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Deposition Of Titanium By Gaseous Reaction, Louis John Reitsma Jr.

Masters Theses

"Previous investigations undertaken at the Missouri School of Mines and Metallurgy on the deposition of titanium involved the use of fused salt baths, aqueous solutions, and cementation processes. The fused salt baths produced satisfactory coatings on small metal parts. Some difficulty was encountered however, when the coating of large articles was attempted.

For this reason, it was decided to investigate the possibility of titanium deposition by the reaction of a volatile titanium compound with a metal surface. Two different compounds were proposed for investigation, (1) a lower chloride of titanium and (2) an iodide of titanium. The reaction with the …

Technical Report Writing, Civilian Personnel Division, Office Of The Chief Of Engineers, Department Of The Army, Robert Bolin , Depositor

United States Army Corps of Engineers, Omaha District

This is a brief manual intended primarily to instruct junior engineering personnel working on civil works for the Corps of Engineers in the proper procedures for preparing reports. Some of the contents were papers delivered at a conference on the use of English in Corps of Engineers reports.

The manual is complicated by the Corps of Engineer’s roles as a military organization and as an organization managing civil public works projects and public facilities and by the special problem of having to answer inquiries of members of Congress.

Shortly before this guide was issued, the Engineer School had issued a …

A Study Of Titanium Diffusion Coatings By X-Ray Fluorescent Methods, Alan Bernard Burgess

Masters Theses

"As the only previous determinations of the chemical composition of the titanium coatings had been analyses of the average composition of the entire coating, the determination of the variation in chemical composition throughout the coating was suggested. From this information, it was proposed that a better insight might be gained as to the extent and mechanism of diffusion in the coatings. It was also hoped to correlate the results with concurrent work being done on the phases present in the titanium coatings. From this correlation, it might be possible to show which phases are responsible for the desirable properties of …

A Study Of Tunnel Demolition By Hasty Methods, Richard Lee Bullock

Masters Theses

"The use of explosives to construct obstacles which impede the enemy or close his routes of communication has long been employed by our armies. They have developed fairly effective methods for destroying bridges, setting up road craters and constructing abatis. However, one phase of obstacle construction, that of tunnel demolition, has been neglected in that no procedures or methods have been formulated which will aid in the proper destruction of tunnels.

At the present time, under the auspices of the Department of the Army, The Missouri School of Mines and Metallurgy is conducting a research program on tunnel demolition. The …

The Preparation Of Titanium Tetrachloride From Rutile, Nalin Sen

Masters Theses

"In recent years, considerable interest has been shown in the manufacture of titanium metal because of its outstanding properties both physical and chemical. The commercial process for the preparation of metallic titanium, known as the Kroll process, consists essentially of the reduction of titanium tetrachloride with magnesium in an inert atmosphere to produce titanium metal with magnesium chloride as a by-product.

Since, titanium tetrachloride is the basic compound from which to prepare metallic titanium by the Kroll process, much thought has been given to the preparation of titanium tetrachloride from titanium ores such as rutile or ilmenite.

The present work …

Further Studies Of Vapor-Liquid Equilibria Of Methanol-Ethylene Glycol-Water, Herbert Benjamin Sachs

Masters Theses

"The freezing points of the ternary system methanol-glycol-water have been investigated by Conrad, Hill and Ballman. The vapor-liquid equilibria of the same system was studied by Sjoberg. These investigations were carried out to determine the properties of the system relative to its possible use as an antifreeze mixture.

Since Sjoberg's work in 1948, the improved Othmer equilibrium still has been introduced for vapor-liquid experimental determinations. It is therefore the purpose of the present investigation to evaluate the use of this still, compare results with those obtained by Sjoberg, and analyze ternary mixtures for the entire range of glycol concentrations.

The …

Preparation And Separation Of Metallic Chlorides, Norbert Felix Neumann

Doctoral Dissertations

"The use of chlorine and chlorine compounds as metallurgical reagents has long been known to the metallurgical industry. Recent developments in corrosion resistant metals and alloys as well as new equipment and techniques have led to a revival of chlorine processes. Many of the objections to the use of chlorine in metallurgical operations have been overcome and many are being reconsidered, as evidenced by the new processes in which chlorine and chlorides are the primary reagents. The Betterton process employs chlorine or lead chloride for the dezincing of lead. Ductile zirconium and titanium have been made by reducing their chlorides …

Nanbo₃ - Batio₃ - Basno₃ Ceramic Dielectrics, William Dean Mckee

Doctoral Dissertations

"A. The Problem.

