Digital Commons Network^™

การใช้ตัวทำละลายร่วมในปฏิกิริยาทรานเอสเทอร์ริฟิเคชันของน้ำมันปาล์มโอเลอิน โดยมีโซเดียมฟอสเฟตเป็นตัวเร่งปฏิกิริยา, ศรัณยู ถาวรพัทธ์

Chulalongkorn University Theses and Dissertations (Chula ETD)

งานวิจัยฉบับนี้เป็นการศึกษาถึงผลกระทบของตัวทำละลายร่วมในการทำปฏิกิริยาทรานเอสเทอร์ริฟิเคชั่นของน้ำมันปาล์มโอเลอินและเมทานอลโดยใช้ตัวเร่งปฏิกิริยาวิวิธพันธ์เป็นโซเดียมฟอสเฟต ทำการทดลองในเครื่องปฏิกรณ์แบบกะชนิดถังกวน ความเร็วรอบในการปั่นกวน 600 รอบต่อนาที ปริมาณตัวเร่งปฏิกิริยา ร้อยละ 0.5 โดยน้ำหนักน้ำมันพืช อัตราส่วนโดยโมลของเมทานอลต่อน้ำมันพืชเท่ากับ 6:1 ถึง 30:1 ชนิดตัวทำละลายร่วมที่เลือกใช้คือ อะซิโตนและเตตระไฮโดรฟูแรน ปริมาณตัวทำละลายร่วมร้อยละ 10 และ 20 โดยน้ำหนักน้ำมัน อุณหภูมิในการทำปฏิกิริยา 60 90 140 190 องศาเซลเซียส ผลการทดลองแสดงให้เห็นว่า ตัวทำละลายร่วมไม่ส่งผลกระทบต่อค่าคงที่ทางจลน์พลศาสตร์ของปฏิกิริยา และยังส่งผลเสียในการเจือจางตัวเร่งปฏิกิริยาและสารตั้งต้นในการทำปฏิกิริยาที่สภาวะอุณหภูมิสูง (190 องศาเซลเซียส) นอกจากนี้ การทำปฏิกิริยาทรานเอสเทอร์ริฟิเคชั่นชอบการทำปฏิกิริยาในสภาวะที่มีความเข้มข้นของเมทานอลในวัฏภาคที่ทำปฏิกิริยาสูงๆ การละลายเข้าด้วยกันที่มากเกินไปของเมทานอลและน้ำมันพืชจะส่งให้ปฏิกิริยาเกิดช้าลงแทน

Online Self-Learning System For Prediabetes Patients, Ye Moe Myint

Chulalongkorn University Theses and Dissertations (Chula ETD)

This thesis implements a web-based application that combines a 3D learning center and educational game to facilitate the monitoring, management, and treatment of patients with prediabetes mellitus, by providing exercise plans and controlled diets. The application utilizes advanced web technologies, 3D modeling, and gamification principles to create an engaging learning experience. User-centered design ensures usability, and testing demonstrates positive outcomes, including increased knowledge, motivation, and engagement. This research contributes to digital health interventions by empowering prediabetes patients with informed decision-making and healthy habits. Future directions include expanding the application, refining the user interface, and evaluating long-term impact on prediabetes management.

Effect Of Air Pollution On Number Of Visits With Pneumonia And Influenza:Before Vs. During Covid-19 Outbreak In Thailand, Benjawan Roudreo

Chulalongkorn University Theses and Dissertations (Chula ETD)

The COVID-19 pandernic had effect on changes in people, environment, and health risk. This was a unique research opportunity to assess the effects on the risk of respiratory infectious diseases resulting from the changes in air pollution during COVID-19 outbreak. This study estimated the relative risks (RRs) of hospital visits with pneumonia and influenza associated with air pollution (PM10 PM25 NO2 and ⊖ y} by using Poison with generalized additive model (GAM) and compared the different RRs of pneumonia and influenza before vs. during the COVID-19 outbreak in Khon Kaen province and its vicinity. For results, before the COVID-19 period, …

Analysis Of Bio-Alcohols With Mie-Scattering And Ltc For Lowered Emissions In Pcci, Cesar E. Carapia

