Digital Commons Network^™

Magnetic Interaction Reversal In Watermelon Nanostructured Cr-Doped Fe Nanoclusters, Maninder Kaur, Qilin Dai, Mark Bowden, Mark H. Engelhard, Yaqiao Wu, Jinke Tang, You Qiang

Materials Science and Engineering Faculty Publications and Presentations

Cr-doped core-shell Fe/Fe-oxide nanoclusters (NCs) were synthesized at varied atomic percentages of Cr from 0 at. % to 8 at. %. The low concentrations of Cr (%) were selected in order to inhibit the complete conversion of the Fe-oxide shell to Cr₂O₃ and the Fe core to FeCr alloy. The magnetic interaction in Fe/Fe-oxide NCs (~25 nm) can be controlled by antiferromagnetic Cr-dopant. We report the origin of σ-FeCr phase at very low Cr concentration (2 at. %) unlike in previous studies, and the interaction reversal from dipolar to exchange interaction in watermelon-like Cr-doped core-shell NCs.

The Cost Of Green Infrastructure: Worth The Investment?, Martha Sheils

Green Infrastructure

Is GI worth the investment?

• LID techniques often lead to cost savings when we look at WHOLE PROJECT COSTS

• Natural Infrastructure investments for flood control, drinking water protection and wildlife habitat can yield SIGNIFICANT AVOIDED COSTS and additional co-benefits to communitites

Assessing The Performance Of A Northern Gulf Of Mexico Tidal Model Using Satellite Imagery, Stephen C. Medeiros, Scott C. Hagen, Naira Chaouch, Jesse Feyen, Marouane Temimi, John F. Weishampel, Yuji Funakoshi, Reza Khanbilvardi

Publications and Research

Tidal harmonic analysis simulations along with simulations spanning four specific historical time periods in 2003 and 2004 were conducted to test the performance of a northern Gulf of Mexico tidal model. A recently developed method for detecting inundated areas based on integrated remotely sensed data (i.e., Radarsat-1, aerial imagery, LiDAR, Landsat 7 ETM+) was applied to assess the performance of the tidal model. The analysis demonstrates the applicability of the method and its agreement with traditional performance assessment techniques such as harmonic resynthesis and water level time series analysis. Based on the flooded/non-flooded coastal areas estimated by the integrated remotely …

Rheological Investigation Of The Shear Strength, Durability, And Recovery Of Alginate Rafts Formed By Antacid Medication In Varying Ph Environments, Brooke M. Elliott, Kathleen E. Steckbeck, Lisa R. Murray, Kendra Erk

School of Materials Engineering Faculty Publications

The mechanical response of alginate rafts formed by mixing liquid alginate antacid medication (Gaviscon® Extra Strength Liquid Antacid) with acidic solutions was investigated by deforming isolated rafts in a shear rheometer. As rafts were deformed to varying magnitudes of applied strain, rheological parameters were identified and related to the overall strength, durability, and recoverability of rafts formed at different pH (1.1 – 1.7) and aging conditions (0.5 – 4 hr). Rafts formed in the lowest acidity solutions (pH 1.4, 1.7) were elastically weak (G₀’ = 60, 42 Pa for un-aged raft) yet maintained their elasticity during applied …

Dynamic Nanochannels For Biosensing Applications, Joseph B. Oxborrow

Theses and Dissertations

Inexpensive label-free detection of biomarker panels in serum could revolutionize earlycancer diagnosis and treatment. Such detection capabilities may be possible with dynamicnanochannels in conjunction with electrical impedance measurement. In Dr. Greg Nordin's lab I designed, fabricated and tested several iterations of these sensors with polydimethyl-siloxane microfluidics. The final design yielded a dynamic nanochannel array sensor thatshowed a 140% impedance change when exposed to 14µM bovine serum albumin in phos-phate buffered saline. For the geometry and noise limits of the tested device, simulationsindicated that a minimum detectable concentration of 20pM with specifically bound strep-tavidin should be possible. However, the polydimethylsiloxane approach …

