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55th Annual Rocky Mountain Conference On Magnetic Resonance

Rocky Mountain Conference on Magnetic Resonance

Final program, abstracts, and information about the 55th annual meeting of the Rocky Mountain Conference on Magnetic Resonance, co-endorsed by the Colorado Section of the American Chemical Society and the Society for Applied Spectroscopy. Held in Denver, Colorado, July 28 - August 1, 2013.

Entropy Applications In Industrial Engineering, Saeed Zamiri Marvizadeh

Department of Industrial and Management Systems Engineering: Dissertations, Theses, and Student Research

Entropy is a fundamental measure of information content which has been applied in a wide variety of fields. We present three applications of entropy in the industrial engineering field: dispatching of Automatic Guided Vehicles (AGV), ranking and selection of simulated systems based on the mean performance measure, and comparison between random variables based on cumulative probability distributions.

The first application proposes three entropy-based AGV dispatching algorithms. We contribute to the body of knowledge by considering the consequence of potential AGV moves on the load balance of the factory before AGVs are dispatched. Kullback-Leibler directed divergence is applied to measure the …

Efferent Copy And Corollary Discharge Motor Control Behavior Associated With A Hopping Activity, Wangdo Kim, António P. Veloso, Filipa João, Sean S. Kohles

Mechanical and Materials Engineering Faculty Publications and Presentations

Hoppers respond not only to stimuli from the ground surfaces but also to cues generated by their own behaviors. This leads to desensitization because although the afferent and reafferent signals have distinct causes, they are carried by the same sensory channels. From a behavioral viewpoint, it may be necessary to distinguish between signals from the two causes especially when monitoring changes in the external environment separate from those due to self-movement. We were able to separate afferent sensory stimuli from self-generated, reafferent signals using an action oriented perception system and dynamic programming approach. This effort addressed the question of how …

Searching For Stable SiNCN Clusters: Combination Of Stochastic Potential Surface Search And Pseudopotential Plane-Wave Car-Parinello Simulated Annealing Simulations, Xiaofeng F. Duan, Lingyu Huang, Larry W. Burggraf

Faculty Publications

To find low energy Si_nC_n structures out of hundreds to thousands of isomers we have developed a general method to search for stable isomeric structures that combines Stochastic Potential Surface Search and Pseudopotential Plane-Wave Density Functional Theory Car-Parinello Molecular Dynamics simulated annealing (PSPW-CPMD-SA). We enhanced the Sunders stochastic search method to generate random cluster structures used as seed structures for PSPW-CPMD-SA simulations. This method ensures that each SA simulation samples a different potential surface region to find the regional minimum structure. By iterations of this automated, parallel process on a high performance computer we located hundreds to …

Computer Vision Based, Non-Contacting Deformation And Shape Measurements: A Revolution In Progress, Michael A. Sutton

Journal of the South Carolina Academy of Science

The rapid expansion of computer technology in the past thirty years has impacted society in innumerable ways. Of interest for this discussion is the breath-taking change in measurement sciences that has occurred as the digital age dawned and has now become part of our daily lives. In particular, the effect on image-based, non-contacting measurements will be described and the continuing revolutionary impact that the resulting technology has engendered will be reviewed. Additionally, the unprecedented expansion of capabilities will be highlighted by presenting a set of illustrative example studies.

Hybrid System For Enhancing Algal Growth Using Vertical Membranes, David J. Bayless, Ben J. Stuart

Mechanical and Aerospace Engineering Faculty Research & Creative Works

A method for enhancing gas-to-liquid transfer rate and algal growth using vertical membranes suspended over a pond, wherein the membranes are formed of fibers. An aqueous solution is applied to the top edges of the membranes through a series of headers. The membranes are exposed to a stream of gas containing soluble gas species as the aqueous solution migrates downwardly through the membranes by virtue of gravity-assisted capillary action. The aqueous solution collects the soluble gases from the gas stream, thus promoting the growth of photosynthetic organisms on the membranes and in the pond. The membranes facilitate a gradual introduction …

Understanding The Role Of Gravity In The Crystallization Suppression Of Zblan Glass, Anthony Torres

Civil Engineering ETDs

Fluorozirconate glasses, such as ZBLAN (ZrF4-BaF2-LaF3-AlF3-NaF), have the potential for optical transmission from 0.3 μm in the UV to 7 μm in the IR region. However, crystallites formed during the fiber drawing process prevent this glass from achieving its low loss-capability. Other researchers have shown that microgravity processing leads to suppressed crystal growth in ZBLAN glass, which can lead to lower transmission loss in the desired mid-IR range. However, the mechanism governing crystal growth suppression has not been thoroughly investigated. In the present research multiple ZBLAN samples were subjected to a heating and quenching test apparatus on a parabolic aircraft …