College of Graduate Studies: Theses & Dissertations

An investigation was conducted on the optimal engine parameters for facilitating lower NOX and soot emissions of PCCI combustion with either ethanol or n-butanol. The PFI fuels selected were tested at loads of 3, 4, and 5 Bar IMEP for a total of 28 total combustion tests with variations made to the EGR% and boost pressure for each test in order to find the optimal emissions strategy. A Mie-scattering spray fuel analysis was also conducted on the three fuels to gain insight on their influence on combustion/emissions characteristics. It was found that ethanol had a greater average Sauter Mean Diameter …

Ecological Restoration Of Lead/Zinc/Copper Mine Tailings: Phytomanagement And Amendment Strategies To Enhance Substrate Functionality And Biomass Production, Mariam K. Al-Lami

Doctoral Dissertations

“The extreme physiochemical characteristics of mine tailings inhibit microbial processes and natural plant growth. Consequently, vast and numerous tailings sites remain barren for decades and highly susceptible to wind and water erosion. Phytostabilization is a cost-effective and ecologically productive remediation approach; however, tailings revegetation is generally challenging and must often be assisted with appropriate soil amendments. Amendments applied individually in greenhouse studies discussed herein revealed notable improvement in bioenergy crops growth only with biosolids treatments. Recalcitrant carbon amendments (biochar and humus) showed notable impact only on tailings physichochemical and hydraulic properties. Nevertheless, biosolids may not support sustained vegetation due to …

Investigation Of Flow Characteristics In An Open Channel With One-Line Semicircular Vegetation Patches, Hemanta D. Karki

Theses: Doctorates and Masters

Experiments are conducted in an open channel with semi-circular patches distributed on one sidewall of the channel in which velocity distribution, turbulent intensity, and vortex generation are analyzed. The resistance force offered by a vegetation patch causes the change in water depth which have a broader application in river management, bank stabilization, and flood control.

The measurement is conducted in the laboratory with the help of different measuring devices like Laser doppler velocimeter, particle image velocimeter, measuring scale, and so on. From the experiment, the velocity distribution in a longitudinal direction suggests that the flow is fully developed after a …

Nondestructive Detection Of Codling Moth Infestation In Apples Using Pixel-Based Nir Hyperspectral Imaging With Machine Learning And Feature Selection, Nader Ekramirad, Alfadhl Y. Khaled, Lauren E. Doyle, Julia R. Loeb, Kevin D. Donohue, Raul T. Villanueva, Akinbode A. Adedeji

Electrical and Computer Engineering Faculty Publications

Codling moth (CM) (Cydia pomonella L.), a devastating pest, creates a serious issue for apple production and marketing in apple-producing countries. Therefore, effective nondestructive early detection of external and internal defects in CM-infested apples could remarkably prevent postharvest losses and improve the quality of the final product. In this study, near-infrared (NIR) hyperspectral reflectance imaging in the wavelength range of 900–1700 nm was applied to detect CM infestation at the pixel level for three organic apple cultivars, namely Gala, Fuji and Granny Smith. An effective region of interest (ROI) acquisition procedure along with different machine learning and data processing …

Real-Time Monitoring Of Cell Death Progress Using Capacitance Spectroscopy, Suyang Wu

Electronic Theses and Dissertations

Biologics, including the monoclonal antibody (mAb), has experienced rapid development in the last decade. However, the price of biologics is often prohibitively high because of the low process efficiency. Delaying the inevitable cell death improves the productivity of upstream bioprocessing, whose success relies on monitoring the cell death onset that indicates the timing for preventive actions.

This study proposes to develop a real-time monitoring model that quantifies the dying cell percentage in lab-scale bioreactors using capacitance spectroscopy. The capacitance spectroscopy contains cell death-related information due to various physical properties changes during the cell death process, e.g., cytoplasmic conductivity change. The …

Pertumbuhan Dan Hasil Dua Kultivar Bayam Pada Sistem Budidaya Hidroponik Untuk Lahan Sempit, Syariful Mubarok, Asyifa Mardatillah, Anne Nuraini