Timoshenko Beam Effects In Lateral-Mode Microcantilever-Based Sensors In Liquids, Joshua A. Schultz, Stephen M. Heinrich, Fabien Josse, Nicholas J. Nigro, Isabelle Dufour, Luke A. Beardslee, Oliver Brand

Civil and Environmental Engineering Faculty Research and Publications

Recent experimental and analytical research has shown that higher in-fluid quality factors (Q) are achieved by actuating microcantilevers in the lateral flexural mode, especially for microcantilevers having larger width-to-length ratios. However, experimental results show that for these geometries the resonant characteristics predicted by the existing analytical models differ from the measurements. A recently developed analytical model to more accurately predict the resonant behaviour of these devices in viscous fluids is described. The model incorporates viscous fluid effects via a Stokes-type fluid resistance assumption and `Timoshenko beam' effects (shear deformation and rotatory inertia). Unlike predictions based on Euler-Bernoulli beam …

Deployed Communications In An Austere Environment: A Delphi Study, Andrew Soine, James Harker, Alan R. Heminger

Faculty Publications

The information and communications technology (ICT) field is undergoing a period of tremendous change. The exponential growth rate of ICT capability in recent decades, which has had an undeniable effect on every aspect of our society, will likely have ramifications for military operations in austere environments. 1 The Air Force’s 689th Combat Communications Wing commissioned a study to forecast the future of mobile ICT in such environments. Researchers at the Air Force Institute of Technology chose to employ the Delphi technique as the methodology for executing this task. The following scenario, based on the results of that study, demonstrates how …

On The Equivalences And Differences Of Evolutionary Algorithms, Haiping Maa, Dan Simon, Minrui Feic, Zixiang Chen

Electrical and Computer Engineering Faculty Publications

Evolutionary algorithms (EAs) are fast and robust computation methods for global optimization, and have been widely used in many real-world applications. We first conceptually discuss the equivalences of various popular EAs including genetic algorithm (GA), biogeography-based optimization (BBO), differential evolution (DE), evolution strategy (ES) and particle swarm optimization (PSO). We find that the basic versions of BBO, DE, ES and PSO are equal to the GA with global uniform recombination (GA/GUR) under certain conditions. Then we discuss their differences based on biological motivations and implementation details, and point out that their distinctions enhance the diversity of EA research and applications. …

Performance Analysis Of Non-Linear Adaptive Control Laws Using Hardware In The Loop Of An Unmanned Aerial System, Brendon Lyons

Doctoral Dissertations and Master's Theses

In practical applications, an Unmanned Aerial System's (UAS) baseline performance is dictated by how well it can follow a given trajectory with limited stress on the actuators. However, these can be insufficient performance metrics when the UAS is allowed to adapt to an unpredicted external influence such as turbulence or actuation failure, while maintaining a satisfactory baseline performance.

In this thesis, different control laws based on the formation flight geometry problem, nonlinear dynamic inversion and an artificial immune system adaptive mechanism , are implemented in hardware-in-the-loop as a precursor for in-flight testing. These controllers are compared based on three performance …

Biologically Enhanced Cathode Design For Improved Capacity And Cycle Life For Lithium-Oxygen Batteries, Dahyun Oh, Jifa Qi, Yi-Chun Lu, Yong Zhang, Yang Shao-Horn, Angela Belcher

Faculty Publications

Lithium-oxygen batteries have a great potential to enhance the gravimetric energy density of fully packaged batteries by two to three times that of lithium ion cells. Recent studies have focused on finding stable electrolytes to address poor cycling capability and improve practical limitations of current lithium-oxygen batteries. In this study, the catalyst electrode, where discharge products are deposited and decomposed, was investigated as it has a critical role in the operation of rechargeable lithium-oxygen batteries. Here we report the electrode design principle to improve specific capacity and cycling performance of lithium-oxygen batteries by utilizing high-efficiency nanocatalysts assembled by M13 virus …

