Digital Commons Network^™

Electrosynthesis Of P-Aminobenzenearsenic Acid, Chun-An Ma, Qin-An Zheng, Qiang Zhou, Ying-Hua Xu

Journal of Electrochemistry

The electrochemical reduction of p-nitrophenyl arsonit acid to p-aminobenzenearsenic acid was studied using controlled-current electrolysis.The results showed that the yield of p-aminobenzenearsenic acid was determinated by the following factors:the concentrations of sulphuric acid,the amount of additive,temperature and the concentrations of p-nitrophenyl arsenic acid.The optimum electrolytic conditions were obtained to be is 10% H₂SO₄,1% NaCl,80 ℃,25 g/350 mL p-nitrophenyl arsenic acid and 10 A·dm^-2.The yield of arsanilic acid could be reached 64.7% under the optimum electrolytic conditions.

Application Of An Efficient Nonconventional Heterogeneous Catalyst For Biodiesel Synthesis From Pongamia Pinnata Oil, Y. C. Sharma, Bhaskar Singh, John Korstad

College of Science and Engineering Faculty Research and Scholarship

Recycled chicken eggshells after calcination have been used as a nonconventional heterogeneous catalyst for biodiesel synthesis from karanja oil from the pongam tree (Pongamia pinnata). The catalyst was characterized on X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, and differential thermal analysis/thermogravimetric analysis (DTA/TGA). The formation of the calcium oxide phase was confirmed at 900°C after calcination. A high biodiesel yield of 95.0% and conversion of 97.4% was obtained at an 8:1 (alcohol/oil) molar ratio, 2.5 wt%catalyst, and 2.5 h reaction time at 65±°0.5C. The biodiesel conversion was determined by Fourier transform nuclear magnetic resonance (FTNMR) spectroscopy.

Biological Treatment Of Milk And Soybean Wastewater With Bioproducts, Tianzhu Bi

ETD Archive

Dairy industries discharge larger amounts of wastewater as compared to other food industries. Wastewater contains high amount of total organic carbon materials and nutrients, such as fat, protein, and lactose. Biological treatment is widely used to treat this kind of wastewater due to the fluctuation of amount and content of dairy wastewater. This study investigated removal of total organic carbon (TOC) from two types of dairy wastewater-milk and soy milk wastewater. The bioproducts used in experiments were baker's yeast, beer's yeast, live liquid microorganism (LLMO), Enforcer Overnite Toilet Care Liquid, and Enforcer Overnite Toilet Care Granular. The parameters included in …

A Risk-Based Approach For Examining Vertical Separation Distances In On-Site Wastewater Treatment Sytems, Anthony M. Janicek

ETD Archive

Regulations regarding the use of on-site wastewater treatment systems in many states lack a sufficient scientific basis, which in many cases restricts the use of on-site systems, drives up cost, and restricts innovation of new treatment technologies. Of particular regulatory concern is the minimum vertical separation distance (VSD) located in the area between the trench bottom of the subsurface soil absorption system and any restricting or limiting layer. The minimum VSD needed for proper effluent treatment is based on many complex and interrelated factors regarding physical, chemical, and biological soil conditions at a particular site. Research has shown that depending …

Santa Clara Magazine, Volume 51 Number 4, Spring 2010, Santa Clara University

Santa Clara Magazine

14 - BENDING LIGHT By Steven Boyd Saum. They wanted to show that green living is not a compromise. So, for the international Solar Decathlon, the SCU-led Team California built a house of light and wonder. And it was dazzling enough to win No. 3 on the planet.

22 - CONNECT THE DOTS By Scott Brown '93. From border security to disaster preparedness, Secretary of Homeland Security Janet Napolitano '79 has one immense portfolio. She's also the point person on immigration. How to put those together?

28 - THIS PLACE WE CALL HOME By Kristina Chiapella '09 '09. Generations ago, …

Study Of Strawberry Flavored Milk Under Pulsed Electric Field Processing, Daniela Bermúdez-Aguirre, Jaime A. Yáñez, C. Patrick Dunne, Neal M. Davies, Gustavo V. Barbosa-Cánovas

United States Army: Publications

Few studies exist on flavored milk processed by pulsed electric fields (PEF). The main concern is product stability. This study aimed to analyze the degradation of coloring agent Allura Red in strawberry milk under PEF. Four systems were tested containing Allura Red: two commercial milks and two model systems. PEF conditions were 40 kV/cm, 48 pulses (2.5 μs), and 55 °C; coloring agent was quantified via RP-HPLC. After processing, only minor changes were observed in color, Allura Red concentration, and pH. During storage (32 d) at refrigerated conditions (4 °C) commercial samples maintained pH above 6. Model systems dropped below …