Jurnal Kultivasi

Hidroponik merupakan salah satu teknik sistem budidaya yang biasa digunakan di lahan sempit seperti di perkotaan. Tujuan dari penelitian ini adalah untuk menentukan sistem budidaya bayam yang paling baik untuk diterapkan pada sistem urban farming pada lahan sempit, misalnya di kawasan pemukiman padat penduduk di bagian timur Jakarta. Rancangan Acak Kelompok Lengkap yang digunakan dalam penelitian ini terdiri dari dua kultivar bayam dan tiga sistem budidaya yaitu budidaya konvensional, sistem hidroponik Wick dan NFT. Hasil penelitian menunjukkan bahwa sistem NFT menghasilkan pertumbuhan dan hasil terbaik yang ditunjukkan oleh jumlah daun, diameter batang, luas daun, panjang akar, volume akar dan berat …

Evaluasi Kualitas Nutrisi Microgreen Bayam Merah Dan Hijau Menggunakan Cahaya Buatan, Aida Fadlilah Rahmani, Syariful Mubarok, Mochamad Arief Soleh, Boy Macklin Pareira Prawiranegara

Jurnal Kultivasi

Permasalahan yang muncul untuk mengusahakan pertanian perkotaan adalah semakin sulitnya menemukan lahan pertanian yang dimiliki masyarakat dan kesempatan waktu yang minim untuk budidaya tanaman. Permasalahan tersebut dapat diatasi salah satunya dengan menggunakan sistem hidroponik ditambah pencahayaan buatan untuk kebutuhan pertumbuhan tanaman. Penanaman microgreen dalam ruangan merupakan salah satu cara untuk memudahkan masyarakat dalam berbudidaya tanaman. Percobaan ini bertujuan untuk mempelajari jenis warna cahaya buatan terhadap kualitas nutrisi microgreen bayam merah dan bayam hijau. Penelitian dilaksanakan di Laboratorium Analisis Tanaman dan Pasca Panen Hortikultura, Fakultas Pertanian, Universitas Padjadjaran. Rancangan percobaan yang digunakan yaitu Rancangan Acak Kelompok dengan dua faktor perlakuan, yaitu …

Evaluating And Enhancing Iron Removal Via Filterable Iron Precipitates Formation During Coal-Waste Bioleaching, Prasenjit Podder, Zongliang Zhang, Rick Q. Honaker, Michael L. Free, Prashant K. Sarswat

Mining Engineering Faculty Publications

Iron removal via jarosite precipitate formation is a commonly used technique in various hydrometallurgical processes. Excess iron removal often becomes essential to an overall metal recovery circuit. This is particularly important to processes involving iron-bearing minerals. A technique, which involved the use of pyrite to generate acid for leaching, for iron removal is critical to enabling the process. Iron removal using CaO or similar reagents is expensive and often results in lost product. In the present study, various compounds that facilitate jarosite formation, namely Na₂SO₄, NH₄OH, KCl, and KOH, were utilized and their effect …

Lupa: An Excursion Vehicle For The Moons Of Mars, Shannon Kavanagh, Bo Lewis, Alex Odinamba, Joshua Mulhern

Senior Design Project For Engineers

Our team has designed a spacecraft and mission for exploring the moons of Mars. The Lithological and Ultraviolet Photometry Assessment (LUPA) excursion vehicle is capable of crew habitation, autonomous rendezvous, and in-vacuum sample collection all in support of a parallel Mars surface mission to be carried out in the year 2040. Our project's key focus areas revolve around orbital mechanics, space vehicle propulsion analysis, scientific exploration, and the management of various interconnected spacecraft subsystems.

Novel Approaches For Enhancing Cell Survival And Function In Vivo, Ou Wang

Department of Chemical and Biomolecular Engineering: Dissertations, Theses, and Student Research

FDA has approved several cell-based therapeutics and hundreds of cell therapy clinical trials are ongoing. Cells will be a significant type of medicine after small molecule and protein drugs. However, several obstacles need to be addressed to achieve the widespread use of cellular therapeutics. The first challenge is the low efficacy of cell transplantation due to low retention, survival, integration, and function of cells in vivo. The second challenge is producing a massive number of cells for clinical treatment with cost-effectively and reproducibly technologies.