Development Of Surface Based Platforms For Biomolecular Recognition And Protease Assays, Jose Cornejo

Chemical and Biological Engineering ETDs

The discovery of analytical tools for biomolecular recognition in the area of diagnostics is a research trend rich in innovative methods. Some of the main drivers found in this area are the constant need for low cost devices and biosensors, simplicity in design and operation, and time efficiency. In this thesis we present novel approaches for the development of protease activity assays. Our focus of study is the protease assay development process on two types of characterized platforms: microspheres and self-assembled monolayers (SAMs) on flat surfaces. The surface preparation and conjugation process with biological components of interest is presented along …

Defining And Evaluating Agile Construction Management For Reducing Time Delays In Construction, Fei Han

Civil Engineering ETDs

Both competitive market forces and growing societal needs have triggered the demand for rapid delivery of construction projects, or at a minimum, for projects completed on schedule. However, schedule delays are common and recurring in construction, inevitably resulting in rework, cost overruns and legal claims. As projects become increasingly complicated, delays arise in a more unpredictable manner. The initial motivation for this research is to explore a systematic flexibility to deal with delays caused by complex changes in construction and meanwhile enhance the overall project performance. Accordingly, agile construction management is proposed in terms of a conceptual framework. Derived from …

Experimental Characterization And Modeling Of Aspect-Rario-Dependent Diffusion Of Nanocrystals In Nanochannels, Louis Tribby

Chemical and Biological Engineering ETDs

The investigation of aspect-ratio-dependent diffusion and equilibrium partitioning of semiconductor nanocrystals in rectangular nanochannels has been undertaken. The nanocrystals are terminated with hydrocarbon ligands and suspended in toluene, considered an aprotic solvent. Time-dependent concentration profiles are measured as a function of distance from the channel entrance by the calibrated fluorescence intensity of the nanocrystals. Both the forward diffusion of the nanocrystals and their reverse diffusion are characterized. Nanocrystals are first allowed to diffuse forward from a reservoir into the nanochannels over a long period (\u2265 3 days) until the inlet concentration reaches a steady state. Subsequently, these nanocrystals are allowed …

Am-Fm Analysis Of Structural And Functional Magnetic Resonance Images, Alvaro Emilio Ulloa Cerna

Electrical and Computer Engineering ETDs

This thesis proposes the application of multi-dimensional Amplitude-Modulation Frequency-Modulation (AM-FM) methods to magnetic resonance images (MRI). The basic goal is to provide a framework for exploring non-stationary characteristics of structural and functional MRI (sMRI and fMRI). First, we provide a comparison framework for the most popular AM-FM methods using different filterbank configurations that includes Gabor, Equirriple and multi-scale directional designs. We compare the performance and robustness to Gaussian noise using synthetic FM image examples. We show that the multi-dimensional quasi-local method (QLM) with an equiripple filterbank gave the best results in terms of instantaneous frequency (IF) estimation. We then apply …

Improvements In Diffusion Weighted Imaging Through A Composite Body And Insert Gradient Coil System, Peter Austin Jepsen

Theses and Dissertations

Diffusion Magnetic Resonance Imaging (DMRI) is a class of Magnetic Resonance Imaging (MRI) techniques with broad medical applications ranging from characterization of tumors and brain damage to potential prediction of stroke. Gradient coil and signal-to- noise ratio (SNR) constraints limit spatial resolution, accuracy, and scan time in DMRI. Achieving high b-values (measures of a scan's sensitivity to diffusion) often require scans with long diffusion gradient pulses, leading to significant magnetic resonance (MR) signal decay before the signal can be sampled. This signal loss reduces the accuracy of diffusion parameter estimation. The ability to sample the MR signal sooner while maintaining …

The Use Of Co-Culturing In Solid Substrate Cultivation And Possible Solutions To Scientific Challenges, Wanying Yao, Sue E. Nokes

Biosystems and Agricultural Engineering Faculty Publications

This perspective systematically summarizes the use of solid substrate co‐cultures in agriculture, food, plant, and industrial biotechnology applications. The summarization is organized by organism, i.e. fungus, bacteria, yeast and then co‐cultivation of either two or three organisms. Generally, in solid substrate co‐culture, the organisms synergistically penetrate and degrade the solid substrate, thereby increasing product yield and productivity over a monoculture. Efforts to increase co‐culture performance include optimizing process parameters (pH, temperature, moisture, and oxygen demand) and defining the acceptable types of substrate. Scientific challenges exist in understanding the interactions between microbial stains, such as viability, suite of products, and bio‐transformations. …