Acute Caffeine Consumption Enhances The Executive Control Of Visual Attention In Habitual Consumers, Tad T. Brunyé, Caroline R. Mahoney, Harris R. Lieberman, Grace E. Giles, Holly A. Taylor

United States Army: Publications

Recent work suggests that a dose of 200–400 mg caffeine can enhance both vigilance and the executive control of visual attention in individuals with low caffeine consumption profiles. The present study seeks to determine whether individuals with relatively high caffeine consumption profiles would show similar advantages. To this end, we examined the effects of four caffeine doses (0 mg, 100 mg, 200 mg, 400 mg) on low- and high-level visual attention in individuals with high consumption profiles (n = 36), in a double-blind study using a repeated measures design. Results from the Attention Network Test indicated that caffeine enhanced both …

Raman Spectroscopic Modeling Of T- Lymphocyte Activation And Detection Of Acute Renal Allograft Rejection, Kristian L. Brown

Wayne State University Dissertations

ABSTRACT

RAMAN SPECTROSCOPIC MODELING OF T-LYMPHOCYTE ACTIVATION AND DETECTION OF ACUTE RENAL ALLOGRAFT REJECTION

By

KRISTIAN L. BROWN

2010

Advisor: Gregory Auner, PhD

Major: Biomedical Engineering

Degree: Doctor of Philosophy

Despite the advances made in the area of kidney transplantation, the disparity between the demand and available donated organs remains a dominant and unresolved issue. Given the paucity of available renal allografts the preservation of existing grafts is vital. One factor that has negatively impacted renal allograft survival is acute rejection (AR). Traditionally, kidney transplant centers have used elevations in serum creatinine as a screening tool for detecting AR. However, …

Enriched Coal Ash Utilization For Augmenting Production Of Rice Under Acid Lateritic Soil, S. Karmakar, B.N. Mittra, B.C. Ghosh

Coal Combustion and Gasification Products Journal Archive

The use of industrial wastes such as fly ash (FA) or rice husk ash (RHA), along with paper factory sludge (PFS), farmyard manure (FYM), and chemical fertilizers (CF), under integrated nutrient management, was studied in acid lateritic soil on rice. Application of combined fertilization sources increased growth, yield attributes, and yield (up to 92.3 and 9.7% over control and CF, respectively) of wet season rice. The uptake of N, P, K, Ca, Mg, Fe, Mn, Zn, Cu, and Co was increased under combined fertilization sources. The study also indicated that such integrated plant nutrition system improved physico-chemical properties of soil …

The Journal Of Undergraduate Research: Volume 08

The Journal of Undergraduate Research

This is the complete issue of the South Dakota State University Journal of Undergraduate Research, Volume 8.

Time And Degree Of Glycemic Derangement Are Associated With Increased Mortality In Trauma Patients In The Setting Of Tight Glycemic Control, Michael G. Corneille, Celina Villa, Steven Wolf, Joel E. Michalek, Inkyung Jung, Charles E. Wade, John G. Meyers, Daniel L. Dent, Deborah Mueller, Ronald M. Stewart

United States Army: Publications

BACKGROUND: Tight glucose control (TGC) may reduce mortality in critically ill trauma patients. We hypothesize that euglycemia is beneficial, and a measure considering time and degree of hyperglycemia is most associated with mortality.

METHODS: We performed a review of intensive care unit trauma patients admitted for more than 3 days between January 2005 and December 2007 on a TGC protocol with a goal of 80 to 110 mg/dL. Hyperglycemic, hypoglycemic, and euglycemic time ranges, and area of interpolated curves above and below 80 to 110 mg/dL were assessed. Associations with mortality were based on logistic regression models adjusted for age, …

Activity Of Topical Antimicrobial Agents Against Multidrug-Resistant Bacteria Recovered From Burn Patients, Jessie S. Glasser, Charles H. Guymon, Katrin Mende, Steven E. Wolf, Duane R. Hospenthal, Clinton K. Murray

United States Army: Publications

Background:

Topical antimicrobials are employed for prophylaxis and treatment of burn
wound infections despite no established susceptibility breakpoints, which are becoming vital in an era of multidrug-resistant (MDR) bacteria. We compared two methods of determining topical antimicrobial susceptibilities.