Scalar Differential Equation For Slowly-Varying Thickness-Shear Modes In At-Cut Quartz Resonators With Surface Impedance For Acoustic Wave Sensor Application, Huijing He, Jiashi Yang, John A. Kosinski

Department of Mechanical and Materials Engineering: Faculty Publications

For time-harmonic motions, we generalize a 2-D scalar differential equation derived previously by Tiersten for slowly-varying thickness-shear vibrations of AT-cut quartz resonators. The purpose of the generalization is to include the effects of surface acoustic impedance from, e.g., mass layers or fluids for sensor applications. In addition to the variation of fields along the plate thickness, which is considered in the usual 1-D acoustic wave sensor models, the equation obtained also describes in-plane variations of the fields, and therefore can be used to study the vibrations of finite plate sensors with edge effects. The equation is compared with the theory …

Development Of A Computational Approach To Assess Hip Fracture And Repair: Considerations Of Intersubject And Surgical Alignment Variability, Azhar Ali

Electronic Theses and Dissertations

Hip fracture remains a major public health concern due to the significant number of occurrences and mortality rates. Intertrochanteric fractures are the most common type of fracture and are typically caused by a fall. Intramedullary osteosynthesis is a common surgical practice to repair intertrochanteric fractures, but revisions are often required. The work presented in this thesis aims to improve the realism and fidelity of computational models of hip fracture, which can be an effective alternative to costly and labor-intensive clinical in-vivo and experimental in-vitro testing. Intersubject variability is inherently present in anatomy and material relations. Statistical shape and intensity models …

2013 Scholarly Productivity Report, Missouri University Of Science And Technology

Civil, Architectural and Environmental Engineering Scholarly Productivity Reports

No abstract provided.

Extreme Learning Machines, Erik Cambria, Guang Bin Huang, Liyanaarachchi Lekamalage Chamara Kasun, Hongming Zhou, Chi Man Vong, Jiarun Lin, Jianping Yin, Zhiping Cai, Qiang Liu, Kuan Li, Victor C.M. Leung, Liang Feng, Yew Soon Ong, Meng Hiot Lim, Anton Akusok, Amaury Lendasse, Francesco Corona

Engineering Management and Systems Engineering Faculty Research & Creative Works

No abstract provided.

Physiological Fluid Specific Agglomeration Patterns Diminish Gold Nanorod Photothermal Characteristics, Kristen K. Comfort, Jared W. Speltz, Bradley M. Stacy, Larry R. Dosser, Saber M. Hussain

Chemical and Materials Engineering Faculty Publications

Investigations into the use of gold nanorods (Au-NRs) for biological applications are growing exponentially due to their distinctive physicochemical properties, which make them advantageous over other nanomaterials. Au-NRs are particularly renowned for their plasmonic characteristics, which generate a robust photothermal response when stimulated with light at a wavelength matching their surface plasmon resonance. Numerous reports have explored this nanophotonic phenomenon for temperature driven therapies; however, to date there is a significant knowledge gap pertaining to the kinetic heating profile of Au-NRs within a controlled physiological setting. In the present study, the impact of environmental composition on Au-NR behavior and degree …

The Humanistic Side Of Engineering: Considering Social Science And Humanities Dimensions Of Engineering In Education And Research, Morgan Hynes, Jessica Swenson

Journal of Pre-College Engineering Education Research (J-PEER)

Mathematics and science knowledge/skills are most commonly associated with engineering’s pre-requisite knowledge. Our goals in this paper are to argue for a more systematic inclusion of social science and humanities knowledge in the introduction of engineering to K-12 students. As part of this argument, we present a construct for framing the humanistic side of engineering with illustrative examples of what appealing to the humanistic side of engineering can look like in a classroom setting, and opportunities for research that examines the dynamics the humanistic side of engineering introduces into engineering learning and teaching. The illustrative examples are drawn from interactions …