Aqueous Henry's Law Constants, Infinite Dilution Activity Coefficients, And Water Solubility: Critically Evaluated Database, Experimental Analysis, And Prediction Methods, Sarah Ann Brockbank

Theses and Dissertations

A database containing Henry's law constants, infinite dilution activity coefficients and solubility data of industrially important chemicals in aqueous systems has been compiled. These properties are important in predicting the fate and transport of chemicals in the environment. The structure of this database is compatible with the existing DIPPR® 801 database and DIADEM interface, and the compounds included are a subset of the compounds found in the DIPPR® 801 database. Thermodynamic relationships, chemical family trends, and predicted values were carefully considered when designating recommended values. Henry's law constants and infinite dilution activity coefficients were measured for toluene, 1-butanol, anisole, 1,2-difluorobenzene, …

A Prototype Decision Support Tool For Ballast Water Risk Management Using A Combination Of Hydrodynamic Models And Agent-Based Modelling, Fleming T. Hansen, Jesper H. Andersen, Michael Potthof, Thomas Uhrenholdt, Hong D. Vo, Olof Lindén

NSBWO

We report the development of a prototype Decision Support Tool (DST) for modelling the risks of spreading of non-indegenous invasive species via ballast water. The DST constitutes of two types of models: A 3D hydrodynamical model calculates the currents in the North Sea and Danish Straits, and an agent-based model estimates the dispersal of selected model organisms with the prevailing currents calculated by the 3D hydrodynamical model. The analysis is concluded by a post processing activity, where scenarios of dispersal are combined into an interim estimate of connectivity within the study area. The latter can be used as a tool …

Navigating The Academic Job Search For Environmental Engineers: Guidance For Job Seekers And Mentors, David A. Ladner, Stephanie C. Bolyard, Defne Apul, Andrew J. Whelton

Publications

Students and postdoctoral associates interested in tenure-track environmental engineering positions have limited resources to aid them. The Student Services Committee (SSC) of the Association of Environmental Engineering and Science Professors (AEESP) organized a workshop to fill some of the need. Newly hired faculty and experienced search committee and department chairs shared information on how to create competitive applications. Students and postdoctoral associates were also provided with individualized feedback on their faculty application packages. Survey data were collected for all participants, and these data are presented in this paper along with tips shared during the workshop and information collected from the …

Narrow Grass Hedge Effects On Nutrient Transport Following Swine Slurry Application, John E. Gilley, Shannon L. Bartelt-Hunt, Seth J. Lamb, Xu Li, David B. Marx, Daniel D. Snow, David B. Parker, Brian L. Woodbury

Department of Agricultural and Biological Systems Engineering: Faculty Publications

The effectiveness of a narrow grass hedge in reducing runoff nutrient loads following swine slurry application was examined. Slurry was applied to 0.75 m wide by 4.0 m long plots established on an Aksarben silty clay loam soil located in southeast Nebraska. Manure treatments consisted of no manure application and manure application to meet the 1, 2, or 3 year nitrogen (N) requirements for corn. Runoff water quality was measured during three 30 min simulated rainfall events. The grass hedge did not significantly reduce runoff nutrient transport after the swine slurry, which contained relatively small amounts of manure, was applied. …

Finite Element Modeling Of Phosphorus Leaching Through Floodplain Soils Dominated By Preferential Flow Pathways, Ryan P. Freiberger, Derek M. Heeren, Garey A. Fox

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Phosphorus is a critical nutrient in soils, providing both positive and negative effects to different systems. While optimum crop growth requires a range of P above 0.2 mg/L, preventing surface water enrichment generally requires P to be below 0.03 mg/L. Proper application and control of phosphorus is important to increase farming efficiency and to protect freshwater systems from toxic algal growth. While the movement of phosphorus through many soil types has been well-documented, the presence of highly conductive, gravel outcrops and macropores in soil can have a significant, poorly-documented effect on phosphorus movement. In the Ozark ecoregion, for example, the …

Metal-Based Nanoparticle Interactions With The Nervous System: The Challenge Of Brain Entry And The Risk Of Retention In The Organism, Robert A. Yokel, Eric A. Grulke, Robert C. Macphail

Pharmaceutical Sciences Faculty Publications

This review of metal-based nanoparticles focuses on factors influencing their distribution into the nervous system, evidence they enter brain parenchyma, and nervous system responses. Gold is emphasized as a model metal-based nanoparticle and for risk assessment in the companion review. The anatomy and physiology of the nervous system, basics of colloid chemistry, and environmental factors that influence what cells see are reviewed to provide background on the biological, physical–chemical, and internal milieu factors that influence nervous system nanoparticle uptake. The results of literature searches reveal little nanoparticle research included the nervous system, which about equally involved in vitro and in …