The purpose of this investigation was to form by ceramic processes a number of compositions in the ternary system NaNbO₃ - BaSnO₃ - BaTiO₃, to determine certain dielectric properties of these, to study them by means or x-ray diffraction, and to determine the extent or correlation possible between the compositional variation of dielectric properties and the x-ray results.

Compositions investigated contained 50 mole percent or less BaSnO₃. Materials and methods of forming were chosen with the intent that the final bodies should be pure oxide compositions as represented in the ternary …

A Study Of The Structure Of Titanium Diffusion Coatings On Iron And Steel, Pao-Jen Chao

Masters Theses

"The Problem of the Thesis: A series of experiments have been made in the Metallurgical. Engineering Department of the Missouri School of Mines and Metallurgy for the investigation of titanium diffusion coatings. The technique of applying the titanium diffusion coatings on iron and steel is still in the experimental stage. A few of the physical properties and chemical compositions of such coatings have been determined, but the structures have not yet been extensively studied. As the correlations of the structures and the desirable properties are valuable for improving the quality or titanium diffusion coatings on iron and steel, an investigation …

The Properties Of Cold Rolled - Stress Relief Annealed 70-30 Cartridge Brass, Robert F. Hartmann

Professional Degree Theses

"Because of the possible commercial application of the proposed treatment of 70-30 brass, this work was undertaken. In addition, the data resulting from this work will result in a better understanding of the treatment of brass.

The objectives of this work were as follows:

1. Determine if higher strength and better spring properties can be realized from a process for commercial 70-30 cartridge brass wherein the regular recrystallizing anneals between rolling reductions are replaced by stress relief anneals.
2. Determine if it is possible, using the above process, to produce essentially fully recrystallized metal with an average grain size below that usually …

Design Of A Subsonic Wind Tunnel Electrical System, William A. Wundrack

Professional Degree Theses

"The purpose of this thesis is to present information and data used in the planning and construction of an electrical distribution system and main drive system for a wind tunnel designed for Chance Vought Aircraft Company of Dallas, Texas, by Sverdrup & Parcel, Incorporated, Consulting Engineers of St. Louis. Preliminary negotiations were started with Chance Vought Aircraft Company in March 1953, and the wind tunnel calibrations were started in October 1954. Between those dates all design, installation drawings, and construction were completed.

The data used in preparing this thesis were taken from daily records, records of conferences, personal records, correspondence …

Aspects Of Quality Control In Foreign Manufacturing Operations, Erich Rolaff

Professional Degree Theses

"The present thesis is being written to illustrate some aspects of quality control in foreign manufacturing operations; that is, foreign to the United States. It is obvious that the conditions and probable variations from U. S. practice in any manufacturing industry will vary tremendously according to the industry under review. In the present case we shall be dealing with manufacturing operations involving the production of so-called "dry cells" and "dry batteries", and to a somewhat lesser degree with the production of projector arc carbons for use in motion picture theater projection. It will be, therefore, helpful if a brief history …

An Analysis Of A Shunt-Peaked Video Amplifier And Feedback Pair Having The Same Edge Response, Bernard J. Regenauer

Electrical and Computer Engineering ETDs

Statement of the problem. It is the purpose of this study (1) to investigate the feasibility of employing a feedback pair instead of a shunt-peaked video amplifier in a typical circuit application; (2) to determine the steady-state gain ratio between a feedback pair and a single shunt-peaked video amplifier having the same edge response (rise time and overshoot) and to analyze the effect of varying either the rise time or overshoot of both circuits upon this ratio; (3) to make a limited study of the steady state gain ratio of a feedback pair and a cascade of two shunt-peaked video …

Flexural Properties Of Corrugated Metal Roofing, Howard L. Wakeland

CCFSS Library (1939 - present)

Introduction Roofing materials that combine shelter, fire safety, durability, and strength have largely replaced such historic types of roofing covering as straw, leaves, tile, bark and various wooden coverings. Thus, we have such modern roof coverings as asphalt composition, cement-asbestos, and metal. Of these, metal roofing is used more than any other on farm service buildings. Approximately 40 per cent of present day farm service buildings in the United States are roofed with metal. This proportion continues to increase as more and more metal roofing materials are made available for rural construction. The wide use of metal roofing is due …

The Preparation Of 2-Aminophenol-4-Sulfonic Acid From Sulfanilic Acid, Edward Jacob Mach

Theses

Sulfanilic acid (I) was examined for purity and character. Sodium and potassium salts were acetylated and their isolation and yields were investigated.