Methods:

Isolates of Pseudomonas aeruginosa, methicillin-resistant Staphylococcus aureus (MRSA), extended spectrum beta-lactamase (ESBL) producing Klebsiella pneumoniae, and Acinetobacter baumanii-calcoaceticus (ABC) from burn patients were tested using broth microdilution and agar well diffusion to determine minimum inhibitory concentrations (MICs) and zones of inhibition (ZI). Isolates had systemic antibiotic resistance and clonality determined. MDR included resistance to antibiotics in three or more …

Microalgal Bioremediation Of Nutrients In Wastewater And Carbon Dioxide In Flue Gas, Anand Murali Narasimhan

Masters Theses

"Microalgae are potential biofuel feedstocks that can provide solutions to the twin challenges of energy security and environmental pollution. They have great potential for the removal of excess nitrogen and phosphorus from wastewater including the farm runoff. They can capture carbon dioxide in the flue gas from coal fired power plants thereby reducing greenhouse gas and also producing algal biomass, which can be converted into biofuel. In this study, the nutrient consumption of Scenedesmus algae was investigated in a batch culture and the biomass yield was determined. Algae were able to utilize carbon in the form of soluble carbonates which …

Finite Element Analysis And Fatigue Test On The Bicuspids To Support Theory Of Abfraction, Madhuchandra Mahadevaswamy

Masters Theses

"Abfraction is a small crack or notch found at the cervical areas of a teeth due to the loss of enamel tissues in the teeth. Proposed explanations for are that it is caused by toothbrush abrasion, acid erosion, and the mechanical forces applied on the teeth due to chewing, biting, tongue activity. There is disagreement among dentists as to the primary causes of abfraction. Some dentists believe that abfraction is caused by toothbrush abrasion and erosion due to acidic food and drinks. Other dentists believe that tensile and compressive forces acting on the teeth from non-axial, cyclical loading over an …

A Biomechanical Comparison Of Locking Compression Plate Constructs With Plugs/Screws In Osteoporotic Bone Model, Krishna P. Desai

Browse all Theses and Dissertations

Locking compression plates are proven to be safe for use in open reduction and internal fixation (ORIF) especially in osteoporotic bones. Because of various combinations of holes, the system provides more options for clinicians to use either locking screws or non-locking screws. This clinical research introduces screw like plugs which can be used along with the screws in case of locking compression plates. Experimental work was performed to determine the effectiveness of the plugs. The results showed that there is not a significant difference between the groups which used plugs and did not use the plugs, both in case of …

Effluent Organic Nitrogen (Eon): Bioavailability And Photochemical And Salinity-Mediated Release, Deborah A. Bronk, Quinn N. Roberts, Marta P. Sanderson, Elizabeth A. Canuel, Patrick G. Hatcher, Rajaa Mesfioui, Katherine C. Filippino, Margaret R. Mulholland, Nancy G. Love

Chemistry & Biochemistry Faculty Publications

The goal of this study was to investigate three potential ways that the soluble organic nitrogen (N) fraction of wastewater treatment plant (WWTP) effluents, termed effluent organic N (EON), could contribute to coastal eutrophication - direct biological removal, photochemical release of labile compounds, and salinity-mediated release of ammonium (NH₄+). Effluents from two WWTPs were used in the experiments. For the bioassays, EON was added to water from four salinities (∼0 to 30) collected from the James River (VA) in August 2008, and then concentrations of N and phosphorus compounds were measured periodically over 48 h. Bioassay results, based …

Branched And Spiral Organic Nanotubes Based On The Self-Assembly Of Bile Acids, Xuejun Zhang

Electronic Theses and Dissertations

The self-assembly of chiral amphiphilic molecules in aqueous solutions is of particular interest because the chirality of individual molecules is often expressed in their supermolecular structures. Self-assembled tubes made of chiral amphiphilic molecules represent useful supramolecular architectures which hold promise as controlled release vehicles for drug delivery, encapsulates for functional molecules, and nanoreactors for chemical reactions. Lithocholic acid (LCA) is a secondary bile acid with the concentration being identical to that of cholesterol in the hepatic bile and gallbladder. It has a rigid, nearly planar hydrophobic steroid nucleus, with four hydrogen atoms and one hydroxyl group directed toward the concave …

Microalgae Harvesting By Flocculation With Polymer-Coated Magnetite Particles, Humayun Shariff

