration levels. Enhancement factors, which could …


Magnetic Resonance Image Processing Using Levy Distributed Anisotropic Diffusion, Jonathan Blackledge, Matthew Blackledge Jan 2011

Magnetic Resonance Image Processing Using Levy Distributed Anisotropic Diffusion, Jonathan Blackledge, Matthew Blackledge

Conference papers

We consider the physical nature of the self-diffusion of water molecules in tissue and explore how (Nuclear) Magnetic Resonance (MR) imaging may be used as a means of measuring the rate of diffusion in vivo. A discussion is presented on how these techniques may be implemented as a non-invasive means of assessing the response of tumours to novel therapeutics including some of the basic advantages and disadvantages when compared to other methods. The physical basis and mathematical models for diffusion are considered together with models for the distribution of the diffusion co-efficient including a Levy distributed model. Using a …


Morphological Analysis From Images Of Hyphal Growth Using A Fractional Dynamic Model, Jonathan Blackledge, Dan Barry Jan 2011

Morphological Analysis From Images Of Hyphal Growth Using A Fractional Dynamic Model, Jonathan Blackledge, Dan Barry

Books/Book chapters

The development of methods capable of accurately characterising the morphology of filamentous microbes represents a significant challenge to biotechnologists. This is because the productivity of many industrial fermentation processes is heavily dependent on the morphological form adopted by an organism. It is therefore of significant value if a quantitative model and associated metric(s) for morphological forms determined by complex phenotypes can be determined non-invasively, e.g. through image analysis. Specific interest is in the quantification of the branching behaviour of an organism. This is due to the link between branching frequency, biomass and metabolite production. In this paper we present a …


Simulated Performance Intensity Functions, Andrew Hines, Naomi Harte Jan 2011

Simulated Performance Intensity Functions, Andrew Hines, Naomi Harte

Conference papers

Measuring speech intelligibility for different hearing aid fitting methods in a simulated environment would allow rapid prototyping and early design assessment. A simulated performance intensity function (SPIF) test methodology has been developed to allow experimentation using an auditory nerve model to predict listeners’ phoneme recognition. The test discriminates between normal hearing and progressively degrading levels of sensorineural hearing loss. Auditory nerve discharge patterns, presented as neurograms, can be subjectively ranked by visual inspection. Here, subjective inspection is substituted with an automated ranking using a new image quality metric that can quantify neurogram degradation in a consistent manner. This work reproduces …


Hollow Hydroxyapatite Microspheres For Controlled Delivery Of Proteins, H. Fu, M. N. Rahaman, D. E. Day Jan 2011

Hollow Hydroxyapatite Microspheres For Controlled Delivery Of Proteins, H. Fu, M. N. Rahaman, D. E. Day

Materials Science and Engineering Faculty Research & Creative Works

Hollow hydroxyapatite (HA) microspheres were prepared by reacting solid microspheres of a lithium-calcium-borate glass (106-150 microns) for 2 days in K2HPO4 solution (0.02 M; 37°C) and evaluated as a controlled delivery device for a model protein, bovine serum albumin (BSA). the as-prepared HA microspheres had a hollow core with a diameter equal to 0.6 the external diameter, a surface area of V100 m2/g, and a mesoporous shell wall (pore size of ≈13 nm). after loading the hollow HA microspheres with a solution of BSA, release of the BSA into a medium of phosphate-buffered saline (PBS) …


Use Of Bio Ethanol The Key Solution For A More Sustainable Road Transport, Alberto A. Boretti Jan 2011

Use Of Bio Ethanol The Key Solution For A More Sustainable Road Transport, Alberto A. Boretti

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Life Cycle Analysis (LCA) of alternative transportation fuels clearly shows the advantages of reducing the use of nonrenewable fossil fuels vs. renewable synthetic and biologic novel fuels to reduce the emissions of carbon dioxide. Being based on the natural or synthetic recycle of carbon dioxide through the use of renewable energy sources, use of these renewable fuels does not imply depletion of natural resources and is therefore sustainable in the long term. Renewable fuels and advanced internal combustion engines and powertrains are the technologies that in addition to be the most likely to produce benefits in term of carbon balance …


Use Of Bio-Ethanol And Bio-Diesel The Key Solution For A More Sustainable Road Transport, Alberto Boretti Jan 2011

Use Of Bio-Ethanol And Bio-Diesel The Key Solution For A More Sustainable Road Transport, Alberto Boretti

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Life Cycle Analysis (LCA) of alternative transportation fuels clearly shows the advantages of reducing the use of nonrenewable fossil fuels vs. renewable biologic novel fuels to reduce the emissions of carbon dioxide. Being based on the natural recycle of carbon dioxide through the use of renewable energy sources, use of these renewable fuels does not imply depletion of natural resources and is therefore sustainable in the long term. Renewable fuels and advanced internal combustion engines and powertrains are the technologies that in addition to be the most likely to produce benefits in term of carbon balance and fossil fuel saving, …


In-Silico Hyperthermia Performance Of A Near-Field Patch Antenna At Various Positions On A Human Body Model, Sergio Curto, Terrence See, Patrick Mcevoy, Max Ammann, Zhi Ning Chen Jan 2011

In-Silico Hyperthermia Performance Of A Near-Field Patch Antenna At Various Positions On A Human Body Model, Sergio Curto, Terrence See, Patrick Mcevoy, Max Ammann, Zhi Ning Chen

Articles

A compact patch applicator designed to enhance targeted energy coupling at 434 MHz is a key enabler for sensitizing temperature increments in body regions containing superficial tumours. A detailed FDTD body model is used to explore simulated RF coupling and temperature increments for typical clinical conditions. The antenna impedance matching, specific absorption rate and thermal distribution parameters are evaluated to identify applied performance outcomes. The analysis reveals physiological-RF coupling patterns for an optimised closely-coupled single element applicator.


Blood Vessel Diameter Estimation System Using Active Contours, Jane Courtney, Ana Tizon Jan 2011

Blood Vessel Diameter Estimation System Using Active Contours, Jane Courtney, Ana Tizon

Conference Papers

The study and analysis of blood vessel geometry has become the basis of medical applications related to early diagnosis and effective monitoring of therapies in vascular diseases. This paper presents a new method to trace the outline of blood vessels from imperfect images and extract useful information about their dimensions in an automated manner. The system consists of a segmentation procedure that uses two Active Contours to detect blood vessel boundaries and a novel approach to measure blood vessel diameters directly as the distance between two points. We have succeeded in designing and implementing an automated, robust, measurement method that …


Reaction Rates Of Ozone And Terpenes Adsorbed To Model Indoor Surfaces, M. Springs, J. R. Wells, Glenn Morrison Jan 2011

Reaction Rates Of Ozone And Terpenes Adsorbed To Model Indoor Surfaces, M. Springs, J. R. Wells, Glenn Morrison

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Reaction rates and reaction probabilities have been quantified on model indoor surfaces for the reaction of ozone with two monoterpenes (Δ3-carene and d-limonene). Molar surface loadings were obtained by performing breakthrough experiments in a plug-flow reactor (PFR) packed with beads of glass, polyvinylchloride or zirconium silicate. Reaction rates and probabilities were determined by equilibrating the PFR with both the terpene and the ozone and measuring the ozone consumption rate. to mimic typical indoor conditions, temperatures of 20, 25, and 30°C were used in both types of experiments along with a relative humidity ranging from 10% to 80%. the molar surface …