Hip Proprioceptors Preferentially Modulate Reflexes Of The Leg In Human Spinal Cord Injury, Tanya Onushko, Allison S. Hyngstrom, Brian D. Schmit

Biomedical Engineering Faculty Research and Publications

Stretch-sensitive afferent feedback from hip muscles has been shown to trigger long-lasting, multijoint reflex responses in people with chronic spinal cord injury (SCI). These reflexes could have important implications for control of leg movements during functional activities, such as walking. Because the control of leg movement relies on reflex regulation at all joints of the limb, we sought to determine whether stretch of hip muscles modulates reflex activity at the knee and ankle and, conversely, whether knee and ankle stretch afferents affect hip-triggered reflexes. A custom-built servomotor apparatus was used to stretch the hip muscles in nine chronic SCI subjects …

Zein: Novel Natural Polymer For Nanoparticle- And Film-Mediated Gene Delivery, Jessica D. Taylor

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Gene delivery, the introduction of DNA into cells, is applicable to gene therapy, DNA vaccination, functional genomics and diagnostics, tissue engineering, and drug-eluting medical devices. Particulates incorporating DNA are promising vehicles for gene delivery and overcome some of the barriers that hinder successful gene transfer, with the ability to protect DNA and provide for controlled, localized, and sustained release and transfection. Furthermore, innovative new gene delivery strategies that incorporate DNA particulates or complexes within films or coatings for devices and scaffolds could further provide for controlled and sustained transfection at the site of implant. Zein, a hydrophobic protein from corn, …

Fiber Pigtailed Thin Wall Capillary Coupler For Excitation Of Microsphere Wgm Resonator, Haining Wang, Xinwei Lan, Jie Huang, Lei Yuan, Cheol-Woon Kim, Hai Xiao

Electrical and Computer Engineering Faculty Research & Creative Works

In this paper, we demonstrate a fiber pigtailed thin wall capillary coupler for excitation of Whispering Gallery Modes (WGMs) of microsphere resonators. The coupler is made by fusion-splicing an optical fiber with a capillary tube and consequently etching the capillary wall to a thickness of a few microns. Light is coupled through the peripheral contact between inserted microsphere and the etched capillary wall. The coupling efficiency as a function of the wall thickness was studied experimentally. WGM resonance with a Q-factor of 1.14 x 10⁴ was observed using a borosilicate glass microsphere with a diameter of 71 µm. The …

Kinetics Of Tomato Peroxidase Inactivation By Atmospheric Pressure Cold Plasma Based On Dielectric Barrier Discharge, Patrick J. Cullen, Shashi Pankaj, N. Misra

Articles

Atmospheric pressure cold plasma technology is an emerging nonthermal food technology for microbiological decontamination of food and bio-materials. This study demonstrates the applicability of in-package cold plasma technology as a novel means to inactivation of enzymes. The kinetics of inactivation of tomato peroxidase as a model enzyme was studied at 30, 40 and 50kV, for up to 5’ of atmospheric air dielectric barrier discharge plasma treatments. The enzyme activity was found to decrease with both treatment time and voltage, the former variable exhibiting a more pronounced effect. Kinetic models viz. first-order, Weibull and logistic models were fitted to the experimentally …

The Effect Of The Probiotic Pediococcus Acidilactici On The Gut Microbiota Ecology Of Rainbow Trout (Oncorhynchus Mykiss Walbaum) Analysed Using Dgge, Alice Anderson

The Plymouth Student Scientist

The microbiota of the gastrointestinal tract heavily influences the health, growth and survival of fish. Probiotics have proved effective in improving fish productivity in aquaculture. Research suggests that probiotics, supplemented in the feed, may elicit these benefits by altering the ecology of the gastrointestinal microbiota. The probiotic Pediococcus acidilactici has been successfully used for terrestrial animals and humans but its use in aquatic organisms has been less researched. In the present study, rainbow trout Oncorhynchus mykiss (Walbaum) were fed a diet that contained Ped. Acidilactici, or a control diet. Analysis of the posterior digesta bacteria, using a non-culture dependant technique, …

Osmotic Regulation Of The Amphipod Gammarus Chevreuxi (Sexton, 1912), Sam Houston