Masters Theses

"Although microalgae are considered to be one of the potentially significant feedstock for renewable biofuels, harvesting them efficiently from culture ponds has been a major hurdle. The conventional harvesting methods such as centrifugation and filtration are very time and labor intensive processes. Gravimetrical settlement with the aid of cationic flocculants is the most widely employed technique, but suffers from the difficulty in recovering microalgae floes. Furthermore, recycling of these flocculants after the harvesting process is not possible. Polymer-coated magnetite particles have been investigated for applications in various fields. This research has focused on the development of a novel and efficient …

Parameterization Of Microwave Assisted Oil Extraction And Its Transesterification To Biodiesel, Akanksha V. Kanitkar

LSU Master's Theses

Currently, a majority of the world’s energy needs are met through use of fossil fuels, petroleum, coal and natural gas. The depletion of petroleum reserves, rising and extremely volatile crude oil prices, and environmental concerns have led to search for renewable and environmentally friendly fuels. The ultimate goal of this research was to develop, test and optimize a batch microwave system using traditional and alternate non-food feedstocks. Microwave assisted extraction (MAE) of oil from conventional feedstocks (soybeans and rice bran) and an alternative feedstock (Chinese tallow tree (CTT) seeds) was carried out. The study concluded that MAE of oil is …

Quantification Of Energy Intake Using Food Image Analysis, Sertan Kaya

LSU Master's Theses

Obtaining real-time and accurate estimates of energy intake while people reside in their natural environment is technically and methodologically challenging. The goal of this project is to estimate energy intake accurately in real-time and free-living conditions. In this study, we propose a computer vision based system to estimate energy intake based on food pictures taken and emailed by subjects participating in the experiment. The system introduces a reference card inclusion procedure, which is used for geometric and photometric corrections. Image classification and segmentation methods are also incorporated into the system to have fully-automated decision making.

Investigating The Use Of Bioengineered Oyster Reefs As A Method Of Shoreline Protection And Carbon Storage, Daniel D. Dehon

LSU Master's Theses

The Louisiana Gulf Coast is losing land at an alarming rate for a combination of reasons. At the same time carbon dioxide is accumulating in the atmosphere and the oceans by the increased burning of fossil fuels. Therefore, bioengineered oyster dominated artificial reefs have been developed in an effort to mitigate erosion while storing carbon in the oyster shells. These reefs support the growth of a native oyster species, Crassostrea virginica, which are considered ecological engineers and serve to improve water quality, protect coastal wetlands, capture and store carbon, and enhance the economy. Evaluation of test pieces showed the addition …

Antioxidant Nanoparticles As Delivery Systems, Carlos Ernesto Astete R.

LSU Doctoral Dissertations

The goal of the study was to develop antioxidant polymeric nanoparticles as a new delivery system for food and pharmaceutical applications. Natural antioxidants like alpha-tocopherol, vitamin C, and carnosine, are responsible to protect biological systems against free radicals attack. The conjugation of vitamin C-vitamin E (EC) and alpha-tocopherol-carnosine (VECAR) were performed to obtain antioxidant surfactants which were used for polymeric nanoparticle synthesis. The surfactant made of á-tocopherol (vitamin E) and ascorbic acid (vitamin C) of antioxidant properties dubbed as EC was used to make poly(lactic-co-glycolic) acid (PLGA) nanoparticles. Self-assembled EC nanostructures and PLGA-EC nanoparticles were made by nanoprecipitation, and the …

Designing A Whey Protein Based Material As A Scaffold For Bone Regeneration, Mia Dvora

LSU Doctoral Dissertations

A novel gel material was designed and optimized for use as a bone tissue regeneration scaffold. Whey protein isolate (WPI), the primary component of the material, underwent considerable testing for conformity to a set of known material characteristics required for application in bone regeneration. WPI gels of different compositions were fabricated by thermally inducing gelation of high-concentration protein suspensions, and characterized for compressive strength and modulus, hydration swelling and drying properties, mechanical behavior change due to polysaccharide additives, and intrinsic pore network structure. The gels were also tested for their compatibility with MC3T3-E1 cells, and interactions such as cell adhesion, …

Arsenite Oxidation By Pure Cultures Of Thiomonas Arsenivorans Strain B6 In Bioreactor Systems, Aniruddha Dastidar