Secondary Students' Conceptual Understanding Of Engineering As A Field, Devlin B. Montfort, Shane Brown, Victoria Whritenour

Journal of Pre-College Engineering Education Research (J-PEER)

Researchers have long been interested in how to recruit and retain more and more diverse students into engineering programs. One consistent challenge in this research is understanding the impacts of interventions from the point of view of the student, and how their preconceptions may influence that effectiveness. This study investigated how secondary students understand the concept of engineering, including what engineering is and what engineers do. The purpose of this work was to describe students’ conceptions of engineering, and to determine how those perceptions relate to student interest in engineering careers. The investigation was founded on the theoretical framework of …

Experimental Design Methodology Applied To The Oxidation Of Quinolines In Aqueous Medium By Electro-Fenton Process, Souhaila Trabelsi Souissi, Nihal Oturan, Nizar Bellakhal, Mehmet A. Oturan

Journal of Electrochemistry

The degradation behavior of 8-hydroxyquinoleine sulfate (8-HQS), a model molecule of quinolines, was studied in an aqueous medium by electro-Fenton process using a carbon felt cathode and a platinum anode. The great oxidation ability of this process is due to a large production of hydroxyl radical (OH) by electrochemically induced Fenton’s reagent (H₂O₂, Fe²⁺). Hydroxyl radicals are very powerful oxidizing agents which react on organics up to complete mineralization. A factorial experimental design was used for determining the operating parameters on the degradation of 8-HQS in an aqueous medium. The results showed that the …

Soil Mercury And Its Response To Atmospheric Mercury Deposition Across The Northeastern United States, Xue Yu, Charles T. Driscoll, Richard A. F. Warby, Mario Montesdeoca, Chris E. Johnson

Civil and Environmental Engineering - All Scholarship

Terrestrial soil is a large reservoir of atmospherically deposited mercury (Hg). However, few studies have evaluated the accumulation of Hg in terrestrial ecosystems in the northeastern United States, a region which is sensitive to atmospheric Hg deposition. We characterized Hg and organic matter in soil profiles from 139 sampling sites for five subregions across the northeastern United States and estimated atmospheric Hg deposition to these sites by combining numerical modeling with experimental data from the literature. We did not observe any significant relationships between current net atmospheric Hg deposition and soil Hg concentrations or pools, even though soils are a …

Engineered Nanotopography On Electrospun Plla Microfibers Modifies Raw 264.7 Cell Response, Nicholas J. Schaub, Tara Britton, Rupak Rajachar, Ryan J. Gilbert

Chemical and Biochemical Engineering Faculty Research & Creative Works

In this study, we created a new method of electrospinning capable of controlling the surface structure of individual fibers (fiber nano topography). The nano topographical features were created by a phase separation in the fibers as they formed. To control the phase separation, a nonsolvent (a chemical insoluble with the polymer) was added to an electrospinning solution containing poly-l-lactic acid (PLLA) and chloroform. The nano topography of electro spun fibers in the PLLA/chloroform solution was smooth. However, adding a small weight (< 2% of total solution) of a single nonsolvent (water, ethanol, or dimethyl sulfoxide) generated nanoscale depressions on the surface of the fibers unique to the nonsolvent added. Additionally, nanoscale depressions on electro spun fibers were observed to change with dimethyl sulfoxide (DMSO) concentration in the PLLA/chloroform solution. A nonlinear relationship was found between the concentration of DMSO and the number and size of nano topographical features. The surface depressions did not alter the hydrophobicity of the scaffold or degradation of the scaffold over a two-day period. To determine if fiber nano topography altered cell behavior, macrophages (RAW 264.7 cells) were cultured on fibers with a smooth nano topography or fibers with nanoscale depressions. RAW 264.7 cells spread less on fibers with nanoscale depressions than fibers with a smooth topography (p < 0.05), but there were no differences between groups with regard to cell metabolism or the number of adherent cells. The results of this study demonstrate the necessity to consider the nano topography of individual fibers as these features may affect cellular behavior. More importantly, we demonstrate a versatile method of controlling electro spun fiber nano topography. © 2013 American Chemical Society.