In this thesis, we proposed and investigated two approaches to address these challenges. To begin …

The Application Of Mathematical Optimization And Flavor-Detection Technologies For Modeling Aroma Of Hops, Yutong Liu

Department of Food Science and Technology: Dissertations, Theses, and Student Research

In recent years, proprietary hops (Citra, Simcoe, and Mosaic) become the most sought-after hops among brewers due to their excellent aroma. However, they are restricted to the owners unless other growers purchase the costly licensing agreements. Many public hops are available to the growers without any additional costs, but their aroma is difficult to match to the proprietary hops. Although proprietary and public hop varieties are unique in their aroma profiles, all hops varieties contain similar volatile compounds, merely differ in the quantity of different individual compounds. The main objective of this thesis was to investigate the feasibility of matching …

Determining The Psychosocial Needs Of The Nurses Of Covid-19 Patients, Allison Stevens

ATU Theses and Dissertations 2021 - Present

Nurses are a vital element of the COVID-19 healthcare crisis and have been since the beginning of the COVID-19 response. The professional strain put on nurses included, but is not limited to: changing professional roles, rapidly changing policies and procedures, an influx of patients—particularly of high acuity, and change in workplace morale. However, nurses also had to carry the burdens of living as a member of society, family member, friend, community member, and above all, simply as a person surviving a pandemic themselves. With all of the stressors nurses have endured, it stands to reason that their psychosocial needs have …

Assessment Of Stormwater Infrastructure For Mitigating Flooding And Non-Point Source Pollution, Helia Farzaneh

Civil Engineering Theses - Archive

Flooding is the top natural hazard impacting coastal and inland communities in Texas. Beyond its destructive impact on rising waters in communities, flooding-induced stormwater negatively affects the quality of large bodies of water. Stormwater runs over land, washes off pollutants, and deposits them into rivers which causes water quality issues in bays and estuaries. In addition, the stormwater increases nutrients, sediments, oxygen-demanding substances, pathogens, and toxins which results in hypoxia in the aquatic system. During the last 5-6 years, severe storm events such as Tropical Storm Beta (September 2020), Tropical Storm Imelda (September 2019), Hurricane Harvey (August 2017) have caused …

Understanding The Behavior Of The Covid-19 Pandemic Using Data Analytics, Mohammad Reza Davahli

Electronic Theses and Dissertations, 2020-2023

In December 2019, China announced the breakout of a new virus identified as coronavirus SARS-CoV-2 (COVID-19), which soon grew exponentially and became a global pandemic. Despite strict actions to mitigate the spread of the virus in various countries, the COVID-19 pandemic resulted in a significant loss of human life in 2020 and 2021. To better understand the pandemic, this doctoral research incorporated data analytics to evaluate the behavior and impacts of the virus. The doctoral research contributed to the scientific body of the knowledge in different ways including (1) presenting a systematic literature review of current research and topics about …

Siderophore-Mediated Zinc Acquisition Enhances Enterobacterial Colonization Of The Inflamed Gut, Judith Behnsen, Hui Zhi, Allegra T. Aron, Venkateswaran Subramanian, William Santus, Michael H. Lee, Romana R. Gerner, Daniel Petras, Janet Z. Liu, Keith D. Green, Sarah L. Price, Jose Camacho, Hannah Hillman, Joshua Tjokrosurjo, Nicola P. Montaldo, Evelyn M. Hoover, Sean Treacy-Abarca, Benjamin A. Gilston, Eric P. Skaar, Walter J. Chazin, Sylvie Garneau-Tsodikova, Matthew B Lawrenz, Robert D Perry, Sean-Paul Nuccio, Pieter C. Dorrestein, Manuela Raffatellu

Pharmacy Nuclear Magnetic Resonance Center Faculty Publications

Zinc is an essential cofactor for bacterial metabolism, and many Enterobacteriaceae express the zinc transporters ZnuABC and ZupT to acquire this metal in the host. However, the probiotic bacterium Escherichia coli Nissle 1917 (or “Nissle”) exhibits appreciable growth in zinc-limited media even when these transporters are deleted. Here, we show that Nissle utilizes the siderophore yersiniabactin as a zincophore, enabling Nissle to grow in zinc-limited media, to tolerate calprotectin-mediated zinc sequestration, and to thrive in the inflamed gut. We also show that yersiniabactin’s affinity for iron or zinc changes in a pH-dependent manner, with increased relative zinc binding as the …