The salts were nitrated with mixed acids and the reaction mixtures were treated in various ways to ascertain a good method for isolating the desired 2-nitro-sulfanilic acid (II). An attempt was made to characterize the reaction products, and to devise quantitative methods to estimate the yield of 2-nitrosulfanilic acid. A previously unreported by-product of the nitration, 2,4,6-tri-nitroaniline (He), was isolated. Several new salts of 2-nitrosulfanilic acid were prepared, and a possible new derivative was observed from the reaction …

A Mathematical And Experimental Investigation Of The Application Of Air Spring To Shock Testing Machines, Eric E. Ungar

Mechanical Engineering ETDs

The applications of many modern devices require them to be able to perform their functions satisfactorily after having been subjected to transient accelerations of considerable magnitude. Some Devices are required to operate even during the period of acceleration.

Since failure of components or sub-assemblies during the actual operation of the entire assembly would in general be extremely undesirable and costly (for example, failure of instrumentation in a high-speed aircraft or guided missile might lead to loss of the entire vehicle), it is necessary to test the components and sub-assemblies in order to determine whether they may be exposed to accelerations …

Prestressed Concrete Design For The Alameda Bridge, Louis Gonzaga Archuleta

Civil Engineering ETDs

No abstract provided.

An Experimental And Theoretical Investigation Of The Characteristics Of A Magnetic Amplifier, Merle H. Wittmeyer

Electrical and Computer Engineering ETDs

Many excellent analyses of magnetic amplifiers have been published. As in every investigation, however, there are many details not explained. The purpose of this investigation was to explain some of the details of magnetic amplifier characteristics.

The Transient Response Of A Distributed Amplifier, Thomas D. Lusk

Electrical and Computer Engineering ETDs

The purpose of this paper is to describe the transient behavior of a simple constant-K distributed amplifier stage. The derivation of the transfer function is carried out using the Laplace Transform for the case where losses in the lines are considered to be zero. The various characteristics of the amplifier response to a unit step function are discussed and the effects of losses and other modifying factors upon the idealized response are evaluated. Finally design procedures are derived which allow the circuit designer to determine the circuit parameters necessary for good transient responses. These procedures are applied to the design …

Servo-Stabilization Of Drift In Wide-Band D-C Amplifiers., Joel M. Simmons Jr.

Electrical and Computer Engineering ETDs

It was the purpose of this study to determine the suitability of a comparator and negative feedback circuit (servo-type) as a general utility method of reducing the end effect (zero-drift) of changing static characteristics of the vacuum tubes and other associated components in wide-band direct-coupled amplifiers. A brief description of the drift servo-stabilization system and its drift reducing characteristics are as follows.

Solution Of Some Chemical Plant Problems Associated With The Manufacture Of Insecticides, Lawrence Ralph Hinken

Professional Degree Theses

"This thesis describes the solutions of a variety of developmental, production, and general engineering problems encountered in a chemical plant. This plant produces resins, solvents, and insecticides. Most of the problems considered here are patented or are of a secret nature. These details are, in the main, satisfactory temperatures, molar ratios, times of reaction, and space-time data. Therefore, it is the purpose of this discussion to be general but, in the main, to give the outline of the thinking which derived these solutions. Some of these solutions were of minor economic value, some were vital to the success of the …

Guide To The Preparation Of Military Reports Of A Technical Nature, The Engineer School, Fort Belvoir, Virginia, Robert L. Bolin Depositor

United States Army: Publications

This is a brief text prepared for instructional purposes at the US Army Engineer School at Fort Belvoir, VA.

The manuscript covering the preparation of a technical report has been prepared for two reasons: first, to serve as a basic text for instructing student officers in the techniques of report writing and second, to serve as a means of reference. Student officers cannot be expected to retain in their minds all the minute details of report writing to which they are exposed during their period of school training. Considerable time may elapse after graduation and before they are called on …

The Closure Of Thin Wall Pressure Vessels, Archie W. Culp Jr.