Mammalian Cells Preferentially Internalize Hydrogel Nanodiscs Over Nanorods And Use Shape-Specific Uptake Mechanisms, Rachit Agarwal, Vikramjit Singh, Patrick Jurney, Li Shi, S. Sreenivasan, Krishnendu Roy

Faculty Publications

Size, surface charge, and material compositions are known to influence cell uptake of nanoparticles. However, the effect of particle geometry, i.e., the interplay between nanoscale shape and size, is less understood. Here we show that when shape is decoupled from volume, charge, and material composition, under typical in vitro conditions, mammalian epithelial and immune cells preferentially internalize disc-shaped, negatively charged hydrophilic nanoparticles of high aspect ratios compared with nanorods and lower aspect-ratio nanodiscs. Endothelial cells also prefer nanodiscs, however those of intermediate aspect ratio. Interestingly, unlike nanospheres, larger-sized hydrogel nanodiscs and nanorods are internalized more efficiently than their smallest counterparts. …

Global Change Factors On Ecosystem Invasibility, Raj Lal, Jeffrey Dukes, Michael J. Schuster, Nick G. Smith

The Summer Undergraduate Research Fellowship (SURF) Symposium

Current climate and human-induced changes are projected to alter many regimes of ecosystem functioning. It is projected that invasive species, nonnative species that can be of great detriment to an ecosystem, will benefit under these conditions. The Prairie Invasion and Climate Experiment (PRICLE) studies the effects of two global change factors – N addition and altered precipitation – on invasive species success and the traits that are selected for in a mixed-grass prairie ecosystem. PRICLE is a two by two factorial design over three replications in a restored mixed-grass prairie ecosystem. The major findings from the community traits examination of …

A Clamped Dual-Ridged Waveguide Measurement System For The Broadband, Nondestructive Characterization Of Sheet Materials, Milo W. Hyde Iv, Michael J. Havrilla

Faculty Publications

A novel two-port probe which uses dual-ridged waveguides for the nondestructive, broadband characterization of sheet materials is presented. The new probe is shown to possess approximately 2 to 3 times the bandwidth of traditional coaxial and rectangular/circular waveguide probe systems while maintaining the structural robustness characteristic of rectangular/circular waveguide probe systems. The theoretical development of the probe is presented, namely, by applying Love’s equivalence theorem and enforcing the continuity of transverse fields at the dual-ridged waveguide apertures, a system of coupled magnetic field integral equations is derived. The system of coupled magnetic field integral equations is solved using the method …

Detection Of Foodborne Pathogens By Micro-Filtration Using A Continuous Cell Concentrator Device, Klaire E. Jeffries, Eduardo Ximenes, Michael R. Ladisch

The Summer Undergraduate Research Fellowship (SURF) Symposium

Protecting consumers from foodborne illness is an important health concern facing the food industry today. An important deficiency exposed by foodborne illness is the inability to track contaminated food back to the source in a timely manner. Although there are established methods that detect bacterial pathogen contamination, they are limited in distinguishing viable bacteria reliably and quickly. Currently, food pathogen testing requires lengthy culture steps, which many times are delayed even longer due to the lack of in-house testing labs. Typically, two to three days elapses between when the food is sampled and the test results are available. This study …

Synthesis And Characterization Of Nucleic Acid-Functionalized Nanomaterials, Brianna S. Carroll, Jong Hyun Choi

The Summer Undergraduate Research Fellowship (SURF) Symposium

Motor proteins such as kinesin move along microtubules in order to transport cellular cargos throughout the cell by obtaining energy from RNA hydrolysis which allows the cell to complete the tasks needed to stay alive. In this work, we developed synthetic molecular motors using DNA enzymes (DNAzyme) and fluorescent nanomaterials which mimic the functions and structures of motor proteins. A DNAzyme-capped CdS nanoparticle and a RNA-functionalized single-walled carbon nanotube (SWCNT) were used as a walker and a track in the motor platform, respectively. As a walking mechanism, the DNAzyme cleaved the RNA substrates in the presence of metal cations. The …