Investigation On Effects Of Lactate Adaptation Using Metabolic Indicators And Amino Acids To Explore Cell Metabolism, Lisa Uy

All Theses

Biopharmaceutical products are drugs that are made from living cells. One protein type of high importance to biopharmaceuticals is monoclonal antibodies. Monoclonal antibodies allow for highly specific, targeted treatment of diseases and detection of molecules related to diseases. With major roles in detecting and/or treating diseases like human immunodeficiency virus (HIV), coronavirus disease 2019 (COVID-19), and some cancers, monoclonal antibodies are in demand. This demand has led to a need for efficient cell culture systems to produce high yields of protein with minimal waste. The most commonly used cell culture system for these high-value proteins is Chinese hamster ovary (CHO) …

Greenhouse Tomatoes: Process Simulation, Juan Gabriel Marin Jr.

Graduate Theses and Dissertations

Growing population demand and challenges brought on by climate change have spurred the need for more resilient fruit and vegetable supply chains. One agricultural technology of significant interest is the use of greenhouses for food production. Greenhouses create a stable and adaptable environment for crops such as tomatoes to grow year-round. Fresh tomatoes are the second most consumed vegetable per capita in U.S. diets, currently averaging 20.7 pounds. The growing consumption of fresh tomatoes has been the result of increasing cultural diversity in the United States.

To meet the growing demand, Venlo-type greenhouses have been frequently used by growers. It …

Multifunctional Programmable Self-Assembled Nanoparticles In Nanomedicine, Yoshie Sakamaki

Graduate Theses and Dissertations

Developing methodologies to control the architecture of nanoparticles (NPs) at the atomic level prevents their inhomogeneity and leads to a variety of expected functions. Rationally designed nanoparticles can either be programmed or crystallized structures into pre-determined structures achieving tunable particle pore size and physiochemistry. In this dissertation, two broad classes of multifunctional nanoparticles are developed, metal-organic frameworks and DNA-NP aggregates.

Metal-organic frameworks are a novel class of highly porous crystalline materials built from organic linkers and metal cluster-based secondary building units. However, applications in bioremediation have not been developed very well especially in applications regarding drug delivery systems (DDS). The …

A Systematic Stakeholder-Driven Framework For Empirical Characterization And Parameterization Of Human Agents For Agent-Based Modeling Of Older Adults' Transportation, Nilufer Oran Gibson

Industrial, Manufacturing, and Systems Engineering Dissertations - Archive

Standard of living for health and well-being of oneself and of one’s family is a human right. Vulnerable populations are incapable of maintaining an adequate standard of living due to several reasons, such as financial constraints, racial profiling, health conditions, aging, and the combination of these reasons. To alleviate their vulnerability, the most basic needs of the vulnerable populations must be met. Transportation is the essential link to the resources to address the basic needs of the vulnerable populations. Transportation solutions tailored for vulnerable populations to meet their basic needs have multiple dimensions that require the involvement of all government …

Social Media Influencers (Smis) In Context: A Literature Review, Charles Alves De Castro, Isobel O'Reilly Dr, Aiden Carthy

Articles

This review focused on three main areas, "Social Media Influencers (SMIs) in Context, The Impact of SMIs on Adolescents, and Consumer Behaviour in a Digital Era – Generation Z in Perspective". This article aims to further the overall understanding of SMIs and outlines the impact of SMIs on adolescents‘ lives. Thus, the main objective of this literature review is to raise awareness within the marketing field about the influence of social media influencers on adolescents and how brands promote their products and content through social media influencers. The review comprised a regular search using electronic journal databases and secondary data …

Synthesis And Assessment Of Sustainable Fuels For Transportation And Space Exploration, Katerina Chagoya

Electronic Theses and Dissertations, 2020-2023

As global energy sources transition towards renewable energy, the demand for sustainable fuels has never been greater. The sheer scale of this transition will require numerous solutions to accommodate for the diverse and complex situations worldwide. This dissertation will discuss 3 studies: the utilization of CO2 waste gas to produce fuels sustainably, characterizing biofuels for efficient use in automobiles, and developing a solid, emissonless fuel intended for spaceflight but also applicable on Earth. The hydrogenation of CO2 into value-added molecules could reduce greenhouse gas emissions if waste stream CO2 were captured for conversion. We found that atomic vacancies induced in …