Masters Theses

"The object of this thesis is to find various methods of closing thin wall aluminum cylinders. Such a closure must be strong enough, that when internal pressure is applied, ultimate failure will occur along a longitudinal element of the cylinder and not at the closure. Moreover, such a method must not only be mechanically sound, but it must be readily adaptable to mass production"--Introduction.

A Fundamental Study Of Clay Drying Using Ware Of Large Cross Section, Robert F. Grady Iii

Masters Theses

"The drying of clay has been studied extensively in the past by many investigators, some of whom attempted to relate this information to the structure of clay and thereby develop a more vivid picture, while others studied the mechanism of drying in its own right in order to present a useable theory that would allow improvements in the drying operation.

At present the literature is unable to present a theory of the mechanism of drying that is sufficiently general to cover the observed aspects of clay drying. Many and varied mechanisms are presented, but correlation is seldom completely evident between …

Horizontal Pressures On Retaining Walls Due To Line Surface Loads, John B. Heagler

Masters Theses

"Among the oldest types of structures with which engineers have had to deal are those which serve to laterally restrain masses of earth, or to prevent earth embankments from assuming their natural angle of repose. This is necessary where space is limited or the natural slope would encroach upon other property. These structures, usually called retaining walls, are subjected to forces, both lateral and vertical due to the pressures exerted by the backfill material and any loads imposed on the backfill material. The first step in the design of the retaining wall is to determine the magnitude, position, and line …

Deposition Of Metallic Coatings From Fused Salt Baths, Andrew Hessler Larson

Masters Theses

"This thesis is the result of an investigation undertaken to study some of the important factors affecting the deposition of metallic diffusion coatings on other metals immersed in a fused salt bath….

There are many methods which have been devised to obtain diffusion coatings on various metals. One which is quite well known and used commercially is the process of “chromizing” which produces a diffusion layer if chromium on another metal. One method of “chromizing” consists of immersing the specimen to be coated in a mixed chloride fused bath containing chromium metal flakes. Another method consists of packing a low …

Corrosion Products Of Titanium In Fused Salt Baths, Kai-Chai Chiou

Masters Theses

"Titanium is gaining great interest in the modern metal industry because of its natural abundance and its desirable physical and chemical properties. Among them, its excellent corrosion resistance, such as the resistance to normal atmosphere attack, humid and saline atmosphere attack, sea water attack, and nitric acid attack, is the most prominent characteristic being welcomed by the engineers. The usefulness of titanium would be greatly increased if it were possible to plate titanium on other metals, thus increasing the corrosion resistance of these other metals.

Much concern, at present, has been given to the possibilities of the electrodeposition of titanium …

Heat Flow In A Two-Dimensional Steady-Flow System Without Radial Symmetry, George H. Parharoglu

Masters Theses

"As the extent of the science of heat conduction depends on the multiplicity of the boundary conditions that can be applied to the basic differential equation, a particular case in which the use of one set boundary conditions for the development of the general equation for the temperature distribution as well as the the amount of heat flow in a steady-state, two-dimensional heat flow system with a source of heat plased at the center of or along the axis of a cylinder, and without radial symmetry has been the object of this problem. Radial symmetry means the variation of temperature …

Tunnel Rehabilitation, Jay C. Dotson

Masters Theses

"This paper is an outgrowth of research conducted at Missouri School of Mines and Metallurgy over a two year period. The purpose of the study is to assemble into one volume information that is pertinent to the rehabilitation of tunnels. Notwithstanding the voluminous size of the paper, much descriptive material necessarily has been omitted because of the far-reaching scope of tunneling practices and of the specialized fields therein. An extensive bibliography has been prepared to supplement the material that has been selected for presentation. Through consultation with tunnel men of all ranks, observations in the field, and an intensive search …

Effect Of Carbon Content In Steels Upon The Deposition Of Titanium From A Fused Salt Bath, Reinhard Paul Abendroth

Masters Theses

"STATEMENT OF PROBLEM Previous work done at the Missouri School of Mines and Metallurgy on the deposition of titanium upon various metals, especially iron and steel, bas shown that titanium can be deposited upon ingot iron and. low carbon steels with comparitive ease. Difficulty was encountered in attempts to deposit titanium upon steels of higher carbon content and upon cast irons.

For this reason, it was decided to investigate more thoroughly the relationship between the carbon content of various steels and the quality of titanium coatings deposited on these steels. Once this relationship had been established, a suitable theoretical explanation …