Bicistronic Design For Precise And Reliable Gene Expression, Nidhi N. Menon, Jenna Rickus

The Summer Undergraduate Research Fellowship (SURF) Symposium

Despite having progressed extensively in the field of synthetic biology in terms of DNA synthesis, analysis and transplanting, we still cannot reliably, quantitatively measure expression of new genetic constructs. We engineered a biobrick compatible expression cassette to control transcription and translation initiation which can be reused in new genetic contexts. Previous research has shown that the Bicistronic design have much lesser variations in expression with varying genes of interest as compared to the regular monocistronic design.(Mutalik, Endy, Guimaraes, Cambray, Lam, Juul, Tran & Paull, 2013) The Bicistronic design(BCD) consists of two Shine-Dalgarno sequences in its translation element which when combined …

Determination Of Master Compliance Curve For Extruded Semolina Pasta, Laura E. Emery, Martin Okos

The Summer Undergraduate Research Fellowship (SURF) Symposium

The dependence of the rate of relaxation of semolina pasta on moisture content and temperature and how it affects shrinkage during drying has not yet been determined. The purpose of this research was to develop an equation that relates moisture content and temperature in order to obtain a master curve for creep of the product. When found, this equation could help to optimize the drying process and increase the quality of the final pasta product. Semolina flour mixed with water and propionic acid to create a 35% wet basis product was extruded on a C.W. Brabender 2523 to obtain a …

Artificial Yeast Polarization Controlled By Chemical Gradient, James K. Nolan, Bernard Tao

The Summer Undergraduate Research Fellowship (SURF) Symposium

Engineering synthetic multicellular systems will lead to new synthetic biology technological platforms, inform developmental biology through recapitulation of natural systems and possibly unveil novel morphologies with practical applications not before reached throughout natural history (Maharbiz, 2012). Creating an exogenous molecular circuit that will polarize unicellular cells into “apical” and “basal” domains relative to a substrate plane would fulfill a missing component towards fully multicellular synthetic cellular communities (Maharbiz, 2012). To this end, a PIP₃ polarization network previously designed by Chau and associates (Chau, Walter, Gerardin, Tang, Lim 2012) was coupled to the specific activation by niacin of a recombinant …

The Efficacy And Optimization Of Somatosensory Intracortical Microstimulation In Rats, Sean P. Mcdowell, Ryan S. Verner, Kevin J. Otto Dr.

The Summer Undergraduate Research Fellowship (SURF) Symposium

Demand exists for brain-machine interfaces that offer a wide range of sensory feedback along with volitional motor control to individuals with limited control of natural sensory or motor function. As these sensorimotor devices are developed, it is necessary to improve the interaction between the prostheses and higher-level cortical structures. Optimizing these somatosensory stimulation parameters will require the use of a high-throughput experimental design. To address this, one Sprague-Dawley rat was trained to respond to auditory stimuli during a conditioned-avoidance behavior task and then implanted with a penetrating microelectrode array in the part of the somatosensory cortex corresponding to the left …

In Vivo Method For Labeling And Tracking Cells In The Mammalian Limb Bud, James T. Mccarthy, Andrew Schilb, Sarah Calve

The Summer Undergraduate Research Fellowship (SURF) Symposium

The extracellular matrix (ECM) is composed of many different proteins excreted by cells and is believed to play a very important role in development as well as regeneration and wound healing. In this research, a method to determine the ECM’s effect on the migration of muscle progenitor cells into the mammalian limb bud was investigated. It has traditionally been difficult to obtain in vivo images of the limb bud, due to the difficulty of maintaining embryos in culture and limitations of imaging techniques. In this study, we have worked on optimizing the culture conditions to allow growth of mouse embryos …