University of Kentucky Doctoral Dissertations

The removal of arsenic toxicity from water is accomplished by a preliminary preoxidative step transforming the most toxic form, arsenite (As (III)), to the least toxic form, arsenate (As (V)). The potential of As (III) oxidation to As (V) was initially investigated in batch reactors using the chemoautotrophic Thiomonas arsenivorans strain b6 under varying initial As (III) and cell concentrations and at optimal pH and temperature conditions (pH 6.0 and temperature 30°C). The strain b6 completely oxidized As (III) to As (V) during exponential growth phase for lower levels of As (III) concentrations (≤ 100 mg/L) but continued into stationary …

Value-Added Processing Of Rice And Rice By-Products, Rebecca C. Schramm

LSU Doctoral Dissertations

World competition has encouraged United States rice farmers and rice mills to be efficient in farming and production practices. Efforts to augment economic competitiveness include development of new varieties, improvements in milling practices, and identification of uses for rice products and by-products. The research detailed in this dissertation adds to the body of knowledge in milling practices and identification of uses for rice bran. To improve the prediction of milled rice quality at industrial scale, correlations for milling quality among laboratory, pilot, and industrial scale mills were identified for Clearfield 161. Final industrial product whiteness was ten points higher than …

Optimization Of Parameters And Study Of Kinetics In Lactulose Production By Lactose Isomerization Using Strong Basic Anion Exchange Resin, Arvind Nanduri

Masters Theses

"In this work, an experimental design was employed to investigate the effects of different operating conditions on the isomerization of lactose to lactulose by using strong basic anion exchange resin (AMBERLITE-IRA 402). Temperature, resin/lactose mass ratio and pH were considered to be the three factors affecting the conversion of lactose. Box-Behnken design was then used to optimize the operating conditions for maximum response and also to study the various interaction and main effects of the factors. The analysis of variance (ANOVA) of the experimental data showed a high correlation coefficient R² (0.99) and a low root mean square error (2.84) …

A New Green Chemistry Method Based On Plant Extracts To Synthesize Gold Nanoparticles, Milka Odemariz Montes Castillo

Open Access Theses & Dissertations

Extraordinary chemical and physical properties exhibited by nanomaterials, as compared to their bulk counterparts, have made the area of nanotechnology a growing realm in the past three decades. It is the nanoscale size (from 1 to 100 nm) and the morphologies of nanomaterials that provide several properties and applications not possible for the same material in the bulk. Magnetic and optical properties, as well as surface reactivity are highly dependent on the size and morphology of the nanomaterial. Diverse nanomaterials are being widely used in molecular diagnostics as well as in medicine, electronic and optical devices. Among the most studied …

Composition-Structure-Property Relationships In Multicomponent Bioactive Glasses, Sharon Murphy

Theses

Silicate glasses function effectively as bone grafts by stimulating bone regeneration through gene activation. However these materials offer little therapeutic potential for the regeneration of healthy bone in those suffering from metabolic bone diseases such as osteoporosis. Examining the composition-structure-property relationships arising from the incorporation of therapeutic ions such as strontium (Sr) and zinc (Zn) into such glasses in order to allow for healthy bone regeneration and antibacterial efficacy, as well as sodium (Na) to allow for controlled ion release was the objective of this work. Eight calcium-strontium-sodium-zinc-silicate glass compositions were produced, based on incremental additions of Sr and Na. …

Patterns Of Dipeptide Usage For Gene Prediction, Dayananda Sagar Gangadharaiah

Browse all Theses and Dissertations

As the number of complete genomes that have been sequenced continues to grow rapidly, the identification of genes regions in DNA sequence data remains one of the most important open problems in bio-informatics. Improving the accuracy of such gene finding tools by a small percentage would affect accurate predictions of many genes of an organism (Zhu et al., 2010). This thesis presents a novel approach for identifying coding regions of a genome based on dipeptide usage.

The patterns in dipeptide usage are used to discriminate between coding and non-coding DNA regions. Two sample T-tests are used as tests of significance …

Computer-Based Skeletal Age Assessment Using Hand/Wrist Radiographs In Children 8-18 Years Old, Zhihong Ni

Browse all Theses and Dissertations

Children's skeletons mature at different rates, and they can be affected by a variety of factors including disease, hormone imbalance or genetics. The assessment of skeletal maturity is a frequently performed procedure that allows the detection of hormonal, growth or genetic disorders. Several methods have been developed to estimate skeletal maturity. Most methods evaluate hand/wrist radiographs using indicators such as the ratios of various bone widths, the onset of the ossification of epiphysis and epiphyseal-diaphyseal fusion. Among those methods, the FELS method differs from others in the application of different grades to each indicator and the provision of a confidence …