The Plymouth Student Scientist

This study investigated osmotic regulation in the amphipod, Gammarus chevreuxi, and is the first publication of this organism’s osmotic regulatory curves. Unlike most estuarine amphipods studied to date which are hyperosmotic regulators, G. chevreuxi is a hyper-hyposmotic regulator. The hyperosmotic gradient maintained by G. chevreuxi in dilute media is very low (~120mmol.L-1), which has been interpreted as evidence of freshwater ancestry among the Crustacea. Salinity acclimation did not appear to affect heart rate or pleopod beat frequency. The gill cells responsible for ion uptake appeared to be smaller in high salinities or distorted. The apical membrane in concentrated media shows …

Triclosan Enriches For Dehalococcoides-Like Chloroflexi In Anaerobic Soil At Environmentally Relevant Concentrations, Patrick J. Mcnamara, Mark J. Krzmarzick

Civil and Environmental Engineering Faculty Research and Publications

Triclosan is an antimicrobial agent that is discharged to soils with land-applied wastewater biosolids, is persistent under anaerobic conditions, and yet its impact on anaerobic microbial communities in soils is largely unknown. We hypothesized that triclosan enriches for Dehalococcoides-like Chloroflexi because these bacteria respire organochlorides and are likely less sensitive, relative to other bacteria, to the antimicrobial effects of triclosan. Triplicate anaerobic soil microcosms were seeded with agricultural soil, which was not previously exposed to triclosan, and were amended with 1 mg kg⁻¹ of triclosan. Triplicate control microcosms did not receive triclosan, and the experiment was run for …

Optimization Of Solar Cell Arrays Using The Fibonacci Search Algorithm, Felicia Tyyan Farrow

Electrical & Computer Engineering Theses & Dissertations

In our energy hungry world, there is a growing demand to develop creative mechanisms to extract, conserve, and use energy from different resources. The use of solar cells to extract and convert solar energy into electrical energy is a growing and popular field of study because solar energy is clean, free, and renewable. One limitation for photovoltaic (PU) or solar technology is its loss in efficiency and availability as a result of shading or partial shading. Shading or partial shading decreases the total capable output power that the PV system can produce because the array is receiving irradiation from the …

Nanowell-Trapped Charged Ligand-Bearing Nanoparticle Surfaces – A Novel Method Of Enhancing Flow-Resistant Cell Adhesion, Phat L. Tran, Jessica R. Gamboa, Katherine E. Mccracken, Mark R. Riley, Marvin J. Slepian, Jeong-Yeal Yoon

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Assuring cell adhesion to an underlying biomaterial surface is vital in implant device design and tissue engineering, particularly under circumstances where cells are subjected to potential detachment from overriding fl uid fl ow. Cell–substrate adhesion is a highly regulated process involving the interplay of mechanical properties, surface topographic features, electrostatic charge, and biochemical mechanisms. At the nanoscale level, the physical properties of the underlying substrate are of particular importance in cell adhesion. Conventionally, natural, pro-adhesive, and often thrombogenic, protein biomaterials are frequently utilized to facilitate adhesion. In the present study, nanofabrication techniques are utilized to enhance the biological functionality of …

Impact Of Measurement Scale On Infiltration And Phosphorus Leaching In Ozark Floodplains, Derek M. Heeren, Garey A. Fox, Daniel E. Storm, Brian E. Haggard, Chad J. Penn, Todd Halihan

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Increased nutrient loads have resulted in several adverse impacts on surface water quality, including excessive algal growth, fish kills, and drinking water taste and odor issues across the United States and especially in the Ozark ecoregion of northeastern Oklahoma and northwestern Arkansas. The significance of this problem has been highlighted by litigation, with one case even reaching the U.S. Supreme Court (Arkansas et al. v. Oklahoma et al., 503 U.S. 91) which required the upstream state to meet downstream water quality standards. The overarching objective of this line of research was to characterize phosphorus leaching to alluvial aquifers in the …

Application Of Isothermal Calorimetry To The Study Of Phosphorus Sorption Onto Soils In A Flow-Through System, Chad J. Penn, Derek M. Heeren, Garey A. Fox

Department of Agricultural and Biological Systems Engineering: Faculty Publications

The degree, mechanisms, and kinetics of phosphorus (P) sorption onto soils can have a significant influence on leaching losses of P from soil. The objectives of this study were to measure the impact of retention time (RT) on P sorption in a flow-through system intended to simulate downward movement of a P solution through two different riparian soils, and determine if isothermal titration calorimetry (ITC) can provide useful information reflective of flow-through results. Topsoil from two riparian/alluvial soils was sampled and characterized for P concentrations and parameters related to P sorption. Flow-through P sorption experiments were conducted in order to …