The Bridge Newsletter Winter 2021, Missouri University Of Science And Technology

The Bridge Newsletter

-S&T contributes to infrastructure through national center
-Brinkmann leads Missouri Highways and Transportation Commission
-Wu wins NSF CAREER Award for 2D metals work
-Academy of Civil Engineers induction and 150^th celebration

Evaluation Of A Novel Approach For Assessing Biological Activity In Agricultural Soils, Karla Melgar

Department of Agricultural and Biological Systems Engineering: Dissertations, Theses, and Student Research

Soil health is a key factor impacting soil resilience and fertility in crop production systems. Favorable soil physical and biological conditions facilitate plant nutrient absorption and nutrient cycling. Demonstrating to farmers the impacts and changes in soil biological activity under different soil management practices has been a challenge due to the limited availability of inexpensive tools for quantifying this component of soil health. The primary goal of this study was to present a simple and readily accessible tool for evaluating soil biological activity to promote the use of organic amendments in crop fields. Research plots were established in two studies …

Computational Modeling Of 3d-Printed Lactobacillus-Antibiotic Scaffolds For Bacterial Vaginosis., Veeresh P. Rai

Electronic Theses and Dissertations

The standard treatment for bacterial vaginosis (BV) is currently antibiotics, such as metronidazole, clindamycin, or tinidazole. These antibiotics are highly effective in getting rid of bacteria in the female reproductive tract (FRT); however, there are some bacteria that provide benefits to the FRT which also get expunged. While there are many strains of bacteria that play a beneficial role in the FRT, lactobacilli are among the most important. These bacteria are responsible for maintaining a healthy environment in the FRT via pH regulation by lactic acid metabolism. Antibiotics eliminate all bacteria from an environment, including lactobacilli, and as a result, …

Integration Of Internet Of Things And Health Recommender Systems, Moonkyung Yang

Electronic Theses, Projects, and Dissertations

The Internet of Things (IoT) has become a part of our lives and has provided many enhancements to day-to-day living. In this project, IoT in healthcare is reviewed. IoT-based healthcare is utilized in remote health monitoring, observing chronic diseases, individual fitness programs, helping the elderly, and many other healthcare fields. There are three main architectures of smart IoT healthcare: Three-Layer Architecture, Service-Oriented Based Architecture (SoA), and The Middleware-Based IoT Architecture. Depending on the required services, different IoT architecture are being used. In addition, IoT healthcare services, IoT healthcare service enablers, IoT healthcare applications, and IoT healthcare services focusing on Smartwatch …

Machine Learning For Unmanned Aerial System (Uas) Networking, Jian Wang

Doctoral Dissertations and Master's Theses

Fueled by the advancement of 5G new radio (5G NR), rapid development has occurred in many fields. Compared with the conventional approaches, beamforming and network slicing enable 5G NR to have ten times decrease in latency, connection density, and experienced throughput than 4G long term evolution (4G LTE). These advantages pave the way for the evolution of Cyber-physical Systems (CPS) on a large scale. The reduction of consumption, the advancement of control engineering, and the simplification of Unmanned Aircraft System (UAS) enable the UAS networking deployment on a large scale to become feasible. The UAS networking can finish multiple complex …

Hydrothermal Processes For Extraction And Conversion Of Biomass To Produce Biofuels And Value-Added Products, Anuj Hemant Thakkar

Civil & Environmental Engineering Theses & Dissertations

An integrated biorefinery approach based on subcritical hydrothermal processes was developed to maximize utilization of biomass components by producing multiple products. Biomass from various sources like agricultural waste (lignocellulose), food waste (spent yeast), and dedicated cultivation (micro-algae) was used in this research.

Corn stover (agricultural waste) was hydrothermally pretreated to remove lignin and xylan while preserving most of the glucan. The pretreated corn stover was utilized to produce levulinic acid (thermochemically) and fermentable sugars (biochemically). The solid residue generated during levulinic acid production was utilized to produce biocarbon electrode material. The results generated from the experiments were used for designing …